CN101563162B - 铂-锗沸石催化剂的再生 - Google Patents

铂-锗沸石催化剂的再生 Download PDF

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Publication number
CN101563162B
CN101563162B CN2007800471046A CN200780047104A CN101563162B CN 101563162 B CN101563162 B CN 101563162B CN 2007800471046 A CN2007800471046 A CN 2007800471046A CN 200780047104 A CN200780047104 A CN 200780047104A CN 101563162 B CN101563162 B CN 101563162B
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catalyst
psia
chlorine
zeolite
temperature
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Chinese (zh)
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CN101563162A (zh
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P·E·艾里斯
G·G·贾图
A·K·卡马梅多瓦
S·F·米切尔
S·A·施蒂文森
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Saudi Basic Industries Corp
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/90—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/06—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12—Treating with free oxygen-containing gas
    • B01J38/18—Treating with free oxygen-containing gas with subsequent reactive gas treating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/42—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using halogen-containing material
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/74—Noble metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/904—Catalyst rehabilitation by reversion from different compound

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2007800471046A 2006-12-20 2007-12-19 铂-锗沸石催化剂的再生 Expired - Fee Related CN101563162B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/642,421 2006-12-20
US11/642,421 US7745675B2 (en) 2006-12-20 2006-12-20 Regeneration of platinum-germanium zeolite catalyst
PCT/US2007/025875 WO2008082534A2 (en) 2006-12-20 2007-12-19 Regeneration of platinum-germanium zeolite catalyst

Publications (2)

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CN101563162A CN101563162A (zh) 2009-10-21
CN101563162B true CN101563162B (zh) 2011-10-12

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US (1) US7745675B2 (https=)
EP (1) EP2109502A4 (https=)
JP (1) JP5443167B2 (https=)
CN (1) CN101563162B (https=)
MY (1) MY147731A (https=)
WO (1) WO2008082534A2 (https=)
ZA (1) ZA200905021B (https=)

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US7906696B2 (en) * 2007-01-22 2011-03-15 Saudi Basic Industries Corporation Process of using zeolite catalyst for hydrocarbon conversion
US8993468B2 (en) 2007-05-24 2015-03-31 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—Ge zeolites
US8969232B2 (en) * 2007-05-24 2015-03-03 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation 2
US9221723B2 (en) * 2007-05-24 2015-12-29 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation-1
WO2008153759A2 (en) 2007-05-24 2008-12-18 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof-bimetallic deposition
WO2009067331A2 (en) * 2007-11-16 2009-05-28 Exxonmobil Chemical Patents Inc. Catalyst regeneration process
US8664144B2 (en) 2008-12-23 2014-03-04 Chevron Phillips Chemical Company Lp Methods of reactivating an aromatization catalyst
JP5423028B2 (ja) * 2009-02-12 2014-02-19 株式会社明電舎 芳香族炭化水素製造方法
EA022683B1 (ru) * 2009-11-02 2016-02-29 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ превращения низших алканов в ароматические углеводороды
CN102596864B (zh) * 2009-11-02 2015-11-25 国际壳牌研究有限公司 丙烷和丁烷转化为芳香烃的方法
US20120277089A1 (en) * 2009-11-06 2012-11-01 Mahesh Venkataraman Iyer Process for the regeneration of hydrocarbon conversion catalysts
SG185516A1 (en) * 2010-05-12 2012-12-28 Shell Int Research Process for the conversion of lower alkanes to aromatic hydrocarbons
CN102294274A (zh) * 2010-06-22 2011-12-28 南通扬子催化剂有限公司 一种用于贵金属催化剂氯化、还原连续生产的工艺
US8912108B2 (en) 2012-03-05 2014-12-16 Chevron Phillips Chemical Company Lp Methods of regenerating aromatization catalysts
US8716161B2 (en) 2012-03-05 2014-05-06 Chevron Phillips Chemical Company Methods of regenerating aromatization catalysts
US8772192B2 (en) * 2012-06-29 2014-07-08 Saudi Basic Industries Corporation Germanium silicalite catalyst and method of preparation and use
US9387467B2 (en) 2012-09-26 2016-07-12 Chevron Phillips Chemical Company Lp Aromatization catalysts with high surface area and pore volume
US9782758B2 (en) * 2013-04-23 2017-10-10 Saudi Basic Industries Corporation Method of preparing hydrocarbon aromatization catalyst, the catalyst, and the use of the catalyst
US10207255B2 (en) 2013-11-22 2019-02-19 Saudi Basic Industries Corporation Catalyst with improved activity/selectivity for light naphtha aromatization
EP3096880A4 (en) 2014-01-21 2017-08-30 KiOR, LLC Process of reactivating a metal contaminated biomass conversion catalyst
CN110225796A (zh) 2016-12-20 2019-09-10 环球油品有限责任公司 用于管理轻质石蜡脱氢方法中催化剂上的硫的方法
CA3047726C (en) 2016-12-20 2024-02-13 Uop Llc Process for managing sulfur on catalyst in a light paraffin dehydrogenation process
US10821427B2 (en) * 2017-05-03 2020-11-03 Exxonmobil Chemical Patents Inc. Processes for regenerating catalysts
WO2018204000A1 (en) * 2017-05-03 2018-11-08 Exxonmobil Chemical Patents Inc. Processes for regenerating catalysts
US10799858B2 (en) 2018-03-09 2020-10-13 Uop Llc Process for managing sulfur compounds on catalyst
CN112316987A (zh) * 2019-08-05 2021-02-05 中国石油化工股份有限公司 一种积碳低碳烷烃脱氢催化剂的脱硫方法

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US5157201A (en) * 1990-06-22 1992-10-20 Exxon Chemical Patents Inc. Process for adsorbing sulfur species from propylene/propane using regenerable adsorbent
CN1224408A (zh) * 1996-05-29 1999-07-28 埃克森化学专利公司 甲苯甲基化制备对二甲苯

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Publication number Publication date
JP2010513507A (ja) 2010-04-30
ZA200905021B (en) 2010-04-28
EP2109502A4 (en) 2013-10-09
WO2008082534A3 (en) 2008-09-12
US7745675B2 (en) 2010-06-29
CN101563162A (zh) 2009-10-21
US20080154079A1 (en) 2008-06-26
EP2109502A2 (en) 2009-10-21
WO2008082534A2 (en) 2008-07-10
MY147731A (en) 2013-01-15
JP5443167B2 (ja) 2014-03-19

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