CN101560418B - Method for producing fossil fuel oil and water mixing fuel additive - Google Patents
Method for producing fossil fuel oil and water mixing fuel additive Download PDFInfo
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- CN101560418B CN101560418B CN2008101280339A CN200810128033A CN101560418B CN 101560418 B CN101560418 B CN 101560418B CN 2008101280339 A CN2008101280339 A CN 2008101280339A CN 200810128033 A CN200810128033 A CN 200810128033A CN 101560418 B CN101560418 B CN 101560418B
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
Abstract
The invention provides a method for producing fossil fuel oil and water mixing fuel additive with eternally unseparated fossil fuel oil water fossil fuel oil and water and a method for producing fossil fuel oil and water fuel, the fossil fuel oil and water mixing fuel additive has lowering ignition point burning point and rising flame temperature of the fossil fuel oil after adding water, and no increase of carbon dioxide in the atmospheric air. the method for producing fossil fuel oil and water mixing fuel additive includes the following process: the process of producing methoxyl sulfate; theprocess of producing regenerative ester; the process of producing mono-ethylidene methanol; the process of producing cyclic amine ethanol; the process of mixing the manufactured. regenerative ester a nd oleic acid or plant fatty acid with stirring, and the mixing the manufactured. mono-ethylidene methanol and cyclic amine ethanol andammine or ethandiol with stirring in order. the method for producing fossil fuel oil and water fuel includes that 5 to 25% of the fossil fuel oil and water mixing fuel additive produced by the above method and 50 to 70 %fossil fuel oil are mixed and stirred, and 10to 35% of water is mixed with stirring for several times, and the fossil fuel oil and water fuel is obtained.
Description
Technical field
the present invention relates to heavy oil, light oil, add additive in the fossil oil oil such as kerosene, and mixing water and the fossil oil oil that obtains adds the technology of water fuel wherein, particularly relate to the manufacture method of fossil oil oil-water fuel blend additive and the manufacture method that fossil oil oil adds water fuel, the fuel blend additive of described fossil oil oil and water makes fossil oil oil not form emulsion (emulsification) state with water, prolonged preservation is not separated yet, contain the waste edible oil that does not increase carbonic acid gas in atmosphere by the plant life cycle in the raw material that uses, vegetables oil, animal wet goods of animal or plant nature oil.The manufacture method that described fossil oil oil adds water fuel is to use the fuel blend additive of this fossil oil oil and water to add water fuel as additive manufacturing fossil oil oil when mixing fossil oil fuel and water.
Background technology
For the high fuel price that reduces fossil oil oil or the gas of discharging when reducing its burning, developing a kind of fossil oil oil that has mixed water in fossil oil oil and adding water fuel.It is mixing water in fossil oil oil that fossil oil oil adds water fuel, and adds additive and obtain in order to effectively mix.
Patent documentation 1: JP 2006-2058
Summary of the invention
But existing fossil oil oil adds water fuel when mixing fossil oil fuel and water and additive, forms emulsion (emulsification) state, exist fossil oil oil and moisture from problem, be difficult to prolonged preservation.Due to the impact of sneaking into of water, the burning-point that also exists fossil oil oil to add water fuel improves but degradation problem at burning flame temperature.
in view of above-mentioned problem has proposed the present invention, the problem that exists with solution, during being to supply raw materials, its purpose contains the manufacture method of fuel blend additive of the fossil oil oil of of animal or plant nature oil and water and the manufacture method that fossil oil oil adds water fuel, described fossil oil oil makes fossil oil oil not separate with water is prolonged with the fuel blend additive of water, and burning flame temperature rises when fossil oil oil adds the burning-point decline of water fuel, can not increase the carbonic acid gas in atmosphere, the manufacture method that described fossil oil oil adds water fuel is to use the fuel blend additive of this fossil oil oil and water to add water fuel as additive manufacturing fossil oil oil when mixing fossil oil fuel and water.
In order to reach above purpose, the 1st invention of the present invention relates to the manufacture method of the fuel blend additive of a kind of fossil oil oil and water, the method comprises following operation, namely, the operation of mix and blend sulfuric acid and methyl alcohol manufacturing " sulfuric acid methoxyl group " (referring to that the monomer of sulfuric acid and the monomer of methyl alcohol are with admixture and deposit, and do not form reactant); " the sulfuric acid methoxyl group " that the above-mentioned operation of mix and blend is made and of animal or plant nature oil are made the operation of regeneration ester; The operation of mix and blend methyl alcohol and ethylene glycol manufacturing " single ethylidene methyl alcohol " (referring to that ethylene glycol monomer and methyl alcohol monomer are with admixture and deposit, and do not form reactant); The operation of mix and blend monoethanolamine and hexahydroaniline manufacturing " cyclammonium ethanol " (referring to that monoethanolamine monomer and hexahydroaniline monomer are with admixture and deposit, and do not form reactant); And the above-mentioned operation of mix and blend regeneration ester and oleic acid or the vegetable fatty acid made, stir successively in the gained material and sneak into single ethylidene methyl alcohol that above-mentioned operation makes and the operation of cyclammonium ethanol and ammonia or ethylene glycol.
Wherein, of animal or plant nature oil comprises waste edible oil, vegetables oil, animal oil.
The 3rd invention relates to the manufacture method that a kind of fossil oil oil adds water fuel, the method is fossil oil oil and the fuel blend additive of water and 50%～70% the fossil oil oil mix and blend that will make in 5%～25% the 1st invention, again 10%～35% moisture is blended into wherein for several times and stirs, make fossil oil oil and add water fuel.
Wherein, fossil oil oil comprises heavy oil, light oil, kerosene.
By above record as can be known: according to the present invention, by adding fossil oil oil-water fuel blend additive, water is blended in the fossil oil oil that fossil oil oil adds water fuel equably, and then as fuel, the gas of discharging in the time of can reducing thus burning is simultaneously because sneaking into of water can be reduced fuel cost.And, even fossil oil oil and water mixing can not formed emulsion (emulsification) state yet, therefore, can prevent that fossil oil oil from adding the fossil oil oil of water fuel prolonged with water and separate, can prevent because of fossil oil oil and moisture from the variety of issue that produces.And, can reduce the burning-point that fossil oil oil adds water fuel, can also improve burning flame temperature simultaneously, can widen the range of application that fossil oil oil adds water fuel.In addition, by use waste edible oil, vegetables oil, animal wet goods of animal or plant nature oil in the raw material of fossil oil oil-water fuel blend additive, can also greatly suppress to be added by the fossil oil oil of sneaking into burning the increase of carbonic acid gas in the atmosphere of fuel blend additive generation of fossil oil oil in water fuel and water.
Description of drawings
The simplified side view of the device that manufacturing process's first half section of the fossil oil oil of [Fig. 1] expression specific embodiment of the invention and the fuel blend additive of water is used.
Manufacturing process's second half section of the fossil oil oil of [Fig. 2] expression specific embodiment of the invention and the fuel blend additive of water and the simplified side view that fossil oil oil adds the device that uses in the manufacturing process of water fuel.
Nomenclature
1 filtration unit
2 reactors that dewater
3 stirred pots
4 regeneration ester reducing apparatus
5 separating layers
6 hold-up vessels
The 6a supply-pipe
7 hold-up vessels
The 7a supply-pipe
8 stirred pots
The 8a supply-pipe
9 stirred pots
The 9a supply-pipe
10 hold-up vessels
The 10a supply-pipe
11 stirred pots
The 11a supply-pipe
12 hold-up vessels
The 12a supply-pipe
13 hold-up vessels
The 13a supply-pipe
14 hold-up vessels
The 14a supply-pipe
15 stirred pots
Embodiment
Below, the specific embodiment of the present invention of middle record, be described more specifically the present invention with reference to the accompanying drawings.
Wherein, Fig. 1 means the simplified side view of manufacturing process's first half section equipment therefor of the fuel blend additive of the fossil oil oil of technical solution of the present invention and water, and Fig. 2 means the simplified side view of equipment therefor in manufacturing process's second half section of fuel blend additive of the oily and water of fossil oil and manufacturing process that fossil oil oil adds water fuel.
In figure, filtration unit 1 is used for removing the impurity of waste edible oil, vegetables oil, animal wet goods of animal or plant nature oil.For example comprise fish oil in animal oil.Waste edible oil, vegetables oil, the animal wet goods of animal or plant nature oil of having removed impurity with filtration unit 1 enter the reactor 2 that dewaters.
The reactor 2 that dewaters is used for removing waste edible oil, vegetables oil, the contained moisture of animal wet goods of animal or plant nature oil, also is used for removing the methyl alcohol of the regeneration ester that takes out from aftermentioned separator tank 5.Dewatered waste edible oil, vegetables oil, animal wet goods of animal or plant nature oil enter aftermentioned regeneration ester reducing apparatus 4.
(manufacturing process of sulfuric acid methoxyl group)
Stirred pot 3 is used for the purification of sulphuric acids methoxyl group with preparation regeneration ester.Ratio with the sulfuric acid methoxyl group of stirred pot 3 purifying is to sneak into 3%～5% sulfuric acid (CASNo.192-04696, molecular formula: H with respect to the amount of regeneration ester
2SO
4=98.08) and 5%～10% methyl alcohol (molecular formula: CH
4O, JIS K1501, molecular weight: 32.04), stir, heating rapidly, but heating is suppressed at below 60 ℃, stir about 10 minutes～20 minutes is rotated with 200～300rpm, thereby obtains the sulfuric acid methoxyl group.Stirred pot 3 is arranged on the top of regeneration ester reducing apparatus 4, and the sulfuric acid methoxyl group made from stirred pot 3 is sent in the regeneration ester reducing apparatus 4 of its below.Sneak in the regeneration ester reducing apparatus 4 with the dewatered waste edible oil of reactor 2 that dewaters, vegetables oil, animal wet goods of animal or plant nature oilyly, stir.
(manufacturing process of regeneration ester)
Regeneration ester reducing apparatus 4 is located at the downside of stirred pot 3, to sneaking into through the sulfuric acid methoxyl group of stirred pot 3 purifying in the dewatered waste edible oil of reactor 2 that dewaters, vegetables oil, animal wet goods of animal or plant nature oil and stirring, obtains the ester of regenerating.On regeneration ester reducing apparatus 4, agitator is installed.Sneaking into the time in this regeneration ester reducing apparatus 4 was with the interval stir about that carries out drop 30 minutes.200rpm～300rpm is rotated stirring with per minute, makes the regeneration ester.Can remove the impurity free fatty acids.The amount of this impurity free fatty acids accounts for 0.5%～1.5% of total volume, for the separation that improves free fatty acids is delivered to separating layer 5 with it.
In separating layer 5, with standing about 1～2 day of the precipitation of regeneration contained free fatty acids in ester, be separated into free fatty acids and regeneration ester.The regeneration ester that separates is as the regeneration olein of the fuel blend additive of fossil oil oil and water.
The regeneration ester (regeneration olein) that hold-up vessel 6 stores through separating layer 5 purifying is as the material of stirred pot 11 uses.At hold-up vessel 6 be located at the supply-pipe 6a that is furnished with between stirred pot 11 below it for accommodating source material.The regeneration ester (regeneration olein) that stores in hold-up vessel 6 is put in stirred pot 11 with weight ratio 20%～40% by this supply-pipe 6a.
Hold-up vessel 7 is used for storing oleic acid or vegetable fatty acid, at hold-up vessel 7 be located between stirred pot 11 below it and be furnished with supply-pipe 7a.The oleic acid or the vegetable fatty acid that store in hold-up vessel 7 are put in stirred pot 11 with weight ratio 35%～70% by this supply-pipe 7a.This oleic acid is the contained saturated fatty acid of animals and plants and unsaturated fatty acids, is a kind of tensio-active agent.
CASNo.112-80-1, molecular formula: C
18H
34O
2
(manufacturing process of single ethylidene methyl alcohol)
Stirred pot 8 purifying are blended into the single ethylidene methyl alcohol in stirred pot 11, and the input weight ratio is 10%～15% methyl alcohol (molecular formula: CH
4O, JIS K1501, molecular weight: 32.04) and weight ratio be 3%～4% ethylene glycol (CASNo.107-21-1, molecular formula: HOCH
2CH
2OH, content: more than 99%), stir about 10～15 minutes.Revolution is 200～300rpm, and chemical reaction does not occur.At stirred pot 8 be located between stirred pot 11 below it and be furnished with supply-pipe 8a, described supply-pipe 8a is used for to the single ethylidene methyl alcohol of stirred pot 11 supplies through stirred pot 8 purifying.
(manufacturing process of cyclammonium ethanol)
Stirred pot 9 is tanks that purifying is blended into the cyclammonium ethanol in stirred pot 11, and the input weight ratio is 2.5%～4% monoethanolamine (CASNo.141-43-5, molecular formula: C
2H
7NO, JIS:K8109～1963, molecular weight: 61.08).Sneak into weight ratio and be 6%～12% hexahydroaniline (CASNo.108-91-8, molecular formula: C
6H
13N, 99.17) and stir molecular weight:.Churning time is 10～15 minutes, is rotated stirring with 200～300rpm, and chemical reaction does not occur.At stirred pot 9 be located between stirred pot 11 below it and be furnished with supply-pipe 9a, described supply-pipe 9a is used for to the cyclammonium ethanol of stirred pot 11 supplies through stirred pot 9 purifying.
Hold-up vessel 10 is used for storing ammonia or the ethylene glycol of putting into stirred pot 11.Operating weight is than the ammonia (molecular formula: NH that is 3.5%～5%
4OH, content: 25～28%).Perhaps operating weight is than the ethylene glycol (HOCH that is 3.5%～5%
2CH
2OH, content: more than 99%).At hold-up vessel 10 be located between stirred pot 11 below it and be furnished with supply-pipe 10a, described supply-pipe 10a is used for the ammonia or the ethylene glycol that store in stirred pot 11 supply canisters 10.
(manufacturing process of the fuel blend additive of fossil oil oil and water)
(1) stirred pot 11 is purifying tanks of the fuel blend additive of fossil oil oil and water.At first, dropping into weight ratio in the stirred pot 11 is the regeneration ester that stores in 20%～40% hold-up vessel 6.Next, sneak into the oleic acid or the vegetable fatty acid that store in 35%～70% hold-up vessel 7, stir.Chemical reaction does not occur.Churning time is 10～15 minutes, is rotated stirring with 200～300rpm.
(2) sneak into single ethylidene methyl alcohol through stirred pot 8 purifying in the stirred pot 11.Weight ratio is 10%～20%, stirs.Churning time is 10～15 minutes, is rotated stirring with 200～300rpm.Chemical reaction does not occur.
(3) when finishing, the stirring of above-mentioned (2) sneaks into cyclammonium ethanol through stirred pot 9 purifying in the stirred pot 11.Sneaking into weight ratio is 5%～15%, stirs.Churning time is 15～30 minutes, is rotated stirring with 250～350rpm.Begin to sneak into rear generation chemical reaction.Owing to promptly beginning heating, therefore drop on a small quantity continuously, so that temperature does not rise to more than 55 ℃.
(4) ammonia or the ethylene glycol that store sneak into hold-up vessel 10 when above-mentioned (3) purifying finishes in.Weight ratio is 3.5%～5%, and churning time is 10～15 minutes, is rotated stirring with 250～350rpm, and chemical reaction occurs a little.Because therefore heating drops into a small amount of.
(5) after all process steps finishes, for each reagent is mixed fully, stirred 15～30 minutes, finish to make.Obtain thus the fuel blend additive of fossil oil oil and water.
When (6) using the fuel blend additive of fossil oil oil and water, the fossil oil oil of above-mentioned (5) purifying and the fuel blend additive of water are transferred in hold-up vessel 12, used after standing 5～24 hours.
Stirring in all process steps of above-mentioned (1)～(5) is carried out continuously.
(fossil oil oil adds the manufacturing process of water fuel)
(1) the hold-up vessel 12 of the fuel blend additive that stores fossil oil oil and water, store fossil oil oil for example the hold-up vessel 13 of A heavy oil and storage water hold-up vessel 14 below stirred pot 15 is set.And be furnished with respectively supply- pipe 12a, 13a, 14a, be used for each tank from upside to stirred pot 15 accommodating source materials.Drop into fossil oil oil in this stirred pot 15 and add the fossil oil oil of above-mentioned (6) purifying of 5%～25% of water fuel purifying amount and the fuel blend additive of water, and sneak into 50%～75% as the fossil oil oil in starting material sources A heavy oil for example, begin to stir.With 250～400rpm Stirring 5～15 minutes.
(2) sneak into water when finishing stirring.Mixed volume is 10%～35% of purifying amount, is rotated stirring with 250～400rpm.
(3) method of sneaking into of water: 5%～10% rear stirring 1～2 minute of sneaking into mixed volume.Repeat aforesaid operations, can not form the milky emulsion that emulsification occurs.
(4) water is all sneaked into after with 200～300rpm Stirring 10～15 minutes, finish to make.Obtain thus fossil oil oil and add water fuel.
(analytical results)
In adding the experiment of water fuel, the fossil oil oil that uses fossil oil oil-water fuel blend additive obtains following data.
(1) analytical results: when fossil oil oil-water fuel blend additive is 10%, A heavy oil is 70%, when water is 20%, in the fuel analysis report, the burning-point of A heavy oil is 82.0 ℃ (JISK2265.6); The burning-point that fossil oil oil adds water fuel is 68.5 ℃ (JIS K2265.6).That is, fossil oil oil adds the burning-point of water fuel lower than A heavy oil.
(2) burning data: when fossil oil oil-water fuel blend additive is 10%, A heavy oil is 70%, when water is 20%, during burning is measured relatively, A heavy oil combustion flame temperature is 891 ℃, it is 1123 ℃ that fossil oil oil adds water fuel combustion flame temperature.That is, fossil oil oil adds the burning flame temperature of water fuel higher than A heavy oil.
Need to prove, the present invention is not limited to above-mentioned embodiment, and is self-evident, can carry out various changes without departing from the spirit and scope of the present invention.
Claims (5)
1. the manufacture method of the fuel blend additive of fossil oil oil and water, is characterized in that, comprises following operation:
Mix and blend sulfuric acid and methyl alcohol are made the operation of sulfuric acid methoxyl group;
The sulfuric acid methoxyl group that the above-mentioned operation of mix and blend is made and of animal or plant nature oil are made the operation of regeneration ester;
The operation of the single ethylidene methyl alcohol of mix and blend methyl alcohol and ethylene glycol manufacturing;
Mix and blend monoethanolamine and hexahydroaniline are made the operation of cyclammonium ethanol;
And the above-mentioned operation of mix and blend regeneration ester and oleic acid or the vegetable fatty acid made, the operation of sneaking into successively single ethylidene methyl alcohol of above-mentioned operation manufacturing and cyclammonium ethanol and ammonia or ethylene glycol in the gained material and stirring.
2. the manufacture method of the fuel blend additive of fossil oil oil as claimed in claim 1 and water, wherein, comprise vegetables oil, animal oil in of animal or plant nature oil.
3. the manufacture method of the fuel blend additive of fossil oil oil as claimed in claim 1 and water, wherein, comprise waste edible oil in of animal or plant nature oil.
4. a fossil oil oil adds the manufacture method of water fuel, it is characterized in that, the fossil oil oil of the fossil oil oil that the claim 1 of mix and blend 5%～25% is made and the fuel blend additive of water and 50%～70%, and 10%～35% moisture is sneaked into wherein for several times stir, make fossil oil oil and add water fuel.
5. fossil oil oil as claimed in claim 4 adds the manufacture method of water fuel, wherein, comprises heavy oil, light oil, kerosene in fossil oil oil.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008109072 | 2008-04-18 | ||
| JP2008109072A JP5384021B2 (en) | 2008-04-18 | 2008-04-18 | Method for Producing Petrochemical / Water Mixed Fuel Additive and Method for Producing Petrochemical Hydrous Fuel |
| JP2008-109072 | 2008-04-18 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101560418A CN101560418A (en) | 2009-10-21 |
| CN101560418B true CN101560418B (en) | 2013-11-06 |
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ID=41219403
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008101280339A Active CN101560418B (en) | 2008-04-18 | 2008-07-10 | Method for producing fossil fuel oil and water mixing fuel additive |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP5384021B2 (en) |
| KR (1) | KR101480556B1 (en) |
| CN (1) | CN101560418B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1133875A (en) * | 1995-04-19 | 1996-10-23 | 张继周 | Fuel economizing additive |
| CN1210134A (en) * | 1997-10-23 | 1999-03-10 | 朱贤军 | Fuel additive and preparation thereof |
| CN1343763A (en) * | 2000-09-18 | 2002-04-10 | 刘政吉 | Process for preparing addition used to synthesize diesel oil by adding water to it |
| CN1763158A (en) * | 2005-11-02 | 2006-04-26 | 蔡可而 | Heavy fuel oil additive containing benzopyran multi-hydroxy metal compound |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0633385B2 (en) * | 1986-12-16 | 1994-05-02 | 三菱石油株式会社 | Gelled fuel composition |
| JPH07157781A (en) * | 1993-12-08 | 1995-06-20 | Kao Corp | Production of heavy oil emulsion |
| JP3839385B2 (en) * | 2002-10-03 | 2006-11-01 | 三洋化成工業株式会社 | Emulsifier for emulsion fuel |
| KR100566106B1 (en) * | 2003-03-28 | 2006-03-30 | 한국에너지기술연구원 | Production method of low alkyl ester |
| JP2005133031A (en) * | 2003-10-31 | 2005-05-26 | Masayuki Furuno | Additive for oil/water mixed fuel |
| JP2006002058A (en) * | 2004-06-18 | 2006-01-05 | Sanyo Chem Ind Ltd | Emulsifier for emulsion fuel |
| JP5207718B2 (en) * | 2007-12-05 | 2013-06-12 | 政博 小曽根 | Method for Producing Petrochemical / Water Mixed Fuel Additive and Method for Producing Petrochemical Hydrous Fuel |
-
2008
- 2008-04-18 JP JP2008109072A patent/JP5384021B2/en active Active
- 2008-07-08 KR KR20080066055A patent/KR101480556B1/en active IP Right Grant
- 2008-07-10 CN CN2008101280339A patent/CN101560418B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1133875A (en) * | 1995-04-19 | 1996-10-23 | 张继周 | Fuel economizing additive |
| CN1210134A (en) * | 1997-10-23 | 1999-03-10 | 朱贤军 | Fuel additive and preparation thereof |
| CN1343763A (en) * | 2000-09-18 | 2002-04-10 | 刘政吉 | Process for preparing addition used to synthesize diesel oil by adding water to it |
| CN1763158A (en) * | 2005-11-02 | 2006-04-26 | 蔡可而 | Heavy fuel oil additive containing benzopyran multi-hydroxy metal compound |
Non-Patent Citations (1)
| Title |
|---|
| JP特开2006-2058A 2006.01.05 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20090110766A (en) | 2009-10-22 |
| JP2009256508A (en) | 2009-11-05 |
| JP5384021B2 (en) | 2014-01-08 |
| KR101480556B1 (en) | 2015-01-09 |
| CN101560418A (en) | 2009-10-21 |
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