CN101560119B - Method for producing germanium-enriched amino acid compound fertilizer - Google Patents
Method for producing germanium-enriched amino acid compound fertilizer Download PDFInfo
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- CN101560119B CN101560119B CN2009100113371A CN200910011337A CN101560119B CN 101560119 B CN101560119 B CN 101560119B CN 2009100113371 A CN2009100113371 A CN 2009100113371A CN 200910011337 A CN200910011337 A CN 200910011337A CN 101560119 B CN101560119 B CN 101560119B
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- germanium
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- beans
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 23
- 229910052732 germanium Inorganic materials 0.000 title claims abstract description 13
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- -1 amino acid compound Chemical class 0.000 title claims abstract description 10
- 244000046052 Phaseolus vulgaris Species 0.000 claims abstract description 11
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 claims abstract description 8
- 108090000145 Bacillolysin Proteins 0.000 claims abstract description 6
- 102000035092 Neutral proteases Human genes 0.000 claims abstract description 6
- 108091005507 Neutral proteases Proteins 0.000 claims abstract description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004202 carbamide Substances 0.000 claims abstract description 6
- 235000006008 Brassica napus var napus Nutrition 0.000 claims abstract description 5
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 5
- 238000006243 chemical reaction Methods 0.000 claims abstract description 5
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims abstract description 4
- 229910052776 Thorium Inorganic materials 0.000 claims abstract description 4
- 150000001336 alkenes Chemical class 0.000 claims abstract description 4
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims abstract description 4
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims abstract description 4
- 239000011609 ammonium molybdate Substances 0.000 claims abstract description 4
- 235000018660 ammonium molybdate Nutrition 0.000 claims abstract description 4
- 229940010552 ammonium molybdate Drugs 0.000 claims abstract description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004327 boric acid Substances 0.000 claims abstract description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract description 4
- 229940119177 germanium dioxide Drugs 0.000 claims abstract description 4
- 230000007935 neutral effect Effects 0.000 claims abstract description 4
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims abstract description 4
- 229910000368 zinc sulfate Inorganic materials 0.000 claims abstract description 4
- 229960001763 zinc sulfate Drugs 0.000 claims abstract description 4
- 210000003298 dental enamel Anatomy 0.000 claims abstract description 3
- 240000000385 Brassica napus var. napus Species 0.000 claims abstract 2
- 238000003756 stirring Methods 0.000 claims description 8
- 230000007062 hydrolysis Effects 0.000 claims description 4
- 238000006460 hydrolysis reaction Methods 0.000 claims description 4
- 235000012054 meals Nutrition 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 235000019764 Soybean Meal Nutrition 0.000 claims description 2
- 238000007789 sealing Methods 0.000 claims description 2
- 239000004455 soybean meal Substances 0.000 claims description 2
- 239000004254 Ammonium phosphate Substances 0.000 claims 1
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N ammonium phosphates Chemical group [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 claims 1
- 235000019289 ammonium phosphates Nutrition 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 239000002689 soil Substances 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 6
- 235000013399 edible fruits Nutrition 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000843 powder Substances 0.000 abstract description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 abstract 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 abstract 1
- 239000005696 Diammonium phosphate Substances 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- 239000001099 ammonium carbonate Substances 0.000 abstract 1
- 230000002950 deficient Effects 0.000 abstract 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 abstract 1
- 229910000388 diammonium phosphate Inorganic materials 0.000 abstract 1
- 235000019838 diammonium phosphate Nutrition 0.000 abstract 1
- 239000011259 mixed solution Substances 0.000 abstract 1
- 235000015097 nutrients Nutrition 0.000 abstract 1
- 239000001103 potassium chloride Substances 0.000 abstract 1
- 235000011164 potassium chloride Nutrition 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- 239000013589 supplement Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 5
- 240000008042 Zea mays Species 0.000 description 4
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 4
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 4
- 235000005822 corn Nutrition 0.000 description 4
- 230000012010 growth Effects 0.000 description 4
- 230000000050 nutritive effect Effects 0.000 description 4
- 240000002791 Brassica napus Species 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 210000003608 fece Anatomy 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 239000010871 livestock manure Substances 0.000 description 2
- 239000011785 micronutrient Substances 0.000 description 2
- 235000013369 micronutrients Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003895 organic fertilizer Substances 0.000 description 2
- 238000010010 raising Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000008162 cooking oil Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 210000000003 hoof Anatomy 0.000 description 1
- 230000003050 macronutrient Effects 0.000 description 1
- 235000021073 macronutrients Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses a method for producing germanium-enriched amino acid compound fertilizer which can promote the crops to grow, increase the crop yield, supplement nutrient elements and organic substances that are deficient in the soil, improve the quality of fruits and increase the organic germanium content in the crops. The method comprises: bean pulp is added into an enamel reaction kettle and soaked into water until evenly absorbing the water; the water solution is added with industrial concentrated sulfuric acid to be stirred at the temperature of 110-120 DEG C for hydrolyzation; when the temperature in the kettle tank is reduced to 80 DEGC, the reactants are added with ammonium hydrogen carbonate to regulate the PH value to be neutral, and then is continuously cooled to normal temperature; when being stirred, the obtained mixed solution is sequentially added with the following components diammonium phosphate, urea, zinc sulfate, copper sulphate, boric acid, ammonium molybdate, thorium alkene nitrate, germanium dioxide, potassium chloride, colza cake powder and neutral protease; after being dried, granulated and staying over night, 10% of supernate is taken.
Description
Technical field:
The utility model relates to a kind of production method of composite fertilizer, especially a kind ofly both can promote crop growth, improved crop yield, replenish the nutritive element and the organic substance that lack in soil, and can improve again fruit quality, improve the production method of the germanium-enriched amino acid compound fertilizer of organic germanium content in farm crop.
Background technology:
At present, be to promote crop growth, be widely used mineral manure (being chemical fertilizer), organic fertilizer and with these two kinds of fertilizer that fertilizer mixes in agriculture production.Can give soil, environment and crop and fruit quality because of mineral manure and bring problems, people more and more pay attention to research, production and the use of organic fertilizer.For example, China Patent No. is 92109786.7 document description, and a kind of hair, hoof or skin and soyflour with animal made raw material, hydrolysis obtains hydrolyzed solution as catalyzer with urea, then the method that adds macronutrient and micronutrient element reaction to produce amino-acid compound fertilizer.China Patent No. has been 95103995.4 document description a kind of fertilizer that utilizes the preparations such as kilnitamin, EDTA, plant-growth regulator and trace element.China Patent No. is that 96105618.5 patent documentations have been described take Keratin sulfate and soyflour as raw material, as catalyzer and add the sulfuric acid pyrohydrolysis and obtain hydrolyzed solution, then add micronutrient element, Chinese medical extract and medical stone extracting solution etc. to produce amino-acid compound fertilizer with urea.Although these fertilizer can improve crop yield, improve fruit quality, but also can replenish nutritive element and the organic substance that lacks in soil, can not allow farm crop be rich in is of value to the organic germanium of HUMAN HEALTH composition.
Summary of the invention:
The present invention is in order to solve the existing above-mentioned technical problem of prior art, provide a kind of and both can promote crop growth, improve crop yield, replenish the nutritive element and the organic substance that lack in soil, can improve again the production method of the germanium-enriched amino acid compound fertilizer of organic germanium content in farm crop.
Technical solution of the present invention is: a kind of production method of germanium-enriched amino acid compound fertilizer is characterized in that carrying out as follows:
A. add dregs of beans and water in enamel reaction still, the mass ratio of dregs of beans and water is 1: 1.5, is dipped to the dregs of beans suction evenly;
B. add the industrial vitriol oil that equates with Soybean Meal, sealing makes the interior temperature of reactor tank be warmed up to 110～120 ℃, stirs hydrolysis 10 hours;
When c. in the reactor tank, temperature is cooled to 80 ℃ naturally, adds bicarbonate of ammonia and transfer PH to neutral, continue to be cooled to normal temperature;
D. add while stirring in order following component take the dregs of beans amount as radix: 1.6～1.7 times of DAP, 0.97～0.98 times of urea, 0.012 times of zinc sulfate, 0.012 times of copper sulfate, 0.016 times of boric acid, 0.016 times of ammonium molybdate, the nitric acid alkene thorium of 0.008 times, 0.0001～0.001 times of germanium dioxide, 1.3 times of Repone K, 1.3～1.4 times of coarse colza meals, 0.0012 times of neutral protease.
E. drying-granulating or hold over night are got 10% supernatant liquor.
The present invention interacts by the raw material of rational proportion, can promote crop growth, improves crop yield, replenish the nutritive element and the organic substance that lack in soil, can improve again the content of organic germanium in fruit quality, raising farm crop.
Embodiment:
A kind of production method of germanium-enriched amino acid compound fertilizer is characterized in that carrying out as follows:
A. to 5m
3Enamel reaction still in add entry 750Kg, then add bean cake powder 500Kg while stirring, till being dipped to dregs of beans suction evenly;
B. stir the limit by high-order trough rim and slowly add industrial vitriol oil 500Kg, build cover, 110～120 ℃ of interlayer heat temperature raisings, continuously stirring hydrolysis 10 hours;
C. reactor is lowered the temperature or interlayer when adding cold water and being cooled to 80 ℃ naturally, and still is pressed to zero pound, after confirming to fall zero, uncaps, and adds 806Kg bicarbonate of ammonia and transfers pH value to be neutral, continues to naturally cool to normal temperature;
D. add while stirring in order following component take 500Kg as radix: 1.6～1.7 times of DAP, 0.97～0.98 times of urea, 0.012 times of zinc sulfate, 0.012 times of copper sulfate, 0.016 times of boric acid, 0.016 times of ammonium molybdate, the nitric acid alkene thorium of 0.008 times, 0.0001～0.001 times of germanium dioxide, 1.3 times of Repone K, 1.3～1.4 times of coarse colza meals, 0.0012 times of neutral protease.
E. drying-granulating or hold over night are got 10% supernatant liquor.
Coarse colza meal in raw materials used be China's two No. 3 (oily 002-1998 is examined in Hubei Province) take Hua Zhong Agriculture University as standard, the trust Grain and Cooking Oil Processing Factory processes.Neutral protease is that the model that Wuxi zymin factory produces is the subtilis neutral protease (enzyme activity is 100000u/g) of A.S1398.Other raw materials all can directly be bought in market.
Experimental example:
10 mu of corn fields are divided equally into two, each 5 mu of ground.Wherein 5 mu are contrast ground, execute the 50Kg Common compound fertilizer for every mu and make base fertilizer, other 5 mu for experimental field with embodiment of the present invention compositing fertilizer as corn field base fertilizer, use 30Kg for every mu, all the other management are carried out routinely.
Spray liquid in corn jointing stage, boot stage and filling stage, every mu experimental field with 100～500 times of embodiment of the present invention liquid fertilizer dilute with waters, then spray 250～500L, and contrast ground replaces with underground water.
Result is as shown in the table.
| Project | This production method | The original production method |
| Fertilizer application amount (kg) | 150 (Gu fertile)+15 (liquid fertilizers) | 250 (Gu fertile) |
| Per mu yield (kg) | 966 | 798 |
| The average germanic amount of corn (mg/kg) | 1.48 | 0.034 |
Claims (1)
1. the production method of a germanium-enriched amino acid compound fertilizer is characterized in that carrying out as follows:
A. add dregs of beans and water in enamel reaction still, the mass ratio of dregs of beans and water is 1: 1.5, is dipped to the dregs of beans suction evenly;
B. add the industrial vitriol oil that equates with Soybean Meal, sealing makes the interior temperature of reactor tank be warmed up to 110～120 ℃, stirs hydrolysis 10 hours;
C. during greenhouse cooling to 80 ℃, add bicarbonate of ammonia and transfer pH to neutral in the still tank, continue to be cooled to normal temperature;
D. add while stirring in order following component take the dregs of beans amount as radix: 1.6～1.7 times of Secondary ammonium phosphates, 0.97～0.98 times of urea, 0.012 times of zinc sulfate, 0.012 times of copper sulfate, 0.016 times of boric acid, 0.016 times of ammonium molybdate, the nitric acid alkene thorium of 0.008 times, 0.0001～0.001 times of germanium dioxide, 1.3 times of Repone K, 1.3～1.4 times of coarse colza meals, 0.0012 times of neutral protease;
E. drying-granulating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100113371A CN101560119B (en) | 2009-04-29 | 2009-04-29 | Method for producing germanium-enriched amino acid compound fertilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100113371A CN101560119B (en) | 2009-04-29 | 2009-04-29 | Method for producing germanium-enriched amino acid compound fertilizer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101560119A CN101560119A (en) | 2009-10-21 |
| CN101560119B true CN101560119B (en) | 2013-06-12 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100113371A Expired - Fee Related CN101560119B (en) | 2009-04-29 | 2009-04-29 | Method for producing germanium-enriched amino acid compound fertilizer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101560119B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103086784B (en) * | 2011-10-27 | 2014-06-25 | 胡茂森 | Amino acid biological fertilizer added with enzyme, and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1110265A (en) * | 1994-04-11 | 1995-10-18 | 北京市潮白河新技术研究所 | Organic compound fertilizer and its process |
| CN1114146A (en) * | 1994-06-25 | 1996-01-03 | 大连水产学院 | Process for preparing compound amino-acid chelating salt and hydrolytic protein |
| CN1379019A (en) * | 2002-04-25 | 2002-11-13 | 丁奕翔 | Composite vegetative amino acid and its preparing process |
| CN1562907A (en) * | 2004-03-30 | 2005-01-12 | 赵良雄 | Self-contained fertilizer of amino acid liquor |
-
2009
- 2009-04-29 CN CN2009100113371A patent/CN101560119B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1110265A (en) * | 1994-04-11 | 1995-10-18 | 北京市潮白河新技术研究所 | Organic compound fertilizer and its process |
| CN1114146A (en) * | 1994-06-25 | 1996-01-03 | 大连水产学院 | Process for preparing compound amino-acid chelating salt and hydrolytic protein |
| CN1379019A (en) * | 2002-04-25 | 2002-11-13 | 丁奕翔 | Composite vegetative amino acid and its preparing process |
| CN1562907A (en) * | 2004-03-30 | 2005-01-12 | 赵良雄 | Self-contained fertilizer of amino acid liquor |
Non-Patent Citations (6)
| Title |
|---|
| 一种多元高浓度复合液肥的生产方法;王存文等;《陕西化工》;19971231(第1期);17-19 * |
| 我国免疫毒理学的研究进展;陈成章;《卫生毒理学杂志》;20000630(第2期);68-71 * |
| 氨基酸微肥的生产和应用进展;邵建华等;《磷肥与复肥》;20000731;第15卷(第4期);48-51 * |
| 王存文等.一种多元高浓度复合液肥的生产方法.《陕西化工》.1997,(第1期), |
| 邵建华等.氨基酸微肥的生产和应用进展.《磷肥与复肥》.2000,第15卷(第4期), |
| 陈成章.我国免疫毒理学的研究进展.《卫生毒理学杂志》.2000,(第2期), |
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| CN101560119A (en) | 2009-10-21 |
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