CN101550286A - Disperse dye composition with high washing fastness - Google Patents
Disperse dye composition with high washing fastness Download PDFInfo
- Publication number
- CN101550286A CN101550286A CNA2009100981849A CN200910098184A CN101550286A CN 101550286 A CN101550286 A CN 101550286A CN A2009100981849 A CNA2009100981849 A CN A2009100981849A CN 200910098184 A CN200910098184 A CN 200910098184A CN 101550286 A CN101550286 A CN 101550286A
- Authority
- CN
- China
- Prior art keywords
- dye
- formula
- dye monomer
- monomer
- washing fastness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 18
- 239000000986 disperse dye Substances 0.000 title claims abstract description 11
- 238000005406 washing Methods 0.000 title claims abstract description 11
- 239000000975 dye Substances 0.000 claims abstract description 68
- 239000000178 monomer Substances 0.000 claims abstract description 39
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 9
- 239000000835 fiber Substances 0.000 abstract description 9
- 238000004043 dyeing Methods 0.000 abstract description 8
- 239000004576 sand Substances 0.000 abstract description 5
- 238000007639 printing Methods 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract 1
- 238000001694 spray drying Methods 0.000 abstract 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 239000013543 active substance Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 239000007859 condensation product Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 3
- 229920005552 sodium lignosulfonate Polymers 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 2
- 229920004935 Trevira® Polymers 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- -1 super fine denier Substances 0.000 description 2
- KTHUKEZOIFYPEH-UHFFFAOYSA-N 1-benzylnaphthalene Chemical compound C=1C=CC2=CC=CC=C2C=1CC1=CC=CC=C1 KTHUKEZOIFYPEH-UHFFFAOYSA-N 0.000 description 1
- VQIRFOAILLIZOY-UHFFFAOYSA-N 2-[5-acetamido-n-(2-acetyloxyethyl)-4-[(2-bromo-4,6-dinitrophenyl)diazenyl]-2-ethoxyanilino]ethyl acetate Chemical compound C1=C(N(CCOC(C)=O)CCOC(C)=O)C(OCC)=CC(N=NC=2C(=CC(=CC=2Br)[N+]([O-])=O)[N+]([O-])=O)=C1NC(C)=O VQIRFOAILLIZOY-UHFFFAOYSA-N 0.000 description 1
- ROPYWXVRNREIQD-UHFFFAOYSA-N 2-[n-(2-cyanoethyl)-4-[(2,6-dichloro-4-nitrophenyl)diazenyl]anilino]ethyl acetate Chemical compound C1=CC(N(CCC#N)CCOC(=O)C)=CC=C1N=NC1=C(Cl)C=C([N+]([O-])=O)C=C1Cl ROPYWXVRNREIQD-UHFFFAOYSA-N 0.000 description 1
- CULIYQPRUGMRRT-UHFFFAOYSA-N 2-chloro-n-[2-[(2-cyano-4-nitrophenyl)diazenyl]-5-(diethylamino)phenyl]acetamide Chemical compound ClCC(=O)NC1=CC(N(CC)CC)=CC=C1N=NC1=CC=C([N+]([O-])=O)C=C1C#N CULIYQPRUGMRRT-UHFFFAOYSA-N 0.000 description 1
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 description 1
- WBCXRDHKXHADQF-UHFFFAOYSA-N 4,11-diamino-2-(3-methoxypropyl)naphtho[2,3-f]isoindole-1,3,5,10-tetrone Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C(N)=C(C(N(CCCOC)C1=O)=O)C1=C2N WBCXRDHKXHADQF-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019357 lignosulphonate Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Landscapes
- Coloring (AREA)
Abstract
The invention discloses a disperse dye composition with high washing fastness, which comprises the following components in percentage by weight: 5.8 to 44 percent of dye monomer A shown as formula (1); 3.0 to 31.9 percent of dye monomer B shown in formula (2-1) and/or dye monomer C shown in formula (2-2); 0.65-3.85% of a dye monomer D shown in a formula (3), and the balance of an auxiliary agent. The dye composition of the invention can be ground into liquid by a sand mill or a grinding machine, and is powdery and granular after spray drying, so that series of blue, brown, black and extra black dyes can be obtained, and the dye composition is particularly suitable for superfine fiber and superfine denier dyeing and printing, and has high dyeing yield, good leveling property and good washing fastness after dyeing.
Description
Technical field
The present invention relates to a kind of disperse dye composition, be applicable to the dyeing and the stamp of terylene and BLENDED FABRIC thereof, the dispersion/activity that also is applicable to polyester/cotton blended fabric is specially adapted to the dyeing of ultra-fine fibre with the slurry stamp.
Background technology
Fast development along with recent trevira, ultra-fine fibre, superfine Denier fibre have appearred, because it has minimum linear density and high-specific surface area, make its fabric have high spreadability, soft, comfortable and easy to wear, therefore become the focus textile raw material that domestic and international textile enterprise is used to develop grade textiles.Though at present conventional dispersed dye dye on also can be reluctantly, but dyestuff and interfibrous molecular attraction reduce greatly, the dye uptake that is apparent that most dyestuff descends significantly, and the each side fastness of dying the back cloth all has in various degree decline, especially washing fastness to influence the most obvious.
At this problem, having some occurs at the dispersed dye of ultra-fine fibre specially, as publication number is the Chinese patent application of CN 101376752, disclose a kind of dispersed black dye that is applicable to ultra-fine fibre, formed by C.I. Disperse Blue-60, C.I. Disperse Blue-79 .1, C.I. EX-SF DISPERSE BLUE EX-SF 300 77, C.I. DISPERSE YELLOW 114, C.I. Disperse Red 311, sodium lignosulfonate and dust laying oil.
Summary of the invention
The invention provides a kind of both can be on general trevira dyeing and printing, more can on ultra-fine fibre, super fine denier, dye and the disperse dye composition of stamp.
Disperse dye composition of the present invention, form by following component by weight percentage: 5.8%~44% as the formula (1) dye monomer A:
3.0%~31.9% suc as formula the dye monomer B shown in (2-1) and/or suc as formula the dye monomer C shown in (2-2):
0.65%~3.85% as the formula (3) dye monomer D:
Surplus is an auxiliary agent.
A kind of preferred disperse dye composition, form by following component by weight percentage: 10.0%~30.0% as the formula (1) dye monomer A, 3.0%~10.0% suc as formula the dye monomer B shown in (2-1) and/or suc as formula the dye monomer C shown in (2-2), 0.8%~3..0% dye monomer D as the formula (3), surplus is an auxiliary agent.The dye composite of this proportioning not only possesses higher washing fastness, possesses higher dye uptake simultaneously.
Described auxiliary agent is dispersed dye dispersion agent, diffusant and tensio-active agents thereof etc. commonly used when composite, preferably includes one of following or its mixture: naphthalene sulfonic acidformaldehyde condensation product, sulfonated lignin, alkyl naphthalene sulfonic acid formaldehyde condensation products.As condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic formaldehyde condensation compound (dispersing agent CNF), sodium lignosulfonate (xylogen 85A, 83A) etc.
High washing fastness disperse dye composition of the present invention can be used by the below method and prepare:
After dye monomer A, dye monomer B and/or dye monomer C, dye monomer D mixed by said ratio, in the presence of auxiliary agent, water or other tensio-active agent, carry out corpusculed with pulverizers such as sand mill or shredders; Also the former dyestuff of dye monomer A, dye monomer B and/or dye monomer C, dye monomer D can be carried out corpusculed with pulverizers such as sand mill or shredders respectively in the presence of auxiliary agent, water or other tensio-active agent, mix by said ratio again.
Described dye monomer A, dye monomer B, dye monomer C, dye monomer D all can adopt the commercially available prod.
It is aqueous that high washing fastness dye composite of the present invention can grind the back with sand mill or shredder, be powdery, particulate state after the spraying drying, and adjustment composition cooperation ratio can get the series dyes of blue, brown, black, goth black look.The compatibleness of this dye composite is fabulous, and lifting force, dye uptake, Dry Sack rate, equalization are all good than general dispersed dye, are specially adapted to ultra-fine fibre, and the dyeing of super fine denier and stamp dye back dye yield height, equalization is good, washing fastness is good.
Embodiment
The invention will be further described below in conjunction with embodiment, but protection scope of the present invention is not limited to this.
Embodiment 1~18
Shown in table 1 data, with dye monomer A, dye monomer B, dye monomer C, dye monomer D, after adding water and piece together to mix with condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF), naphthalene sulfonic acidformaldehyde condensation product (dispersing agent NNO), sodium lignosulfonate (xylogen 85A, 83A), tensio-active agent, grind dispersion with sand milling, carry out spraying drying then.
The C.I.DISP BLUE 284# that dye monomer A shown in its Chinese style (1) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, the C.I.DISPRED311# that C.I.DISP BROWN 19:1#, C.I.DISP BROWN 19# that dye monomer B, C shown in formula (2-1), (2-2) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce, dye monomer D shown in the formula (3) can select for use Zhejiang Province Runtu intercalated Co., Ltd to produce.
Table 1:
The dye composition that dispersed dye, auxiliary agent, the water that the foregoing description is made makes after mixing carries out performance test, and testing method is as follows:
Respectively get the dispersed dye that 0.5 gram embodiment 1~18 makes, water is mixed with the dispersed dye suspension that concentration is 0.5g/500ml respectively, getting 20ml mixes with the water of 80ml, regulate dye bath pH to 5 with acetic acid, be warmed up to 60 ℃ then, put into the 2g superfine Denier fibre simultaneously respectively and carry out high-temperature pressure dyeing, in 35 minutes, be warmed up to 130 ℃, be incubated 50 minutes, sampling when being cooled to 80 ℃.
Observe cloth specimen coloured light and adopt GB/T2397-2003, GB/T9337-2001, GB/T3921-1997, GB/T3920-1997, GB/T5718-1997 to measure its dyefastness.
Adopt conventional disperse dye composition as a comparison case, as disperse black dye composition (45%C.I. DISPERSE ORANGE 30 200 288#, 15%C.I. 63 DISPERSE Violet 63 93:1#, 40%C.I. EX-SF DISPERSE BLUE EX-SF 300 291:3#).
Measurement result sees Table 2.
Table 2 unit: level
The embodiment title | Lifting force | Dye uptake | Washing fastness | Crock fastness | Sublimation fastness (180 ℃) |
Embodiment 1 | A | 78% | 5 | 4-5 | 4-5 |
Embodiment 2 | A | 86% | 5 | 5 | 4-5 |
Embodiment 3 | A | 74% | 5 | 5 | 4-5 |
Embodiment 4 | A | 75% | 5 | 5 | 4-5 |
Embodiment 5 | A | 72% | 5 | 4-5 | 4-5 |
Embodiment 6 | A | 73% | 5 | 5 | 4-5 |
Embodiment 7 | A | 73.5% | 5 | 5 | 4-5 |
Embodiment 8 | A | 85% | 5 | 5 | 4-5 |
Embodiment 9 | A | 74% | 5 | 5 | 4-5 |
Embodiment 10 | A | 86% | 5 | 4-5 | 4-5 |
Embodiment 11 | A | 79% | 5 | 5 | 4-5 |
Embodiment 12 | A | 72% | 5 | 5 | 4-5 |
Embodiment 13 | A | 76% | 5 | 5 | 4-5 |
Embodiment 14 | A | 87% | 5 | 5 | 4-5 |
Embodiment 15 | A | 85% | 5 | 4-5 | 4-5 |
Embodiment 16 | A | 82% | 5 | 5 | 4-5 |
Embodiment 17 | A | 83.5% | 5 | 5 | 4-5 |
Embodiment 18 | A | 74% | 5 | 5 | 4-5 |
Comparative Examples | C | 65% | 3 | 3-4 | 3-4 |
。
Claims (2)
1, a kind of disperse dye composition with high washing fastness, form by following component by weight percentage:
5.8%~44% as the formula (1) dye monomer A:
3.0%~31.9% suc as formula the dye monomer B shown in (2-1) and/or suc as formula the dye monomer C shown in (2-2):
0.65%~3.85% as the formula (3) dye monomer D:
Surplus is an auxiliary agent.
2, disperse dye composition as claimed in claim 1, it is characterized in that: form by following component by weight percentage: 10.0%~30.0% as the formula (1) dye monomer A, 3.0%~10.0% suc as formula the dye monomer B shown in (2-1) and/or suc as formula the dye monomer C shown in (2-2), 0.8%~3.0% as the formula (3) dye monomer D, surplus is an auxiliary agent.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200910098184A CN101550286B (en) | 2009-05-06 | 2009-05-06 | Disperse dye composition with high washing fastness |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200910098184A CN101550286B (en) | 2009-05-06 | 2009-05-06 | Disperse dye composition with high washing fastness |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101550286A true CN101550286A (en) | 2009-10-07 |
CN101550286B CN101550286B (en) | 2012-10-10 |
Family
ID=41154789
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN200910098184A Active CN101550286B (en) | 2009-05-06 | 2009-05-06 | Disperse dye composition with high washing fastness |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101550286B (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101870501A (en) * | 2010-07-07 | 2010-10-27 | 陶国来 | Method for processing dispersed dye coupling solution by utilizing ceramic membrane and corresponding system |
CN101914309A (en) * | 2010-07-19 | 2010-12-15 | 浙江闰土股份有限公司 | Environment-friendly composite disperse dye composition capable of performing discharge printing |
CN102504595A (en) * | 2011-11-15 | 2012-06-20 | 东营安诺其纺织材料有限公司 | Azo dye composition, preparation method thereof and use method thereof |
CN107722668A (en) * | 2017-09-30 | 2018-02-23 | 浙江万丰化工有限公司 | A kind of azo dye composition and its application |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100558821C (en) * | 2006-07-12 | 2009-11-11 | 浙江龙盛集团股份有限公司 | Composite disperse dye |
CN101376752B (en) * | 2007-08-28 | 2011-11-30 | 上海安诺其纺织化工股份有限公司 | High washing fastness dispersed black dye for superfine fibre |
-
2009
- 2009-05-06 CN CN200910098184A patent/CN101550286B/en active Active
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101870501A (en) * | 2010-07-07 | 2010-10-27 | 陶国来 | Method for processing dispersed dye coupling solution by utilizing ceramic membrane and corresponding system |
CN101914309A (en) * | 2010-07-19 | 2010-12-15 | 浙江闰土股份有限公司 | Environment-friendly composite disperse dye composition capable of performing discharge printing |
CN101914309B (en) * | 2010-07-19 | 2013-04-24 | 浙江闰土股份有限公司 | Environment-friendly composite disperse dye composition capable of performing discharge printing |
CN102504595A (en) * | 2011-11-15 | 2012-06-20 | 东营安诺其纺织材料有限公司 | Azo dye composition, preparation method thereof and use method thereof |
CN107722668A (en) * | 2017-09-30 | 2018-02-23 | 浙江万丰化工有限公司 | A kind of azo dye composition and its application |
CN107722668B (en) * | 2017-09-30 | 2019-07-30 | 浙江万丰化工有限公司 | A kind of azo dye composition and its application |
Also Published As
Publication number | Publication date |
---|---|
CN101550286B (en) | 2012-10-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN100577744C (en) | Black and blue series environment-friendly disperse dye composition | |
CN101798472B (en) | Black and blue disperse dye composition | |
CN101333343B (en) | Red disperse dyes composition of synthetic high fastness series | |
CN101629026B (en) | Back-blue dispersed dye composition | |
CN100422270C (en) | Composite disperse red dye composition | |
CN102352125B (en) | Disperse black and blue dye composition | |
CN102516812B (en) | Complex blue dye composition, complex dispersion blue dye and preparation method thereof | |
CN101792615A (en) | Environment-friendly dark blue and black series compound disperse dye and production method thereof | |
CN101768376A (en) | Environment-friendly disperse dye composition | |
CN1995154A (en) | Disperse orange dye composition and disperse dye | |
CN101280123B (en) | Mesothermal environment-friendly disperse dye composition | |
CN100374511C (en) | Mixed black and blue series combined disperse dye | |
CN102002259A (en) | High-fastness black and blue disperse dye composite | |
CN104448928A (en) | Disperse blue dye composition, disperse dye, preparation method and application | |
CN102229757B (en) | Disperse dye composition with a color range of yellow to golden yellow | |
CN101550286B (en) | Disperse dye composition with high washing fastness | |
CN102226040B (en) | Disperse grey dye composition | |
CN101265370B (en) | Medium-temperature-type environmental protection dispersion orange dyes | |
CN102220031B (en) | Black-and-blue series disperse dye composition | |
CN102229756B (en) | Mesothermal disperse blue dye composition | |
CN101914309B (en) | Environment-friendly composite disperse dye composition capable of performing discharge printing | |
CN101602896B (en) | Brown disperse dye composition | |
CN104448926B (en) | A kind of deep color dispersion dyes composition | |
CN100383193C (en) | Disperse red dye composition | |
CN102993778B (en) | Disperse blue dye composition and disperse blue dye and preparation method and application thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant |