CN101549977A - 一种复合胶凝材料及其生产方法 - Google Patents
一种复合胶凝材料及其生产方法 Download PDFInfo
- Publication number
- CN101549977A CN101549977A CNA2009100433878A CN200910043387A CN101549977A CN 101549977 A CN101549977 A CN 101549977A CN A2009100433878 A CNA2009100433878 A CN A2009100433878A CN 200910043387 A CN200910043387 A CN 200910043387A CN 101549977 A CN101549977 A CN 101549977A
- Authority
- CN
- China
- Prior art keywords
- flyash
- abrasive material
- grinding
- type abrasive
- compound additive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 25
- 239000002131 composite material Substances 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title abstract description 15
- 239000010881 fly ash Substances 0.000 claims abstract description 29
- 238000000227 grinding Methods 0.000 claims abstract description 20
- 239000002893 slag Substances 0.000 claims abstract description 18
- 239000000654 additive Substances 0.000 claims abstract description 14
- 230000000996 additive effect Effects 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 6
- 239000010703 silicon Substances 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 239000003082 abrasive agent Substances 0.000 claims description 17
- 239000003469 silicate cement Substances 0.000 claims description 14
- 239000011149 active material Substances 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 11
- 239000003638 chemical reducing agent Substances 0.000 claims description 10
- 230000004913 activation Effects 0.000 claims description 9
- 239000012190 activator Substances 0.000 claims description 8
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 8
- 238000009628 steelmaking Methods 0.000 claims description 5
- CCEKAJIANROZEO-UHFFFAOYSA-N sulfluramid Chemical group CCNS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F CCEKAJIANROZEO-UHFFFAOYSA-N 0.000 claims description 5
- 239000002956 ash Substances 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 239000004567 concrete Substances 0.000 abstract description 13
- 239000002699 waste material Substances 0.000 abstract description 9
- 239000011398 Portland cement Substances 0.000 abstract description 2
- 229910000831 Steel Inorganic materials 0.000 abstract description 2
- 239000004574 high-performance concrete Substances 0.000 abstract description 2
- 239000010959 steel Substances 0.000 abstract description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract description 2
- 241000876852 Scorias Species 0.000 abstract 1
- 239000011575 calcium Substances 0.000 description 12
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 11
- 229960004418 trolamine Drugs 0.000 description 11
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 10
- 229910052791 calcium Inorganic materials 0.000 description 10
- 239000004568 cement Substances 0.000 description 9
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 8
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 8
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 8
- -1 fluorgypsum Chemical compound 0.000 description 7
- 229910052602 gypsum Inorganic materials 0.000 description 7
- 239000010440 gypsum Substances 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 6
- 229920005610 lignin Polymers 0.000 description 6
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 5
- 235000011941 Tilia x europaea Nutrition 0.000 description 5
- 239000001110 calcium chloride Substances 0.000 description 5
- 229910001628 calcium chloride Inorganic materials 0.000 description 5
- 239000004571 lime Substances 0.000 description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- 235000019353 potassium silicate Nutrition 0.000 description 4
- 235000010288 sodium nitrite Nutrition 0.000 description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 4
- LDMOEFOXLIZJOW-UHFFFAOYSA-N 1-dodecanesulfonic acid Chemical compound CCCCCCCCCCCCS(O)(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 229920005646 polycarboxylate Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- FOGYNLXERPKEGN-UHFFFAOYSA-N 3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfopropyl)phenoxy]propane-1-sulfonic acid Chemical class COC1=CC=CC(CC(CS(O)(=O)=O)OC=2C(=CC(CCCS(O)(=O)=O)=CC=2)OC)=C1O FOGYNLXERPKEGN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 230000003487 anti-permeability effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 235000013877 carbamide Nutrition 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 150000004683 dihydrates Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005552 sodium lignosulfonate Polymers 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- UPCXAARSWVHVLY-UHFFFAOYSA-N tris(2-hydroxyethyl)azanium;acetate Chemical compound CC(O)=O.OCCN(CCO)CCO UPCXAARSWVHVLY-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- DETXZQGDWUJKMO-UHFFFAOYSA-N 2-hydroxymethanesulfonic acid Chemical compound OCS(O)(=O)=O DETXZQGDWUJKMO-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 101100002917 Caenorhabditis elegans ash-2 gene Proteins 0.000 description 1
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 229910001586 aluminite Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 description 1
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 1
- AMAICRYCMCVAHT-UHFFFAOYSA-K calcium;sodium;trichloride Chemical compound [Na+].[Cl-].[Cl-].[Cl-].[Ca+2] AMAICRYCMCVAHT-UHFFFAOYSA-K 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229910001653 ettringite Inorganic materials 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 239000011396 hydraulic cement Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical class NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229940045136 urea Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/006—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mineral polymers, e.g. geopolymers of the Davidovits type
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00293—Materials impermeable to liquids
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/29—Frost-thaw resistance
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
本发明公开了一种复合胶凝材料及其生产方法，它包括硅酸盐水泥、粉煤灰、钢渣粉、粒化高炉矿渣、火山灰质混合材、硅灰、硫酸盐激发剂、碱性激发剂、外加剂等，通过混磨、搅拌等工艺得到所需粉体；它具有早强高、和易性好、抗冻抗渗性能好，废弃物的掺量高、不污染环境等优点，同时能有效提高混凝土的稳定性，成本低廉，工艺简单，可作为高性能复合水泥使用或用作高性能混凝土的胶结料。
Description
技术领域
本发明属于胶凝材料技术领域，特别涉及一种利用粉煤灰和工业矿渣生产的复合胶凝材料及其生产方法。
背景技术
粉煤灰和矿渣固体废弃物的处理与利用已倍受世界各国的关注，我国历年积累的废弃物总量已超过亿吨，大量的废弃物未经任何有效处理进行排放，占用耕地、污染环境，因此彻底治理污染，使废渣变废为宝，是我们义不容辞的历史使命。在我国常采用原状粉煤灰或磨细矿渣作为水泥的混合材及混凝土的掺合料，由于技术上的原因，粉煤灰和矿渣作为原材料生产胶凝材料时，参量低、活性不高、稳定性差，影响建筑工程的质量；虽然现在粉煤灰的激发与活化研究的方法较多，主要是机械磨细法、石灰碱激发法、蒸养法，采用这些方法生产成本较高、投资大、工艺复杂，大规模应用一直没有得到突破。
发明内容
本发明所要解决的技术问题是：提供一种综合利用粉煤灰或矿渣等废弃物生产早强高、和易性好、抗冻抗渗性能好的复合胶凝材料；废弃物的掺量高、不产生环境污染，可以有效提高胶凝材料的性能和砼的稳定性，加速胶凝材料的早期水化，保证后期强度的稳定性，可以作为高性能复合水泥或高性能砼的胶结料。
解决其技术问题所采用的技术方案是：
一种复合胶凝材料包括硅酸盐水泥和粉煤灰，其特征在于各组份的重量百分比为：硅酸盐水泥20-70％，粉煤灰10-55％，活性材0-65％，硫酸盐激发剂0.5-8％，碱性激发剂0.5-15％，复合外加剂0.05-3.5％，减水剂0-1％，引气剂0-0.025％；所述活性材包括钢渣粉、粒化高炉矿渣、火山灰质混合材、硅灰等，它们可以单独使用或组合使用；所述复合外加剂包括早强剂、助磨剂、阻锈剂等，选取其中两种或两种以上进行组合使用。
所述的硫酸盐激发剂包括二水石膏、半水石膏、无水石膏、磷石膏、氟石膏、芒硝等，它们可以单独使用或组合使用，优选使用二水石膏。
所述的碱性激发剂包括石灰、水玻璃、氢氧化钠、氢氧化钾等，它们可以单独使用或组合使用，优选使用石灰或水玻璃。
所述复合外加剂中的早强剂包括氯盐类，例如氯化钠、氯化钙、氯化铝等；硫酸盐类，例如硫酸钠、硫酸钙、硫酸铝、硫酸铝钾等；水溶性有机化合物类，例如三乙醇胺、甲酸盐、乙酸盐、丙酸盐、甲醇、乙醇等，它们可以单独使用或组合使用。该早强剂可优选为氯化钙、氯化铝、硫酸钙、硫酸铝或三乙醇胺，更优选为氯化钙或硫酸钙。
所述复合外加剂中的助磨剂包括醇类，例如乙二醇、丙二醇等；醇胺类，例如三乙醇胺下脚料、三乙醇胺、三异丙醇胺、醋酸三乙醇胺、二乙醇胺、N，N-二甲基乙醇胺、乙醇胺等；木质素磺酸盐类，例如木质素磺酸钠；烷基磺酸盐类，例如十二烷基苯磺酸钠；脂肪酸及其盐类，例如甲酸、硬脂酸、油酸、尿素等，它们可以单独使用或组合使用。该助磨剂可优选为三乙醇胺下脚料、三乙醇胺、尿素或十二烷基苯磺酸钠，更优选为三乙醇胺或十二烷基苯磺酸钠。
所述复合外加剂中的阻锈剂包括亚硝酸/硝酸盐，例如亚硝酸钠、硝酸钙等；磷酸盐，例如磷酸钠、磷酸钙等；氯铝酸盐，例如氯铝酸钙；苯甲酸盐，例如苯甲酸钠，它们可以单独使用或组合使用。该阻锈剂可优选为亚硝酸钠、硝酸钙或氯铝酸钙，更优选为硝酸钙。
所述减水剂包括木质素磺酸盐类，例如木质素磺酸钙、木质素磺酸钠、木质素磺酸镁、丹宁等；多环芳香族磺酸盐类，例如萘和萘的同系磺化物与甲醛缩合物的盐、胺基磺酸盐等；水溶性树脂磺酸盐类，例如磺化三聚氰胺树脂、磺化古码隆树脂等；脂肪族类，例如聚羧酸盐、聚丙烯酸盐、脂肪族羟甲基磺酸盐高缩聚物、脂肪醇聚氧乙烯醚硫酸盐等，它们可以单独使用或组合使用。该减水剂可优选为木质素磺酸钙、萘磺化物与甲醛缩合物的盐、聚羧酸盐或脂肪醇聚氧乙烯醚硫酸盐，更优选为木质素磺酸钙或脂肪醇聚氧乙烯醚硫酸盐。
所述引气剂包括松香树脂类，例如松香热聚物、松香皂等；烷基和烷基芳烃磺酸盐类，例如十二烷基磺酸盐、烷基苯磺酸盐、烷基苯酚聚氧乙烯醚等；脂肪醇磺酸盐类，例如脂肪醇聚氧乙烯醚、脂肪醇聚氧乙烯磺酸钠、脂肪醇硫酸钠等，它们可以单独使用或组合使用。该引气剂可优选为十二烷基磺酸盐或脂肪醇聚氧乙烯磺酸钠。
本发明所述复合胶凝材料的生产方法，包括如下步骤：
(1)按上述配方将粉煤灰、硫酸盐激发剂、碱性激发剂等依次加入磨机，混磨20-80分钟，再依次加入复合外加剂、减水剂、引气剂等，磨至所需细度得到I型磨料，然后将I型磨料和硅酸盐水泥加入混合机，搅拌均匀，即得A型复合胶凝材料；
(2)也可以按上述配方将粉煤灰、硫酸盐激发剂、碱性激发剂等依次加入磨机，混磨10-50分钟，再加入活性材混磨10-30分钟后，依次加入复合外加剂、减水剂、引气剂等，磨至所需细度得到II型磨料，最后将II型磨料和硅酸盐水泥加入混合机，搅拌均匀，即得B型复合胶凝材料；
上述I型磨料和II型磨料的细度为45um方孔筛筛余不得超过20％。
本发明采用细磨的粉煤灰/活性材不仅具有填料效应和细集料的效应，而且参与了水泥的水化反应，与Ca(OH)2反应生成硅酸钙、铝酸钙等水泥石以及不溶于水的硅铝化合物，有效的堵塞了砼的毛细通道，增加了砼的密实度，提高了砼的耐水性能和抗渗性，提高了砼的强度；同时粉煤灰/活性材取代了大量水泥，改善了混凝土拌和物的流动性和保水性，对废弃的粉煤灰/活性材起到了很好的综合利用；将硫酸盐激发剂和碱性激发剂与粉煤灰/活性材一起混磨，机械磨细与化学激化共同作用，不仅反应速度快，活性高，OH离子能有效激活粉煤灰/活性材中的SiO2和Al2O3生成硅酸钙(C-S-H)和钙矾石，SO4 2-离子的存在有利于Ca(OH)2溶解和OH离子的浓度提高，促进水泥石中水合钙矾石的生成，加速水泥的水化，提高水泥石早期强度，改善砼的内部晶体结构，增强砼致密度和耐久性；同时还加入了复合外加剂、减水剂和引气剂等，加速激化进程，提高激化程度，同时赋予其多功能，具有早强防冻性能、能够有效防止钢筋混凝土中钢筋的锈蚀、原料容易粉磨，改善粉煤灰/活性材与水泥的相容性，提高混凝土的强度、耐久性与和易性。
本发明的有益效果是：采用了较多的粉煤灰/活性材，废弃物得到了很好的综合利用、掺量高、不污染环境、节约资源，贮存和运输方便，同时复合胶凝材料具有早强高、和易性好、抗冻抗渗性能好，高密实度、高耐久性和高均匀性，可有效提高砼的稳定性。
具体实施方式
选用的粉煤灰、钢渣粉、粒化高炉矿渣、火山灰质混合材和硅灰等都是火力发电厂、钢铁厂和冶金厂排放的废渣，经过加工后作为本发明的原料。粉煤灰应符合GB/T 1596-2005的规定；钢渣粉应符合GB/T 20491-2006的规定；粒化高炉矿渣应符合GB/T 18046-2000的规定；火山灰质混合材应符合GB/T2847-2005的规定；硅灰应符合JTJ 275-2000附录A的规定；复合外加剂、减水剂和引气剂应符合JC/T 667-2004和GB 50119-2003的规定；硅酸盐水泥应符合GB 175-1999的规定。
根据工程和客户的实际需要，通过调整发明配方，可以获得所需要的性能指标，下面通过具体实施方式对本发明作进一步说明，但并不意味着对本发明保护范围的限定。
实施例1
采用配方按重量百分比计：52.5级硅酸盐水泥30％，粉煤灰55％，石膏3.09％，石灰9.6％，氯化钙0.5％，三乙醇胺0.5％，亚硝酸钠1％，木质素磺酸钙0.3％，十二烷基磺酸盐0.01％，其中磨料需研磨至45um筛余不大于10％，按照本发明的生产方法进行加工，得到A型复合胶凝材料；经检测其强度指标达到32.5R级。
实施例2
采用配方按重量百分比计：52.5级硅酸盐水泥20％，粉煤灰10％，粒化高炉矿渣65％，石膏1.9％，水玻璃1％，硫酸钙1.5％，三乙醇胺0.05％，脂肪醇聚氧乙烯醚硫酸钠0.545％，十二烷基磺酸钠0.005％，其中磨料需研磨至45um筛余不大于15％，按照本发明的生产方法进行加工，得到B型复合胶凝材料；经检测其强度指标达到42.5R级。
实施例3
采用配方按重量百分比计：42.5级硅酸盐水泥50％，粉煤灰10％，钢渣粉10％，粒化高炉矿渣15％，火山灰质混合材8％，硅灰2％，石膏2.25％，石灰1.5％，氯化钙0.5％，三乙醇胺0.05％，硝酸钙0.5％，木质素磺酸钙0.2％，其中磨料需研磨至45um筛余不大于12％，按照本发明的生产方法进行加工，得到B型复合胶凝材料；经检测其强度指标达到32.5R级。
实施例4
采用配方按重量百分比计：42.5R级硅酸盐水泥40％，粉煤灰30％，粒化高炉矿渣23.5％，芒硝3％，氢氧化钠1％，硫酸铝1％，醋酸三乙醇胺0.1％，氯铝酸钙0.8％，聚羧酸盐0.59％，脂肪醇聚氧乙烯醚0.01％，其中磨料需研磨至45um筛余不大于15％，按照本发明的生产方法进行加工，得到B型复合胶凝材料；经检测其强度指标达到32.5级。
实施例5
采用配方按重量百分比计：52.5级硅酸盐水泥70％，粉煤灰25％，石膏2.5％，水玻璃0.5％，氯化钙0.65％，三乙醇胺0.05％，亚硝酸钠1％，木质素磺酸钙0.3％，其中磨料需研磨至45um筛余不大于10％，按照本发明的生产方法进行加工，得到A型复合胶凝材料；经检测其强度指标达到42.5R级。
上述实施例的强度指标按照GB/T 17671-1999《水泥胶砂强度检验方法》(ISO法)(idt ISO 679：1989)检测，其它指标按照GB 12958-1999《复合硅酸盐水泥》检测。
Claims (2)
1、一种复合胶凝材料包括硅酸盐水泥和粉煤灰，其特征在于各组份的重量百分比为：硅酸盐水泥20-70％，粉煤灰10-55％，活性材0-65％，硫酸盐激发剂0.5-8％，碱性激发剂0.5-15％，复合外加剂0.05-3.5％，减水剂0-1％，引气剂0-0.025％；所述活性材包括钢渣粉、粒化高炉矿渣、火山灰质混合材、硅灰等，它们可以单独使用或组合使用；所述复合外加剂包括早强剂、助磨剂、阻锈剂等，选取其中两种或两种以上进行组合使用。
2、根据权利要求1所述的一种复合胶凝材料的生产方法，其特征在于包括如下步骤：
(1)按上述配方将粉煤灰、硫酸盐激发剂、碱性激发剂等依次加入磨机，混磨20-80分钟，再依次加入复合外加剂、减水剂、引气剂等，磨至所需细度得到I型磨料，然后将I型磨料和硅酸盐水泥加入混合机，搅拌均匀，即得A型复合胶凝材料；
(2)也可以按上述配方将粉煤灰、硫酸盐激发剂、碱性激发剂等依次加入磨机，混磨10-50分钟，再加入活性材混磨10-30分钟后，依次加入复合外加剂、减水剂、引气剂等，磨至所需细度得到II型磨料，最后将II型磨料和硅酸盐水泥加入混合机，搅拌均匀，即得B型复合胶凝材料；
上述I型磨料和II型磨料的细度为45um方孔筛筛余不得超过20％。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009100433878A CN101549977A (zh) | 2009-05-14 | 2009-05-14 | 一种复合胶凝材料及其生产方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009100433878A CN101549977A (zh) | 2009-05-14 | 2009-05-14 | 一种复合胶凝材料及其生产方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101549977A true CN101549977A (zh) | 2009-10-07 |
Family
ID=41154509
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2009100433878A Pending CN101549977A (zh) | 2009-05-14 | 2009-05-14 | 一种复合胶凝材料及其生产方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101549977A (zh) |
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974319A (zh) * | 2010-10-21 | 2011-02-16 | 北京中煤矿山工程有限公司 | 一种井巷注浆和软土压密注浆用双液速凝浆液 |
| CN102154015A (zh) * | 2011-02-10 | 2011-08-17 | 刘建忠 | 地基处理组合物及其地基注入施工方法 |
| CN102648167A (zh) * | 2009-11-26 | 2012-08-22 | 建筑研究和技术有限公司 | 用于制造耐化学性建筑化学产品的无机粘合剂体系 |
| CN102765903A (zh) * | 2012-07-26 | 2012-11-07 | 宁波市胜源技术转移有限公司 | 一种高性能混凝土拌料 |
| CN102863251A (zh) * | 2012-10-10 | 2013-01-09 | 信阳天意节能技术有限公司 | 硅酸盐水泥发泡保温板材或砌块及其制作方法 |
| CN102875099A (zh) * | 2012-10-29 | 2013-01-16 | 中冶建工集团有限公司 | 刚性防水套管快速封堵材料的组成及配比 |
| CN103344540A (zh) * | 2013-06-28 | 2013-10-09 | 武汉理工大学 | 一种连续表征水泥石密实度的装置及测试方法 |
| CN103755197A (zh) * | 2013-12-19 | 2014-04-30 | 柳州正菱集团有限公司 | 一种混凝土早强剂 |
| CN104326720A (zh) * | 2014-10-13 | 2015-02-04 | 武汉钢铁(集团)公司 | 利用钢渣生产胶凝材料的生产方法及胶凝材料 |
| CN105152563A (zh) * | 2015-10-28 | 2015-12-16 | 山东众森科技股份有限公司 | 一种磺酸盐系水泥助磨剂原材料及其制备方法 |
| CN105347755A (zh) * | 2015-11-11 | 2016-02-24 | 浙江大学宁波理工学院 | 高耐久性水泥基复合胶凝材料 |
| CN105645813A (zh) * | 2016-01-22 | 2016-06-08 | 河南城建学院 | 一种桥梁桥面加固水泥添加剂及其制备方法 |
| CN106082902A (zh) * | 2016-06-16 | 2016-11-09 | 济南大学 | 一种金矿尾矿选铁后废渣充填用的复合水泥固化剂 |
| CN106396597A (zh) * | 2016-08-30 | 2017-02-15 | 卓达新材料科技集团威海股份有限公司 | 一种碱激发粉煤灰修补砂浆及其制备方法 |
| CN107344818A (zh) * | 2016-05-06 | 2017-11-14 | 大老板水泥有限公司 | 添加剂和使用所述添加剂生产水泥组合物的方法 |
| CN108191332A (zh) * | 2017-12-29 | 2018-06-22 | 常州思宇知识产权运营有限公司 | 一种轻质保温隔墙板 |
| CN109574615A (zh) * | 2018-11-14 | 2019-04-05 | 湖北冶金地质研究所(中南冶金地质研究所) | 一种石英石泥浆改性磷石膏制备高掺量固废物胶凝材料的方法 |
| CN111320432A (zh) * | 2020-03-31 | 2020-06-23 | 吴军喜 | 一种高性能混凝土 |
| CN112424143A (zh) * | 2018-06-15 | 2021-02-26 | 萨罗德格林巴克有限责任公司 | 包括机械-化学改性的组分的工程混凝土粘合剂组合物及其生产方法 |
| US11021399B2 (en) | 2019-01-23 | 2021-06-01 | United States Gypsum Company | Self-consolidating geopolymer compositions and methods for making same |
| CN114477805A (zh) * | 2021-12-20 | 2022-05-13 | 广东华欣环保科技有限公司 | 一种早强型钢渣胶凝材料 |
| CN115974432A (zh) * | 2023-02-01 | 2023-04-18 | 广东盛瑞科技股份有限公司 | 一种用于水泥土的固废胶凝材料 |
| CN116332544A (zh) * | 2023-03-30 | 2023-06-27 | 广州市建筑科学研究院集团有限公司 | 一种粉煤灰改性剂及其制备方法和应用 |
| CN116675449A (zh) * | 2023-04-10 | 2023-09-01 | 盐城工学院 | 低等级粉煤灰的活化及其制备的水泥材料 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1473785A (zh) * | 2003-08-08 | 2004-02-11 | 鞠秉秀 | 粉煤灰激发剂 |
-
2009
- 2009-05-14 CN CNA2009100433878A patent/CN101549977A/zh active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1473785A (zh) * | 2003-08-08 | 2004-02-11 | 鞠秉秀 | 粉煤灰激发剂 |
Cited By (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102648167A (zh) * | 2009-11-26 | 2012-08-22 | 建筑研究和技术有限公司 | 用于制造耐化学性建筑化学产品的无机粘合剂体系 |
| CN102648167B (zh) * | 2009-11-26 | 2015-11-25 | 建筑研究和技术有限公司 | 用于制造耐化学性建筑化学产品的无机粘合剂体系 |
| CN101974319B (zh) * | 2010-10-21 | 2012-11-14 | 北京中煤矿山工程有限公司 | 一种井巷注浆和软土压密注浆用双液速凝浆液 |
| CN101974319A (zh) * | 2010-10-21 | 2011-02-16 | 北京中煤矿山工程有限公司 | 一种井巷注浆和软土压密注浆用双液速凝浆液 |
| CN102154015A (zh) * | 2011-02-10 | 2011-08-17 | 刘建忠 | 地基处理组合物及其地基注入施工方法 |
| CN102154015B (zh) * | 2011-02-10 | 2013-08-21 | 广东电白建设集团有限公司 | 地基注入施工方法 |
| CN102765903A (zh) * | 2012-07-26 | 2012-11-07 | 宁波市胜源技术转移有限公司 | 一种高性能混凝土拌料 |
| CN102863251B (zh) * | 2012-10-10 | 2014-05-07 | 信阳天意节能技术有限公司 | 硅酸盐水泥发泡保温板材或砌块及其制作方法 |
| CN102863251A (zh) * | 2012-10-10 | 2013-01-09 | 信阳天意节能技术有限公司 | 硅酸盐水泥发泡保温板材或砌块及其制作方法 |
| CN102875099A (zh) * | 2012-10-29 | 2013-01-16 | 中冶建工集团有限公司 | 刚性防水套管快速封堵材料的组成及配比 |
| CN103344540B (zh) * | 2013-06-28 | 2016-02-03 | 武汉理工大学 | 一种连续表征水泥石密实度的测试方法 |
| CN103344540A (zh) * | 2013-06-28 | 2013-10-09 | 武汉理工大学 | 一种连续表征水泥石密实度的装置及测试方法 |
| CN103755197A (zh) * | 2013-12-19 | 2014-04-30 | 柳州正菱集团有限公司 | 一种混凝土早强剂 |
| CN104326720A (zh) * | 2014-10-13 | 2015-02-04 | 武汉钢铁(集团)公司 | 利用钢渣生产胶凝材料的生产方法及胶凝材料 |
| CN105152563A (zh) * | 2015-10-28 | 2015-12-16 | 山东众森科技股份有限公司 | 一种磺酸盐系水泥助磨剂原材料及其制备方法 |
| CN105347755A (zh) * | 2015-11-11 | 2016-02-24 | 浙江大学宁波理工学院 | 高耐久性水泥基复合胶凝材料 |
| CN105645813A (zh) * | 2016-01-22 | 2016-06-08 | 河南城建学院 | 一种桥梁桥面加固水泥添加剂及其制备方法 |
| CN107344818A (zh) * | 2016-05-06 | 2017-11-14 | 大老板水泥有限公司 | 添加剂和使用所述添加剂生产水泥组合物的方法 |
| CN106082902A (zh) * | 2016-06-16 | 2016-11-09 | 济南大学 | 一种金矿尾矿选铁后废渣充填用的复合水泥固化剂 |
| CN106396597A (zh) * | 2016-08-30 | 2017-02-15 | 卓达新材料科技集团威海股份有限公司 | 一种碱激发粉煤灰修补砂浆及其制备方法 |
| CN108191332A (zh) * | 2017-12-29 | 2018-06-22 | 常州思宇知识产权运营有限公司 | 一种轻质保温隔墙板 |
| CN112424143A (zh) * | 2018-06-15 | 2021-02-26 | 萨罗德格林巴克有限责任公司 | 包括机械-化学改性的组分的工程混凝土粘合剂组合物及其生产方法 |
| CN109574615A (zh) * | 2018-11-14 | 2019-04-05 | 湖北冶金地质研究所(中南冶金地质研究所) | 一种石英石泥浆改性磷石膏制备高掺量固废物胶凝材料的方法 |
| US11021399B2 (en) | 2019-01-23 | 2021-06-01 | United States Gypsum Company | Self-consolidating geopolymer compositions and methods for making same |
| CN111320432A (zh) * | 2020-03-31 | 2020-06-23 | 吴军喜 | 一种高性能混凝土 |
| CN114477805A (zh) * | 2021-12-20 | 2022-05-13 | 广东华欣环保科技有限公司 | 一种早强型钢渣胶凝材料 |
| CN114477805B (zh) * | 2021-12-20 | 2023-01-06 | 广东华欣环保科技有限公司 | 一种早强型钢渣胶凝材料 |
| CN115974432A (zh) * | 2023-02-01 | 2023-04-18 | 广东盛瑞科技股份有限公司 | 一种用于水泥土的固废胶凝材料 |
| CN116332544A (zh) * | 2023-03-30 | 2023-06-27 | 广州市建筑科学研究院集团有限公司 | 一种粉煤灰改性剂及其制备方法和应用 |
| CN116675449A (zh) * | 2023-04-10 | 2023-09-01 | 盐城工学院 | 低等级粉煤灰的活化及其制备的水泥材料 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101549977A (zh) | 一种复合胶凝材料及其生产方法 | |
| CN102167558B (zh) | 磷矿工业废渣活性激发用激发剂及其制备方法与应用 | |
| CN108585730B (zh) | 一种高强超硫磷石膏矿渣水泥混凝土及其制备方法 | |
| CN101182141B (zh) | 一种利用铁尾矿制备高强结构材料的方法 | |
| CN100445231C (zh) | 土建材料固化剂及制配方法 | |
| CN102584322B (zh) | 粉煤灰基多孔人造石的制备方法 | |
| CN102515673A (zh) | 固硫灰水泥基自流平材料 | |
| CN108623196A (zh) | 一种石灰激发大掺量工业废渣低碳水泥及其制备方法 | |
| CN104876459A (zh) | 一种粉煤灰活性激发剂及大掺量高钙粉煤灰水泥 | |
| CN112723843A (zh) | 一种弱碱激发镍渣高强混凝土的制备方法 | |
| CN109399975B (zh) | 一种赤泥固硫灰钢渣粉耦合激发胶凝材料及其应用 | |
| CN112110661A (zh) | 一种磷石膏矿渣基水泥的制备方法 | |
| CN110372308A (zh) | 一种钛石膏废渣复合胶凝材料及其应用 | |
| CN113698167A (zh) | 软基加固复合基材及多种类固废常温重组制备软基加固复合基材的方法 | |
| Bazaldua-Medellin et al. | Composite hydraulic binders based on fluorgypsum: Reactions, properties and sustainability | |
| CN109437699B (zh) | 一种使用复合盐溶液和矿渣、粉煤灰制备胶凝材料的方法 | |
| CN101412595A (zh) | 一种利用高岭土尾砂制备混凝土掺合料的方法 | |
| CN101973724A (zh) | 一种膨胀剂 | |
| CN112174553A (zh) | 一种复合激活低钙粉煤灰水泥及其制备方法 | |
| Hu et al. | Preparation of CSH seeds from solid waste and its application as Portland cement accelerator | |
| CN115466098B (zh) | 一种环保高抗裂性抹灰砂浆及其制备方法 | |
| CN102557563A (zh) | 一种低收缩全尾矿细骨料轨枕混凝土及其制备方法 | |
| CN105198337A (zh) | 一种海工水泥砌块的生产方法 | |
| CN116217193A (zh) | 用于岛礁的碱激发全固废海水海砂珊瑚混凝土及制备工艺 | |
| CN109081626A (zh) | 一种混凝土外加剂、制备方法、使用方法及应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: CHANGSHA YUANPENG CHEMICAL TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: LV YUNZHENG Effective date: 20120312 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 410323 CHANGSHA, HUNAN PROVINCE TO: 410008 CHANGSHA, HUNAN PROVINCE |
|
| TA01 | Transfer of patent application right |
Effective date of registration: 20120312 Address after: 410008 Hunan province Changsha Kaifu District, Furong Road Subdistrict Office Community Ying Xia Feng Ting Road two lane 59 Applicant after: Changsha Yuanpeng Chemical Technology Co., Ltd. Address before: 410323, Yongan City, Liuyang Province town of Hunan affluent community ranked 139 Applicant before: Lv Yunzheng |
|
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20091007 |