CN101538743B - Solvent method for biologically preparing bamboo fiber - Google Patents
Solvent method for biologically preparing bamboo fiber Download PDFInfo
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- CN101538743B CN101538743B CN2009101115887A CN200910111588A CN101538743B CN 101538743 B CN101538743 B CN 101538743B CN 2009101115887 A CN2009101115887 A CN 2009101115887A CN 200910111588 A CN200910111588 A CN 200910111588A CN 101538743 B CN101538743 B CN 101538743B
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Abstract
The invention provides a technology for preparing bamboo fiber by 1, 4-butanediol in a solvent method, which comprises the steps of preparing bamboo into bamboo filaments; soaking the bamboo filaments in the solvent and heating to remove lignin, hemicellulose and other impurities on the surface of the cellulose; preparing into coarse bamboo fibre; beating the coarse bamboo fibre, washing with water simultaneously, and then spin-drying through a centrifuge; bleaching and cleaning; conducting mellowing to the bamboo fiber; soft-impressing the bamboo fiber; stowing fermentation and curing, and finally obtaining the bamboo fiber with spinnability after opening and carding. The solvent adopted by the invention has high boiling point and stable chemical property and can be recycled; the whole technological process does not generate black liquor and seriously pollute the environment, and belongs to clean techniques; the obtained natural bamboo fiber has the remarkable advantages of moisture absorption, quick dry, coolness, comfort, antibacterium, deodorization and the like; and the method has low cost and good economic benefit and environmental protection benefit.
Description
Technical field
The invention belongs to weaving and use new material technology field, more specifically relate to a kind of solvent method for biologically preparing bamboo fiber.
Background technology
The preparation of bamboo fiber was still having report in the disclosed patent in the past, and traditional method is to adopt caustic soda to carry out the lignin and the hemicellulose of the process removal bamboo wood of boiling, though made fiber to a certain extent, but equally with paper-making pulping produced a large amount of black liquor, because of black liquor is difficult to administer, bring severe contamination to environment.The present invention adopts solvent method for biologically preparing bamboo fiber, can recycle, and extracts lignin and hemicellulose from spent solvent, has reduced the problem in the environmental protection, in the prior art as yet not relevant for process with solvent method for biologically preparing bamboo fiber.
Summary of the invention
The object of the invention provides a kind of technology for preparing bamboo fiber with solvent method; the boiling point height of the solvent that adopts, chemical property is stable, can recycle; whole technical process does not produce black liquor; not to the environment structure severe contamination, belong to cleaning and give birth to process, obtain natural bamboo fiber; has hydroscopic fast-drying; cool and comfortable and antibacterial and deodouring etc. are significantly a bit, and be with low cost, has good economic benefits and environmental protection benefit.
Solvent method for biologically preparing bamboo fiber of the present invention is characterized in that: the preparation process of described method is:
(1) bamboo prepares the well-thought-out plan silk;
(2) with the bamboo silk through the immersion of solvent, the lignin that adds the heat abstraction cellulose surface, hemicellulose and other impurity; Preparation well-thought-out plan crude fibre
(3) the bamboo crude fibre is beaten water flushing simultaneously, centrifuge dries;
(4) bleaching clean;
(5) bamboo fibre is carried out soft treatment;
(6) with the soft pressure of bamboo fibre;
(7) heap storage fermentation health, the bamboo fiber that can obtain to have spinnability after the shredding combing.
Of the present inventionly be significantly a little: the solvent boiling point height that the present invention adopts, chemical property is stable, can recycle, whole technical process does not produce black liquor, to the environment structure severe contamination, does not belong to process for cleanly preparing.Make bamboo fiber and kept its physical characteristic, the surface still have countless fine grooves, in have cavity, edge crackle is arranged, just as capillary, can between Shun, absorb and evaporate moisture content, moisture absorption, lead wet and permeability occupies first of each fiber, has good deodorization, an anti-ultraviolet function.Can effectively suppress staphylococcus aureus, Candida albicans, Escherichia coli etc., antibiotic rate height.Higher, the good springiness of bamboo fiber intensity, its fabric have good wear resistance, drapability and gas permeability in addition, and good dyeability, bamboo fiber by pure spin or blending after can be used for producing underwear, nightwear, T-shirt, undershirt, gym outfit, socks, infant's clothes etc.Woven fabric is produced jacket, Casual Wear, Western-style clothes suit, shirt, one-piece dress, bedding and towel, bath towel etc.Bamboo fiber also can be used for producing new material products such as foot pad, summer sleeping mat, sofa cloth, carpet, gauze, mouth mask in addition, new technology can be utilized mao bamboon or bamboo kinds such as green bamboo and China pink, high boiling solvent (hbs) is recyclable to be recycled, and has good economic benefit and social benefit.
Description of drawings
Fig. 1 is preparation technology's flow chart of the present invention.
The specific embodiment
The preparation process of described method is:
(1) bamboo prepares the well-thought-out plan silk; Remove behind the surf green on bamboo wood surface to be placed on and add 5 tons of soak at room temperature of water in the fermentation vat after one month newly felling bamboo with 1 ton, bamboo wood is removed ring, and to be split into the wide bamboo chip of 10～20mm along machine direction air-dry, bamboo chip is put into the pressure cooking of heating of band pressure heatable container to be handled, bamboo chip after boiling is handled is by beating or multistage spreading well-thought-out plan silk, the temperature that the pressure cooking of wherein heating is handled is about 190 ℃, and the time is 6～8 hours; The digestion media that adopts is water or organic solvent; The digestion media that adopts when boiling is handled is water or organic solvent; Described organic solvent be for weight concentration 80% 1, the 4-butanediol solution, the consumption of described organic solvent and bamboo chip is by weight 1: 4.5-5.
(2) with the bamboo silk through the immersion of solvent, the lignin that adds the heat abstraction cellulose surface, hemicellulose and other impurity; Preparation well-thought-out plan crude fibre: solvent be weight concentration 65% 1, the 4-butanediol solution, the soak time of described organic solvent 12 hours, soaking temperature is 85 ℃, the consumption of described organic solvent and bamboo silk is 1 by weight: 4.5-5.
(3) the bamboo crude fibre is beaten water flushing simultaneously, centrifuge dries;
(4) bleaching clean: bleaching liquor adopts the H that contains weight concentration 6%
2O
2, weight concentration 0.3%DTPA, weight concentration 1～2%Na
2SiO
3, the aqueous solution of weight concentration 3～4%NaOH, bleaching temperature are 100～110 ℃, the time is 1.5～2 hours.
(5) bamboo fibre is carried out soft treatment: adopt the aqueous solution of the level and smooth silicone oil of weight concentration 5% to heat to 40 fens clock times of 50 ℃ of insulations.
(6) with the soft pressure of bamboo fibre: physics is softening, adopts softener spray oil emulsion to carry out soft pressure.
(7) heap storage fermentation health, temperature is controlled at more than 20 ℃ in the room of heap storage fermentation, and relative humidity is controlled between 50%～70%, the heap storage time: spring and summer was controlled at 5～6 days season, autumn and winter season was controlled at about 10 days, can obtain to have the bamboo fiber of spinnability after the shredding combing.
Below be several embodiments of the present invention, further specify the present invention, but the present invention not only is limited to this.
Embodiment 1
The mao bamboon brush of fresh felling is blue or green, after in the normal temperature pond, soaking one month, go joint to split sheet, again bamboo chip is placed in the autoclaving pot, with 1 ton of over dry bamboo wood, add 5 tons of weight concentrations and be 80% 1, the 4-butanediol aqueous solution, heat to 190 ℃ of constant temperature boilings 8 hours, allow dissolution with solvents remove lignin in the bamboo wood, impurity such as hemicellulose, Separation of Solid and Liquid after the boiling, spent solvent is extracted lignin and hemicellulose, the recovery solvent recycle is used, bamboo chip adopts machinery to beat the well-thought-out plan silk, uses to tremble numb machine the bamboo silk is shaken up, to remove bamboo powder and tabasheer, the bamboo powder of shaking up is Powdered, tabasheer is tiny bulk, becomes loose clean through the bamboo silk of shaking up, and is 80 ℃ with temperature, 1 of weight concentration 65%, 4-butanediol aqueous solution soaking 2 hours, by the dissolution of solvent, make the further delignification of bamboo silk, take off hemicellulose and other impurity, adopt beater that the bamboo silk is beaten, use the hot water injection simultaneously, clean the organic solvent that comprises in the bamboo, recycle, with 1200 rev/mins of dryings of industrial centrifugal machine, the bamboo silk that dries is placed in the bleaching container, adds bleaching liquid, bleaching liquid contains the H of weight concentration 6%
2O
2, the DTPA of weight concentration 0.3%, the Na of weight concentration 1～2%
2SiO
3, the NaOH of weight concentration 3～4% is warmed up to 100 ℃-110 ℃ and bleached 1.5-2 hour, makes the fiber in the bamboo silk obtain softening and bleaching.The hot wash of bleaching back is with 1200 rev/mins of dryings of industrial centrifugal machine.Again the bamboo silk is placed in the container of the pre-heated aqueous solution that contains level and smooth silicone oil weight concentration 5% and carried out soft treatment 40 minutes, take out and dry, carry out the soft pressure in spray oil emulsion limit, limit with softener again, bamboo silk after the soft pressure is carried out heap storage to be handled, temperature generally is controlled at more than 20 ℃ in the room of heap storage fermentation, relative humidity is controlled between 50%～70%, the heap storage time is with seasonal variations, spring and summer generally is controlled at about 5～6 days season, autumn and winter season generally was controlled at about 10 days,, carry out shredding and combing at last, can obtain the bamboo fiber of spinnability.
Embodiment 2
The green bamboo brush of fresh felling is blue or green, after in the normal temperature pond, soaking one month, go joint to split sheet, again bamboo chip is placed in the autoclaving pot, with 1 ton of over dry bamboo wood, add 5 tons of weight concentrations and be 80% 1, the 4-butanediol aqueous solution, heat to 180 ℃ of constant temperature boilings 6 hours, allow dissolution with solvents remove lignin in the bamboo wood, impurity such as hemicellulose, Separation of Solid and Liquid after the boiling, spent solvent is extracted lignin and hemicellulose, reclaiming molten Ji recycles, bamboo chip adopts machinery to beat the well-thought-out plan silk, uses to tremble numb machine the bamboo silk is shaken up, to remove bamboo powder and tabasheer, the bamboo powder of shaking up is Powdered, tabasheer is tiny bulk, becomes loose clean through the bamboo silk of shaking up, and is 80 ℃ with temperature, weight concentration be 65% 1,4-butanediol aqueous solution soaking 2 hours, by the dissolution of solvent, make the further delignification of bamboo silk, take off hemicellulose and other impurity, adopt beater that the bamboo silk is beaten, use the hot water injection simultaneously, clean the organic solvent that comprises in the bamboo, recycle, with 1200 rev/mins of dryings of industrial centrifugal machine, the bamboo silk that dries is placed in the bleaching container, adds bleaching liquid, bleaching liquid contains the H of weight concentration 4%
2O
2, the DTPA of weight concentration 0.3%, the Na of weight concentration 1～2%
2SiO
3, the NaOH of weight concentration 3～4% is warmed up to 100 ℃-110 ℃ and bleached 1.5-2 hour, makes the fiber in the bamboo silk obtain softening and bleaching.The hot wash of bleaching back is with 1200 rev/mins of dryings of industrial centrifugal machine.Again the bamboo silk is placed in the container of the pre-heated aqueous solution that contains level and smooth silicone oil weight concentration 5% and carried out soft treatment 40 minutes, take out and dry, carry out the soft pressure in spray oil emulsion limit, limit with softener again, bamboo silk after the soft pressure is carried out heap storage to be handled, temperature generally is controlled at more than 20 ℃ in the room of heap storage fermentation, relative humidity is controlled between 50%～70%, the heap storage time is with seasonal variations, spring and summer generally is controlled at about 5～6 days season, autumn and winter season generally was controlled at about 10 days, carry out shredding and combing at last, can obtain the bamboo fiber of spinnability.
Embodiment 3
The China pink brush of fresh felling is blue or green, after in the normal temperature pond, soaking one month, go joint to split sheet, again bamboo chip is placed in the autoclaving pot, with 1 ton of over dry bamboo wood, add 4.5 tons of weight concentrations and be 80% 1, the 4-butanediol aqueous solution, heat to 170 ℃ of constant temperature boilings 10 hours, allow dissolution with solvents remove lignin in the bamboo wood, impurity such as hemicellulose, Separation of Solid and Liquid after the boiling, spent solvent is extracted lignin and hemicellulose, reclaim molten Ji and recycle, bamboo chip adopts machinery to beat the well-thought-out plan silk, use and tremble numb machine the bamboo silk is shaken up, to remove bamboo powder and tabasheer, the bamboo powder of shaking up is Powdered, and tabasheer is tiny bulk, become loose clean through the bamboo silk of shaking up, with temperature is 80 ℃, weight concentration be 65% 1,4-butanediol aqueous solution soaking 2 hours is by the dissolution of solvent, make the further delignification of bamboo silk, take off hemicellulose and other impurity, adopt beater that the bamboo silk is beaten, use the hot water injection simultaneously, clean the organic solvent that comprises in the bamboo, recycle,, the bamboo silk that dries is placed in the bleaching container with 1200 rev/mins of dryings of industrial centrifugal machine, add bleaching liquid, bleaching liquid contains the H of weight concentration 6%
2O
2, the DTPA of weight concentration 0.3%, the Na of weight concentration 2%
2SiO
3, the NaOH of weight concentration 3% is warmed up to 100 ℃-110 ℃ and bleached 1.5-2 hour, makes the fiber in the bamboo silk obtain softening and bleaching.The hot wash of bleaching back is with 1200 rev/mins of dryings of industrial centrifugal machine.Again the bamboo silk is placed in the container of the pre-heated aqueous solution that contains level and smooth silicone oil weight concentration 5% and carried out soft treatment 40 minutes, take out and dry, carry out the soft pressure in spray oil emulsion limit, limit with softener again, bamboo silk after the soft pressure is carried out heap storage to be handled, temperature generally is controlled at more than 20 ℃ in the room of heap storage fermentation, relative humidity is controlled between 50%～70%, the heap storage time is with seasonal variations, spring and summer generally is controlled at about 5～6 days season, autumn and winter season generally was controlled at about 10 days, carry out shredding and combing at last, can obtain the bamboo fiber of spinnability.
Claims (5)
1. the method for a solvent method for biologically preparing bamboo fiber, it is characterized in that: the preparation process of described method is:
(1) bamboo prepares the well-thought-out plan silk;
(2) with the bamboo silk through the immersion of solvent, the lignin that adds heat abstraction bamboo silk, hemicellulose and other impurity; Preparation well-thought-out plan crude fibre;
(3) the bamboo crude fibre is beaten water flushing simultaneously, centrifuge dries;
(4) bleaching clean;
(5) bamboo fibre is carried out soft treatment;
(6) with the soft pressure of bamboo fibre;
(7) heap storage fermentation health, the bamboo fiber that can obtain to have spinnability after the shredding combing; The concrete steps of described step (1) are: will newly fell bamboo and remove behind the surf green on bamboo wood surface to be placed on 1 ton and add 5 tons of water soak at room temperature in the fermentation vat after one month, bamboo wood is removed ring, and to be split into the wide bamboo chip of 10～20mm along machine direction air-dry, bamboo chip is put into the pressure cooking of heating of band pressure heatable container handle, the bamboo chip after boiling is handled is by beating or multistage spreading well-thought-out plan silk; The temperature that the described pressure cooking of heating is handled is 190 ℃, and the time is 6～8 hours;
The digestion media that adopts when described boiling is handled is an organic solvent; Described organic solvent be for weight concentration 80% 1, the 4-butanediol aqueous solution, the consumption of described organic solvent and bamboo chip is by weight 1: 4.5-5; Solvent in the described step (2) be weight concentration 65% 1, the 4-butanediol aqueous solution, the soak time of described solvent 2 hours, soaking temperature is 80 ℃, the consumption of described solvent and bamboo silk is 1 by weight: 4.5-5.
2. the method for solvent method for biologically preparing bamboo fiber according to claim 1, it is characterized in that: the bleaching clean of described step (4) is: bleaching liquor adopts the H that contains weight concentration 6%
2O
2, weight concentration 0.3%DTPA, weight concentration 1～2%Na
2SiO
3, the aqueous solution of weight concentration 3～4%NaOH, bleaching temperature are 100～110 ℃, the time is 1.5～2 hours.
3. the method for solvent method for biologically preparing bamboo fiber according to claim 1, it is characterized in that: described step (5) is carried out soft treatment to bamboo fibre: adopt the aqueous solution of the level and smooth silicone oil of weight concentration 5% to heat to 40 fens clock times of 50 ℃ of insulations.
4. the method for solvent method for biologically preparing bamboo fiber according to claim 1 is characterized in that: in the described step (6) with the soft pressure of bamboo fibre: physics is softening, adopts softener spray oil emulsion to carry out soft pressure.
5. the method for solvent method for biologically preparing bamboo fiber according to claim 1, it is characterized in that: the heap storage fermentation health in the described step (7) is: temperature is controlled at more than 20 ℃ in the room of heap storage fermentation, relative humidity is controlled between 50%～70%, the heap storage time: spring and summer was controlled at 5～6 days season, and autumn and winter season was controlled at 10 days.
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| CN2009101115887A CN101538743B (en) | 2009-04-28 | 2009-04-28 | Solvent method for biologically preparing bamboo fiber |
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| CN2009101115887A CN101538743B (en) | 2009-04-28 | 2009-04-28 | Solvent method for biologically preparing bamboo fiber |
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| CN101538743B true CN101538743B (en) | 2011-07-27 |
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Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101700667B (en) * | 2009-11-23 | 2011-05-18 | 福建省世竹环保科技有限公司 | Bamboo fiber material |
| CN102051691B (en) * | 2011-01-14 | 2012-11-28 | 浙江民心生态科技有限公司 | Production process of bamboo fiber |
| US9630337B2 (en) * | 2011-03-21 | 2017-04-25 | Yi Zhang | Production technology for natural bamboo fibers |
| CN102851748A (en) * | 2011-06-28 | 2013-01-02 | 陈友余 | Straw textile fiber technology |
| CN105177721B (en) * | 2015-08-10 | 2017-11-10 | 赵海荣 | A kind of method of bamboo production bamboo cotton |
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| CN106868603A (en) * | 2016-12-23 | 2017-06-20 | 句容市申兔工艺针织厂 | A kind of handling process of fabric bamboo fibre |
| CN108456933B (en) * | 2018-02-08 | 2019-08-02 | 南通大学 | High temperature orients degumming preparation weaving and the composite material method of rich lignin fibre |
| CN109355896A (en) * | 2018-10-22 | 2019-02-19 | 赵海荣 | A kind of softness and method for moisturizing of bamboo cotton |
| CN109537124A (en) * | 2018-12-04 | 2019-03-29 | 江苏金太阳纺织科技股份有限公司 | A kind of bamboo fiber summer sleeping mat and its dyeing and finishing processing method |
| CN110725011B (en) * | 2019-11-11 | 2022-03-22 | 汉寿宏鑫纺织有限公司 | Bamboo fiber preparation process |
| CN112226900A (en) * | 2020-10-13 | 2021-01-15 | 中国林业科学研究院林业新技术研究所 | Bamboo fiber composite material and preparation method and application thereof |
| CN112323146A (en) * | 2020-11-10 | 2021-02-05 | 徐虎根 | Preparation method of efficient bamboo raw refined fiber |
| CN112358216B (en) * | 2020-11-11 | 2022-01-28 | 揭阳市建宝建材有限公司 | Preparation method of cement water reducing agent |
| CN112877853A (en) * | 2020-12-25 | 2021-06-01 | 新乡市护神特种织物有限公司 | Preparation method of rapid air-drying type fiber fabric for garment production |
| CN114571567B (en) * | 2022-03-03 | 2022-09-23 | 广州泰达纤维制品有限公司 | Manufacturing method of degradable fiber and corresponding intelligent production machine |
| CN115305645A (en) * | 2022-08-08 | 2022-11-08 | 济南圣泉集团股份有限公司 | Plant fiber composite spunlace non-woven fabric and preparation method thereof |
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| CN1824851A (en) * | 2005-12-26 | 2006-08-30 | 苏州市利飞纺织品有限公司 | Preparation of original bamboo fiber by bioenzyme method |
| CN101029459A (en) * | 2006-02-27 | 2007-09-05 | 江苏绿陵生态肥有限公司 | Technology for producing ligin by crop straw refuse |
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- 2009-04-28 CN CN2009101115887A patent/CN101538743B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1824851A (en) * | 2005-12-26 | 2006-08-30 | 苏州市利飞纺织品有限公司 | Preparation of original bamboo fiber by bioenzyme method |
| CN101029459A (en) * | 2006-02-27 | 2007-09-05 | 江苏绿陵生态肥有限公司 | Technology for producing ligin by crop straw refuse |
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Application publication date: 20090923 Assignee: Guangdong Zhukang Material Technology Co., Ltd. Assignor: Fujian Haibosi Chmeical Technology Co., Ltd. Contract record no.: 2019440000008 Denomination of invention: Solvent method for biologically preparing bamboo fiber Granted publication date: 20110727 License type: Exclusive License Record date: 20190118 |