CN101523562B - Step chemical mechanical polishing method - Google Patents

Step chemical mechanical polishing method Download PDF

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Publication number
CN101523562B
CN101523562B CN2007800374633A CN200780037463A CN101523562B CN 101523562 B CN101523562 B CN 101523562B CN 2007800374633 A CN2007800374633 A CN 2007800374633A CN 200780037463 A CN200780037463 A CN 200780037463A CN 101523562 B CN101523562 B CN 101523562B
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China
Prior art keywords
polishing
polysilicon
chemical mechanical
mechanical polishing
oxidant
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Expired - Fee Related
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CN2007800374633A
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Chinese (zh)
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CN101523562A (en
Inventor
俞昌
杨春晓
荆建芬
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Anji Microelectronics Shanghai Co Ltd
Anji Microelectronics Co Ltd
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Anji Microelectronics Shanghai Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3205Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
    • H01L21/321After treatment
    • H01L21/32115Planarisation
    • H01L21/3212Planarisation by chemical mechanical polishing [CMP]
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • H01L21/31051Planarisation of the insulating layers
    • H01L21/31053Planarisation of the insulating layers involving a dielectric removal step

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Mechanical Treatment Of Semiconductor (AREA)
  • Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)

Abstract

The invention relates to a substep chemical-mechanical polishing method. The invention has the concrete steps that: first step, a chemical-mechanical polishing solution with polysilicon removal rate larger or equal to 200A/min is used to eliminate most of the polysilicon but not expose surfaces of polysilicon; and the surfaces of the polysilicon and subsequently exposed surfaces of polysilicon and silicon dioxide are polished after the oxidizer is added into the polishing solution. The method can avoid a phialiform dent defect on the surface, cause the flatness of wafers to heighten, and increase the cleanness of the wafers and a polishing pad simultaneously to cause the technology more stable.

Description

Step chemical mechanical polishing method
Technical field
The present invention relates to a kind of step chemical mechanical polishing method.
Technical background
In the polishing process of polysilicon, can there be following problem usually: more too high because polishing speed is selected than (polycrystalline silicon/silicon dioxide), make when last polishing process stops on the silicon dioxide layer, have the dish-shaped recessed damage of polysilicon unavoidably.As shown in Figure 1, a, b are respectively before the polishing and the structure after the polishing among the figure.And this problem can increase the weight of along with the increase of the groove width between the silicon dioxide.This can cause the performance of device and have a strong impact on.
Therefore, solve the dish-shaped recessed damage defective in surface in the polysilicon polishing process, and the removal problem most important.Patent documentation US2003153189 discloses a kind of method of chemico-mechanical polishing and the composition of polishing fluid, reduces the dish-shaped recessed damage of the polysilicon in the oxide groove through adding a kind of anionic polymer, and reduces production costs.Patent documentation US6191039 has disclosed a kind of two step cmp methods, through the control first step and the pH value (9.5~10.5 in second step; 10.2 finishing method~10.35), time and cost that can the reduction polishing, and planarization effect is preferably arranged.
Brief summary of the invention
The objective of the invention is in order to solve in the polishing process of polysilicon; More too high because of the polishing speed selection than (polycrystalline silicon/silicon dioxide), make when last polishing process stops on the silicon dioxide layer, the problem of the dish-shaped recessed damage in surface appears; A kind of dish-shaped recessed damage ratio of defects in surface that reduces is provided; The wafer flatness is increased, and can increase the cleannes on wafer and the polishing pad simultaneously, make the more stable cmp method of technology.
Above-mentioned purpose of the present invention realizes through following technical proposal: first step, adopt to have that polysilicon removes that speed is removed most polysilicon more than or equal to the chemical mechanical polishing liquid of 200A/min but exposed polysilicon surface not; Second step, in this polishing fluid, add oxidant after, polysilicon surface and the polysilicon that comes out subsequently and silica surface are polished.
Among the present invention, make the polysilicon of the first step remove speed belongs to those skilled in the art more than or equal to 200A/min known technology.
In the method for the present invention, the polishing speed possible range of first step polysilicon is 200~10000A/min; Second step, the polishing speed of polysilicon and silicon dioxide is between 10: 1 and 1: 1 than possible range, optimum range is between 5: 1 and 1: 1.
Among the present invention, the end of the first step can be passed through limiting time, or controls end through the terminal point control system.
Among the present invention, described polishing fluid can comprise at least a abrasive grains and water.Described abrasive grains can be selected from one or more in following seven kinds: silicon dioxide, alundum (Al, ceria, zirconium dioxide, carborundum, polytetrafluoroethylene (PTFE).Being weight percentage that the content of described abrasive grains is preferable is less than or equal to 30%.
Among the present invention, described polishing fluid also can comprise other additives of the prior art, removes rate adaptation agent etc. like pH conditioning agent, complexing agent and/or polysilicon.
Among the present invention, described oxidant can be contain thiooxidant, contain the iodine oxidant, brominated oxidant, oxidizer containing chlorine, hydrogen peroxide solution, Peracetic acid or other peroxide etc.What the addition of described oxidant was preferable is weight percentage 0.1~30%.
Positive progressive effect of the present invention is: can avoid the dish-shaped recessed damage defective in surface, the wafer flatness increased, and can increase the cleannes on wafer and the polishing pad simultaneously, make technology more stable.Polishing effect of the present invention is as shown in Figure 2, and a, b are respectively before the polishing and the structure after the polishing among the figure.Its effect will further specify through embodiment.
Summary of the invention
Mode through embodiment further specifies the present invention below, does not therefore limit the present invention among the described scope of embodiments.
Description of drawings
Fig. 1 is in the conventional polysilicon polishing process, the structure of (a) and polishing back (b) before the polishing.
Fig. 2 carries out the polysilicon polishing for adopting the inventive method, the structure of (a) and polishing back (b) before the polishing.
Embodiment 1 step chemical mechanical polishing method
Polishing fluid: 0.1wt.%Al 2O 3, the pH conditioning agent is KOH, water is surplus, pH=11
Oxidant: AMMONIUM PER SULFATE Al 2(S 2O 8) 3
1. polishing fluid is dripped on the PPG CSYMXP-710 polishing pad, front wafer surface is downward, and the contact pad interface with rotating speed difference rotary finishing dish and the rubbing head of 70rpm and 80rpm, applies the downforce of 1psi simultaneously at polished chip back surface, polish.Polysilicon is removed speed: 200A/min.The polishing fluid flow velocity is 100ml/min, limiting time 2 minutes.
2. in polishing fluid, add 0.1wt.%Al 2(S 2O 8) 3, polish the same first step of polishing condition afterwards.
Embodiment 2 step chemical mechanical polishing methods
Polishing fluid: 30wt.%CeO 2, 1.0wt%EDTA, water are surplus, pH=10.
Oxidant: KIO 3
1. polishing fluid is dripped on the PPG CSY MXP-710 polishing pad, front wafer surface is downward, and the contact pad interface with rotating speed difference rotary finishing dish and the rubbing head of 70rpm and 80rpm, applies the downforce of 3psi simultaneously at polished chip back surface, polish.Polysilicon is removed speed: 900A/min.The polishing fluid flow velocity is 100ml/min, limiting time 2 minutes.
2. in polishing fluid, add 10wt.%KIO 3, polish the same first step of polishing condition afterwards.
Embodiment 3 step chemical mechanical polishing methods
Polishing fluid: 10wt.%ZrO 2, 0.1wt.% polysorbate40, water are surplus, pH=11
Oxidant: KBrO 3
1. polishing fluid is dripped on the PPG CSYMXP-710 polishing pad, front wafer surface is downward, and the contact pad interface with rotating speed difference rotary finishing dish and the rubbing head of 70rpm and 80rpm, applies the downforce of 5psi simultaneously at polished chip back surface, polish.Polysilicon is removed speed: 5000A/min.The polishing fluid flow velocity is 100ml/min, limiting time 2 minutes.
2. in polishing fluid, add 15wt.%KBrO 3, polish the same first step of polishing condition afterwards.
Embodiment 4 step chemical mechanical polishing methods
Polishing fluid: 10wt.%SiC, water are surplus, pH=11
Oxidant: KClO 4
1. polishing fluid is dripped on the PPG CSYMXP-710 polishing pad, front wafer surface is downward, and the contact pad interface with rotating speed difference rotary finishing dish and the rubbing head of 100rpm and 97rpm, applies the downforce of 5psi simultaneously at polished chip back surface, polish.Polysilicon is removed speed: 8000A/min.The polishing fluid flow velocity is 100ml/min, limiting time 2 minutes.
2. in polishing fluid, add 20wt.%KClO 4, polish the same first step of polishing condition afterwards.
Embodiment 5 step chemical mechanical polishing methods
Polishing fluid: 10wt.% polytetrafluoroethylene (PTFE), water are surplus, pH=11
Oxidant: Peracetic acid
1. polishing fluid is dripped on the PPG CSYMXP-710 polishing pad, front wafer surface is downward, and the contact pad interface with rotating speed difference rotary finishing dish and the rubbing head of 70rpm and 80rpm, applies the downforce of 3psi simultaneously at polished chip back surface, polish.Polysilicon is removed speed: 2000A/min.The polishing fluid flow velocity is 100ml/min, limiting time 2 minutes.
2. in polishing fluid, add the 30wt.% Peracetic acid, polish the same first step of polishing condition afterwards.
Embodiment 6 step chemical mechanical polishing methods
Polishing fluid: 10wt.% polystyrene, water are surplus, pH=11
Oxidant: methyl ethyl ketone peroxide
1. polishing fluid is dripped on the PPG CSYMXP-710 polishing pad, front wafer surface is downward, and the contact pad interface with rotating speed difference rotary finishing dish and the rubbing head of 70rpm and 80rpm, applies the downforce of 3psi simultaneously at polished chip back surface, polish.Polysilicon is removed speed: 2600A/min.The polishing fluid flow velocity is 100ml/min, limiting time 2 minutes.
2. in polishing fluid, add the 15wt.% methyl ethyl ketone peroxide, polish the same first step of polishing condition afterwards.
Effect embodiment 1 step chemical mechanical polishing method
Polishing fluid: 10wt.%SiO 2, water is surplus, pH=11.
Oxidant: hydrogen peroxide solution.
1. polishing fluid is dripped on the PPG CSYMXP-710 polishing pad, front wafer surface is downward, and the contact pad interface with rotating speed difference rotary finishing dish and the rubbing head of 70rpm and 80rpm, applies the downforce of 3psi simultaneously at polished chip back surface, polish.Polysilicon is removed speed: 2500A/min.The polishing fluid flow velocity is 100ml/min.
2. in polishing fluid, add the 15wt.% hydrogen peroxide solution, polish the same first step of polishing condition afterwards.Polish results is as shown in table 1:
Polysilicon, silicon dioxide are removed speed and are selected ratio in first, second step of table 1 substep polishing method
Step Polysilicon is removed speed (A/min) Silicon dioxide is removed speed (A/min) Select ratio
First step 2500 300 8.3∶1
Second step 900 300 3∶1
Visible by last table; Compare with first step, after second step added oxidant, polysilicon was removed speed and is significantly reduced; And silicon dioxide removal speed is constant; Make the polycrystalline silicon/silicon dioxide remove rate selection and be reduced to 3: 1, thereby can avoid selecting than too high, make the dish-shaped recessed damage of generation polysilicon when last polishing process stops on the silicon dioxide layer because of polycrystalline silicon/silicon dioxide polishing speed than from 8.3: 1.

Claims (4)

1. step chemical mechanical polishing method; It is characterized in that: first step polishes with having the chemical mechanical polishing liquid of polysilicon removal speed more than or equal to 200 dusts/min, and second step adds oxidant in this polishing fluid polishes, and the addition of described oxidant is weight percentage 10~30%; Wherein, Described polishing fluid comprises at least a abrasive grains and water, and described abrasive grains is selected from one or more in following five kinds: ceria, zirconium dioxide; Carborundum, polytetrafluoroethylene and polystyrene.
2. step chemical mechanical polishing method according to claim 1 is characterized in that: the content of described abrasive grains is weight percentage and is less than or equal to 30%.
3. step chemical mechanical polishing method according to claim 1 is characterized in that: described polishing fluid also comprises pH conditioning agent, complexing agent and/or polysilicon and removes the rate adaptation agent.
4. step chemical mechanical polishing method according to claim 1 is characterized in that: described oxidant for contain thiooxidant, contain the iodine oxidant, brominated oxidant, oxidizer containing chlorine, hydrogen peroxide solution, Peracetic acid or other peroxide.
CN2007800374633A 2006-11-17 2007-11-12 Step chemical mechanical polishing method Expired - Fee Related CN101523562B (en)

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Application Number Priority Date Filing Date Title
CN2007800374633A CN101523562B (en) 2006-11-17 2007-11-12 Step chemical mechanical polishing method

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CN200610118463.3 2006-11-17
CNA2006101184633A CN101188197A (en) 2006-11-17 2006-11-17 Step chemical mechanical polishing method
CN2007800374633A CN101523562B (en) 2006-11-17 2007-11-12 Step chemical mechanical polishing method
PCT/CN2007/003196 WO2008058458A1 (en) 2006-11-17 2007-11-12 Multiplestep cmp method

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CN101523562B true CN101523562B (en) 2012-09-19

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CN101906269A (en) * 2009-06-08 2010-12-08 安集微电子科技(上海)有限公司 Slurry for metal chemical and mechanical polishing and using method thereof
CN101992422B (en) * 2009-08-25 2012-07-25 中芯国际集成电路制造(上海)有限公司 Process control method and system of copper chemical mechanical polishing
CN102148130B (en) * 2010-02-09 2012-11-07 上海华虹Nec电子有限公司 Method for improving control capability of surface photoetching process sensitive to external environment
CN105538047B (en) * 2015-12-11 2017-09-22 中国航空工业集团公司北京航空材料研究院 A kind of surface polishing method of the organic transparent products of aviation

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1232290A (en) * 1998-04-15 1999-10-20 世大积体电路股份有限公司 Shallow slot isolating method for avoiding dishing
US6350693B2 (en) * 1997-11-15 2002-02-26 Taiwan Semiconductor Manufacturing Company Method of CMP of polysilicon
US6589099B2 (en) * 2001-07-09 2003-07-08 Motorola, Inc. Method for chemical mechanical polishing (CMP) with altering the concentration of oxidizing agent in slurry
US6645825B1 (en) * 2000-07-12 2003-11-11 Taiwan Semiconductor Manufacturing Company Planarization of shallow trench isolation (STI)
CN1731567A (en) * 2005-06-22 2006-02-08 中国科学院上海微系统与信息技术研究所 IC copper interconnect one-step chemical machinery burnishing technics and relevant nanometer burnishing liquid

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7199056B2 (en) * 2002-02-08 2007-04-03 Applied Materials, Inc. Low cost and low dishing slurry for polysilicon CMP

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6350693B2 (en) * 1997-11-15 2002-02-26 Taiwan Semiconductor Manufacturing Company Method of CMP of polysilicon
CN1232290A (en) * 1998-04-15 1999-10-20 世大积体电路股份有限公司 Shallow slot isolating method for avoiding dishing
US6645825B1 (en) * 2000-07-12 2003-11-11 Taiwan Semiconductor Manufacturing Company Planarization of shallow trench isolation (STI)
US6589099B2 (en) * 2001-07-09 2003-07-08 Motorola, Inc. Method for chemical mechanical polishing (CMP) with altering the concentration of oxidizing agent in slurry
CN1731567A (en) * 2005-06-22 2006-02-08 中国科学院上海微系统与信息技术研究所 IC copper interconnect one-step chemical machinery burnishing technics and relevant nanometer burnishing liquid

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CN101523562A (en) 2009-09-02
WO2008058458A1 (en) 2008-05-22
CN101188197A (en) 2008-05-28

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