CN101518248A - A set of soluble liquid insecticides with acetamiprid as raw material - Google Patents
A set of soluble liquid insecticides with acetamiprid as raw material Download PDFInfo
- Publication number
- CN101518248A CN101518248A CN200810100975A CN200810100975A CN101518248A CN 101518248 A CN101518248 A CN 101518248A CN 200810100975 A CN200810100975 A CN 200810100975A CN 200810100975 A CN200810100975 A CN 200810100975A CN 101518248 A CN101518248 A CN 101518248A
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- CN
- China
- Prior art keywords
- acetamiprid
- soluble liquid
- avermectin
- emamectin
- ivermectin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
The invention discloses a set of new soluble liquid preparations with acetamiprid as a raw material, which are used for preventing and killing pests in crops as well as cotton, vegetables, fruit trees, flowers and plants and other field and industrial crops. The preparations are prepared with a benzene-free complex solubilizer, an emulsifier and a potentiating agent. The invention is characterized by high efficiency, environment protection, safety for manufacturers and users, etc.
Description
The present invention be a kind of be one group of soluble liquid insecticides of raw material with Acetamiprid (acetamiprid).Efficient, the environmental protection novel form that process with carbosulfan, Avermectin, ivermectin, the former powder of emamectin-benzoate, non-toluene solvent, no benzene cosolvent, emulsifier, synergist etc. respectively by the former powder of Acetamiprid.
For many years, the main medicament that uses of China's agricultural insect pests control be the agent of organophosphorous pesticide list or with the cream preparation of other agriculture chemical compoundings.Because long-term single use, pest resistance to insecticide have the trend that increases year by year, preventive effect descends.Be to substitute high-toxic pesticide, and eliminate in the cream preparation and contain the harm of benzene solvent in a large number, press for that development is efficient, low toxicity, new varieties, novel formulation the producer, user and ecotope.Acetamiprid is a kind of chlorination nicotinoyl broad spectrum pesticide, insect is had tag, stomach toxicity and good systemic activity.To Semipteras such as aphid, aleyrodids; Lepidopteras such as leaf miner, leaf roll snout moth's larva; Multiclass insects such as coleoptera are all effective, are a kind of wide spectrum, efficient, long-acting insecticide.We succeed in developing the composite novel form of the present invention through repetition test.
Purpose of the present invention, be to provide a kind of preparation rationally, dispersed, emulsibility is good, to the producer and user's safety, environment amenable soluble liquid insecticides.
Implementation method of the present invention below is described in detail in detail:
In the soluble liquid insecticides of the present invention (by weight percentage), Acetamiprid 1～20%, carbosulfan 1～30%, Avermectin (or ivermectin, emamectin-benzoate) 0.1～10%.No benzene cosolvent 0～30%, emulsifier 1～35%, bleeding agent 0～15%, synergist 0～5%, antioxidant 0.1～1%, all the other are non-toluene solvent.
Carbosulfan of the present invention is the interior suction of a kind of carbamates, broad spectrum disinfestation, kills mite, nematocide.It is the low kind that poisons of carbofuran.
Avermectin of the present invention is the tunning of A Foman streptomycete Streptomyces avermitilis, the mixture of being made up of the homologue of eight structural similarities.The general B that uses more
1a, B
1bMixture.Described ivermectin is the hydrogenating reduction product of Avermectin.Avermectin, ivermectin are to have strong desinsection, acaricidal activity, wide spectrum, efficient, safe agricultural beastly dual-purpose antibiotic.
Emamectin-benzoate of the present invention is a kind of mixture that contains two kinds of Main Ingredients and Appearances, and a kind of is 4 " (table methylamino)-4 " deoxidation Avermectin B greater than 90%
1aWith less than 4 " (table methylamino)-4 " deoxidation Avermectin B of 10%
1bHave now found that emamectin-benzoate is the highest in the known insecticides to the Lepidoptera insecticidal activity.
Emulsifier of the present invention is formulated by two kinds of non-ionic surface active agent 1:0～20.Also can select cationic surfactant for use, anion surfactant is composite forms.
Bleeding agent of the present invention is JFC, CT-901B, azone etc.
Cosolvent of the present invention, solvent are ketone, ester class, the pure ethers except that toluene, dimethylbenzene, mixed xylenes, purified petroleum benzin, any or several mixture in amide-type, the alkane ketone etc.
Synergist of the present invention is any or several mixture in synergy phosphorus, Butacide, the triphenyl phosphate, and the known material of those skilled in the art.
The method for making of this soluble liquid is earlier former powder of Acetamiprid and Avermectin (or ivermectin, emamectin-benzoate) or the former medicine of carbosulfan to be dissolved in the no benzene cosolvent, add synergist, emulsifier, bleeding agent, antioxidant and solvent again, fully stir, after mixing, leave standstill, filter, it is formulated to weigh.
The present invention can provide by following example:
Example one: take by weighing the former powder 5.26kg of 95% Acetamiprid, the former powder 0.56kg of 90% ivermectin adds no benzene cosolvent 10kg, synergist 2kg, it is fully dissolved, add compound emulsifying agent 15kg again, penetrating agent JFC 2kg, antioxidant BHT 0.5kg, add non-toluene solvent to 100kg, behind the stirring and evenly mixing, leave standstill, filter, promptly obtain 5.5% Acetamiprid ivermectin soluble liquid.
Example two: take by weighing the former powder 5.26kg of 95% Acetamiprid, the former powder 0.53kg of 95% Avermectin adds no benzene cosolvent 10kg, synergist 2kg, it is fully dissolved, add compound emulsifying agent 18kg again, bleeding agent CT-901B 10kg, antioxidant BHT 0.5kg, add non-toluene solvent to 100kg, behind the stirring and evenly mixing, leave standstill, filter, promptly obtain 5.5% Acetamiprid Avermectin soluble liquid.
Example three: take by weighing the former powder 5.26kg of 95% Acetamiprid, the former powder 0.33kg of 90% emamectin-benzoate adds no benzene cosolvent 10kg, synergist 2kg, it is fully dissolved, add compound emulsifying agent 14kg again, bleeding agent CT-901B 10kg, antioxidant BHT 0.5kg, add non-toluene solvent to 100kg, behind the stirring and evenly mixing, leave standstill, filter, promptly obtain 5.3% Acetamiprid emamectin-benzoate soluble liquid.
Example four: take by weighing the former powder 2.11kg of 95% Acetamiprid, 90% carbosulfan crude oil 11kg adds no benzene cosolvent 12kg, synergist 2kg, it is fully dissolved, add compound emulsifying agent 16kg again, bleeding agent CT-901B 10kg, antioxidant BHT 0.5kg, add non-toluene solvent to 100kg, behind the stirring and evenly mixing, leave standstill, filter, promptly obtain 12% Acetamiprid carbosulfan soluble liquid.
Adopt the present invention's 5.5% Acetamiprid soluble liquid control vegetable aphid, indoor biometrics the results are shown in following table, and 1500 and 3000 times of soups 24 hours and 48 hours preventive effects are apparently higher than 5% imidacloprid missible oil, and formulation rate obviously reduces.
The indoor biometrics test
Claims (3)
1, a kind of efficient, environment-friendly type Acetamiprid Avermectin (or ivermectin emamectin-benzoate, carbosulfan) agricultural insecticide, its formulation is a soluble liquid, it is characterized in that this formulation dispersiveness, emulsibility are good, adopt non-toluene solvent, auxiliary agent is formulated.
2, the no benzene cosolvent described in the claim 1 for except that benzene, toluene, mixed xylenes to ketone, ester class, alcohols, alcohol ether, the alkane ketone equal solvent of human body safety.
3, the Acetamiprid Avermectin described in the claim 1 (ivermectin emamectin-benzoate, carbosulfan) soluble liquid, it is characterized in that forming content (by weight percentage), Acetamiprid 1～20%, Avermectin (or ivermectin, emamectin-benzoate) 0.1～10%, carbosulfan 1～30%.No benzene cosolvent 0～30%, emulsifier 1～35%, bleeding agent 0～15%, synergist 0～5%, antioxidant 0.1～1%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810100975A CN101518248A (en) | 2008-02-27 | 2008-02-27 | A set of soluble liquid insecticides with acetamiprid as raw material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810100975A CN101518248A (en) | 2008-02-27 | 2008-02-27 | A set of soluble liquid insecticides with acetamiprid as raw material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101518248A true CN101518248A (en) | 2009-09-02 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200810100975A Pending CN101518248A (en) | 2008-02-27 | 2008-02-27 | A set of soluble liquid insecticides with acetamiprid as raw material |
Country Status (1)
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| CN (1) | CN101518248A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102550586A (en) * | 2010-12-22 | 2012-07-11 | 浙江森得保生物制品有限公司 | Special airplane pest control medicine of binary compounds consisting of emamectin benzoate and acetamiprid |
| CN102726433A (en) * | 2011-04-11 | 2012-10-17 | 浙江森得保生物制品有限公司 | Practical formula for controlling American white moth |
| CN102113505B (en) * | 2010-01-05 | 2013-09-11 | 海南正业中农高科股份有限公司 | Composition containing acetamiprid for controlling brontispa longissima |
-
2008
- 2008-02-27 CN CN200810100975A patent/CN101518248A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102113505B (en) * | 2010-01-05 | 2013-09-11 | 海南正业中农高科股份有限公司 | Composition containing acetamiprid for controlling brontispa longissima |
| CN102550586A (en) * | 2010-12-22 | 2012-07-11 | 浙江森得保生物制品有限公司 | Special airplane pest control medicine of binary compounds consisting of emamectin benzoate and acetamiprid |
| CN102726433A (en) * | 2011-04-11 | 2012-10-17 | 浙江森得保生物制品有限公司 | Practical formula for controlling American white moth |
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Legal Events
| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20090902 |