CN101489960B - 用于制备四氟丙烯和五氟丙烯的催化生产方法 - Google Patents

用于制备四氟丙烯和五氟丙烯的催化生产方法 Download PDF

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Publication number
CN101489960B
CN101489960B CN200780026549.6A CN200780026549A CN101489960B CN 101489960 B CN101489960 B CN 101489960B CN 200780026549 A CN200780026549 A CN 200780026549A CN 101489960 B CN101489960 B CN 101489960B
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hfc
catalyst
product mixture
pentafluoropropene
minutes
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Chinese (zh)
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CN101489960A (zh
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M·J·纳帕
V·N·M·劳
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Chemours Co FC LLC
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EI Du Pont de Nemours and Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/132—Halogens; Compounds thereof with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/26—Fluorinating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN200780026549.6A 2006-07-13 2007-07-11 用于制备四氟丙烯和五氟丙烯的催化生产方法 Active CN101489960B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210144189.2A CN102690165B (zh) 2006-07-13 2007-07-11 用于制备四氟丙烯和五氟丙烯的催化生产方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US83093906P 2006-07-13 2006-07-13
US60/830,939 2006-07-13
PCT/US2007/015751 WO2008008350A2 (en) 2006-07-13 2007-07-11 Catalytic production processes for making tetrafluoropropenes and pentafluoropropenes

Related Child Applications (1)

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CN201210144189.2A Division CN102690165B (zh) 2006-07-13 2007-07-11 用于制备四氟丙烯和五氟丙烯的催化生产方法

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CN101489960A CN101489960A (zh) 2009-07-22
CN101489960B true CN101489960B (zh) 2014-03-05

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CN201210144189.2A Active CN102690165B (zh) 2006-07-13 2007-07-11 用于制备四氟丙烯和五氟丙烯的催化生产方法

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Country Status (7)

Country Link
US (2) US7982073B2 (https=)
EP (3) EP2041054B1 (https=)
JP (1) JP5764291B2 (https=)
CN (2) CN101489960B (https=)
ES (1) ES2523694T3 (https=)
RU (1) RU2451659C2 (https=)
WO (1) WO2008008350A2 (https=)

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US8377327B2 (en) * 2006-06-27 2013-02-19 E I Du Pont De Nemours And Company Tetrafluoropropene production processes
CN101578252B (zh) * 2006-09-05 2013-11-27 纳幕尔杜邦公司 1,2,3,3,3-五氟丙烯生产方法
JP5416587B2 (ja) 2006-10-03 2014-02-12 メキシケム、アマンコ、ホールディング、ソシエダッド、アノニマ、デ、カピタル、バリアブレ プロセス
CN103483140B (zh) * 2006-10-31 2015-09-09 纳幕尔杜邦公司 氟丙烷、卤代丙烯以及2-氯-3,3,3-三氟-1-丙烯与hf的共沸组合物和1,1,1,2,2-五氟丙烷与hf的共沸组合物的制备方法
FR2932799B1 (fr) * 2008-06-18 2010-08-13 Arkema France Procede de preparation de composes fluores
US8487145B2 (en) 2009-06-03 2013-07-16 E I De Pont De Nemours And Company Catalysts and process to manufacture 2,3,3,3-tetrafluoropropene
CN102448921B (zh) * 2009-06-03 2014-04-23 纳幕尔杜邦公司 制备2，3，3，3-四氟丙烯的催化剂和方法
PL2516366T3 (pl) 2009-12-23 2017-04-28 Arkema France Katalityczne fluorowanie 1233xf do 1234yf w fazie gazowej
EP2569269A4 (en) * 2010-05-03 2014-01-29 Arkema Inc DEHYDROFLUORINATION OF PENTAFLUORO CANNES FOR FORMING TETRAFLUOROLEFINS
US8513474B2 (en) * 2010-06-24 2013-08-20 Honeywell International Inc. Process for the manufacture of fluorinated olefins
US8263817B2 (en) * 2010-07-06 2012-09-11 E I Du Pont De Nemours And Company Synthesis of 1234YF by selective dehydrochlorination of 244BB
US9724684B2 (en) * 2011-02-21 2017-08-08 The Chemours Company Fc, Llc Selective catalytical dehydrochlorination of hydrochlorofluorocarbons
GB2492847A (en) * 2011-07-15 2013-01-16 Mexichem Amanco Holding Sa A process for reducing TFMA content in R-1234
WO2013099856A1 (ja) * 2011-12-28 2013-07-04 旭硝子株式会社 ２，３，３，３－テトラフルオロプロペンの精製方法、精製装置および製造方法
GB201207666D0 (en) * 2012-05-02 2012-06-13 Mexichem Amanco Holding Sa Process
KR101500655B1 (ko) 2013-09-17 2015-03-12 한국과학기술연구원 금속불소화물 촉매 제조방법 및 이를 이용한 탈불산화 방법
GB2519572B (en) 2013-10-25 2015-12-30 Mexichem Amanco Holding Sa Process for isomerising (hydro)(halo)fluoroalkenes
MX383780B (es) * 2014-02-13 2025-03-14 Fram Group Ip Llc Composición y método para la fabricación de un aislante para una bujía.
CN110845295A (zh) 2014-08-14 2020-02-28 科慕埃弗西有限公司 通过脱氟化氢来制备E-1，3，3，3-四氟丙烯(HFC-1234ze)的方法
GB2540427B (en) 2015-07-17 2017-07-19 Mexichem Fluor Sa De Cv Process for the preparation of 2,3,3,3-tetrafluoropropene (1234yf)
GB201615197D0 (en) 2016-09-07 2016-10-19 Mexichem Fluor Sa De Cv Catalyst and process using the catalyst
GB201615209D0 (en) 2016-09-07 2016-10-19 Mexichem Fluor Sa De Cv Catalyst and process using the catalyst
CN108014827A (zh) * 2017-12-12 2018-05-11 西安近代化学研究所 一种高比表面纳米氟氧铬催化剂的制备方法
GB2580623A (en) 2019-01-17 2020-07-29 Mexichem Fluor Sa De Cv Method

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US5679875A (en) * 1992-06-05 1997-10-21 Daikin Industries, Ltd. Method for manufacturing 1,1,1,2,3-pentafluoropropene 1,1,1,2,3-pentafluoropropane

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US3258500A (en) 1959-08-17 1966-06-28 Du Pont Process for fluorinating halohydro-carbons
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US4828818A (en) 1987-03-13 1989-05-09 Allied-Signal Inc. Chromium aerogel method of producing same and fluorinating process utilizing same
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US5396000A (en) * 1993-05-24 1995-03-07 E. I. Du Pont De Nemours And Company Process for the manufacture of 1,1,1,2,3,-pentafluoropropane
JP4378779B2 (ja) * 1998-07-17 2009-12-09 ダイキン工業株式会社 含フッ素エタンの製造方法
US6124510A (en) * 1998-07-21 2000-09-26 Elf Atochem North America, Inc. 1234ze preparation
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CN1972887B (zh) * 2004-04-29 2010-10-13 霍尼韦尔国际公司 1,3,3,3-四氟丙烯的合成方法
US7897823B2 (en) * 2004-10-29 2011-03-01 E. I. Du Pont De Nemours And Company Process for production of azeotrope compositions comprising hydrofluoroolefin and hydrogen fluoride and uses of said azeotrope compositions in separation processes
US7423188B2 (en) 2005-11-01 2008-09-09 E. I. Du Pont De Nemours And Company Azeotrope compositions comprising E-1,3,3,3-tetrafluoropropene and hydrogen fluoride and uses thereof
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RU2445302C2 (ru) 2006-06-27 2012-03-20 Е.И. Дюпон Де Немур Энд Компани Способы получения тетрафторпропена
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Also Published As

Publication number Publication date
US7982073B2 (en) 2011-07-19
EP2041054A2 (en) 2009-04-01
CN101489960A (zh) 2009-07-22
WO2008008350A2 (en) 2008-01-17
CN102690165A (zh) 2012-09-26
EP2386533A1 (en) 2011-11-16
EP2386534A1 (en) 2011-11-16
JP2009542812A (ja) 2009-12-03
CN102690165B (zh) 2015-08-19
US8148586B2 (en) 2012-04-03
EP2041054B1 (en) 2014-08-27
ES2523694T3 (es) 2014-11-28
RU2009104933A (ru) 2010-08-20
JP5764291B2 (ja) 2015-08-19
RU2451659C2 (ru) 2012-05-27
US20100004492A1 (en) 2010-01-07
WO2008008350A3 (en) 2008-03-13
US20110237845A1 (en) 2011-09-29

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Effective date of registration: 20180105

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Patentee before: E. I. du Pont de Nemours and Co.

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