CN101469101A - 一种无卤低烟阻燃abs树脂及其制备方法 - Google Patents
一种无卤低烟阻燃abs树脂及其制备方法 Download PDFInfo
- Publication number
- CN101469101A CN101469101A CNA2007101728707A CN200710172870A CN101469101A CN 101469101 A CN101469101 A CN 101469101A CN A2007101728707 A CNA2007101728707 A CN A2007101728707A CN 200710172870 A CN200710172870 A CN 200710172870A CN 101469101 A CN101469101 A CN 101469101A
- Authority
- CN
- China
- Prior art keywords
- abs resin
- halogen
- low smoke
- free low
- retardant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title claims abstract description 45
- 239000003063 flame retardant Substances 0.000 title claims abstract description 44
- 239000000779 smoke Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 40
- 238000002156 mixing Methods 0.000 claims abstract description 18
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 12
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 12
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 8
- 239000011574 phosphorus Substances 0.000 claims abstract description 8
- 238000001816 cooling Methods 0.000 claims abstract description 6
- 150000002736 metal compounds Chemical class 0.000 claims abstract description 3
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 20
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- 235000006708 antioxidants Nutrition 0.000 claims description 10
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 8
- 229940059574 pentaerithrityl Drugs 0.000 claims description 8
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 8
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 7
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 7
- 150000002989 phenols Chemical class 0.000 claims description 7
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 7
- 229910000765 intermetallic Inorganic materials 0.000 claims description 6
- 229920005862 polyol Polymers 0.000 claims description 6
- 150000003077 polyols Chemical class 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 5
- 239000008188 pellet Substances 0.000 claims description 5
- 238000010008 shearing Methods 0.000 claims description 5
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 claims description 4
- WWNGFHNQODFIEX-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate;styrene Chemical compound C=CC=C.COC(=O)C(C)=C.C=CC1=CC=CC=C1 WWNGFHNQODFIEX-UHFFFAOYSA-N 0.000 claims description 4
- 229920000578 graft copolymer Polymers 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
- 229910017090 AlO 2 Inorganic materials 0.000 claims description 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 230000003068 static effect Effects 0.000 claims description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 238000005086 pumping Methods 0.000 claims description 2
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 2
- 229920001897 terpolymer Polymers 0.000 claims description 2
- 239000013638 trimer Substances 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 239000002994 raw material Substances 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 4
- 229910052736 halogen Inorganic materials 0.000 abstract description 4
- 150000002367 halogens Chemical class 0.000 abstract description 4
- -1 crystalline silica aluminate Chemical class 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 238000002485 combustion reaction Methods 0.000 abstract description 2
- 229910002026 crystalline silica Inorganic materials 0.000 abstract 1
- 238000005520 cutting process Methods 0.000 abstract 1
- 238000001125 extrusion Methods 0.000 abstract 1
- 230000004927 fusion Effects 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 231100000053 low toxicity Toxicity 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 4
- 239000002184 metal Substances 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 229910000039 hydrogen halide Inorganic materials 0.000 description 2
- 239000012433 hydrogen halide Substances 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 101100257124 Caenorhabditis elegans sma-10 gene Proteins 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000005662 electromechanics Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002193 fatty amides Chemical class 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/505—Screws
- B29C48/625—Screws characterised by the ratio of the threaded length of the screw to its outside diameter [L/D ratio]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
原料 | 重量份数 |
ABS | 60 |
SMA | 10 |
聚磷酸铵APP | 22.5 |
季戊四醇PER | 7.5 |
晶体硅铝酸盐Zeolites | 1 |
MnSO4·H2O | 1 |
Irganox 1076 | 0.2 |
Irgafos 168 | 0.5 |
N,N′-乙撑双脂肪酰胺 | 0.5 |
弯曲强度(MPa) | 52 |
弯曲模量(Mpa) | 2810 |
Charpy缺口冲击强度(KJ/m2) | 5.4 |
烟密度(Dm) | 200 |
阻燃性UL94(1.6mm) | FV-0 |
燃烧后卤化氢气体(mg/g) | 0 |
弯曲强度(MPa) | 50 | 55 |
弯曲模量(Mpa) | 2760 | 2790 |
Charpy缺口冲击强度(KJ/m2) | 6.0 | 4.5 |
烟密度(Dm) | 400 | 180 |
阻燃性UL94(1.6mm) | FV-1 | FV-0 |
燃烧后卤化氢气体(mg/g) | 0 | 0 |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2007101728707A CN101469101B (zh) | 2007-12-24 | 2007-12-24 | 一种无卤低烟阻燃abs树脂及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2007101728707A CN101469101B (zh) | 2007-12-24 | 2007-12-24 | 一种无卤低烟阻燃abs树脂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101469101A true CN101469101A (zh) | 2009-07-01 |
CN101469101B CN101469101B (zh) | 2012-05-30 |
Family
ID=40826915
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2007101728707A Expired - Fee Related CN101469101B (zh) | 2007-12-24 | 2007-12-24 | 一种无卤低烟阻燃abs树脂及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101469101B (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102259877A (zh) * | 2011-05-24 | 2011-11-30 | 四川春飞精细化工有限公司 | 超细铝硅酸共晶体阻燃剂及其生产方法 |
CN102532781A (zh) * | 2010-12-07 | 2012-07-04 | 合肥杰事杰新材料股份有限公司 | 一种高光泽耐刮擦abs类树脂及其制备方法 |
CN109735049A (zh) * | 2019-01-30 | 2019-05-10 | 五邑大学 | 一种改性勃姆石无卤阻燃abs复合材料及其制备方法 |
-
2007
- 2007-12-24 CN CN2007101728707A patent/CN101469101B/zh not_active Expired - Fee Related
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102532781A (zh) * | 2010-12-07 | 2012-07-04 | 合肥杰事杰新材料股份有限公司 | 一种高光泽耐刮擦abs类树脂及其制备方法 |
CN102259877A (zh) * | 2011-05-24 | 2011-11-30 | 四川春飞精细化工有限公司 | 超细铝硅酸共晶体阻燃剂及其生产方法 |
CN109735049A (zh) * | 2019-01-30 | 2019-05-10 | 五邑大学 | 一种改性勃姆石无卤阻燃abs复合材料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN101469101B (zh) | 2012-05-30 |
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Owner name: HEFEI GENIUS NEW MATERIAL CO., LTD. Free format text: FORMER OWNER: SHANGHAI GENIUS ADVANCED MATERIAL (GROUP) CO., LTD. Effective date: 20110324 |
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Free format text: CORRECT: ADDRESS; FROM: 201109 NO. 800, BEISONG ROAD, MINHANG DISTRICT, SHANGHAI TO: 230601 NO. 2388, LIANHUA ROAD, ECONOMIC AND TECHNOLOGICAL DEVELOPMENT ZONE, HEFEI CITY, ANHUI PROVINCE |
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Effective date of registration: 20110324 Address after: 230601 No. 2388 Lianhua Road, Hefei Economic Development Zone, Anhui, China Applicant after: Hefei Genius New Materials Co., Ltd. Address before: 201109 Minhang District North Road, Shanghai, No. 800 Applicant before: Shanghai Genius Advanced Material (Group) Co., Ltd. |
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Denomination of invention: Halogen-free low smoke flame-retardant ABS resin and preparation thereof Effective date of registration: 20150810 Granted publication date: 20120530 Pledgee: Hefei Xingtai financing Company limited by guarantee Pledgor: Hefei Genius New Materials Co., Ltd. Registration number: 2015340000013 |
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Date of cancellation: 20161121 Granted publication date: 20120530 Pledgee: Hefei Xingtai financing Company limited by guarantee Pledgor: Hefei Genius New Materials Co., Ltd. Registration number: 2015340000013 |
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