CN101463102B - 基于二烯烃的聚合物的氢化 - Google Patents
基于二烯烃的聚合物的氢化 Download PDFInfo
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- CN101463102B CN101463102B CN2008101866701A CN200810186670A CN101463102B CN 101463102 B CN101463102 B CN 101463102B CN 2008101866701 A CN2008101866701 A CN 2008101866701A CN 200810186670 A CN200810186670 A CN 200810186670A CN 101463102 B CN101463102 B CN 101463102B
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- hydrogenation
- acid
- polymkeric substance
- catalyzer
- monomer
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- 238000005984 hydrogenation reaction Methods 0.000 title claims abstract description 112
- 229920000642 polymer Polymers 0.000 title abstract description 39
- 150000001993 dienes Chemical class 0.000 title abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 94
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003960 organic solvent Substances 0.000 claims abstract description 17
- 229910052751 metal Inorganic materials 0.000 claims abstract description 12
- 239000002184 metal Substances 0.000 claims abstract description 12
- 239000000126 substance Substances 0.000 claims description 73
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 37
- 239000000178 monomer Substances 0.000 claims description 28
- 229910052763 palladium Inorganic materials 0.000 claims description 18
- 229920013649 Paracril Polymers 0.000 claims description 16
- 238000007334 copolymerization reaction Methods 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- 229910052697 platinum Inorganic materials 0.000 claims description 10
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 8
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 8
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 8
- 150000002825 nitriles Chemical class 0.000 claims description 8
- 230000036571 hydration Effects 0.000 claims description 7
- 238000006703 hydration reaction Methods 0.000 claims description 7
- -1 platinum metals Chemical class 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 6
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- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims description 4
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- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 4
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- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
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- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 2
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- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 2
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- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
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- 239000003054 catalyst Substances 0.000 abstract description 26
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- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 10
- 239000002245 particle Substances 0.000 description 10
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- 229910052703 rhodium Inorganic materials 0.000 description 4
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
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- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 3
- 125000005907 alkyl ester group Chemical group 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
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- 229910052760 oxygen Inorganic materials 0.000 description 3
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- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
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- 125000003118 aryl group Chemical group 0.000 description 2
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- 101100030361 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) pph-3 gene Proteins 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
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- 229910052707 ruthenium Inorganic materials 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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- Chemical Kinetics & Catalysis (AREA)
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- Polymers & Plastics (AREA)
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- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Catalysts (AREA)
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Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07123381A EP2075262A1 (en) | 2007-12-17 | 2007-12-17 | Hydrogenation of diene-based polymers |
| EP07123381.1 | 2007-12-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101463102A CN101463102A (zh) | 2009-06-24 |
| CN101463102B true CN101463102B (zh) | 2013-06-19 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008101866701A Expired - Fee Related CN101463102B (zh) | 2007-12-17 | 2008-12-16 | 基于二烯烃的聚合物的氢化 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7897695B2 (enExample) |
| EP (2) | EP2075262A1 (enExample) |
| JP (1) | JP5393129B2 (enExample) |
| KR (1) | KR20090065448A (enExample) |
| CN (1) | CN101463102B (enExample) |
| BR (1) | BRPI0805394A2 (enExample) |
| CA (1) | CA2645576A1 (enExample) |
| TW (1) | TWI432468B (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5338322B2 (ja) * | 2008-01-11 | 2013-11-13 | ダイキン工業株式会社 | 空気調和装置の室内ユニット |
| KR101589353B1 (ko) * | 2010-07-28 | 2016-01-27 | 란세스 도이치란트 게엠베하 | 디엔-기재 중합체의 수소화 |
| WO2017170585A1 (ja) * | 2016-03-31 | 2017-10-05 | 日本ゼオン株式会社 | 金属担持型触媒および水素化共役ジエン系重合体の製造方法 |
| CN114262394B (zh) * | 2020-09-16 | 2023-08-18 | 浙江赞昇新材料有限公司 | 液体氢化丁腈橡胶及其制备方法和应用 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4510293A (en) * | 1982-12-23 | 1985-04-09 | Nippon Zenn Co. Ltd. | Process for hydrogenating conjugated diene polymers |
| CN1834113A (zh) * | 2005-03-18 | 2006-09-20 | 兰科瑟斯有限公司 | 二烯基聚合物的无有机溶剂氢化 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US3454644A (en) | 1966-05-09 | 1969-07-08 | Shell Oil Co | Homogeneous hydrogenation process employing a complex of ruthenium or osmium as catalyst |
| US3700637A (en) * | 1970-05-08 | 1972-10-24 | Shell Oil Co | Diene-nitrile rubbers |
| US4337329A (en) | 1979-12-06 | 1982-06-29 | Nippon Zeon Co., Ltd. | Process for hydrogenation of conjugated diene polymers |
| US4501685A (en) | 1982-09-10 | 1985-02-26 | Johnson Matthey Public Limited Company | Catalytic selective hydrogenation of aliphatic unsaturation in copolymers |
| DE3514403A1 (de) | 1985-04-20 | 1986-10-23 | Bayer Ag, 5090 Leverkusen | Verfahren zur hydrierung nitrilgruppenhaltiger ungesaettigter polymerer |
| JPH01213306A (ja) | 1988-02-22 | 1989-08-28 | Nippon Zeon Co Ltd | 共役ジエン系重合体の水素化方法 |
| US4876314A (en) | 1988-11-09 | 1989-10-24 | Shell Oil Company | Hydrogenation process |
| US4892928A (en) | 1988-10-12 | 1990-01-09 | Shell Oil Company | Hydrogenation process |
| JP2732273B2 (ja) | 1988-12-29 | 1998-03-25 | 日本ゼオン株式会社 | ニトリル基含有水素化重合体の製造方法 |
| JPH02289603A (ja) * | 1989-02-01 | 1990-11-29 | Nippon Zeon Co Ltd | 水素化炭化水素樹脂の連続的製造方法 |
| US5047581A (en) * | 1989-08-25 | 1991-09-10 | Fmc Corporation | Isolation of cis-isomers from isomeric mixtures of cis/transcyclopropanecarboxylates |
| JP2757056B2 (ja) | 1990-03-01 | 1998-05-25 | 日本ゼオン株式会社 | ニトリル基含有不飽和共重合体の水素化方法 |
| US5057581A (en) | 1990-05-02 | 1991-10-15 | University Of Waterloo | Polymer hydrogenation process |
| CS217291A3 (en) | 1990-07-19 | 1992-02-19 | Dsm Nv | Catalyst systems based on palladium for selective hydrogenation of diene polymers and copolymers |
| US5399632A (en) | 1992-09-30 | 1995-03-21 | Exxon Research & Engineering Co. | Hydrogenation process for unsaturated homo and copolymers |
| KR100201228B1 (ko) | 1995-10-17 | 1999-06-15 | 박찬구 | 리빙중합체의 수첨방법 |
| US5705571A (en) | 1996-05-17 | 1998-01-06 | Taiwan Synthetic Rubber Corporation | Process for selective hydrogenation of conjugated diene polymer |
| US5837158A (en) | 1996-09-23 | 1998-11-17 | Sandia Corporation | Polymer formulations for gettering hydrogen |
| US6063307A (en) | 1996-09-23 | 2000-05-16 | Shepodd; Timothy Jon | Polymer system for gettering hydrogen |
| US6110397A (en) | 1998-10-29 | 2000-08-29 | Shepodd; Timothy J. | Polymer formulations for gettering hydrogen |
| KR20010113766A (ko) * | 1999-03-19 | 2001-12-28 | 그래햄 이. 테일러 | 수소화 블록 공중합체 |
| KR100348761B1 (ko) | 1999-11-26 | 2002-08-13 | 금호석유화학 주식회사 | 공액디엔을 포함하는 중합체의 선택적 수소화 방법 |
| CA2329844A1 (en) | 2000-12-28 | 2002-06-28 | Bayer Inc. | Esbo enhanced hydrogenation |
| TW593386B (en) | 2001-06-12 | 2004-06-21 | Bayer Inc | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
| CA2350280A1 (en) | 2001-06-12 | 2002-12-12 | Bayer Inc. | Low molecular weight hydrogenated nitrile rubber |
| TW546307B (en) | 2002-10-25 | 2003-08-11 | Tsrc Corp | Method for hydrogenating conjugated diene polymer |
| US7345115B2 (en) | 2005-03-18 | 2008-03-18 | Lanxess Inc. | Organic solvent-free hydrogenation of diene-based polymers |
-
2007
- 2007-12-17 EP EP07123381A patent/EP2075262A1/en not_active Withdrawn
-
2008
- 2008-11-18 EP EP08169329.3A patent/EP2072534B1/en not_active Not-in-force
- 2008-12-02 CA CA002645576A patent/CA2645576A1/en not_active Abandoned
- 2008-12-11 BR BRPI0805394-4A patent/BRPI0805394A2/pt not_active IP Right Cessation
- 2008-12-16 JP JP2008320190A patent/JP5393129B2/ja not_active Expired - Fee Related
- 2008-12-16 KR KR1020080127716A patent/KR20090065448A/ko not_active Ceased
- 2008-12-16 US US12/335,927 patent/US7897695B2/en not_active Expired - Fee Related
- 2008-12-16 TW TW097148848A patent/TWI432468B/zh not_active IP Right Cessation
- 2008-12-16 CN CN2008101866701A patent/CN101463102B/zh not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4510293A (en) * | 1982-12-23 | 1985-04-09 | Nippon Zenn Co. Ltd. | Process for hydrogenating conjugated diene polymers |
| CN1834113A (zh) * | 2005-03-18 | 2006-09-20 | 兰科瑟斯有限公司 | 二烯基聚合物的无有机溶剂氢化 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2645576A1 (en) | 2009-06-17 |
| TWI432468B (zh) | 2014-04-01 |
| US20090270562A1 (en) | 2009-10-29 |
| US7897695B2 (en) | 2011-03-01 |
| JP2009144159A (ja) | 2009-07-02 |
| TW200942556A (en) | 2009-10-16 |
| BRPI0805394A2 (pt) | 2012-02-22 |
| JP5393129B2 (ja) | 2014-01-22 |
| KR20090065448A (ko) | 2009-06-22 |
| EP2072534A1 (en) | 2009-06-24 |
| EP2075262A1 (en) | 2009-07-01 |
| EP2072534B1 (en) | 2014-01-29 |
| CN101463102A (zh) | 2009-06-24 |
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Effective date of registration: 20151119 Address after: 274000 Shandong city of Heze province Dongming County wusheng Economic Development Zone Patentee after: SHANDONG YUHUANG CHEMICAL Co.,Ltd. Address before: Ontario Patentee before: Lanxess Inc. |
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Address after: 274000 Shandong city of Heze province Dongming County wusheng Economic Development Zone Patentee after: SHANDONG YUHUANG CHEMICAL Co.,Ltd. Address before: 274000 Shandong province Yi Ze wusheng County of Dongming City Economic Development Zone Patentee before: SHANDONG YUHUANG CHEMICAL Co.,Ltd. |
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