CN101423632A - 一种用于发泡材料的组合物和发泡材料 - Google Patents
一种用于发泡材料的组合物和发泡材料 Download PDFInfo
- Publication number
- CN101423632A CN101423632A CNA2007101654756A CN200710165475A CN101423632A CN 101423632 A CN101423632 A CN 101423632A CN A2007101654756 A CNA2007101654756 A CN A2007101654756A CN 200710165475 A CN200710165475 A CN 200710165475A CN 101423632 A CN101423632 A CN 101423632A
- Authority
- CN
- China
- Prior art keywords
- polyethylene
- composition
- foam material
- contact
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 57
- 239000000463 material Substances 0.000 title claims abstract description 15
- 238000005187 foaming Methods 0.000 title claims abstract description 14
- -1 polyethylene, ethylene vinyl acetate Polymers 0.000 claims abstract description 85
- 239000004698 Polyethylene Substances 0.000 claims abstract description 77
- 229920000573 polyethylene Polymers 0.000 claims abstract description 77
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 23
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 22
- 239000006261 foam material Substances 0.000 claims description 57
- 239000003795 chemical substances by application Substances 0.000 claims description 45
- 238000006277 sulfonation reaction Methods 0.000 claims description 24
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 22
- 230000026030 halogenation Effects 0.000 claims description 18
- 238000005658 halogenation reaction Methods 0.000 claims description 18
- 239000000126 substance Substances 0.000 claims description 16
- 230000003647 oxidation Effects 0.000 claims description 14
- 238000007254 oxidation reaction Methods 0.000 claims description 14
- 239000000460 chlorine Substances 0.000 claims description 13
- 229910052801 chlorine Inorganic materials 0.000 claims description 13
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 12
- 229920001684 low density polyethylene Polymers 0.000 claims description 12
- 239000004702 low-density polyethylene Substances 0.000 claims description 12
- 230000004048 modification Effects 0.000 claims description 10
- 238000012986 modification Methods 0.000 claims description 10
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 9
- 229910052736 halogen Inorganic materials 0.000 claims description 9
- 150000002367 halogens Chemical class 0.000 claims description 9
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical group C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 8
- 239000012764 mineral filler Substances 0.000 claims description 8
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- 150000004008 N-nitroso compounds Chemical class 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 230000006835 compression Effects 0.000 abstract description 8
- 238000007906 compression Methods 0.000 abstract description 8
- 239000004088 foaming agent Substances 0.000 abstract description 3
- 229920001903 high density polyethylene Polymers 0.000 description 34
- 239000004700 high-density polyethylene Substances 0.000 description 34
- ZQMIGQNCOMNODD-UHFFFAOYSA-N diacetyl peroxide Chemical compound CC(=O)OOC(C)=O ZQMIGQNCOMNODD-UHFFFAOYSA-N 0.000 description 20
- 238000000034 method Methods 0.000 description 14
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 12
- 239000007789 gas Substances 0.000 description 12
- 238000002156 mixing Methods 0.000 description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 238000005660 chlorination reaction Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- 230000002140 halogenating effect Effects 0.000 description 4
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000005502 peroxidation Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 1
- MEJAPGGFIJZHEJ-UHFFFAOYSA-N 5-acetamido-1,3,4-thiadiazole-2-sulfonyl chloride Chemical compound CC(=O)NC1=NN=C(S(Cl)(=O)=O)S1 MEJAPGGFIJZHEJ-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 1
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 229960001701 chloroform Drugs 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- FAMRKDQNMBBFBR-BQYQJAHWSA-N diethyl azodicarboxylate Chemical compound CCOC(=O)\N=N\C(=O)OCC FAMRKDQNMBBFBR-BQYQJAHWSA-N 0.000 description 1
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- FRVCGRDGKAINSV-UHFFFAOYSA-L iron(2+);octadecanoate Chemical compound [Fe+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O FRVCGRDGKAINSV-UHFFFAOYSA-L 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229940068921 polyethylenes Drugs 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical class NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Description
Claims (11)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2007101654756A CN101423632B (zh) | 2007-10-29 | 2007-10-29 | 一种用于发泡材料的组合物和发泡材料 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2007101654756A CN101423632B (zh) | 2007-10-29 | 2007-10-29 | 一种用于发泡材料的组合物和发泡材料 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101423632A true CN101423632A (zh) | 2009-05-06 |
CN101423632B CN101423632B (zh) | 2011-08-17 |
Family
ID=40614528
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2007101654756A Expired - Fee Related CN101423632B (zh) | 2007-10-29 | 2007-10-29 | 一种用于发泡材料的组合物和发泡材料 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101423632B (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101967244A (zh) * | 2010-10-26 | 2011-02-09 | 浙江理工大学 | 一种抗菌聚乙烯泡沫塑料及其制备方法 |
CN103319790A (zh) * | 2013-03-04 | 2013-09-25 | 鲁奎 | 一种epdm海绵橡胶用发泡剂 |
CN105440416A (zh) * | 2015-12-31 | 2016-03-30 | 浙江万里新材料科技有限公司 | 一种超低压缩永久变形性空调管用材料 |
CN105670082A (zh) * | 2016-03-16 | 2016-06-15 | 湖北祥源新材科技股份有限公司 | 一种吸声材料及其制备工艺 |
CN106632863A (zh) * | 2015-10-30 | 2017-05-10 | 惠州市环美盛新材料有限公司 | 一种非化学交联聚乙烯发泡片及其制备方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1370798A (zh) * | 2001-02-26 | 2002-09-25 | 四川大学 | 辐照交联制备乙烯-醋酸乙烯共聚物/线性低密度聚乙烯泡沫塑料的方法 |
CN100549082C (zh) * | 2006-08-02 | 2009-10-14 | 福州大学 | Eva/pe/淀粉复合发泡材料的制备方法 |
CN100569839C (zh) * | 2007-09-12 | 2009-12-16 | 四川大学 | 臭氧氧化提高eva/pe共混发泡材料性能的方法 |
-
2007
- 2007-10-29 CN CN2007101654756A patent/CN101423632B/zh not_active Expired - Fee Related
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101967244A (zh) * | 2010-10-26 | 2011-02-09 | 浙江理工大学 | 一种抗菌聚乙烯泡沫塑料及其制备方法 |
CN103319790A (zh) * | 2013-03-04 | 2013-09-25 | 鲁奎 | 一种epdm海绵橡胶用发泡剂 |
CN103319790B (zh) * | 2013-03-04 | 2016-04-06 | 鲁奎 | 一种epdm海绵橡胶用发泡剂 |
CN106632863A (zh) * | 2015-10-30 | 2017-05-10 | 惠州市环美盛新材料有限公司 | 一种非化学交联聚乙烯发泡片及其制备方法 |
CN105440416A (zh) * | 2015-12-31 | 2016-03-30 | 浙江万里新材料科技有限公司 | 一种超低压缩永久变形性空调管用材料 |
CN105670082A (zh) * | 2016-03-16 | 2016-06-15 | 湖北祥源新材科技股份有限公司 | 一种吸声材料及其制备工艺 |
CN105670082B (zh) * | 2016-03-16 | 2018-03-23 | 湖北祥源新材科技股份有限公司 | 一种吸声材料及其制备工艺 |
Also Published As
Publication number | Publication date |
---|---|
CN101423632B (zh) | 2011-08-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101423632B (zh) | 一种用于发泡材料的组合物和发泡材料 | |
Ibrahim et al. | Thermoplastic natural rubber blends | |
CN102257047B (zh) | 交联发泡用组合物、交联发泡体及使用其的鞋用中底 | |
CN101597378B (zh) | 一种热塑性动态硫化橡胶的制备方法 | |
CN104231419B (zh) | 高减震乙烯‑醋酸乙烯酯橡胶发泡鞋用材料及其制备方法 | |
US20100099784A1 (en) | Thermoplastic elastomer foaming material | |
CN101148522A (zh) | 自然交联聚乙烯电缆料制造工艺 | |
CN101274999A (zh) | 一种新型复合发泡剂 | |
CN1887929A (zh) | 聚氨酯泡沫用聚醚多元醇的制备方法及制得产品的应用 | |
KR20100114074A (ko) | 분해 가능한 환경친화형 폴리프로필렌 발포 플라스틱 및 그의 제조방법 | |
CN101121792A (zh) | 臭氧氧化提高eva/pe共混发泡材料性能的方法 | |
JP5008965B2 (ja) | 連続気泡発泡体とその製造方法 | |
CN104004259B (zh) | 发泡聚烯烃组合物、聚烯烃泡沫材料及其制备方法和由该组合物制备的制品 | |
CN111925661A (zh) | 一种丁基橡胶/沥青防水材料及其制备方法 | |
US4186163A (en) | Method of manufacturing thermoplastic ionom foam products | |
CN108164977A (zh) | 一种tpu预发泡改性料及其制备方法 | |
TW202229433A (zh) | 具有優異熔融彈性之乙烯乙酸乙烯酯複合樹脂組成物及其應用 | |
CN100484977C (zh) | 一种适于发泡的支化聚丙烯及其制备方法 | |
CN109385017A (zh) | 复合橡胶及其制备方法和其在eva发泡中的应用 | |
EP1238010B1 (en) | Use of a masterbatch to produce a cork | |
CN102492228A (zh) | 发泡橡胶及其制备方法 | |
KR940006459B1 (ko) | 열가소성 수지 발포용 조성물 | |
JP2825886B2 (ja) | 加硫ゴム成形体およびその製造方法 | |
KR102565837B1 (ko) | 발포효율을 개선한 무기화학 발포제 적용 발포체 조성물 | |
KR100357907B1 (ko) | 신발 겉창용 발포체 조성물 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20201210 Address after: No.60, North Third Ring Road, Chengbei Park, Jingjiang Economic Development Zone, Taizhou City, Jiangsu Province, 214500 Patentee after: Jingjiang Lidong Technology Co.,Ltd. Address before: 518119 BYD Industrial Park, Yanan Road, Kwai Chung Town, Longgang District, Guangdong, Shenzhen Patentee before: BYD Co.,Ltd. |
|
CP01 | Change in the name or title of a patent holder | ||
CP01 | Change in the name or title of a patent holder |
Address after: No.60, North Third Ring Road, Chengbei Park, Jingjiang Economic Development Zone, Taizhou City, Jiangsu Province, 214500 Patentee after: Jiangsu Lidong Machinery Technology Co.,Ltd. Address before: No.60, North Third Ring Road, Chengbei Park, Jingjiang Economic Development Zone, Taizhou City, Jiangsu Province, 214500 Patentee before: Jingjiang Lidong Technology Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210903 Address after: 214500 No. 28, Yingbin East Road, Jingjiang City, Taizhou City, Jiangsu Province Patentee after: Jiangsu Huarong Investment Development Co.,Ltd. Address before: No.60, North Third Ring Road, Chengbei Park, Jingjiang Economic Development Zone, Taizhou City, Jiangsu Province, 214500 Patentee before: Jiangsu Lidong Machinery Technology Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20230327 Address after: 214500 No. 28, Yingbin East Road, Jingjiang City, Taizhou City, Jiangsu Province Patentee after: Jingjiang City Chengzhong Village Investment and Construction Co.,Ltd. Address before: 214500 No. 28, Yingbin East Road, Jingjiang City, Taizhou City, Jiangsu Province Patentee before: Jiangsu Huarong Investment Development Co.,Ltd. |
|
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110817 |