CN101422153A - Insecticidal composition containing pymetrozine - Google Patents
Insecticidal composition containing pymetrozine Download PDFInfo
- Publication number
- CN101422153A CN101422153A CNA2008101752876A CN200810175287A CN101422153A CN 101422153 A CN101422153 A CN 101422153A CN A2008101752876 A CNA2008101752876 A CN A2008101752876A CN 200810175287 A CN200810175287 A CN 200810175287A CN 101422153 A CN101422153 A CN 101422153A
- Authority
- CN
- China
- Prior art keywords
- thiophene worm
- pyrrole aphid
- aphid ketone
- worm quinoline
- quinoline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims description 13
- 239000005925 Pymetrozine Substances 0.000 title abstract description 9
- QHMTXANCGGJZRX-WUXMJOGZSA-N pymetrozine Chemical compound C1C(C)=NNC(=O)N1\N=C\C1=CC=CN=C1 QHMTXANCGGJZRX-WUXMJOGZSA-N 0.000 title abstract description 9
- 230000000749 insecticidal effect Effects 0.000 title description 2
- 241001124076 Aphididae Species 0.000 claims abstract description 53
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 claims abstract description 13
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 128
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims description 92
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 74
- 229930192474 thiophene Natural products 0.000 claims description 64
- 150000002576 ketones Chemical class 0.000 claims description 45
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 28
- 239000002917 insecticide Substances 0.000 claims description 14
- 150000001412 amines Chemical class 0.000 claims description 13
- 230000000361 pesticidal effect Effects 0.000 claims description 11
- 229930014345 anabasine Natural products 0.000 claims description 10
- 239000000375 suspending agent Substances 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 7
- 239000004562 water dispersible granule Substances 0.000 claims description 7
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- 239000000575 pesticide Substances 0.000 abstract description 9
- 150000001875 compounds Chemical class 0.000 abstract description 7
- 235000013399 edible fruits Nutrition 0.000 abstract description 6
- 235000013311 vegetables Nutrition 0.000 abstract description 6
- 239000005941 Thiamethoxam Substances 0.000 abstract description 3
- PGOOBECODWQEAB-UHFFFAOYSA-N (E)-clothianidin Chemical compound [O-][N+](=O)\N=C(/NC)NCC1=CN=C(Cl)S1 PGOOBECODWQEAB-UHFFFAOYSA-N 0.000 abstract description 2
- 239000005888 Clothianidin Substances 0.000 abstract description 2
- 241000258937 Hemiptera Species 0.000 abstract description 2
- NWWZPOKUUAIXIW-FLIBITNWSA-N thiamethoxam Chemical compound [O-][N+](=O)\N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-FLIBITNWSA-N 0.000 abstract description 2
- MTXSIJUGVMTTMU-UHFFFAOYSA-N Neonicotine Natural products N1CCCCC1C1=CC=CN=C1 MTXSIJUGVMTTMU-UHFFFAOYSA-N 0.000 abstract 3
- HOKKPVIRMVDYPB-UVTDQMKNSA-N (Z)-thiacloprid Chemical compound C1=NC(Cl)=CC=C1CN1C(=N/C#N)/SCC1 HOKKPVIRMVDYPB-UVTDQMKNSA-N 0.000 abstract 1
- 239000005940 Thiacloprid Substances 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 22
- -1 antifreeze Substances 0.000 description 19
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- 238000009313 farming Methods 0.000 description 12
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- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 8
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 8
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- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 2
- DFPAKSUCGFBDDF-UHFFFAOYSA-N Nicotinamide Chemical compound NC(=O)C1=CC=CN=C1 DFPAKSUCGFBDDF-UHFFFAOYSA-N 0.000 description 2
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- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
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- 241000018137 Trialeurodes vaporariorum Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
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- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
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- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 2
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
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- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
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- VIESAWGOYVNHLV-UHFFFAOYSA-N 1,3-dihydropyrrol-2-one Chemical class O=C1CC=CN1 VIESAWGOYVNHLV-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- SVMKRYZQIZTMPR-UHFFFAOYSA-N 3-[(6-chloropyridin-3-yl)methyl]-2H-1,3-thiazole Chemical class C1=NC(Cl)=CC=C1CN1C=CSC1 SVMKRYZQIZTMPR-UHFFFAOYSA-N 0.000 description 1
- JCUDAMKYTWVICI-UHFFFAOYSA-N 4-benzyl-2,3-dimethylphenol Chemical compound C1=C(O)C(C)=C(C)C(CC=2C=CC=CC=2)=C1 JCUDAMKYTWVICI-UHFFFAOYSA-N 0.000 description 1
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- 241000254173 Coleoptera Species 0.000 description 1
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- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a disinsection compound comprising Pymetrozine, in particular to a disinsection compound of Pymetrozine and a new neonicotine pesticide; wherein, the new neonicotine pesticide is selected one from Thiacloprid, Clothianidin or Thiamethoxam. The compound is mainly characterized in that the weight ratio of the Pymetrozine to the new neonicotine pesticide of the disinsection compound is 0.01 to 100: 1. The invention also relates to application thereof on controlling plant lice and white flies on fruit trees, economic crops and vegetables.
Description
Technical field
The invention belongs to technical field of pesticide, be specifically related to a kind of pyrrole aphid ketone and meta-tolyl-N-methylcarbamate (MTMC), the composite composition of carbaryl, be used to prevent and treat the insect on fruit tree, economic crops, the vegetables.
Background technology
Pyrrole aphid ketone, English name: (pymetrozine), molecular formula: C
10H
11N
5O, chemical name: 4,5-dihydro-6-methyl-4-(3-pyridine methylene amino)-1,2,4-3 (2H)-ketone,
Its structural formula is:
Pyrrole aphid ketone is a kind of sucking pest to be had the very efficient novel insecticide of high selectivity, is mainly used in Bemisia tabaci, the control of insects such as thrips, aphid, trialeurodes vaporariorum, leafhopper, rice fulgorid.Controlling insects such as aphid, plant hopper and trialeurodes vaporariorum on crops field, vegetables field, ornamental plants, fruit tree just is used widely.
Thiophene worm quinoline, English name (thiacloprid0, molecular formula: C
10H
9ClN
4S, chemical name: 3-(6-chloro-3-picolyl)-1,3-thiazoles quinoline-2-base fork cyanamide,
Its structural formula is:
Thiophene worm quinoline is wide spectrum, interior absorption chloro nicotinic insecticide, acts on insect nicotinic acid acetylcholinergic receptor.Be mainly used in paddy rice, fruit, vegetables, cotton and prevent and kill off most of insects.
Thiophene worm piperazine, English name (Thiamethoxam), molecular formula: C
8H
10ClN
5O
3S, chemical name: 3-(2-chloro-5-thiazolyl methyl)-5-methyl-N-nitro-4H-1,3, the 5-tetrahydrochysene,
Structural formula is:
Thiophene worm piperazine is a kind of novel high-efficiency low-toxicity broad spectrum pesticide.Be second generation anabasine insecticide, the mechanism of action is similar to first generation anabasine insecticides such as Imidacloprids, but has higher activity.To insect have stomach toxicity, tag, systemic action, characteristics such as speed of action is fast, the lasting period is long.Better to preventive effects such as sucking pest such as aphid, plant hopper, leafhopper, aleyrodids.
Thiophene worm amine, English name (clothianidin), molecular formula: C
6H
8ClN
5O
2S, chemical name: (E)-1-(2-chloro-1,3-thiazoles-5-ylmethyl)-3-methyl-2-2-nitroguanidine,
Structural formula is:
Thiophene worm amine is a kind of novel nicotinamide insecticide that is used on paddy rice, vegetables, fruit tree and other crop Semiptera, coleoptera, diptera and some Lepidoptera class pest such as control anti-ly eliminates aphis, leafhopper, thrips, plant hopper, have efficient, wide spectrum, consumption is few, toxicity is low (the little poison level of preparation), the drug effect lasting period is long, to crop do not have poisoning, safe in utilization, do not have advantages such as cross resistance with conventional pesticide, remarkable interior suction and osmosis are arranged, and are the another kinds that substitutes high malicious organophosphorous pesticide.
Practical application proves, anabasine insecticides such as thiophene worm piperazine have very strong insecticidal activity, to Homoptera, lepidoptera pest, as aphid, aleyrodid, cotton bollworm etc., increase gradually in the bitch resistance, the agent of agricultural chemicals list descends gradually to the effect of control of insect, and agriculture chemical compounding can obviously provide drug effect, and delays the generation of pest resistance to insecticide.Still find no pass pyrrole aphid ketone and thiophene worm piperazine, thiophene worm quinoline, the composite Pesticidal combination of thiophene worm amine up to now.
Summary of the invention
The purpose of this invention is to provide a kind of Pesticidal combination that contains pyrrole aphid ketone that is used to prevent and treat fruit tree, economic crops, vegetable-crop pest-insect.
Technical scheme of the present invention is:
A kind of Pesticidal combination that contains pyrrole aphid ketone is characterized in that comprising pyrrole aphid ketone and anabasine insecticide, and pyrrole aphid ketone and anabasine insecticide weight ratio are 0.01～100:1.
Described anabasine insecticide is selected from a kind of in thiophene worm quinoline, thiophene worm amine or the thiophene worm piperazine.
Optimum weight part of pyrrole aphid ketone and anabasine insecticide is 1 part～80 parts of pyrrole aphid ketone in the Pesticidal combination that contains pyrrole aphid ketone of the present invention, 1 part～80 parts of anabasines.
The described Pesticidal combination total content that contains pyrrole aphid ketone is 1%～99%.
Said composition adds auxiliary agent and excipients can be made into wetting powder, water dispersible granules, suspending agent, aqueous emulsion, microemulsion, missible oil.
Described auxiliary agent and excipients comprise: dispersant, wetting agent, disintegrant, solvent, emulsifier, antifreeze, defoamer, thickener, filler.
Described dispersant is selected from one or more in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, the fatty acid glyceride APEO.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, DBSA, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, the soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, the sodium bicarbonate.
Described solvent is selected from: N, dinethylformamide, cyclohexanone, toluene, dimethylbenzene, dimethyl sulfoxide (DMSO), methyl alcohol, ethanol, 3-methyl cyclohexanol ketenes, N one octylpyrrolidone, N-pyrrolidones, propyl alcohol, butanols, ethylene glycol, diethylene glycol, ethylene glycol monomethyl ether, butyl ether, ethyl acetate, vegetable oil, acetonitrile one or more.
Described emulsifier is selected from: agricultural newborn 500# (alkyl benzene calcium sulfonate), OP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600# phosphate (phenyl phenol polyoxy ethyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, farming newborn 400# (benzyl dimethyl phenol polyoxy ethyl ether), farming newborn 600# (phenyl phenol polyoxy ethyl ether), Nongru-700 # (alkylphenol-formaldehyde resin polyoxy ethyl ether), peaceful newborn 36# (phenethyl fluosite polyoxy ethyl ether), farming newborn 1600# (phenethyl phenol polyoxy ethyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), farming newborn 33# (alkylaryl polyoxyethylene polyoxypropylene ether), farming newborn 34# (alkylaryl polyoxyethylene poly-oxygen propylene aether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), in the AEO series (the pure APEO of fat) one or more.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, the urea.
Described defoamer is selected from: one or more in silicone oil, silicone compound, C10-20 saturated fat acid compounds, the C8-10 aliphatic alcohols compound.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, the polyvinyl alcohol.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Pesticidal combination of the present invention compared with prior art produces following beneficial effect: (1) is compared with single agent, and said composition has notable synergistic to lepidoptera pest, has obviously improved control efficiency; (2) one medicines are controlled more, and a dispenser can prevent and treat various pests simultaneously and reduce control recruitment cost; (3) alternative height agricultural chemicals, and reduce the field dosage significantly, effectively reduce environmental pollution and residue of pesticide; (4) have concurrently quick-acting and long-acting; (5) reduction is to the toxicity of warm blooded animal; (6) be particularly useful for preventing and treating cotton aphid, the vegetables aleyrodid is remarkably productive.
Embodiment
Below in conjunction with embodiment to further instruction of the present invention.
Embodiment 1:70% pyrrole aphid ketone thiophene worm quinoline wetting powder
Take by weighing pyrrole aphid ketone 30g, thiophene worm quinoline 40g, neopelex 4g, sodium lignin sulfonate 8g, draw back powder 2g, white carbon 8g, kaolin is mended to 100g, above-mentioned formulation material is mixed, in stirred tank, evenly stir, behind airslide disintegrating mill, mixing, promptly can be made into 70% pyrrole aphid ketone thiophene worm quinoline wetting powder.
The part by weight of pyrrole aphid ketone and thiophene worm quinoline can change between 0.01～100:1 (routine 1:69,10:60,90:10,99:1) in the present embodiment, and both total weight items are 70%, form new embodiment.
Thiophene worm quinoline can also be replaced to thiophene worm piperazine, thiophene worm amine forms new embodiment.Embodiment 2:75% pyrrole aphid ketone thiophene worm quinoline water dispersible granules
Take by weighing pyrrole aphid ketone 30g, thiophene worm quinoline 45g, neopelex 3g, sodium lignin sulfonate 9g, diatomite is mended to 100g, formulation material is mixed, pulverize with micro jet, through mediating, add then and carry out granulation, drying, screening in the fluidized bed prilling dryer after sample analysis is made 75% pyrrole aphid ketone thiophene worm quinoline water dispersible granules.
The part by weight of pyrrole aphid ketone and thiophene worm quinoline can change between 0.01～100:1 (routine 1:69,10:60,90:10,99:1) in the present embodiment, and both total weight items are 75%, form new embodiment.
Thiophene worm quinoline can also be replaced to thiophene worm piperazine, thiophene worm amine forms new embodiment.Embodiment 3:35% pyrrole aphid ketone thiophene worm quinoline suspending agent
Pyrrole aphid ketone 15g, thiophene worm quinoline 20g, farming breast 1600
#2g, polycarboxylate 4g, ethylene glycol 4g, polyethylene glycol 1g, silicone oil 0.4g, water is supplied 100g, with back all the other components except that crossing active ingredient in the above-mentioned formulation material, mix through high speed shear, add active ingredient, ball milling is 2～3 hours in ball mill, makes particle diameter all below 5 μ m, makes 35% pyrrole aphid ketone thiophene worm quinoline suspending agent.
The part by weight of pyrrole aphid ketone and thiophene worm quinoline can change between 0.01～100:1 (routine 1:69,10:60,90:10,99:1) in the present embodiment, and both total weight items are 35%, form new embodiment.
Thiophene worm quinoline can also be replaced to thiophene worm piperazine, thiophene worm amine forms new embodiment.Embodiment 4:40% pyrrole aphid ketone thiophene worm quinoline missible oil
Pyrrole aphid ketone 15g, thiophene worm quinoline 25g, dimethyl sulfoxide (DMSO) 10g, cyclohexanone 20g, farming breast 500
#4g, farming breast 600
#4g, Nongru-700
#2g, dimethylbenzene is supplied 100g.Above-mentioned formulation material is mixed, former medicine is dissolved in the organic solvent, add other auxiliary agents such as emulsifier again, under agitation mixed dissolution can make 40% pyrrole aphid ketone thiophene worm quinoline missible oil.
The part by weight of pyrrole aphid ketone and thiophene worm quinoline can change between 0.01～100:1 (routine 1:69,10:60,90:10,99:1) in the present embodiment, and both total weight items are 40%, form new embodiment.
Thiophene worm quinoline can also be replaced to thiophene worm piperazine, thiophene worm amine forms new embodiment.Embodiment 5:20% pyrrole aphid ketone thiophene worm quinoline aqueous emulsion
Pyrrole aphid ketone 8g, thiophene worm quinoline 12g, cyclohexanone 15g, vegetable oil 10g, farming breast 1600
#2g, farming breast 500
#4g, ethylene glycol 4g, polyethylene glycol 1g, silicone oil 0.4g, water is supplied 100g.Above-mentioned formulation material is mixed, active ingredient, solvent, emulsifier, co-emulsifier are added together, make and be dissolved into even oil phase; Water, antifreeze, thickener, defoamer are mixed, become the homogeneous water.Under high-speed stirred, water is added oil phase, can make 20% pyrrole aphid ketone thiophene worm quinoline aqueous emulsion.
The part by weight of pyrrole aphid ketone and thiophene worm quinoline can change between 0.01～100:1 (routine 1:69,10:60,90:10,99:1) in the present embodiment, and both total weight items are 40%, form new embodiment.
Thiophene worm quinoline can also be replaced to thiophene worm piperazine, thiophene worm amine forms new embodiment.
Embodiment 6:15% pyrrole aphid ketone thiophene worm quinoline microemulsion
Pyrrole aphid ketone 6g, thiophene worm quinoline 9g, cyclohexanone 15g, vegetable oil 10g, farming breast 1600
#8g, farming breast 500
#7g, ethylene glycol 4g, silicone oil 0.4g, water is supplied 100g.The compound method of microemulsion: be that emulsifier and water are mixed and made into water, then former medicine under agitation added water, make 15% pyrrole aphid ketone thiophene worm quinoline microemulsion.
The part by weight of pyrrole aphid ketone and thiophene worm quinoline can change between 0.01～100:1 (routine 1:69,10:60,90:10,99:1) in the present embodiment, and both total weight items are 40%, form new embodiment.
Thiophene worm quinoline can also be replaced to thiophene worm piperazine, thiophene worm amine forms new embodiment.
Implementation of an application example one: control rice fulgorid field trial
Medicament: pyrrole aphid ketone Thiamethoxam compound preparation (Shaanxi Welch Crop Protection Co., Ltd. develops, provides); 25% pymetrozine suspension agent (Kesheng Group Co., Ltd., Jiangsu Prov., commercial); 25% thiophene worm piperazine water dispersible granules (just reaching (Suzhou) crop protection Co., Ltd earlier, commercial).
Crop: paddy rice; Subjects: rice fulgorid
The result is as shown in table 1.
From subordinate list 1 as can be seen, 1 day, 3 days, 7 days average preventive effects are 62.83%, 71.14%, 68.17% behind 6 preparation medicines of the present invention; 69.75%, 82.42%, 86.71%; 76.61%, 83.99%, 91.59%; 71%, 81.32%, 88.74%; 71.77%, 85.08%, 90.93%; 75.17%, 85.68%, 92.39%.The preventive effect of contrast medicament 25% pymetrozine suspension agent, 25% thiophene worm piperazine water dispersible granules is respectively 49.02%, 62.75%, 74.08%; 58.71%, 72.08%, 85.06%.The present invention is under the little or essentially identical condition of dosage, and quick-acting, lasting effect and preventive effect are better than contrasting medicament or suitable with the contrast medicament, and in this test dose scope, to rice safety, the medicament that can be used as the control rice fulgorid is fully promoted the use of.
Table 1 is handled chemical control rice hoppers field efficacy
Implementation of an application example two: control cotton aphid field trial
Medicament: pyrrole aphid ketone thiophene worm quinoline complex preparation (Shaanxi Welch Crop Protection Co., Ltd. develops, provides); 25% pymetrozine suspension agent (Kesheng Group Co., Ltd., Jiangsu Prov., commercial); 480 grams per liter thiophene worm quinoline suspending agents (Tianjin Xingguang Agricultural Chemicals Factory, commercial).
Crop: cotton; Subjects: aphid
The result is as shown in table 2.
Table 2 is handled chemical control cotton aphid drug effect
From subordinate list 2 to find out, behind 6 preparation medicines of the present invention 5,10 days, 20 days under the little or essentially identical condition of dosage, quick-acting, lasting effect and preventive effect are better than contrasting medicament or suitable with the contrast medicament, in this test dose scope, to cotton safety, the medicament that can be used as the control cotten aphid is fully promoted the use of.
Implementation of an application example three: control cucumber Bemisia tabaci drug effect
Medicament: pyrrole aphid ketone thiophene worm amine complex preparation (Shaanxi Welch Crop Protection Co., Ltd. develops, provides); 25% pymetrozine suspension agent (Kesheng Group Co., Ltd., Jiangsu Prov., commercial); 50% thiophene worm amine water dispersible granules (SUMITOMO CHEMICAL chemistry pillar commercial firm, commercial).
Crop: cucumber; Subjects: Bemisia tabaci
Result such as table 3 show.
Table 3 is handled chemical control field Bemisia tabaci drug effect
As seen from Table 3, medicament of the present invention is outstanding to the Bemisia tabaci control efficiency, and all owing to contrasting medicament, the lasting period is long, and in test dose, plant growth is normal, and each is handled medicament and poisoning phenomenon to cucumber all do not occur, illustrates that it is safe to cucumber.At present, the emergence control of Bemisia tabaci is mainly answered chemical control, but because the body surface of Bemisia tabaci is had wax, and breeding is fast, generation overlap, very easily develop immunity to drugs, bring many difficulties, so the science medication is very important to chemical control, when selecting for use medicament to carry out emergence control, require mixture preparation that quick-acting is preferably not only arranged, reduce the agricultural chemicals access times, delay pesticide resistance and produce, medicament of the present invention can address that need, thereby has very big promotional value.
Claims (4)
1, a kind of Pesticidal combination that contains pyrrole aphid ketone is characterized in that comprising pyrrole aphid ketone and anabasine insecticide, and pyrrole aphid ketone and anabasine insecticide weight ratio are 0.01～100:1.
2, the pyrrole aphid ketone Pesticidal combination that contains according to claim 1 is characterized in that: described anabasine insecticide is selected from a kind of in thiophene worm quinoline, thiophene worm amine or the thiophene worm piperazine.
3, the Pesticidal combination that contains pyrrole aphid ketone according to claim 1 is characterized in that: the composition total content is 1%～99%.
4,, it is characterized in that said composition can be made into wetting powder, water dispersible granules, suspending agent, aqueous emulsion, microemulsion, missible oil according to the described Pesticidal combination that contains pyrrole aphid ketone of claim 1 to 3.
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Cited By (12)
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| CN101878775A (en) * | 2010-07-15 | 2010-11-10 | 甘波 | Pesticidal composition containing thiacloprid and pymetrozine |
| CN102326566A (en) * | 2011-07-20 | 2012-01-25 | 陕西上格之路生物科学有限公司 | Insecticidal composition containing epoxy insect pyridine and pymetrozine |
| CN102388906A (en) * | 2011-09-30 | 2012-03-28 | 山东京蓬生物药业股份有限公司 | Synergistic insecticidal composition containing clothianidin and pymetrozine, and application thereof |
| CN101569312B (en) * | 2009-06-05 | 2012-05-02 | 贵州大学 | Pesticide compound containing pymetrozine and thiamethoxam, preparation method and application thereof |
| CN101731244B (en) * | 2010-01-25 | 2012-07-04 | 陕西上格之路生物科学有限公司 | Insecticidal composition containing insecticidal piperidine and pymetrozine |
| CN102763669A (en) * | 2012-07-04 | 2012-11-07 | 河北威远生物化工股份有限公司 | Insecticidal pesticide composition |
| CN103329925A (en) * | 2013-07-12 | 2013-10-02 | 安徽美兰农业发展股份有限公司 | Water dispersible granule of thiamethoxam and pymetrozine composite pesticide and preparation method thereof |
| CN103548838A (en) * | 2013-08-21 | 2014-02-05 | 陕西康禾立丰生物科技药业有限公司 | Single-dose pymetrozine and composition thereof |
| CN104336045A (en) * | 2014-10-22 | 2015-02-11 | 合肥星宇化学有限责任公司 | Insecticide composition and preparation and use thereof |
| CN105145612A (en) * | 2015-08-01 | 2015-12-16 | 华中农业大学 | Insecticidal composition containing pymetrozine and thiacloprid and preparation method |
| CN107372664A (en) * | 2017-08-04 | 2017-11-24 | 韦卓熙 | A kind of persistent pesticide |
| CN113712036A (en) * | 2021-08-31 | 2021-11-30 | 山西运城绿康实业有限公司 | Pymetrozine and thiamethoxam compound insecticide and preparation method thereof |
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| CN101569312B (en) * | 2009-06-05 | 2012-05-02 | 贵州大学 | Pesticide compound containing pymetrozine and thiamethoxam, preparation method and application thereof |
| CN101731244B (en) * | 2010-01-25 | 2012-07-04 | 陕西上格之路生物科学有限公司 | Insecticidal composition containing insecticidal piperidine and pymetrozine |
| CN101878775A (en) * | 2010-07-15 | 2010-11-10 | 甘波 | Pesticidal composition containing thiacloprid and pymetrozine |
| CN102326566B (en) * | 2011-07-20 | 2013-08-28 | 陕西上格之路生物科学有限公司 | Insecticidal composition containing epoxy insect pyridine and pymetrozine |
| CN102326566A (en) * | 2011-07-20 | 2012-01-25 | 陕西上格之路生物科学有限公司 | Insecticidal composition containing epoxy insect pyridine and pymetrozine |
| CN102388906A (en) * | 2011-09-30 | 2012-03-28 | 山东京蓬生物药业股份有限公司 | Synergistic insecticidal composition containing clothianidin and pymetrozine, and application thereof |
| CN102763669A (en) * | 2012-07-04 | 2012-11-07 | 河北威远生物化工股份有限公司 | Insecticidal pesticide composition |
| CN103329925A (en) * | 2013-07-12 | 2013-10-02 | 安徽美兰农业发展股份有限公司 | Water dispersible granule of thiamethoxam and pymetrozine composite pesticide and preparation method thereof |
| CN103329925B (en) * | 2013-07-12 | 2014-07-09 | 安徽美兰农业发展股份有限公司 | Water dispersible granule of thiamethoxam and pymetrozine composite pesticide and preparation method thereof |
| CN103548838A (en) * | 2013-08-21 | 2014-02-05 | 陕西康禾立丰生物科技药业有限公司 | Single-dose pymetrozine and composition thereof |
| CN104336045A (en) * | 2014-10-22 | 2015-02-11 | 合肥星宇化学有限责任公司 | Insecticide composition and preparation and use thereof |
| CN104336045B (en) * | 2014-10-22 | 2016-06-01 | 合肥星宇化学有限责任公司 | A kind of insect-killing composition and preparation, purposes |
| CN105145612A (en) * | 2015-08-01 | 2015-12-16 | 华中农业大学 | Insecticidal composition containing pymetrozine and thiacloprid and preparation method |
| CN107372664A (en) * | 2017-08-04 | 2017-11-24 | 韦卓熙 | A kind of persistent pesticide |
| CN113712036A (en) * | 2021-08-31 | 2021-11-30 | 山西运城绿康实业有限公司 | Pymetrozine and thiamethoxam compound insecticide and preparation method thereof |
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Application publication date: 20090506 Assignee: SHAANXI SUNGER ROAD BIO-SCIENCE Co.,Ltd. Assignor: Shaanxi Welch Crop Protection Co.,Ltd. Contract record no.: 2018610000024 Denomination of invention: Insecticidal composition containing pymetrozine Granted publication date: 20130102 License type: Common License Record date: 20181010 |
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| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 715500, Shaanxi County, Pucheng province Chen Town Chemical Industry Park Patentee after: Shaanxi yitianfeng crop Technology Co.,Ltd. Address before: 715500, Shaanxi County, Pucheng province Chen Town Chemical Industry Park Patentee before: Shaanxi Welch Crop Protection Co.,Ltd. |
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| OL01 | Intention to license declared | ||
| OL01 | Intention to license declared |