CN101415696B - 制备氧化烯的方法 - Google Patents

制备氧化烯的方法 Download PDF

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Publication number
CN101415696B
CN101415696B CN2007800118891A CN200780011889A CN101415696B CN 101415696 B CN101415696 B CN 101415696B CN 2007800118891 A CN2007800118891 A CN 2007800118891A CN 200780011889 A CN200780011889 A CN 200780011889A CN 101415696 B CN101415696 B CN 101415696B
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reaction system
reaction
zone
minisize reaction
minisize
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Chinese (zh)
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CN101415696A (zh
Inventor
伯恩哈德·古奇
伯恩德·法布里
斯蒂芬·弗兰岑
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Cognis IP Management GmbH
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/14—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00783—Laminate assemblies, i.e. the reactor comprising a stack of plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00801—Means to assemble
    • B01J2219/0081—Plurality of modules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00819—Materials of construction
    • B01J2219/00824—Ceramic
    • B01J2219/00828—Silicon wafers or plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00819—Materials of construction
    • B01J2219/00831—Glass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00819—Materials of construction
    • B01J2219/00833—Plastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00858—Aspects relating to the size of the reactor
    • B01J2219/0086—Dimensions of the flow channels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00858—Aspects relating to the size of the reactor
    • B01J2219/00862—Dimensions of the reaction cavity itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00867—Microreactors placed in series, on the same or on different supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00869—Microreactors placed in parallel, on the same or on different supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00889—Mixing

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2007800118891A 2006-04-01 2007-03-23 制备氧化烯的方法 Expired - Fee Related CN101415696B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102006015268A DE102006015268A1 (de) 2006-04-01 2006-04-01 Verfahren zur Herstellung von Alkylenoxiden
DE102006015268.9 2006-04-01
PCT/EP2007/002576 WO2007112866A1 (de) 2006-04-01 2007-03-23 Verfahren zur herstellung von alkylenoxiden

Publications (2)

Publication Number Publication Date
CN101415696A CN101415696A (zh) 2009-04-22
CN101415696B true CN101415696B (zh) 2012-08-22

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CN2007800118891A Expired - Fee Related CN101415696B (zh) 2006-04-01 2007-03-23 制备氧化烯的方法

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US (1) US7943790B2 (enExample)
EP (1) EP2001858B1 (enExample)
JP (1) JP2009532397A (enExample)
KR (1) KR101384935B1 (enExample)
CN (1) CN101415696B (enExample)
DE (2) DE102006015268A1 (enExample)
ES (1) ES2599847T3 (enExample)
PL (1) PL2001858T3 (enExample)
WO (1) WO2007112866A1 (enExample)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007039874B9 (de) * 2007-08-20 2010-12-09 Zylum Beteiligungsgesellschaft Mbh & Co. Patente Ii Kg Verfahren zur Herstellung von Epoxiden durch Oxidation von Olefinen in der homogenen Gasphase
BRPI0915854A2 (pt) 2008-07-14 2015-08-04 Basf Se Processo para preparar óxido de etileno
EP2313385A2 (en) * 2008-07-14 2011-04-27 Velocys Inc. Process for making ethylene oxide using microchannel process technology
US8524927B2 (en) 2009-07-13 2013-09-03 Velocys, Inc. Process for making ethylene oxide using microchannel process technology
JP5742390B2 (ja) * 2011-03-31 2015-07-01 株式会社Ihi 窒化ガリウム結晶の成長方法
CN107216296B (zh) * 2016-03-22 2020-07-17 中国石油化工股份有限公司 在微通道反应器内制备环氧丙烷的方法
CN112979587B (zh) * 2019-12-12 2022-12-02 中国科学院大连化学物理研究所 一种微通道反应器合成环氧丙烷的方法
EP4368649A1 (en) 2022-11-14 2024-05-15 Cliq Swisstech (The Netherlands) B.V. Continuous processs for the manufacture of urea urethanes

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19741645A1 (de) 1997-09-22 1999-03-25 Bayer Ag Verfahren und Vorrichtung zur Oxidation organischer Verbindungen in flüssiger Phase unter Verwendung peroxidischer Oxidationsmittel
DE10020632A1 (de) * 2000-04-27 2001-10-31 Merck Patent Gmbh Verfahren zur Expodierung von Olefinen
DE10042746A1 (de) * 2000-08-31 2002-03-28 Degussa Verfahren und Vorrichtung zum Durchführen von Reaktionen in einem Reaktor mit spaltförmigen Reaktionsräumen
DE10257239B3 (de) 2002-12-04 2004-07-01 INSTITUT FüR ANGEWANDTE CHEMIE BERLIN-ADLERSHOF E.V. Verfahren zur Photooxigenerierung von Olefinen in Mikrostrukturreaktoren
JP2004285001A (ja) 2003-03-24 2004-10-14 Sumitomo Chem Co Ltd 含酸素化合物の製造方法
DE10317451A1 (de) 2003-04-16 2004-11-18 Degussa Ag Reaktor für heterogen katalysierte Reaktionen
EP1786797B1 (en) 2004-08-12 2014-11-26 Velocys, Inc. Process for converting ethylene to ethylene oxide using microchannel process technology
DE102004050506A1 (de) * 2004-10-15 2006-04-20 Degussa Ag Verfahren zur Herstellung von Olefinoxiden und Peroxiden, Reaktor und dessen Verwendung

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Torsten Berndt et al..Gas-Phase Epoxidation of Propylene and Ethylene.《Ind. Eng. Chem. Res.》.2005,第44卷(第4期),645-650. *

Also Published As

Publication number Publication date
ES2599847T3 (es) 2017-02-03
CN101415696A (zh) 2009-04-22
DE202006020415U1 (de) 2008-07-03
PL2001858T3 (pl) 2017-03-31
WO2007112866A1 (de) 2007-10-11
KR20080104345A (ko) 2008-12-02
DE102006015268A1 (de) 2007-10-25
JP2009532397A (ja) 2009-09-10
US7943790B2 (en) 2011-05-17
EP2001858B1 (de) 2016-07-27
KR101384935B1 (ko) 2014-04-11
EP2001858A1 (de) 2008-12-17
US20090253944A1 (en) 2009-10-08

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