CN101394924B - 氧化反应器和氧化方法 - Google Patents

氧化反应器和氧化方法 Download PDF

Info

Publication number
CN101394924B
CN101394924B CN2006800528590A CN200680052859A CN101394924B CN 101394924 B CN101394924 B CN 101394924B CN 2006800528590 A CN2006800528590 A CN 2006800528590A CN 200680052859 A CN200680052859 A CN 200680052859A CN 101394924 B CN101394924 B CN 101394924B
Authority
CN
China
Prior art keywords
oxidation
oxygen
membrane component
reaction chamber
reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2006800528590A
Other languages
English (en)
Chinese (zh)
Other versions
CN101394924A (zh
Inventor
S·韦尔斯
B·朗安克
R·克雷恩施密特
B·霍廷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp Industrial Solutions AG
Original Assignee
Uhde GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uhde GmbH filed Critical Uhde GmbH
Publication of CN101394924A publication Critical patent/CN101394924A/zh
Application granted granted Critical
Publication of CN101394924B publication Critical patent/CN101394924B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2475—Membrane reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/024—Oxides
    • B01D71/0271—Perovskites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B01J12/007—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0278—Feeding reactive fluids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/065—Feeding reactive fluids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02—Preparation of oxygen
    • C01B13/0229—Purification or separation processes
    • C01B13/0248—Physical processing only
    • C01B13/0251—Physical processing only by making use of membranes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2210/00—Purification or separation of specific gases
    • C01B2210/0043—Impurity removed
    • C01B2210/0046—Nitrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • General Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
CN2006800528590A 2005-12-14 2006-12-05 氧化反应器和氧化方法 Expired - Fee Related CN101394924B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102005060171A DE102005060171A1 (de) 2005-12-14 2005-12-14 Oxidationsreaktor und Oxidationsverfahren
DE102005060171.5 2005-12-14
PCT/EP2006/011629 WO2007068369A1 (de) 2005-12-14 2006-12-05 Oxidationsreaktor und oxidationsverfahren

Publications (2)

Publication Number Publication Date
CN101394924A CN101394924A (zh) 2009-03-25
CN101394924B true CN101394924B (zh) 2012-07-04

Family

ID=37907494

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2006800528590A Expired - Fee Related CN101394924B (zh) 2005-12-14 2006-12-05 氧化反应器和氧化方法

Country Status (13)

Country Link
US (1) US20090018373A1 (enExample)
EP (1) EP1968738B1 (enExample)
JP (1) JP5366556B2 (enExample)
KR (1) KR101376082B1 (enExample)
CN (1) CN101394924B (enExample)
CA (1) CA2634263A1 (enExample)
DE (1) DE102005060171A1 (enExample)
DK (1) DK1968738T3 (enExample)
EA (1) EA200870037A1 (enExample)
EG (1) EG26485A (enExample)
ES (1) ES2397966T3 (enExample)
WO (1) WO2007068369A1 (enExample)
ZA (1) ZA200805086B (enExample)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7666449B2 (en) * 2001-06-20 2010-02-23 Metaproteomics, Llc Anti-inflammatory pharmaceutical compositions for reducing inflammation and the treatment or prevention of gastric toxicity
WO2009071463A2 (de) * 2007-12-03 2009-06-11 Basf Se Oxidative methankopplung via membranreaktor
DE102008013292A1 (de) 2008-03-07 2009-09-10 Borsig Process Heat Exchanger Gmbh Verfahren zum Regenerieren von Sauerstoff-leitenden keramischen Membranen sowie Reaktor
DE102009039920A1 (de) 2009-09-03 2011-03-10 Karl-Heinz Tetzlaff Verfahren und Vorrichtung zur Nutzung von Sauerstoff bei der Dampfreformierung von Biomasse
DE102009060489A1 (de) 2009-12-29 2011-06-30 Uhde GmbH, 44141 Vorrichtung und Verfahren zur Regelung der Sauerstoffpermeation durch nicht-poröse Sauerstoffanionen leitende keramische Membranen und deren Verwendung
JP2012091984A (ja) * 2010-10-28 2012-05-17 Mitsubishi Heavy Ind Ltd 高温シール材料、高温シール体、及び高温シール体を含む酸素透過モジュール
NL2006245C2 (en) * 2011-02-18 2012-08-21 Stichting Energie MEMBRANE REACTOR AND PROCESS FOR THE PRODUCTION OF A GASEOUS PRODUCT WITH SUCH REACTOR.
CA2833018A1 (en) 2011-04-13 2012-10-18 Michael Klein Gas delivery method and apparatus
CN103130748B (zh) * 2011-11-29 2015-04-29 岳阳昌德化工实业有限公司 一种环己烯氧化的方法
EP2607301A1 (de) * 2011-12-20 2013-06-26 Karl-Heinz Tetzlaff Vorrichtung und Verfahren zur Erdgasreformierung
US9969645B2 (en) 2012-12-19 2018-05-15 Praxair Technology, Inc. Method for sealing an oxygen transport membrane assembly
US20140219884A1 (en) * 2013-01-07 2014-08-07 Sean M. Kelly High emissivity and high temperature diffusion barrier coatings for an oxygen transport membrane assembly
US9296671B2 (en) 2013-04-26 2016-03-29 Praxair Technology, Inc. Method and system for producing methanol using an integrated oxygen transport membrane based reforming system
US9212113B2 (en) 2013-04-26 2015-12-15 Praxair Technology, Inc. Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming and auxiliary heat source
US9611144B2 (en) 2013-04-26 2017-04-04 Praxair Technology, Inc. Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system that is free of metal dusting corrosion
US9938145B2 (en) 2013-04-26 2018-04-10 Praxair Technology, Inc. Method and system for adjusting synthesis gas module in an oxygen transport membrane based reforming system
WO2015054219A2 (en) 2013-10-07 2015-04-16 Praxair Technology, Inc. Ceramic oxygen transport membrane array reactor and reforming method
US10822234B2 (en) 2014-04-16 2020-11-03 Praxair Technology, Inc. Method and system for oxygen transport membrane enhanced integrated gasifier combined cycle (IGCC)
US9789445B2 (en) 2014-10-07 2017-10-17 Praxair Technology, Inc. Composite oxygen ion transport membrane
US10441922B2 (en) 2015-06-29 2019-10-15 Praxair Technology, Inc. Dual function composite oxygen transport membrane
US10118823B2 (en) 2015-12-15 2018-11-06 Praxair Technology, Inc. Method of thermally-stabilizing an oxygen transport membrane-based reforming system
US9938146B2 (en) 2015-12-28 2018-04-10 Praxair Technology, Inc. High aspect ratio catalytic reactor and catalyst inserts therefor
KR102154420B1 (ko) 2016-04-01 2020-09-10 프랙스에어 테크놀로지, 인코포레이티드 촉매-함유 산소 수송막
JP6845102B2 (ja) * 2017-06-30 2021-03-17 日本特殊陶業株式会社 改質構造体および改質装置
EP3797085A1 (en) 2018-05-21 2021-03-31 Praxair Technology, Inc. Otm syngas panel with gas heated reformer

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5573737A (en) * 1994-09-27 1996-11-12 The United States Of America As Represented By The United States Department Of Energy Functionally gradient material for membrane reactors to convert methane gas into value-added products
EP0962422B1 (en) * 1998-06-03 2003-12-10 Praxair Technology, Inc. Syngas reactor with ceramic membrane

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2081170C (en) * 1992-10-22 2002-12-24 Alaa-Eldin Moustafa Adris Fluidized bed reaction system for steam/hydrocarbon gas reforming to produce hydrogen
AU706663B2 (en) * 1994-09-23 1999-06-17 Standard Oil Company, The Oxygen permeable mixed conductor membranes
US5681373A (en) * 1995-03-13 1997-10-28 Air Products And Chemicals, Inc. Planar solid-state membrane module
BR9601078A (pt) * 1995-05-18 1998-01-06 Praxair Technology Inc Processo para a remoção de oxigênio a partir de uma corrente de alimentação para a obtenção de uma corrente de produto empobrecida em oxigênio
US5820655A (en) * 1997-04-29 1998-10-13 Praxair Technology, Inc. Solid Electrolyte ionic conductor reactor design
US6077323A (en) * 1997-06-06 2000-06-20 Air Products And Chemicals, Inc. Synthesis gas production by ion transport membranes
US6106591A (en) * 1997-06-23 2000-08-22 Praxair Technology, Inc. Process for reducing carbon production in solid electrolyte ionic conductor systems
US6200541B1 (en) * 1997-10-28 2001-03-13 Bp Amoco Corporation Composite materials for membrane reactors
US5935533A (en) * 1997-10-28 1999-08-10 Bp Amoco Corporation Membrane reactor hollow tube module with ceramic/metal interfacial zone
DE60010550T2 (de) * 1999-03-05 2005-05-12 Haldor Topsoe A/S Verfahren zur autothermen katalytischen Dampf-Reformierung
JP2001097789A (ja) * 1999-10-01 2001-04-10 Nippon Steel Corp セラミック複合材料
JP2002085946A (ja) * 2000-09-20 2002-03-26 Teikoku Oil Co Ltd セラミックス膜式反応器およびこれを用いる低圧水素製造方法
US6695983B2 (en) * 2001-04-24 2004-02-24 Praxair Technology, Inc. Syngas production method utilizing an oxygen transport membrane
US20030039601A1 (en) * 2001-08-10 2003-02-27 Halvorson Thomas Gilbert Oxygen ion transport membrane apparatus and process for use in syngas production
JP3914416B2 (ja) * 2001-11-06 2007-05-16 帝国石油株式会社 膜式反応器
JP2003346859A (ja) * 2002-05-23 2003-12-05 Nissan Motor Co Ltd 一酸化炭素除去装置
US7125528B2 (en) * 2002-05-24 2006-10-24 Bp Corporation North America Inc. Membrane systems containing an oxygen transport membrane and catalyst
FR2859115B1 (fr) * 2003-08-28 2005-10-28 Centre Nat Rech Scient Membranes de conduction electronique et oxygene ionique comprenant une couche d'oxyde mixte de vanadium et de magnesium

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5573737A (en) * 1994-09-27 1996-11-12 The United States Of America As Represented By The United States Department Of Energy Functionally gradient material for membrane reactors to convert methane gas into value-added products
EP0962422B1 (en) * 1998-06-03 2003-12-10 Praxair Technology, Inc. Syngas reactor with ceramic membrane

Also Published As

Publication number Publication date
ES2397966T3 (es) 2013-03-12
EP1968738B1 (de) 2012-10-31
EA200870037A1 (ru) 2009-12-30
KR20080077667A (ko) 2008-08-25
ZA200805086B (en) 2009-03-25
JP2009519195A (ja) 2009-05-14
CA2634263A1 (en) 2007-06-21
EG26485A (en) 2013-12-10
JP5366556B2 (ja) 2013-12-11
DE102005060171A1 (de) 2007-06-21
DK1968738T3 (da) 2013-01-28
EP1968738A1 (de) 2008-09-17
US20090018373A1 (en) 2009-01-15
CN101394924A (zh) 2009-03-25
KR101376082B1 (ko) 2014-03-19
WO2007068369A1 (de) 2007-06-21

Similar Documents

Publication Publication Date Title
CN101394924B (zh) 氧化反应器和氧化方法
Zhu et al. Microstructural and interfacial designs of oxygen‐permeable membranes for oxygen separation and reaction–separation coupling
Zeng et al. Perovskite-type ceramic membrane: synthesis, oxygen permeation and membrane reactor performance for oxidative coupling of methane
Balachandran et al. Ceramic membrane reactor for converting methane to syngas
US8114193B2 (en) Ion transport membrane module and vessel system
ten Elshof et al. Oxidative coupling of methane in a mixed-conducting perovskite membrane reactor
CN100548443C (zh) 离子迁移膜系统中原料气污染物的去除
Luo et al. Performance of a ceramic membrane reactor with high oxygen flux Ta-containing perovskite for the partial oxidation of methane to syngas
US8455382B2 (en) Fabrication of catalyzed ion transport membrane systems
US6949230B2 (en) Solid state oxygen anion and electron mediating membrane and catalytic membrane reactors containing them
Ten Elshof et al. Activation of methane using solid oxide membranes
EP1027149A1 (en) Catalytic membrane reactor with two component - three dimensional catalysis
EP0896566A1 (en) Solid state oxygen anion and electron mediating membrane and catalytic membrane reactors containing them
Cai et al. High‐performance oxygen transport membrane reactors integrated with IGCC for carbon capture
Zhu et al. A robust mixed‐conducting multichannel hollow fiber membrane reactor
US20050252372A1 (en) Hydrogen separation using oxygen ion-electron mixed conduction membranes
JP2009519195A5 (enExample)
US20100234650A1 (en) Oxygen separation membrane
Siwen et al. Oxygen permeating properties of the mixed conducting membranes without cobalt
Liu et al. Oxygen transport kinetics of MIEC membranes coated with different catalysts
Wang et al. Mixed oxygen ionic and electronic conducting membrane reactors for pure chemicals production
Yaremchenko et al. Performance of tubular SrFe (Al) O3− δ–SrAl2O4 composite membranes in CO2-and CH4-containing atmospheres
Balachandran et al. Development of dense ceramic membranes for methane conversion
Balachandran et al. Dense Ceramic Membranes for Converting Methane to Syngas
Balachandran et al. Development of mixed-conducting ceramic membranes for converting methane to syngas

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C53 Correction of patent of invention or patent application
CB02 Change of applicant information

Address after: Borussia Dortmund

Applicant after: ThyssenKrupp Uhde GmbH

Address before: Borussia Dortmund

Applicant before: Krupp Uhde GmbH

COR Change of bibliographic data

Free format text: CORRECT: APPLICANT; FROM: KRUPP UHDE GMBH TO: THYSSENKRUPP UHDE GMBH

C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120704

Termination date: 20151205

EXPY Termination of patent right or utility model