CN101379989B - Bactericide agent composition containing epoxiconazole and thiophonate-methyl - Google Patents
Bactericide agent composition containing epoxiconazole and thiophonate-methyl Download PDFInfo
- Publication number
- CN101379989B CN101379989B CN2008101329839A CN200810132983A CN101379989B CN 101379989 B CN101379989 B CN 101379989B CN 2008101329839 A CN2008101329839 A CN 2008101329839A CN 200810132983 A CN200810132983 A CN 200810132983A CN 101379989 B CN101379989 B CN 101379989B
- Authority
- CN
- China
- Prior art keywords
- methyl
- thiophanate
- ring azoles
- fluorine ring
- epoxiconazole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003899 bactericide agent Substances 0.000 title abstract description 10
- ZMYFCFLJBGAQRS-IRXDYDNUSA-N (2R,3S)-epoxiconazole Chemical compound C1=CC(F)=CC=C1[C@@]1(CN2N=CN=C2)[C@H](C=2C(=CC=CC=2)Cl)O1 ZMYFCFLJBGAQRS-IRXDYDNUSA-N 0.000 title abstract description 8
- 239000005767 Epoxiconazole Substances 0.000 title abstract description 8
- 239000000203 mixture Substances 0.000 title description 20
- 239000005842 Thiophanate-methyl Substances 0.000 claims abstract description 29
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 claims abstract description 28
- -1 fluorine ring azoles Chemical class 0.000 claims description 26
- 241000221785 Erysiphales Species 0.000 claims description 8
- 235000004936 Bromus mango Nutrition 0.000 claims description 6
- 235000014826 Mangifera indica Nutrition 0.000 claims description 6
- 235000009184 Spondias indica Nutrition 0.000 claims description 6
- 239000002270 dispersing agent Substances 0.000 claims description 6
- 238000009736 wetting Methods 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- 230000000443 biocontrol Effects 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- LCRMGUFGEDUSOG-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 LCRMGUFGEDUSOG-UHFFFAOYSA-N 0.000 claims description 3
- 239000004562 water dispersible granule Substances 0.000 claims description 3
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 230000002528 anti-freeze Effects 0.000 claims description 2
- 239000002518 antifoaming agent Substances 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 239000003599 detergent Substances 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 2
- KSVSZLXDULFGDQ-UHFFFAOYSA-M sodium;4-aminobenzenesulfonate Chemical compound [Na+].NC1=CC=C(S([O-])(=O)=O)C=C1 KSVSZLXDULFGDQ-UHFFFAOYSA-M 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- 241001093152 Mangifera Species 0.000 claims 3
- 239000000375 suspending agent Substances 0.000 claims 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 17
- 201000010099 disease Diseases 0.000 abstract description 8
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 8
- 239000002131 composite material Substances 0.000 abstract description 7
- 240000007594 Oryza sativa Species 0.000 abstract description 6
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 6
- 235000013399 edible fruits Nutrition 0.000 abstract description 6
- 235000009566 rice Nutrition 0.000 abstract description 6
- 235000013311 vegetables Nutrition 0.000 abstract description 6
- 235000021307 Triticum Nutrition 0.000 abstract description 5
- 241000196324 Embryophyta Species 0.000 abstract description 4
- 244000241235 Citrullus lanatus Species 0.000 abstract 2
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 abstract 2
- 241000209140 Triticum Species 0.000 abstract 2
- 241000219094 Vitaceae Species 0.000 abstract 2
- 235000021021 grapes Nutrition 0.000 abstract 2
- 239000004480 active ingredient Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000009472 formulation Methods 0.000 description 4
- 240000007228 Mangifera indica Species 0.000 description 3
- 244000098338 Triticum aestivum Species 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 2
- 240000002791 Brassica napus Species 0.000 description 2
- 235000006008 Brassica napus var napus Nutrition 0.000 description 2
- 235000002566 Capsicum Nutrition 0.000 description 2
- 241000219112 Cucumis Species 0.000 description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
- 240000008067 Cucumis sativus Species 0.000 description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 2
- 241000221662 Sclerotinia Species 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 150000003851 azoles Chemical class 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000000546 pharmaceutical excipient Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000004546 suspension concentrate Substances 0.000 description 2
- 241000198596 Alternaria tomatophila Species 0.000 description 1
- 244000099147 Ananas comosus Species 0.000 description 1
- 235000007119 Ananas comosus Nutrition 0.000 description 1
- 240000008574 Capsicum frutescens Species 0.000 description 1
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 235000009811 Momordica charantia Nutrition 0.000 description 1
- 235000009812 Momordica cochinchinensis Nutrition 0.000 description 1
- 240000001740 Momordica dioica Species 0.000 description 1
- 235000018365 Momordica dioica Nutrition 0.000 description 1
- 240000005561 Musa balbisiana Species 0.000 description 1
- 235000018290 Musa x paradisiaca Nutrition 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 206010064458 Penicilliosis Diseases 0.000 description 1
- 239000006002 Pepper Substances 0.000 description 1
- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 240000003889 Piper guineense Species 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
- 235000008184 Piper nigrum Nutrition 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 241001250070 Sporisorium reilianum Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001390 capsicum minimum Substances 0.000 description 1
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 1
- 239000006013 carbendazim Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000003641 microbiacidal effect Effects 0.000 description 1
- 229940124561 microbicide Drugs 0.000 description 1
- 239000002855 microbicide agent Substances 0.000 description 1
- SNDHDSAARFTTIY-UHFFFAOYSA-N oxirane;2h-triazole Chemical compound C1CO1.C=1C=NNN=1 SNDHDSAARFTTIY-UHFFFAOYSA-N 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a bactericide composite containing epoxiconazole and thiophanate-methyl, and relates to the bactericide composite which shows strong bactericidal activity, and is mainly used for the plant diseases of fruit trees, grapes, vegetables, watermelons, wheat, paddy rice, and the like; the bactericide composite has the effects of protecting and treating crops and is different from other existing pesticide bactericides. The active ingredients of the bactericide composite consist of the thiophanate-methyl and the epoxiconazole; the bactericide composite comprises the raw materials with the weight percentage: 5-50% of epoxiconazole, 10-70% of thiophanate-methyl, 3-25% of accessory ingredient and 10-70% of filler. The bactericide composite having the synergy is applied for controlling various plant diseases of fruit trees, grapes, vegetables, watermelons, wheat and paddy rice.
Description
Technical field
The present invention relates to a kind of bactericidal composition and uses thereof, especially a kind of is the bactericidal composition and the application thereof of main active with fluorine ring azoles and thiophanate-methyl.
Background technology
Fluorine ring azoles (epoxiconazole) is a kind of brand-new (2RS; 3SR)-3-(2-chlorphenyl)-2-(4-fluorophenyl)-2-[(1H1; 2; the 4-triazol-1-yl) methyl] the oxirane triazole bactericidal agent; triple function is protected, treated and root out to tool, and the energy that destroys germ by the respiration that suppresses germ synthesizes and loss of life power.Fluorine ring azoles is by Beyer Co., Ltd's development, and formulation products is 12.5% Ou Bo missible oil, is mainly used in control vegetables, diseases of garden stuff, because its drug cost height uses not extensive.
Thiophanate-methyl (thiophanate-methyl) is a kind of efficient, low toxicity bactericide, and tool prevention and systemic action are because of medicament can change into carbendazim after entering in the plant corpus, so also belong to benzimidazole.Can be widely used in multiple diseases such as grain, cotton, oil, vegetables, fruit tree.Can prevent and treat gibberella zeaze petch of wheat and barley, stinking smut, wheat powdery mildew, leaf blast disease, the rice sheath blight, sclerotinia rot of colza etc.Can be used for sweet potato smut, the big leaf spot of corn, rice purple stalk disease, head smut of sorghum in addition.Thiophanate-methyl for a long time, repeatedly uses on Crop in China, and this makes the target germ strengthen gradually its resistance, is that cost that thiophanate-methyl is prevented and treated disease increases and drug effect reduces greatly.
Summary of the invention
The objective of the invention is provides a kind of applied widely, the fluorine-containing ring azoles that cost is low, effective and the plant sterilization composition of thiophanate-methyl at above-mentioned technical problem.
A further object of the invention provides the purposes of this bactericidal composition.
The objective of the invention is to realize by following measures:
A kind of bactericidal composition, it contains fluorine ring azoles and thiophanate-methyl, and wherein the weight ratio of fluorine ring azoles and thiophanate-methyl is 5～50: 10～70.
Described bactericidal composition, wherein the weight ratio of fluorine ring azoles and thiophanate-methyl is 5～50: 15～60.
Described bactericidal composition, wherein any one formulation that allows on fluorine ring azoles and thiophanate-methyl and known auxiliary agent and the composite patent medicine of excipient.These known auxiliary agents, excipients have dispersant, diffusant, defoamer, wetting agent, disintegrant etc.
Described bactericidal composition, its formulation are wetting powder, suspension emulsion or water dispersible granules.
The application of described bactericidal composition aspect control cereal class, melon and fruit or vegetable crop disease.
Beneficial effect of the present invention:
1, the used fluorine ring azoles of the present invention is a triazole type, and thiophanate-methyl is a kind of benzimidazole germicide, and both are mixed mutually and can produce conflict, but Synergistic reduces dosage, reduces cost.
2, the present composition scope of application increases, be applicable to the crop pest of control cereal class, various melon and fruit, vegetables, particularly prevent and treat crop pests such as paddy rice, wheat, capsicum, banana, mango, pineapple, cucumber, tomato, tobacco, as rice blast, sheath and culm blight, sclerotinia rot of colza, pepper anthracnose, balsam pear scab, oranges and tangerines penicilliosis, powdery mildew of cucumber, early blight of tomato and late blight.
Embodiment
The invention will be further described below in conjunction with embodiment.The preparation method of formulation is conventional method among the embodiment.
Embodiment 1:
With fluorine ring azoles 20g, thiophanate-methyl 50g, detergent LS (to methoxyl group fatty acid Sodium p-aminobenzene sulfonat) 2g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin adds to 100g, mixture carries out comminution by gas stream, makes 70% thiophanate-methyl fluorine ring azoles wetting powder.
Embodiment 2:
With fluorine ring azoles 10g, thiophanate-methyl 40g, wetting dispersing agent polyoxyethylene triphenyl phosphorus hydrochlorate 8g, antifreeze propane diols 5g, thickener xanthans 0.4g, silicone defoaming agent 0.05g
Add water to 100g.Mix and to make 50% thiophanate-methyl epoxiconazole suspension concentrate after ultramicro grinding is filtered.
Embodiment 3:
Fluorine ring azoles 5g, thiophanate-methyl 45g, polyoxyethylene nonylphenol ether 4g, dispersing agent NNO 3g, polyvinyl alcohol 1.2g, sodium bicarbonate 1g, bentonite 30g, kaolin are added to 100g,, make 50% thiophanate-methyl epoxiconazole water dispersant through pulverizing granulation.
Application Example:
Test with the pesticidal preparations biocontrol of mango powdery mildew that the foregoing description makes.
1, test is handled: this test medicine consumption is established three concentration of treatment respectively according to the difference of each composition, but the contrast medicament is respectively commercially available agricultural chemicals 70% thiophanate-methyl wet-milling (WP) and 12.5% epoxiconazole suspension concentrate and the test of blank clear water.
2, each sub-district area of test method is no less than 2 strains for becoming the age fruit tree, repeats 3 times; Inspection drug effect method before the dispenser after investigation and the control is: investigation two strains every sub-district in, every strain press East, West, South, North, in 5 samplings, investigate 2 fringes at every, write down total spike number and sick spike number at different levels, inspection powdery mildew occurrence degree.
3, result of the test is as follows
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable.
Field efficacy is the result show, fluorine ring azoles and thiophanate-methyl composition have good control efficiency to the mango powdery mildew, and control efficiency all is better than single agent kind.
Claims (3)
1. the wetting powder of fluorine ring azoles and thiophanate-methyl is used for the purposes of biocontrol of mango powdery mildew, it is characterized in that, the component of this wetting powder and weight content are: fluorine ring azoles 20g, thiophanate-methyl 50g, detergent is to methoxyl group fatty acid Sodium p-aminobenzene sulfonat 2g, diffusant sodium methylene bis-naphthalene sulfonate 4g, white carbon 5g, kaolin adds to 100g.
2. the suspending agent of fluorine ring azoles and thiophanate-methyl is used for the purposes of biocontrol of mango powdery mildew, it is characterized in that, the component of this suspending agent and weight content are: fluorine ring azoles 10g, thiophanate-methyl 40g, wetting dispersing agent polyoxyethylene triphenyl phosphorus hydrochlorate 8g, antifreeze propane diols 5g, thickener xanthans 0.4g, silicone defoaming agent 0.05g adds water to 100g.
3. the water dispersible granules of fluorine ring azoles and thiophanate-methyl is used for the purposes of biocontrol of mango powdery mildew, it is characterized in that, the component of this water dispersible granules and weight content are: fluorine ring azoles 5g, thiophanate-methyl 45g, polyoxyethylene nonylphenol ether 4g, diffusant sodium methylene bis-naphthalene sulfonate 3g, polyvinyl alcohol 1.2g, sodium bicarbonate 1g, bentonite 30g, kaolin adds to 100g.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101329839A CN101379989B (en) | 2008-07-04 | 2008-07-04 | Bactericide agent composition containing epoxiconazole and thiophonate-methyl |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101329839A CN101379989B (en) | 2008-07-04 | 2008-07-04 | Bactericide agent composition containing epoxiconazole and thiophonate-methyl |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101379989A CN101379989A (en) | 2009-03-11 |
| CN101379989B true CN101379989B (en) | 2011-10-19 |
Family
ID=40460188
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008101329839A Expired - Fee Related CN101379989B (en) | 2008-07-04 | 2008-07-04 | Bactericide agent composition containing epoxiconazole and thiophonate-methyl |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101379989B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103563955B (en) * | 2012-08-08 | 2015-08-19 | 陕西美邦农药有限公司 | A kind of bactericidal composition containing bromuconazole |
| BR102013030596A2 (en) * | 2013-11-28 | 2015-09-22 | Rotam Agrochem Int Co Ltd | method of treating fungicidal infections, fungicidal compositions and their use |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101171919A (en) * | 2007-10-15 | 2008-05-07 | 张少武 | Bactericide agent composition containing active ingredient of epoxiconazole |
-
2008
- 2008-07-04 CN CN2008101329839A patent/CN101379989B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101171919A (en) * | 2007-10-15 | 2008-05-07 | 张少武 | Bactericide agent composition containing active ingredient of epoxiconazole |
Non-Patent Citations (5)
| Title |
|---|
| Rava，Carlos A.《Efficiency of fungicides to control anthracnose and angular leaf spot in common beans》.《Summa phytopathologica》.2002,全文. * |
| Ushakov,N.M.Protection of spring crops in conditions of agricultural bioregulation.《Zemledelie》.2002,全文. * |
| Vildflush，I.R.Efficiency of combined application of liquid nitrogen fertilizer and pesticide for spring wheat grown on soddy podzolic soil.《Agrokhimiya》.2005,全文. * |
| 柏亚罗.具有不同作用机理的杀螨剂.《现代农药》.2005,第4卷(第3期),全文. * |
| 王宁.杀螨剂的进展与展望.《现代农药》.2005,第4卷(第2期),全文. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101379989A (en) | 2009-03-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101548677B (en) | Sterilizing compound of ethirimol and triazole | |
| CN101946775B (en) | Sterilization compound containing triazole fungicide and azoxystrobin | |
| CN104222116B (en) | Containing the agricultural bactericidal composition of the gloomy copper of thiophene | |
| CN101379984A (en) | Bactericidal composition containing azoxystrobin and carbendazim and use thereof | |
| CN103563944A (en) | Bactericidal composition containing pyraclostrobin and tebuconazole and application thereof | |
| CN102239853A (en) | Thifluzamide-containing composite bacteriacide | |
| CN100376158C (en) | Germicide composition containing azoxystrobin and thiophanate-methyl and its application | |
| CN101946792A (en) | Azoxystrobin-prochloraz complex bactericide and application thereof | |
| CN101743993A (en) | Antibacterial composite with bromothalonil and application thereof | |
| CN102027937A (en) | Bactericidal composition containing metconazole and triazole | |
| CN101653131B (en) | Bactericidal composition containing azoxystrobin | |
| CN101961021A (en) | Fluopyram-containing bactericidal composition | |
| CN101379989B (en) | Bactericide agent composition containing epoxiconazole and thiophonate-methyl | |
| CN105638683A (en) | Agricultural bactericidal composition with saisentong | |
| CN101658173A (en) | Sterilization composition containing tetraconazole | |
| CN101933514B (en) | Bactericidal composite with triazole bactericide and chlorothalonil | |
| CN101524069B (en) | Sterilizing composition containing Hexaconazole | |
| CN104106575B (en) | A kind of bactericidal composition containing pungent bacterium amine and olefin conversion | |
| CN103563938A (en) | Bactericidal composition containing pyraclostrobin and difenoconazole and application thereof | |
| CN100364400C (en) | Germicide composition containing pyraclostrobin and chlorothalonil and its application | |
| CN101379983B (en) | Bactericidal composition containing azoxystrobin and triabendazole and use thereof | |
| CN104585185B (en) | A kind of bactericidal composition containing cyprodinil and fluoxastrobin and application thereof | |
| CN103518743B (en) | Sterilizing composition containing boscalid and dimethomorph | |
| CN100360024C (en) | Germicide composition containing propamidine and thiophanate-methyl and its application | |
| CN102599172A (en) | Insecticidal composition and preparation thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20090311 Assignee: Shaanxi Meibang Pesticide Co., Ltd. Assignor: Zhang Shaowu Contract record no.: 2013610000007 Denomination of invention: Bactericide agent composition containing epoxiconazole and thiophonate-methyl Granted publication date: 20111019 License type: Exclusive License Record date: 20130322 |
|
| LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161221 Address after: 715500 Pucheng County of Shaanxi Province agricultural base industrial park Patentee after: Shaanxi Meibang Pesticides Co., Ltd. Address before: 715500 Pucheng province Shaanxi County Chengguan Town Food City Street No. 23 Patentee before: Zhang Shaowu |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20111019 Termination date: 20170704 |