CN101377059A - Durability natural object machining textile - Google Patents

Durability natural object machining textile Download PDF

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Publication number
CN101377059A
CN101377059A CNA2007101313893A CN200710131389A CN101377059A CN 101377059 A CN101377059 A CN 101377059A CN A2007101313893 A CNA2007101313893 A CN A2007101313893A CN 200710131389 A CN200710131389 A CN 200710131389A CN 101377059 A CN101377059 A CN 101377059A
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China
Prior art keywords
durability
natural
fiber
natural object
object machining
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CNA2007101313893A
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Chinese (zh)
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CN101377059B (en
Inventor
于辉
符晔
罗周荣
稻田康二郎
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Toray Fibers and Textiles Research Laboratories China Co Ltd
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Toray Fibers and Textiles Research Laboratories China Co Ltd
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Priority to CN2007101313893A priority Critical patent/CN101377059B/en
Publication of CN101377059A publication Critical patent/CN101377059A/en
Application granted granted Critical
Publication of CN101377059B publication Critical patent/CN101377059B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The present invention discloses a durable textile processed with natural substances. The functional natural substances are attached on the fiber surface of the textile. The natural substances are firmly combined with the fibers of the textile and have good durability. The textile has properties, such as corrosion prevention, resistance to bacteria and health caring, and is an environment-friendly product.

Description

Durability natural object machining textile
Technical field:
The present invention relates to a kind of durability natural object machining textile, this textiles be a kind of have anticorrosion, antibiotic, preserve moisture, the environment-friendly products of performance such as health care.
Technical background:
Along with the raising of people's living standard, people have proposed requirement to performances such as the feature of environmental protection of textiles, anti-corrosive antibacterial, healths.
Developed countries such as America and Europe have made strict requirement to the quality safety of textiles, and under this background, people begin to research and develop textiles safe, function admirable.Derive from vegeto-animal natural characteristic medicament and obtained deep research and application in textile industry, this type of natural goods has good effects such as asepsis environment-protecting, anti-inflammation, anti-corrosive properties, health, have biocompatibility simultaneously, the product that utilizes this type of natural medicament to develop has vast market.Though this type of textiles has lot of advantages, the durability of arrangement processing is not fine behind the natural goods of textiles at present, and particularly the back arrangement processed goods of synthetic fiber the present invention is directed to the exploitation that this shortcoming has been carried out durability natural object machining textile.
Summary of the invention:
The object of the present invention is to provide a kind of have anticorrosion, antibiotic, preserve moisture, the textiles of the durability natural object of health properties processing.
Technical solution of the present invention is:
A kind of durability natural object machining textile is characterized in that: form on the fiber surface of this textiles and be attached with functional natural goods.
Above-mentioned natural goods comprises wherein one or more such as polysaccharide compound, protein-based compound, vegetable oil lipid.Polysaccharide compound is wherein one or more such as shitosan, starch, alginate, gum Arabic, protein-based compound is wherein one or more such as gelatin, milk protein, fibroin albumen, and vegetable oil lipid is wherein one or more such as peppermint essential oil, argy wormwood essential oil, aloe extract.Natural goods by with bridging agent generation graft reaction attached on the fiber, the weight of forming the graft that adheres on the fiber of this textiles be fiber weight 0.05~20%, bridging agent is wherein one or more such as blocked isocyanate class, aldehydes, polyalkenylesters class.
Form the fiber more than 30% in the fiber of this textiles and be in the synthetic fiber such as terylene, nylon, acetate fiber, acrylic fibers one or more.
A kind of production method of durability natural object machining textile is characterized in that: comprise the following steps:
1, the preparation of textiles to be processed.
2, preparation working solution:
With natural goods (shitosan, starch, alginate, gum Arabic, gelatin, milk protein, fibroin albumen, the peppermint essential oil, the argy wormwood essential oil, wherein one or more such as aloe extract), bleeding agent (fatty alcohol-polyoxyethylene ether or alkyl polyoxyethylene ether or propyl alcohol or alkylsulfonate etc.), dispersant (comprises Sodium Polyacrylate, sodium metasilicate, calgon etc.), bridging agent (comprises the blocked isocyanate class, formaldehyde, glutaraldehyde, polyalkenylesters class etc.), pH value conditioning agent is mixed with working solution by following prescription with soft water:
Natural goods Bleeding agent Dispersant Adhesive
2~80g/L 0~5g/L 0~10g/L 1~30g/L
The pH value is 2.0~7.0
All the other all are soft water except that above-mentioned medicament in the working solution
3, pad processing:
Fabric product to be processed are immersed in the working solution, roll dried then with padding machine.
4, prebake:
Fabric after will padding is 80~130 ℃ of fully oven dry down.
5, HEAT SETTING:
With the fabric of prebake HEAT SETTING 30~600 seconds under 130~195 ℃ of conditions.
Product of the present invention has performances such as high-durability, the feature of environmental protection, antibiotic property, anti-corrosive properties, moisture retention.
Natural goods, bridging agent and fiber-reactive are:
A. bridging agent respectively with natural goods and fiber generation graft reaction
B. natural goods and bridging agent generation graft reaction, bridging agent generation self-crosslinking reaction forms space network structure bag and invests fiber surface.
C. bridging agent generation self-crosslinking reaction, natural goods is wrapped in wherein, and bridging agent becomes space network structure bag to invest fiber surface.
The chemical structural formula that contains in the fiber of the present invention:
Figure A200710131389D00061
Or
Figure A200710131389D00062
Or
Figure A200710131389D00063
Or
Figure A200710131389D00064
F: fiber
R: natural goods
X: bridging agent
The invention will be further described below in conjunction with embodiment.
The specific embodiment
Embodiment 1:
A. processing cloth prepares: 100% dacron
B. prepare working solution:
Unit: g/L
Shitosan Gelatin Sodium metasilicate Alkyl polyoxyethylene ether The terminal blockade type of heat reactivity isocyanates
10 5 3 3 20
All soft water except that above-mentioned medicament in the working solution
The pH value is adjusted to 3.0~4.0
C. pad processing:
2 soak 2 rolls, and pick-up rate is 61%
D. dryness finalization:
130 ℃ * 3min drying, 170 ℃ * 45s typing obtains durability natural object machining textile, form the graft that adheres on the fiber surface of this textiles and be fiber weight 1.2%.
Antistatic behaviour before and after processed goods returns through home washings N
The home washings standard: JIS L 0,217 103
Antistatic testing standard: determination method is pressed in JIS L 1094 frictional electrifications
Washing times Rough Processed goods
Before the home washings 6540V 113V
After the home washings 20 times 6135V 2508V
Embodiment 2:
A. processing cloth prepares: 100% dacron
B. prepare working solution:
Unit: g/L
Shitosan The aloe modifier Alkylsulfonate The heat reactivity isocyanates
20 10 3 10
The pH value is 3.0~4.0
C. pad processing: 2 soak 2 rolls, and pick-up rate is 37.4%
D. dryness finalization:
130 ℃ * 2min drying, 170 ℃ * 45s typing obtains durability natural object machining textile, form the graft that adheres on the fiber surface of this textiles and be fiber weight 2.3%.
Antistatic behaviour before and after processed goods returns through home washings N
The home washings standard: JIS L 0,217 103
Antistatic testing standard: determination method is pressed in JIS L 1094 frictional electrifications
Washing times Rough Processed goods
Before the home washings 5784V 256V
After the home washings 20 times 5534V 1508V
Embodiment 3:
A. processing cloth prepares: 100% dacron
B. prepare working solution:
Unit: g/L
Milk protein The aloe modifier Alkylsulfonate The heat reactivity isocyanates
10 5 3 10
The pH value is 6.0~7.0
C. pad processing:
2 soak 2 rolls, and pick-up rate is 98%
D. dryness finalization:
130 ℃ * 2min drying, 170 ℃ * 45s typing obtains durability natural object machining textile, form the graft that adheres on the fiber surface of this textiles and be fiber weight 3.2%.
Water imbibition before and after processed goods returns through home washings N
The home washings standard: JIS L 0,217 103
Antistatic testing standard: JIS L 1907 method of dripping
Washing times Rough Processed goods
Before the home washings 120 seconds <1 second
After the home washings 20 times 120 seconds 1 second
Embodiment 4:
A. processing cloth prepares: 100% nylon fabrics
B. prepare working solution:
Unit: g/L
Shitosan Milk protein Isopropyl alcohol The terminal blockade type of heat reactivity isocyanates
20 10 3 10
The pH value is adjusted to 3.0~4.0 with acetum
C. pad processing:
2 soak 2 rolls, and pick-up rate is 59%
D. dryness finalization:
130 ℃ * 2min drying, 170 ℃ * 45s typing obtains durability natural object machining textile, form the graft that adheres on the fiber surface of this textiles and be fiber weight 2.9%.
Embodiment 5:
Natural goods is one or more in starch, alginate, gum Arabic, milk protein, fibroin albumen, peppermint essential oil, argy wormwood essential oil, the aloe extract, bridging agent is to comprise in blocked isocyanate class, formaldehyde, glutaraldehyde, the polyalkenylesters class one or more, and all the other are with embodiment 1.

Claims (10)

1, a kind of durability natural object machining textile is characterized in that: form on the fiber surface of this textiles and be attached with functional natural goods.
2, durability natural object machining textile according to claim 1 is characterized in that: the fiber of forming this textiles is handled the graft fibres of back grafting natural goods for building bridge on its surface.
3, durability natural object machining textile according to claim 2 is characterized in that: the weight of forming the graft that adheres on the fiber of this textiles be fiber weight 0.05~20%.
4, durability natural object machining textile according to claim 3 is characterized in that: natural goods is one or more in polysaccharide compound, protein-based compound, the vegetable oil lipid; Bridging agent is one or more in blocked isocyanate class, aldehydes, the polyalkenylesters class.
5, durability natural object machining textile according to claim 3 is characterized in that: polysaccharide compound is one or more in shitosan, starch, alginate, the gum Arabic.
6, durability natural object machining textile according to claim 3 is characterized in that: protein-based compound is one or more in gelatin, milk protein, the fibroin albumen.
7, durability natural object machining textile according to claim 3 is characterized in that: vegetable oil lipid is one or more in peppermint essential oil, argy wormwood essential oil, the aloe extract.
8, durability natural object machining textile according to claim 1 and 2 is characterized in that: form the fiber more than 30% in the fiber of this textiles and be in terylene, nylon, acetate fiber, the acrylic fiber one or more.
9, durability natural object machining textile according to claim 1 and 2 is characterized in that: obtain by following production method, textiles padded processing, heat-treat then this product, wherein working solution is made up of following composition by weight:
Natural goods 2-80g/L
Bleeding agent 0-5g/L
Dispersant 0-10g/L
Bridging agent 1-30g/L
All the other all are soft water;
Wherein natural goods is one or more in polysaccharide compound, protein-based compound, the vegetable oil lipid, and bridging agent is one or more in blocked isocyanate class, aldehydes, the polyalkenylesters class.
10, durability natural object machining textile according to claim 9 is characterized in that: heat treated temperature is 80-195 ℃, and the time is 30-600 second.
CN2007101313893A 2007-08-30 2007-08-30 Durability natural object machining textile Expired - Fee Related CN101377059B (en)

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CN101377059B CN101377059B (en) 2012-07-04

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102199876A (en) * 2011-04-19 2011-09-28 五邑大学 Chitosan modified nylon fabric and manufacturing method thereof
CN101781849B (en) * 2010-01-25 2012-01-18 江志清 Method for curing chitosan on fabrics
CN102936835A (en) * 2012-12-05 2013-02-20 苏州大学 Preparation method of nano-silver antibacterial real silk
CN102936836A (en) * 2012-12-07 2013-02-20 苏州大学 Method for preparing antibacterial polyester by use of plant nano-silver
CN103147310A (en) * 2013-03-27 2013-06-12 南通苏州大学纺织研究院 Method for finishing cotton fabrics through spraying plant essential oil
CN103938455A (en) * 2014-04-21 2014-07-23 章敏辉 Process for softening bed products by use of milk
CN104306553A (en) * 2014-09-29 2015-01-28 青海唐古特生物科技有限公司 Food, health product or medicine composition for reducing blood fat
CN104532557A (en) * 2014-12-23 2015-04-22 常熟市中宏针织厂 Finishing process of garment shell fabric
CN104611927A (en) * 2015-02-03 2015-05-13 湖州市菱湖重兆金辉丝织厂 Novel antistatic silk fabric based on pre-irradiation
CN105239371A (en) * 2015-10-20 2016-01-13 安踏(中国)有限公司 Manufacturing method of moisture-retention fabric, fabric, clothing and moisture-retention foam finishing agent
CN105821660A (en) * 2016-05-13 2016-08-03 东莞市联洲知识产权运营管理有限公司 Modified silk fiber with high moisture absorbability and moisture retentivity and preparing method thereof
CN106012554A (en) * 2016-06-02 2016-10-12 湖州市菱湖重兆金辉丝织厂 Down jacket antibacterial finishing agent
CN111321593A (en) * 2018-12-14 2020-06-23 优纤科技(丹东)有限公司 Natural sterilization and deodorization fiber and preparation method thereof

Family Cites Families (4)

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CN1508354A (en) * 2002-12-19 2004-06-30 全球生技股份有限公司 Modified treating agent for fiber and processing and treating method thereof
CN1277978C (en) * 2003-10-16 2006-10-04 内蒙古鄂尔多斯羊绒集团有限责任公司 Multifunctional treating agent
CN1624234A (en) * 2004-10-22 2005-06-08 上海工程技术大学 Modified nanometer dxide multifunction finishing agent, preparation method and its use
CN100491629C (en) * 2007-06-18 2009-05-27 大连利健甲壳素股份有限公司 Antibacterial fabric finishing agent containing chitosan its production and usage

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101781849B (en) * 2010-01-25 2012-01-18 江志清 Method for curing chitosan on fabrics
CN102199876A (en) * 2011-04-19 2011-09-28 五邑大学 Chitosan modified nylon fabric and manufacturing method thereof
CN102199876B (en) * 2011-04-19 2013-01-16 五邑大学 Chitosan modified nylon fabric and manufacturing method thereof
CN102936835A (en) * 2012-12-05 2013-02-20 苏州大学 Preparation method of nano-silver antibacterial real silk
CN102936836A (en) * 2012-12-07 2013-02-20 苏州大学 Method for preparing antibacterial polyester by use of plant nano-silver
CN103147310A (en) * 2013-03-27 2013-06-12 南通苏州大学纺织研究院 Method for finishing cotton fabrics through spraying plant essential oil
CN103147310B (en) * 2013-03-27 2014-08-20 南通苏州大学纺织研究院 Method for finishing cotton fabrics through spraying plant essential oil
CN103938455A (en) * 2014-04-21 2014-07-23 章敏辉 Process for softening bed products by use of milk
CN104306553A (en) * 2014-09-29 2015-01-28 青海唐古特生物科技有限公司 Food, health product or medicine composition for reducing blood fat
CN104306553B (en) * 2014-09-29 2019-04-16 青海唐古特生物科技有限公司 A kind of food of reducing blood lipid, health care product or pharmaceutical composition
CN104532557A (en) * 2014-12-23 2015-04-22 常熟市中宏针织厂 Finishing process of garment shell fabric
CN104611927A (en) * 2015-02-03 2015-05-13 湖州市菱湖重兆金辉丝织厂 Novel antistatic silk fabric based on pre-irradiation
CN105239371A (en) * 2015-10-20 2016-01-13 安踏(中国)有限公司 Manufacturing method of moisture-retention fabric, fabric, clothing and moisture-retention foam finishing agent
CN105821660A (en) * 2016-05-13 2016-08-03 东莞市联洲知识产权运营管理有限公司 Modified silk fiber with high moisture absorbability and moisture retentivity and preparing method thereof
CN105821660B (en) * 2016-05-13 2018-05-15 南京金榜麒麟家居股份有限公司 A kind of modified silk fiber of highly hygroscopic moisture retention and preparation method thereof
CN106012554A (en) * 2016-06-02 2016-10-12 湖州市菱湖重兆金辉丝织厂 Down jacket antibacterial finishing agent
CN111321593A (en) * 2018-12-14 2020-06-23 优纤科技(丹东)有限公司 Natural sterilization and deodorization fiber and preparation method thereof

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