CN100402735C - Fiber processing agent and fiber processed with the fiber processing agent - Google Patents
Fiber processing agent and fiber processed with the fiber processing agent Download PDFInfo
- Publication number
- CN100402735C CN100402735C CNB038159201A CN03815920A CN100402735C CN 100402735 C CN100402735 C CN 100402735C CN B038159201 A CNB038159201 A CN B038159201A CN 03815920 A CN03815920 A CN 03815920A CN 100402735 C CN100402735 C CN 100402735C
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- China
- Prior art keywords
- fiber
- egg shell
- shell membrane
- organic compound
- fibre finish
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention provides a fiber processing agent used for processing a surface of a fiber, and the fiber processing agent contains a soluble eggshell membrane and a reactive organic compound having a reactive group. With the fiber processed with the fiber processing agent having the composition as described above, even when the fiber is used for a long period of time, the eggshell membrane is not removed therefrom and the properties provided by the eggshell membrane can be maintained, so that the fiber has excellent durability and can continuously provide the moisture retention, water-absorbing property, moisture-absorbing property, antistatic property, and wound-treating property.
Description
Technical field
Fiber after the present invention relates to fibre finish and utilizing this fibre finish processing.
Background technology
In the past, used the goods of fiber such as blouse, full dress to flood market with the skin material at the seat of shirt, pants, skirt, wadding, furniture vehicle etc. etc.
These fibres require the characteristic of fibrous material also different according to its different purposes.These desired characteristics have for example moisture retention, water imbibition, hygroscopicity, antistatic property etc.
For example,, often require to have hygroscopicity etc. because of perspiring because be general dress as blouse more.In order to satisfy this hygroscopicity, the fiber of use has multiple.This fiber for example has synthetic fiber such as nylon, polyester, acrylic acid, polyurethane; Natural fabrics such as cotton, fiber crops, wool; The composite fibre that above-mentioned substance is also arranged.
In addition, also carried out following trial, promptly utilized specific fibre finish that these fibers are handled, above-mentioned characteristic is improved, perhaps made it have other special characteristics outside the above-mentioned characteristic.
For example, as everyone knows, egg shell membrane except that can improving above-mentioned characteristic, when be attached to skin surface hinder on the face time, have the effect of curing this wound ahead of time, just has trauma care, therefore, in order to use in big hindering on the face easily, make thin material after the powder of egg shell membrane and fibrous material be mixed together, make sheet material, be used to cure the wound.
But, in the sheet material that constitutes by fibrous material with aforementioned trauma care, in order to make trauma care more effective, there is motion to propose (opening flat 7-246234 communique) following manufacture method with reference to the spy, be about to the aqueous solution preparation of egg shell membrane as solubility, impregnate fabric or do not have thin slices such as fabric in this aqueous solution makes its drying make sheet material.
Utilize this method under only expendable situation such as disposable grade, certainly bring into play characteristics such as trauma care, without any problem.
But, in the described technology of aforesaid communique, with fabric or do not have thin slices such as fabric and be immersed in the aqueous solution that only contains egg shell membrane and make its drying, thereby, a little less than the bed knife of egg shell membrane to sheet material.For this reason, in the washing of carrying out sheet material repeatedly etc., or under the long-term situation about using, egg shell membrane can be removed, and durability reduces, and can not continue to keep characteristics such as moisture retention, water imbibition, hygroscopicity, antistatic property, trauma care.
Summary of the invention
One of purpose of the present invention is to provide a kind of good endurance, can continue the fiber that keeps the fibre finish of moisture retention, water imbibition, hygroscopicity, antistatic property, trauma care and utilize this fibre finish to handle.
Fibre finish of the present invention is to use when handling fiber surface, it is characterized in that, contains the solubility egg shell membrane and has the reactive organic compound of reactive group.
So-called solubility egg shell membrane among the present invention is meant the egg shell membrane of bird egg (representational have egg), utilizes chemicals treatment such as soda acid oxidant reductant to make the egg shell membrane of water-soluble form.
The bird egg that uses in the egg shell membrane is birds eggs such as also available duck's egg, quail egg, Ostrich egg except that egg.
The reductant that uses in the chemicals treatment is representational for example thioglycolic acid (thioglycolic acid), propane thioic acid, 2 mercapto ethanol etc.
In the preparation of the solubility egg shell membrane of using when making fibre finish, at first prepare the aqueous solution of solubility egg shell membrane, and can utilize any method to prepare, the compound method that several typical is for example arranged, in egg shell membrane 1 weight portion, add 10～32 weight portions thioglycolic acid (100% aqueous concentration, 14.3mol), propane thioic acid (aqueous 100%, 11.3mol), the aqueous solution of above concentration about perhaps their mixed material 1mol/ rise.
It is warming up to 50～70 ℃, kept 5～tens of hours, dissolve fully until egg shell membrane.Remove the reductant of use then and just make the aqueous solution.
Concrete is to add acetone in above-mentioned treatment fluid, makes to become after solubility and the lysed egg shell membrane precipitation, removes liquid (reductant), utilizes acetone with sediment washing 1～2 time then, adds water afterwards and makes the aqueous solution.
In addition, other method is after the reductant liquid that will dissolve egg shell membrane for anti-oxidation is made hydrochloric acid acidity, and dialysis water is removed reductant.
Using under the situation of 2 mercapto ethanol as reductant, in order to strengthen reducing power, pH is being transferred to alkalescence one side about 9～10, handling 5～tens of hours down at 50～70 ℃.In this case, because egg shell membrane is difficult to dissolve fully, thereby stop within a certain period of time handling, insoluble matter is removed in centrifugation, and water is dialysed or made dissolving egg shell membrane precipitation with acetone afterwards, extracts, make it be dissolved in water etc. afterwards, the aqueous solution of preparation solubility egg shell membrane.
And, when utilizing alkali to decompose preparation solubility egg shell membrane, in egg shell membrane 1 weight portion, add the aqueous solution of NaOH 1～number N (regulation) or added the aqueous solution (concentration of alcohol 50～70% etc.) of ethanol, under 40～60 ℃ condition, handled 3～6 hours, thereafter in the water and dialyse.
In the fibre finish of the present invention, the previous reaction organic compound preferably contains: the hydrophilic compounds that has polymerisable vinyl in (composition 1) molecule; (composition 2) contains the monomer of hydroxyl, carboxyl, amino, sulfonic group, phosphate; The hydrophilic compounds that (composition 3) has epoxy radicals; (composition 4) has one or more in the compound of '-aziridino.
The concrete example of aforementioned (composition 1) has: polyethyleneglycol diacrylate, polyethylene glycol dimethacrylate, polymer with bis phenol A glycol diacrylate, polymer with bis phenol A ethylene glycol dimethacrylate, bisphenol S polyethylene glycol dimethacrylate etc.
The concrete example of aforementioned (composition 2) has: acrylic acid, methacrylic acid, maleic acid, itaconic acid, acrylamide, Methacrylamide, vinyl sulfonic acid, methacrylic acid hydroxyl propyl ester etc.
The concrete example of aforementioned (composition 3) has polyethyleneglycol diglycidylether etc.
The concrete example of aforementioned (composition 4) has the compound of following chemical formula (1) etc.
The present invention prepares the aqueous solution and the reactive organic compound of the solubility egg shell membrane of above explanation, makes fibre finish.
Except that solubility egg shell membrane and reactive organic compound, also can cooperate silk-fibroin, silk gum, chitosan etc.By cooperating above-mentioned substance, can improve hygroscopicity.
According to the present invention, by it being comprised have the reactive organic compound of reactive group, when using the fiber that carried out fiber treatment etc., egg shell membrane can not be removed long-term.Therefore, because the characteristic that can keep egg shell membrane to have, thereby can make good endurance, can continue to keep the fibre finish of moisture retention, water imbibition, hygroscopicity, antistatic property, trauma care.
Fibre finish of the present invention is the total amount of this fibre finish relatively, preferably contains aforementioned solubility egg shell membrane 0.1～10 quality %, contains previous reaction organic compound 1～20 quality %.More preferably contain aforementioned solubility egg shell membrane 0.2～5 quality %, contain previous reaction organic compound 2～10 quality %.
When aforementioned solubility egg shell membrane less than 0.1 quality %, previous reaction organic compound less than 1 quality %, effect deficiencies such as its moisture retention.In addition, when aforementioned solubility egg shell membrane surpassed 10 quality %, previous reaction organic compound above 20 quality %, the fiber of Chu Liing can become hard sometimes.
Fibre finish of the present invention also can have following formation.
Fibre finish of the present invention uses when handling fiber surface, it is characterized in that, contains the solubility egg shell membrane and has adhesive organic compound.
Here, the solubility egg shell membrane is the solubility egg shell membrane that contains in the fibre finish of the present invention as previously described, omits its explanation at this.
In the fibre finish of the present invention, have aforementioned adhesive organic compound and can utilize reactive organic compound with reactive group as aforementioned.
According to the present invention, when using the fiber that carried out fiber treatment etc., can prevent that also egg shell membrane is removed long-term.
In the fibre finish of the present invention, any at least in the previous reaction organic compound preferably contains following (composition 1)～(composition 5) or more than one: the hydrophilic compounds that has polymerisable vinyl in (composition 1) molecule; (composition 2) contains the monomer of hydroxyl, carboxyl, amino, sulfonic group, phosphate; The hydrophilic compounds that (composition 3) has epoxy radicals; (composition 4) has the compound of '-aziridino; (composition 5) has the compound of isocyanate groups or its precursor.
The concrete example of (composition 1) that contains in the previous reaction organic compound～(composition 4) is identical with above-mentioned (composition 1)～(composition 4) as fibre finish explanation of the present invention, in this description will be omitted.
In (composition 5), the concrete example with compound of isocyanate groups has: chemical formula (i) and the hexamethylene diisocyanate of (ii) representing and 1,3,5-triisocyanate-pentane etc.
OCN-(CH
2)
6-NCO --------(i)
In (composition 5), the concrete example of compound with precursor of isocyanate groups has: the precursor of hexamethylene diisocyanate and 1,3, the precursor of 5-triisocyanate-pentane.Wherein the precursor of hexamethylene diisocyanate for example has: chemical formula (iii) and (iv) expression 1,6-two (methylamino formoxyl)-n-hexane, 1,6-two (phenyl amino formoxyl)-n-hexane.In addition, 1,3, the precursor of 5-triisocyanate-pentane for example has the chemical formula (compound v).
Aforementioned in the fibre finish of the present invention have adhesive organic compound and can use lipophilicity compounds such as wax, polysiloxanes, and/or contain the macromolecular compound of groups such as ether, acrylic, carbamic acid base, amide groups, ester group.
Though have adhesive organic compound is a kind of reactivity that do not have, but itself have suitable lipophile or hydrophily, and adhere to the organic compound of fiber surface, can be used as the organic compound of the softener that fiber, fabric use, level and smooth finishing agent, antistatic agent etc.Specifically, outside lipophilicity compound paraffin removal, the polysiloxanes, neutral grease, mineral oil and animal wet goods are for example arranged, in addition, macromolecular compound for example has polyethylene glycol (two) alkylates, polyol ester, poly-alkylamide, polyacrylate etc.
The present invention can make above-mentioned lipophilicity compound and/or macromolecular compound adhere to fiber surface, can stop to be immersed in intrastitial egg shell membrane protein and to dissolve outside fiber and separate out.For this reason, the same with reactive organic compound, even the fiber of fiber treatment etc. was carried out in long-term use, can prevent that also egg shell membrane from being removed fully.
Fiber of the present invention is characterised in that, utilizes aforesaid fibre finish of the present invention to carry out processing.
The fiber of handling for example has synthetic fiber such as nylon, polyester, acrylic acid, polyurethane; Natural fabrics such as cotton, fiber crops, wool; The composite fibre that above-mentioned substance is also arranged.
The processing method of fibre finish can use any processing method to carry out, and for example can use infusion process, pad dyeing method etc.Infusion process have family warm settled process, heating paddling process etc.
The pad dyeing method has the baking of rolling method, pad steaming process etc.Wherein can use any method during reactive organic compound.Preferably use the baking method of rolling during nonreactive compound.
The present invention handles the fiber that can make good endurance, continue to keep moisture retention, water imbibition, hygroscopicity, antistatic property, trauma care by utilizing the aforementioned fibers finishing agent.
The specific embodiment
More specifically describe the present invention below by embodiment and comparative example.
Embodiment 1
When the preparation fibre finish, at first prepare the aqueous solution of solubility egg shell membrane.Open the egg of band eggshell, remove after the egg liquid, the eggshell that has egg shell membrane that obtains is put into clean water, remove shell breaking with hand, egg shell membrane is immersed in 1% aqueous hydrochloric acid solution 1 hour, and dissolving is attached to the small eggshell on the egg shell membrane, washing afterwards, make its air dry, obtain egg shell membrane.
In this egg shell membrane 50g, add the THIOGLYCOL aqueous solution that 1.5 liters of 5.0mol/ rise.The THIOGLYCOL aqueous acid that will contain egg shell membrane makes the egg shell membrane dissolving 60 ℃ of following heat treated 12 hours.
The aqueous solution of egg shell membrane has been dissolved in filtration, to the water dialysis of hydrochloric acid acidity, removes thioglycolic acid afterwards, makes the solubility egg shell membrane aqueous solution.
Cooperate the above-mentioned solubility egg shell membrane aqueous solution and the reactive organic compound that obtains then, the preparation fibre finish.The concentration of each composition of fibre finish is as follows.
The solid constituent 5.0 quality % of solubility egg shell membrane
Water 89.5 quality %
Reactive organic compound (compound of following chemical formula (2)) 5.0 quality %
Reactive organic compound (compound of following chemical formula (3)) 0.5 quality %
Use the fibre finish obtain like this, (weight per unit area is 120g/m to make the taffeta fabric of polyester 100%
2) impregnation wherein, afterwards, be rolled to impregnation rate 70% with mangle.105 ℃ of steam heat treatments 10 minutes, then, carry out hot water wash (40 ℃, 10 minutes), drying and HEAT SETTING afterwards.
Embodiment 2
Wash the taffeta fabric that obtains similarly to Example 1 with home-use automatic washing machine, 15 minutes, will do the wash 2 times and be set at washing once, wash 10 times.
Embodiment 3
Cooperating the solubility egg shell membrane aqueous solution and having adhesive organic compound is light silicone (light silicone) PS-1000 (Kyoeisha Chemical Co., Ltd.'s system), the fibre finish that preparation the present invention second invention relates to.In addition, the solubility egg shell membrane aqueous solution that uses in this fibre finish preparation utilizes embodiment 1 described compound method to prepare.
The solid constituent 10.0 quality % of solubility egg shell membrane
Light silicone PS-1000 10.0 quality %
Water 80.0 quality %
Then, use the fibre finish obtain like this, (weight per unit area is 120g/m to make the taffeta fabric of polyester 100%
2) impregnation wherein, afterwards, be rolled to impregnation rate 70% with mangle.Afterwards, the taffeta fabric that obtains under 150 ℃, air drier inner drying 5 minutes, is utilized and method that embodiment 2 is same, just 15 minutes are washed to be set at for 2 times and wash 1 time, wash 10 times with home-use full-automatic washing machine.
Comparative example 1
Use and the taffeta fabric of the polyester 100% that embodiment 1 is same, do not carry out the processing of fibre finish etc.
Comparative example 2
Be that with embodiment 1 difference fibre finish only contains the solubility egg shell membrane.The concentration of each composition of fibre finish is as follows.
The solid constituent 5 quality % of solubility egg shell membrane
Water 95 quality %
Thereafter and the same washing of embodiment 2 10 times.
Comparative example 3
With the operation same, use fibre finish, preparation tower husband according to following cooperation preparation with previous embodiment 3
The silk fabric fabric.
The solid constituent 10.0 quality % of solubility egg shell membrane
Water 90.0 quality %
Then and the taffeta fabrics that obtain for 10 times of the same washing of embodiment 3.
Reference example 1
With with aforementioned comparative example 3 identical operations, use fibre finish, the preparation taffeta fabric according to following cooperation preparation.
Light silicone PS-1000 10.0 quality %
Water 90.0 quality %
Then and the thick fabrics of tower husband that obtain for 10 times of the same washing of embodiment 3.
Evaluation method 1
First of embodiment 1,2 and comparative example 1,2 invented the taffeta fabric that relates to, measure hygroscopicity, absorption speed, frictional electrification pressure.In addition, second of embodiment 3 and comparative example 3 and reference example 1 invented the taffeta fabric that relates to, measure absorption speed, frictional electrification pressure.In addition, the sample of taffeta fabric of processing was placed 12 hours under 23 ℃, in relative humidity 30% atmosphere, after the damping, this sample is placed under 30 ℃, relative humidity 80% atmosphere measures its changes in weight, measure aforementioned hygroscopicity thus.Aforementioned water imbibition is measured according to JIS L 1096-A method.Aforementioned frictional electrification is measured according to JIS L 1094-B method at all.This evaluation result is shown in Table 1.
Table 1
| Hygroscopicity [%] | Absorption speed | [V] pressed in frictional electrification | |
| Embodiment 1 | 2.1 | Below 1 second | 200 |
| Embodiment 2 | 2.0 | Below 1 second | 400 |
| Comparative example 1 | 0.1 | Do not absorb water more than 5 minutes yet | 4800 |
| Comparative example 2 | 0.2 | Do not absorb water more than 5 minutes yet | 4500 |
| Embodiment 3 | - | 1～5 second | 1400 |
| Comparative example 3 | - | Do not absorb water more than 5 minutes yet | 4200 |
| Reference example 1 | - | 2～5 minutes | 2800 |
The result who estimates from this evaluation method 1 as can be known, embodiment 1 compares with comparative example 1, hygroscopicity, absorption speed height, frictional electrification is pressed little, everyway is good.Therefore, its water imbibition of fiber, hygroscopicity, the antistatic property that utilizes fibre finish of the present invention (material that contains reactive organic compound) to handle improves.
Comparing embodiment 2 and comparative example 2 as can be known, the hygroscopicity of embodiment 2, absorption speed height, it is little that frictional electrification is pressed, everyway is good.Therefore, utilize fibre finish of the present invention (material that contains reactive organic compound) even the fiber of handling washing also continues to keep its effect, thereby good endurance.
In addition, in comparative example 2, under unwashed A-stage, 500V is pressed in hygroscopicity 2.0%, absorption speed below 1 second, frictional electrification.From this A-stage and the washing after relatively, as prior art, only contain at fibre finish under the situation of solubility egg shell membrane, do not have durability.
In addition, comparing embodiment 3 and comparative example 3 as can be known, embodiment 3 is than comparative example 3 absorption speed height, frictional electrification is pressed little, everyway is good.In addition, embodiment 3 is compared with reference example 1, also can obtain same result.Therefore, the fiber that utilizes fibre finish of the present invention (containing fibre finish) to handle with adhesive organic compound, its water imbibition and antistatic property improve.
Evaluation method 2
Commercially available adhesion zone is attached on the skin, after peeling off, after roughening the skin with acetone solution, the taffeta fabric cloth that embodiment, comparative example are made is fixed on the last arm, 6 hours every days, fixing in specific fate, measure the electric conductivity that volume has the last arm of this cloth.Its evaluation result is shown in Table 2.
Table 2
From the evaluation result of this evaluation method 2 as can be known, embodiment 1 compares with comparative example 1, and it is big that electric conductivity becomes.The value that this electricity is led is big more, and the electrical conductivity of skin is high more, the skin regeneration of the part of pachylosis and improved the skin moisture-keeping state.
Therefore, utilize the fiber of fibre finish of the present invention (material that contains reactive organic compound) processing as can be known, make the part skin regeneration of pachylosisization, thereby trauma care and moisture retention raising.And as the test of this evaluation method 2,, also can confirm to have trauma care effect and moistening effect even use through long-time, thereby, can continue for a long time to keep each characteristic.
Industrial applicibility
The present invention can as the fibre finish of the characteristics such as the moisture retention that improves fiber, water imbibition, hygroscopicity, antistatic property, perhaps improve fiber and the fibre of these characteristics.
Claims (5)
1. one kind at the fibre finish that carries out using when fiber surface is handled, it is characterized in that: contain the solubility egg shell membrane and have the reactive organic compound of reactive group, the previous reaction organic compound contains at least a following composition that is selected from: polyethyleneglycol diacrylate, polyethylene glycol dimethacrylate, polymer with bis phenol A glycol diacrylate, polymer with bis phenol A ethylene glycol dimethacrylate, bisphenol S polyethylene glycol dimethacrylate, polyethyleneglycol diglycidylether.
2. fibre finish as claimed in claim 1 is characterized in that: with respect to the total amount of this fibre finish, contain the aforementioned solubility egg shell membrane of 0.1～10 quality %, contain the previous reaction organic compound of 1～20 quality %.
3. fiber is characterized in that: it utilizes the fibre finishs of claim 1 or 2 records to carry out processing.
4. fibre finish that when handling fiber surface, uses; it is characterized in that: contain the solubility egg shell membrane and have an adhesive organic compound, wherein said to have adhesive organic compound be the macromolecular compound that is selected from the lipophilicity compound of wax and silicone and/or contains ether, acryloyl group, carbamic acid base, acylamino-or ester group.
5. fiber, it is characterized in that: it utilizes the described fibre finish of claim 4 to carry out processing.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002196880 | 2002-07-05 | ||
| JP196880/2002 | 2002-07-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1665979A CN1665979A (en) | 2005-09-07 |
| CN100402735C true CN100402735C (en) | 2008-07-16 |
Family
ID=30112379
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB038159201A Expired - Fee Related CN100402735C (en) | 2002-07-05 | 2003-07-07 | Fiber processing agent and fiber processed with the fiber processing agent |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20050246840A1 (en) |
| EP (1) | EP1541748A4 (en) |
| CN (1) | CN100402735C (en) |
| AU (1) | AU2003281313A1 (en) |
| WO (1) | WO2004005607A1 (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1303282C (en) * | 2002-02-19 | 2007-03-07 | 松本油脂制药株式会社 | Treatment method for imparting properties of absorbing and releasing moisture to fiber |
| US7767297B2 (en) * | 2007-07-30 | 2010-08-03 | Idemitsu Technofine Co., Ltd. | Fiber, fiber assembly, and fiber producing method |
| CN101487189B (en) * | 2008-11-03 | 2011-02-16 | 浙江理工大学 | Fibroin reinforcement process of fragile silk |
| CA2770724A1 (en) | 2009-08-10 | 2011-02-17 | Galenea Corporation | 5-ht inhibiting indole compounds |
| CN102352563A (en) * | 2011-07-29 | 2012-02-15 | 苏州卡奇特纺织有限公司 | Antistatic agent for cotton fabrics |
| CN102352562A (en) * | 2011-07-29 | 2012-02-15 | 苏州卡奇特纺织有限公司 | Antistatic agent for wool acrylic fabric |
| JP2013129938A (en) * | 2011-12-21 | 2013-07-04 | Komatsu Seiren Co Ltd | Functional fiber fabric and method for producing the same |
| CN102766939A (en) * | 2012-06-27 | 2012-11-07 | 吴江亚太化纺有限公司 | Polyamide 66BCF carpet yarn |
| CN103726323A (en) * | 2012-10-16 | 2014-04-16 | 东丽纤维研究所（中国）有限公司 | Durable antistatic terylene textile |
| EP3313464B1 (en) | 2015-06-24 | 2020-08-26 | Biovotec AS | Tissue engineering scaffolds comprising particulate egg shell membrane |
| GB201519923D0 (en) | 2015-11-11 | 2015-12-23 | Biovotec Dac And Biovotec As | Dry biocompatible disintegrateable films for delivering particulate egg shell membrane to a wound |
| CN105544213B (en) * | 2016-01-21 | 2018-05-15 | 苏州印丝特纺织数码科技有限公司 | Polypropylene slurry that a kind of egg shell is modified and preparation method thereof |
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2003
- 2003-07-07 CN CNB038159201A patent/CN100402735C/en not_active Expired - Fee Related
- 2003-07-07 EP EP03741236A patent/EP1541748A4/en not_active Withdrawn
- 2003-07-07 US US10/518,541 patent/US20050246840A1/en not_active Abandoned
- 2003-07-07 AU AU2003281313A patent/AU2003281313A1/en not_active Abandoned
- 2003-07-07 WO PCT/JP2003/008591 patent/WO2004005607A1/en active Application Filing
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04311767A (en) * | 1991-04-09 | 1992-11-04 | Teijin Ltd | Polyurethane resin composition excellent in hydroscopiciyty |
| JPH06158545A (en) * | 1992-11-06 | 1994-06-07 | Kanebo Ltd | Silk fibroin-graft polymer-processed fabric and its production |
| JPH07246234A (en) * | 1994-03-08 | 1995-09-26 | Q P Corp | Sheet material |
| JPH07300770A (en) * | 1994-04-28 | 1995-11-14 | Komatsu Seiren Kk | Modified polyester fiber material and its production |
| JPH08258235A (en) * | 1995-03-22 | 1996-10-08 | Yamato Kagaku Kogyo Kk | Decorative sheet of wall, furniture, notions and the like |
| WO1997040227A1 (en) * | 1996-04-19 | 1997-10-30 | Idemitsu Petrochemical Co., Ltd. | Textile treatments and fibers and textile goods treated therewith |
| JPH10219568A (en) * | 1997-01-31 | 1998-08-18 | Kobayashi Pharmaceut Co Ltd | Surfacing material for water-absorbing material and body-fluid absorbing material produced by using the surfacing material |
| JP2000079659A (en) * | 1998-06-30 | 2000-03-21 | Idemitsu Petrochem Co Ltd | Material for leather-like article and leather-like article wherein material is laminated to base material |
| JP2001172870A (en) * | 1999-12-20 | 2001-06-26 | Toray Ind Inc | Moisture-absorbing fiber structure |
| JP2002129482A (en) * | 2000-10-16 | 2002-05-09 | Okamoto Ind Inc | Synthetic resin leather |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1541748A4 (en) | 2008-02-20 |
| US20050246840A1 (en) | 2005-11-10 |
| WO2004005607A1 (en) | 2004-01-15 |
| AU2003281313A1 (en) | 2004-01-23 |
| EP1541748A1 (en) | 2005-06-15 |
| CN1665979A (en) | 2005-09-07 |
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