CN101357995A - Light transparent and flame retardant changeable fiber reinforced plastics - Google Patents
Light transparent and flame retardant changeable fiber reinforced plastics Download PDFInfo
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- CN101357995A CN101357995A CNA2007100444676A CN200710044467A CN101357995A CN 101357995 A CN101357995 A CN 101357995A CN A2007100444676 A CNA2007100444676 A CN A2007100444676A CN 200710044467 A CN200710044467 A CN 200710044467A CN 101357995 A CN101357995 A CN 101357995A
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Abstract
The invention relates to fiberglass reinforced plastic, in particular to transparent variable flame retardant fiberglass reinforced plastic. The transparent variable flame retardant fiberglass reinforced plastic comprises a transparent flame retardant glass plate layer containing fiber glass and a transparent variable layer. The transparent variable layer is prepared with substance comprising copal gum, photochromic glass micropowder and an initiator according to 100:20-90:1-5 by weight. The preparation method of the transparent variable flame retardant fiberglass reinforced plastic comprises the following steps: the transparent flame retardant glass plate layer is prepared; the mixture of the transparent variable layer is prepared; and the transparent variable layer is prepared. As the technical solution is adopted, the illumination problem in buildings is solved so that the light intensity in the buildings can change with the illumination, thus meeting the requirement of illumination, improving the safety of the buildings and producing great economic benefits.
Description
Technical field
The present invention relates to glass reinforced plastic, particularly a kind of glass reinforced plastic of light transparent and flame retardant changeable.
Background technology
The transparent glass steel is the compound lighting material of a kind of galss fiber reinforced resin, has the intensity height, and is non-friable, good toughness, and therefore the characteristics of easy-formation are widely used in building transparent square, transparent worker-house, transparent booth or the like, remarkable in economical benefits.Yet common transparent glass steel only plays the printing opacity effect, can not regulate the transmitance of light with the variation of light intensity.Common transparent glass steel does not have fire-retardant effect yet.
Summary of the invention
The object of the present invention is to provide a kind of transparent glass steel transmitance and can be fire-retardant that can regulate light with the variation of light intensity.
Realize that the object of the invention technical scheme is: a kind of glass reinforced plastic of light transparent and flame retardant changeable, comprise the printing opacity fireproof glass flaggy and the variable light transmission layer that contain glass fibre, wherein, the variable light transmission layer is prepared from by the material that comprises transparent resin, photochromic glass micro mist and initiator, and their weight proportion is followed successively by: 100: 20-90: 1-5.
Further, the glass reinforced plastic of above-mentioned light transparent and flame retardant changeable, the variation range of its transmittance is 0.6-0.85.Described transparent resin is a kind of in transparent unsaturated polyester resin, the epoxy vinyl resin.Described initiator is a kind of in MEKP, the cyclohexanone peroxide.The preparation material of described variable light transmission layer also comprises the promotor cobalt iso-octoate.
A kind of preparation method of glass reinforced plastic of above-mentioned light transparent and flame retardant changeable comprises the steps:
1), the preparation process of printing opacity fireproof glass flaggy: select transparent resin and glass fibre for use, add the fire retardant material manufacturing.
2), variable light transmission layer mixture preparation process: with transparent resin, photochromic glass micro mist, initiator or contain promotor, by ratio requirement, earlier photochromic glass micro mist uniform mixing in transparent resin, adding initiator then stirs, add promotor mixing at last, standby.
3), the preparation process of variable light transmission layer: with step 2) Zhi Bei variable light transmission layer mixture is coated in the surface cure of step 1) transparent glass steel.
Above-mentioned stating solidified the curing of employing UV-irradiation.The size of above-mentioned photochromic glass micro mist is the 80-100 order.Above-mentioned fire retardant material is a magnesium hydroxide.
Owing to adopted above-mentioned technical solution, efficiently solve the problem of illumination in the buildings, the light intensity in the buildings can be changed with the variation of illumination, satisfied the demand of illumination better, improve the security of buildings, can produce great economic benefit.
Embodiment
Below the present invention is described in further detail.
A kind of glass reinforced plastic of light transparent and flame retardant changeable, comprise the printing opacity fireproof glass flaggy and the variable light transmission layer that contain glass fibre, wherein, the variable light transmission layer is prepared from by the material that comprises transparent resin, photochromic glass micro mist and initiator, and their weight proportion is followed successively by: 100: (20-90): (1-5).
Further, the glass reinforced plastic of above-mentioned light transparent and flame retardant changeable, the variation range of its transmittance is 0.6-0.85.Described transparent resin is a kind of in transparent unsaturated polyester resin, the epoxy vinyl resin.Described initiator is a kind of in MEKP, the cyclohexanone peroxide.The preparation material of described variable light transmission layer also comprises the promotor cobalt iso-octoate.
A kind of preparation method of glass reinforced plastic of light transparent and flame retardant changeable comprises the steps:
1, the preparation of printing opacity fireproof glass flaggy:
Select transparent resin and glass fibre for use, add the fire retardant material manufacturing.
2, variable light transmission layer mixture preparation: a kind of with in the transparent resins such as transparent resin such as unsaturated polyester resin, epoxy vinyl resin, photochromic glass micro mist, initiator, promotor, by ratio requirement, earlier photochromic glass micro mist uniform mixing in transparent resin, adding initiator then stirs, add promotor mixing at last, standby.
3, the preparation of variable light transmission layer: the surface cure that the variable light transmission layer mixture of step 2 preparation is coated in step 1 transparent glass steel.
Embodiment 1
Unsaturated polyester resin SB39: photochromic glass micro mist: cyclohexanone peroxide: cobalt iso-octoate=100: 20: 2: 1.Described unsaturated polyester resin SB39 is that commercially available Dongying City magnificent chemical industry far away limited liability company produces.The photochromic glass micro mist is commercially available Hubei Huaguang New Material Co.,Ltd, and particle diameter is 80 orders.Cyclohexanone peroxide, cobalt iso-octoate are all from Shanghai chemical reagent company limited.
Embodiment 2
Unsaturated polyester resin SB39: photochromic glass micro mist: MEKP: cobalt iso-octoate=100: 50: 3: 1.Described unsaturated polyester resin SB39 is that commercially available Dongying City magnificent chemical industry far away limited liability company produces.The photochromic glass micro mist is commercially available Hubei Huaguang New Material Co.,Ltd, and particle diameter is 100 orders.MEKP, cobalt iso-octoate are all from Shanghai chemical reagent company limited.
Embodiment 3
Unsaturated polyester resin SB39: photochromic glass micro mist: MEKP: cobalt iso-octoate=100: 90: 5: 2.Described unsaturated polyester resin SB39 is that commercially available Dongying City magnificent chemical industry far away limited liability company produces.The photochromic glass micro mist is commercially available Hubei Huaguang New Material Co.,Ltd, and particle diameter is 90 orders.MEKP, cobalt iso-octoate are all from Shanghai chemical reagent company limited.
Embodiment 4
Epoxy vinyl portions of resin photochromic glass micro mist: cyclohexanone peroxide: cobalt iso-octoate=100: 90: 5: 2.Described epoxy vinyl resin is that commercially available Anhui Tai Chang company limited produces.The photochromic glass micro mist is commercially available Hubei Huaguang New Material Co.,Ltd, and particle diameter is 90 orders.Cyclohexanone peroxide, cobalt iso-octoate are from Shanghai chemical reagent company limited.
Embodiment 5
Epoxy vinyl portions of resin photochromic glass micro mist: cyclohexanone peroxide: cobalt iso-octoate=100: 20: 1: 1.Described epoxy vinyl resin is that commercially available Anhui Tai Chang company limited produces.The photochromic glass micro mist is commercially available Hubei Huaguang New Material Co.,Ltd, and particle diameter is 80 orders.Cyclohexanone peroxide, cobalt iso-octoate are from Shanghai chemical reagent company limited.
Embodiment 6
Epoxy vinyl portions of resin photochromic glass micro mist: MEKP: cobalt iso-octoate=100: 40: 3: 1.Described epoxy vinyl resin is that commercially available Anhui Tai Chang company limited produces.The photochromic glass micro mist is commercially available Hubei Huaguang New Material Co.,Ltd, and particle diameter is 100 orders.MEKP, cobalt iso-octoate are from Shanghai chemical reagent company limited.
In the foregoing description if do not add cobalt iso-octoate promotor, can adopt UV-irradiation 10-24 hour with variable light transmission layer mixture solidified to the transparent glass steel.
Above embodiment is only for the usefulness that the present invention is described, but not limitation of the present invention, person skilled in the relevant technique, under the situation that does not break away from the spirit and scope of the present invention, can also make various conversion or modification, therefore all technical schemes that are equal to also should belong to category of the present invention, should be limited by each claim.
Claims (9)
1, a kind of glass reinforced plastic of light transparent and flame retardant changeable, it is characterized in that, comprise the printing opacity fireproof glass flaggy and the variable light transmission layer that contain glass fibre, wherein, the variable light transmission layer is prepared from by the material that comprises transparent resin, photochromic glass micro mist and initiator, and their weight proportion is followed successively by: 100: 20-90: 1-5.
2, the glass reinforced plastic of light transparent and flame retardant changeable according to claim 1 is characterized in that, the variation range of its transmittance is 0.6-0.85.
3, the glass reinforced plastic of light transparent and flame retardant changeable according to claim 1 is characterized in that, described transparent resin is a kind of in transparent unsaturated polyester resin, the epoxy vinyl resin.
4, the glass reinforced plastic of light transparent and flame retardant changeable according to claim 1 is characterized in that, described initiator is a kind of in MEKP, the cyclohexanone peroxide.
5, the glass reinforced plastic of light transparent and flame retardant changeable according to claim 1 is characterized in that, the preparation material of described variable light transmission layer also comprises the promotor cobalt iso-octoate.
6, a kind of preparation method of glass reinforced plastic of light transparent and flame retardant changeable as claimed in claim 1 is characterized in that, comprises the steps:
1), the preparation process of printing opacity fireproof glass flaggy: select transparent resin and glass fibre for use, add the fire retardant material manufacturing.
2), variable light transmission layer mixture preparation process: with transparent resin, photochromic glass micro mist, initiator or contain promotor, by ratio requirement, earlier photochromic glass micro mist uniform mixing in transparent resin, adding initiator then stirs, add promotor mixing at last, standby.
3), the preparation process of variable light transmission layer: with step 2) Zhi Bei variable light transmission layer mixture is coated in the surface cure of step 1) transparent glass steel.
7, the preparation method of the glass reinforced plastic of light transparent and flame retardant changeable according to claim 6 is characterized in that, described curing adopts UV-irradiation to solidify.
8, the preparation method of the glass reinforced plastic of light transparent and flame retardant changeable according to claim 6 is characterized in that, the size of described photochromic glass micro mist is the 80-100 order.
9, the preparation method of the glass reinforced plastic of light transparent and flame retardant changeable according to claim 6 is characterized in that, described fire retardant material is a magnesium hydroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100444676A CN101357995A (en) | 2007-08-01 | 2007-08-01 | Light transparent and flame retardant changeable fiber reinforced plastics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100444676A CN101357995A (en) | 2007-08-01 | 2007-08-01 | Light transparent and flame retardant changeable fiber reinforced plastics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101357995A true CN101357995A (en) | 2009-02-04 |
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ID=40330602
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007100444676A Pending CN101357995A (en) | 2007-08-01 | 2007-08-01 | Light transparent and flame retardant changeable fiber reinforced plastics |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101357995A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102558728A (en) * | 2012-01-13 | 2012-07-11 | 上海多凯复合材料有限公司 | Reinforced acrylic resin compound material |
| CN102816422A (en) * | 2012-07-23 | 2012-12-12 | 苏州多凯复合材料有限公司 | Improved comfort optical fiber composite material |
| CN102816425A (en) * | 2012-09-04 | 2012-12-12 | 苏州多凯复合材料有限公司 | Low thermal radiation type fiber reinforced composite for lighting, daylighting panel and preparation method thereof |
-
2007
- 2007-08-01 CN CNA2007100444676A patent/CN101357995A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102558728A (en) * | 2012-01-13 | 2012-07-11 | 上海多凯复合材料有限公司 | Reinforced acrylic resin compound material |
| CN102816422A (en) * | 2012-07-23 | 2012-12-12 | 苏州多凯复合材料有限公司 | Improved comfort optical fiber composite material |
| CN102816425A (en) * | 2012-09-04 | 2012-12-12 | 苏州多凯复合材料有限公司 | Low thermal radiation type fiber reinforced composite for lighting, daylighting panel and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20090204 |