CN101324026A - Nanometer traditional chinese medicine microcapsule fabric finishing agent, preparation and fabric finishing method - Google Patents
Nanometer traditional chinese medicine microcapsule fabric finishing agent, preparation and fabric finishing method Download PDFInfo
- Publication number
- CN101324026A CN101324026A CNA200810150440XA CN200810150440A CN101324026A CN 101324026 A CN101324026 A CN 101324026A CN A200810150440X A CNA200810150440X A CN A200810150440XA CN 200810150440 A CN200810150440 A CN 200810150440A CN 101324026 A CN101324026 A CN 101324026A
- Authority
- CN
- China
- Prior art keywords
- chinese medicine
- solution
- fabric
- medicine drug
- hours
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention discloses a microencapsulated nano fabric finishing agent of traditional Chinese medicines, which consists of following components by mass percent: 30 to 60 percent of a solution of the microencapsulated finishing agent of the traditional Chinese medicines, 5 to 20 percent of a nano zinc oxide solution, 10 to 15 percent of a aquosity polyurethane solution and 10 to 55 percent of deionized water which are equal to 100 percent in total. A preparation method of the microencapsulated nano fabric finishing agent comprises following steps: according to fabrics to be processed, the selected traditional Chinese medicines are soaked in ethanol, thus obtaining an extracted solution of the traditional Chinese medicines, polylactic acid, an emulsifying agent OP-10 and the extracted solution of the traditional Chinese medicines are produced into a microencapsulated solution of the traditional Chinese medicines with the solid content of 30 to 50 percent, commercial nano zinc oxide powder, tween-80 and the deionized water are adopted to produce a nano zinc oxide solution which is produced into the nano fabric finishing agent of the traditional Chinese medicines with the microencapsulated solution of the traditional Chinese medicines, the aquosity polyurethane and the deionized water. The microencapsulated nano fabric finishing agent of the traditional Chinese medicines can be used for fabric finishing and leading the finished fabrics to have better antisepsis and antivirus effects.
Description
Technical field
The invention belongs to textile technology field, relate to a kind of fabric finishing agent, be specifically related to a kind of nanometer Chinese medicine microcapsule fabric finishing agent, the method that the invention still further relates to the preparation method of this finishing agent and utilize this finishing agent that fabric is put in order.
Background technology
Growing along with society, people's diseases prevention, disease-resistant consciousness constantly strengthen.Have antibiotic, antiviral function, can protect healthy, as to reduce transmission clothes, be subjected to popular favor.And antibiotic, antiviral clothes, the mode that adopts film to isolate mostly, health-care effect is relatively poor.
The textile clothing lining is carried out nano-antibacterial, antiviral arrangement, form antibiotic, antiviral functional layer on the surface of this lining, can strengthen health-care effect, but adopt prior art that the textile clothing lining is carried out antibiotic, antiviral arrangement, antibiotic, antiviral effect is single, poor effect, anti-bacteria and anti-virus functional layer are easy to flush away.
Summary of the invention
The purpose of this invention is to provide a kind of nanometer Chinese medicine microcapsule fabric finishing agent, be used for the arrangement of fabric, make that the fabric after the arrangement has more comprehensively antibiotic, antiviral effect.
Another object of the present invention provides the preparation method of above-mentioned nanometer Chinese medicine microcapsule dressing agent.
A further object of the invention provides a kind of method of utilizing above-mentioned finishing agent to carry out textile finishing, after fabric is put in order, the anti-bacteria and anti-virus functional layer adhesion-tight of fabric face, is difficult for flush away.
The technical solution adopted in the present invention is, a kind of nanometer Chinese medicine microcapsule fabric finishing agent by mass percentage, is made up of following component:
Chinese medicine drug microcapsule solution 30%～60%
Nano oxidized zinc solution 5%～20%
Aqueous polyurethane solution 10%～15%
Deionized water 10%～55%
Above-mentioned each component total amount 100%.
Another technical scheme of the present invention is, a kind of preparation method of above-mentioned fabrics finishing agent carries out according to the following steps:
Step 1: produce the Chinese medicine drug extract
By mass percentage, difference extracting honeysuckle 30%～60%, the capsule of weeping forsythia 20%～50% and Radix Glycyrrhizae 20%～50%, each component total amount 100%, putting into pulverizer pulverizes, obtaining granularity is 100 orders～400 purpose Chinese medicine drug particles, this Chinese medicine drug particles is put into ethanol, the mass ratio of control Chinese medicine drug particles and ethanol is 25%～30%, soaks after 3 hours～6 hours, places in the ultrasonic machine, under 60 ℃～90 ℃ temperature, handled 1 hour～3 hours, and then, filtered, ethanol evaporation is reclaimed, obtain the Chinese medicine drug extract;
Step 2: preparation Chinese medicine drug microcapsule solution
Get Chinese medicine drug extract and emulsifier op-10 that PLA, step 1 make respectively, place in the emulsion reactor, form mixed liquor, the ratio that control the mass ratio of Chinese medicine drug extract and PLA in this mixed liquor and be 1: 2～10, the concentration of emulsifier op-10 is 1.0g/100ml～3.0g/100ml, oil phase and outer water is 1～10: 100, in temperature is 30 ℃～60 ℃ environment, reactor rotating speed 1000r/min～10000r/min, stir 6h～48h, make solid content and be 30%～50% Chinese medicine drug microcapsule solution;
Step 3: prepare nano oxidized zinc solution
By mass percentage, getting granularity respectively is zinc oxide 5%～20%, soil temperature-80 0.1%～0.5% and the deionized water 79.5%～94.9% of 10nm～80nm, each component total amount 100%, put into agitator, under the normal temperature, rotating speed with 10000r/min～12000r/min stirred 24 hours～36 hours, made zinc oxide fully disperse, and obtained nano oxidized zinc solution;
Step 4: preparation nanometer Chinese medicine microcapsule dressing agent
By mass percentage, get the Chinese medicine drug microcapsule solution 30%～60% that step 2 makes, nano oxidized zinc solution 5%～20%, aqueous polyurethane solution 10%～15% and the deionized water 10%～55% that step 3 makes respectively, each component total amount 100%, nano oxidized zinc solution, Chinese medicine drug microcapsule solution and aqueous polyurethane solution are mixed, stirred 1 hour～2 hours, add deionized water and stirring 1 hour～3 hours, and made nanometer Chinese medicine microcapsule dressing agent.
Another technical scheme of the present invention is that a kind of method of utilizing the described finishing agent of claim 1 to carry out textile finishing is characterized in that, specifically carries out according to the following steps:
A. by with the mass percent 3%～10% of fabric, get nanometer Chinese medicine microcapsule dressing agent, put into agitator, add water, stir, form finish solution, the mass percent of this solution and required finish fabric is 70%～90%;
B. adopting existing fabric dressing technology, the finish solution that the last step obtains is put into the dressing container, put into fabric then, is under 50 ℃～70 ℃ the condition in temperature, dipping 40min～60min;
C. will go up the fabric of step after the dressing and dry and cure, finish the anti-bacteria and anti-virus arrangement of fabric.
The present invention has the following advantages:
1. the microcapsule dressing agent that pharmaceutically active ingredient makes in adopting is used for the arrangement of fabric, and human body is not had toxic and side effect.
2. test the antibacterial effect of nanometer/Chinese medicine microcapsules composite antibiosis, antiviral textiles, clothes according to standard GB/T 20944-2007.To nanometer/Chinese medicine microcapsules composite antibiosis, antiviral textiles effect 1 hour, test to the average bacteriostasis rate of Staphylococcus aureus (AATCC6538) greater than 99%, the average bacteriostasis rate of Escherichia coli (8099) is greater than 95%, and the average bacteriostasis rate of Candida albicans (AATCC10231) is greater than 90%.The bacteriostasis rate of 20 each bacterial classifications of washing back still reaches more than 90%.
3. " antivirus test requires design in disinfection technology standard 2002 editions and " the new Chinese medicine preclinical study guideline " according to the Ministry of Public Health, by external Virus culture experiment, detect finishing agent and handle with finishing agent after textiles to influenza virus (RNA viruses) and the antiviral drug effect of herpes simplex virus (dna virus), through nanometer/Chinese medicine microcapsules composite antibiosis, the textiles that antiviral finishing agent is crossed has significant inhibitory effect to the virus of absorption, the virus inhibiting rate generally is higher than 80% during high virus concentration, be higher than 95% during low concentration, low virus load is had the complete inhibition effect.
4. the fabric of putting in order through finishing agent, wash 20 times after, each performance is constant substantially.
The specific embodiment
The present invention is described in detail below in conjunction with the specific embodiment.
Fabric finishing agent of the present invention, by mass percentage, form by following component:
Chinese medicine drug microcapsule solution 30%～60%
Nano oxidized zinc solution 5%～20%
Aqueous polyurethane solution 10%～15%
Deionized water 10%～55%
Above-mentioned each component total amount 100%.
Wherein, nano oxidized zinc solution, by mass percentage, the granularity by 5%～20% is that the deionized water of the zinc oxide of 30nm～80nm, 0.1%～0.5% soil temperature-80 and 79.5%～94.9% is formed.
Wherein, aqueous polyurethane solution is the solution of solid content 40%.
Wherein, Chinese medicine drug microcapsule solution, be made up of Chinese medicine drug extract, PLA and emulsifier op-10, its solid content is 30%～50%, and the mass ratio of Chinese medicine drug extract and PLA is 1: 2～10 in the solution, the concentration of emulsifier op-10 is 1.0g/100ml～3.0g/100ml.
The Chinese medicine drug extract is that the Chinese medicine drug particles is put into ethanol, and the mass ratio of Chinese medicine drug particles and ethanol is 25%～30%, soaks after 3～6 hours, placing in the ultrasonic machine, is under 60～90 ℃ the condition, to utilize ultrasonic Treatment after 1～3 hour in temperature, filter, ethanol evaporation makes.
The Chinese medicine drug particles by mass percentage, is made of each component total amount 100% honeysuckle 30%～60%, the capsule of weeping forsythia 20%～50% and Radix Glycyrrhizae 20%～50%.
Finishing agent of the present invention, according to the difference of required processing fabric, when preparation is used for the Chinese medicine drug extract of finishing agent, the mass ratio difference of the Chinese medicine of choosing.The consumption of the mass ratio of Chinese medicine and nano material, aqueous polyurethane is selected to determine according to the characteristics of the contained group of fiber in the fabric.
All contain antibiotic, effective antiviral components in honeysuckle, the capsule of weeping forsythia and the Radix Glycyrrhizae.As containing chlorogenic acid, inositol, flavonoids, inositol, saponin and tannin etc. in the honeysuckle, has broad-spectrum antibacterial action, various pathogens such as staphylococcus aureus, shigella dysenteriae all there is stronger inhibitory action, multiple pathogenic microorganisms such as Leptospira, influenza virus and pathogenic moulds are also had inhibitory action; Contain forsythol, coumarin, oleanolic acid, saponin etc. in the capsule of weeping forsythia, have heat-clearing, detoxifcation, etc. effect, cure mainly warm, sore, scrofula, erysipelas, class's rash, influenza; The content of glycyrrhizic acid is many about 10 in the Radix Glycyrrhizae, also has sweet mellow wine glycyrrhizin, liquiritin, liquiritigenin, isoliquiritin, different Radix Glycyrrhizae unit, neoliquriitin, neoisoliquiritin etc.Antiulcer, anti-inflammatory, anticonvulsion, antitumor, anti AIDS virus, antiallergic action, detoxifcation, antibechic, analgesia, spasmolysis, reduction cholesterolemia are arranged, increase pharmacological action such as choleresis.
Because the quantum effect and the huge surface energy of nano material, nano zine oxide has the excellent effect of killing that resists to various bacteria and virus.The microcapsules that itself and plurality of Chinese extract are made carry out compound, utilize the complementation of various types of materials characteristic, form the finishing agent with broad-spectrum antiseptic, antivirus action.
Finishing agent of the present invention utilizes the surface-activity of nano zine oxide, the surface-activity of Chinese medicine microcapsules and the acting in conjunction of aqueous polyurethane, under the reasonably optimizing process conditions, forms powerful the combination with fabric fibre, has excellent washing durability.
The preparation method of finishing agent of the present invention, carry out according to the following steps:
Step 1: produce the Chinese medicine drug extract
By mass percentage, difference extracting honeysuckle 30%～60%, the capsule of weeping forsythia 20%～50% and Radix Glycyrrhizae 20%～50%, each component total amount 100%, putting into pulverizer pulverizes, obtaining granularity is 100 orders～400 purpose drug particles, mass ratio by drug particles and ethanol is 25%～30%, this drug particles is put into ethanol soaked 3～6 hours, then, ethanol and drug particles after soaking are placed in the ultrasonic machine, be under 60～90 ℃ the condition in temperature, utilized ultrasonic Treatment 1～3 hour, and afterwards, filtered, and, obtain the Chinese medicine drug extract with the ethanol evaporation recovery;
Step 2: preparation Chinese medicine drug microcapsule solution
Get Chinese medicine drug extract and emulsifier op-10 that PLA, step 1 make respectively, place in the emulsion reactor, form mixed liquor, the concentration of controlling OP-10 in this mixed liquor is 1.0～3.0g/100ml, the mass ratio of Chinese medicine drug extract and PLA is 1: 2～10, oil phase is 1～10: 100 with the ratio of outer water, in temperature is that 30 ℃～60 ℃, reactor rotating speed are in the environment of 1000r/min～10000r/min, stir 6h～48h, make solid content and be 30%～50% Chinese medicine drug microcapsule solution;
Step 3: prepare nano oxidized zinc solution
By mass percentage, getting commercially available granularity respectively is zinc oxide 5%～20%, soil temperature-800.1%～0.5% and the deionized water 79.5%～94.9% of 10nm～80nm, each component total amount 100%, put into agitator, under the normal temperature, rotating speed with 10000r/min～12000r/min stirred 24 hours～36 hours, made zinc oxide fully disperse, and obtained nano oxidized zinc solution;
Step 4: preparation nanometer Chinese medicine microcapsule dressing agent
By mass percentage, get the Chinese medicine drug microcapsule solution 30%～60% that step 2 makes, the nano oxidized zinc solution 5%～20% that step 3 makes respectively, aqueous polyurethane solution 10%～15% and deionized water 10%～55%, the each component total amount is 100%, nano oxidized zinc solution, Chinese medicine drug microcapsule solution and aqueous polyurethane solution are put into agitator, stirred 1 hour～2 hours, afterwards, add deionized water and stirred again 1 hour～3 hours, promptly make nanometer Chinese medicine microcapsule dressing agent.
Fabric finishing method of the present invention specifically may further comprise the steps:
A. by with the mass percent 3%～10% of fabric, get nanometer Chinese medicine microcapsule dressing agent, put into agitator, add water, evenly stir, form finish solution, the mass percent of this solution and required processing fabric is 70%～90%;
B. adopt existing fabric dressing technology, the finish solution that the last step was obtained adds in the dressing container, puts into fabric then, is that dipping 40min～60min soaks into and dressing fabric under 50 ℃～70 ℃ the condition in temperature,
Or fabric is carried out in the submissive typing manufacturing procedure in prior art, fabric is during by soft groove, and squezzing rod pressure adopts conventional pressure, and the speed of a motor vehicle is 9～15 meters/minute, and soft groove as the dressing container, is soaked into and dressing fabric;
Perhaps the fabric semi-finished product washed, in the crease-resistant dressing manufacturing procedure, the spraying machine in immersion slot or the anti-crease finishing equipment as the dressing container, soaked into and dressing fabric in prior art;
C. will go up the fabric of step after the dressing dries and cures
At first by the baking room of setting machine, the temperature in the baking room is 110 ℃～130 ℃ to fabric, and carrying the speed of the conveyer belt of fabric is 9～15 meters/minute, then, enters and cures the room, and the temperature of curing in the room is 150 ℃～180 ℃.
Perhaps can adopt common roller dryer that fabric is dried, bake out temperature is 80 ℃～90 ℃, dries 20 minutes～30 minutes; Then with fabric Gua in oven, under 150～180 ℃ temperature, cured 0.5 minute～5 minutes.
Utilize the curing characteristics of nanometer Chinese medicine microcapsule dressing agent of the present invention, use it for the arrangement process of fabric, bake out temperature when the fabric after making employing nanometer Chinese medicine microcapsule dressing agent of the present invention handle is dried is higher than the bake out temperature of fabric in the prior art, thereby strengthened the cross-link intensity of adhesive material in the nano coating, caused the performance such as washing resistance, flexibility of fabric face coating significantly to improve.
Embodiment 1
Extracting honeysuckle 30Kg, capsule of weeping forsythia 35Kg and Radix Glycyrrhizae 35Kg put into medicinal herb grinder and pulverize respectively, and the drug particles granularity after the pulverizing is 100 orders.Press the mass percent of drug particles quality and ethanol quality 25%, place ethanol to soak 4.5 hours drug particles, then, put into ultrasonic machine, be under 90 ℃ the condition, to handle 3 hours, afterwards in temperature, filter, and ethanol evaporation is reclaimed, obtain the Chinese medicine drug extract.Get PLA, Chinese medicine drug extract and emulsifier op-10 respectively, place in the emulsion reactor, form mixed liquor, the concentration of controlling emulsifier op-10 in this mixed liquor is 1.0g/100ml, the mass ratio of Chinese medicine drug extract and PLA is 1: 10, and the ratio of oil phase and outer water is 1: 100, is that 30 ℃, reactor rotating speed are under the condition of 1000r/min in temperature, stir 6h, make solid content and be 30% Chinese medicine drug microcapsule solution.Getting commercially available granularity respectively is zinc oxide 5Kg, soil temperature-800.1Kg and the deionized water 94.9Kg of 10nm～80nm, puts into agitator, under the normal temperature, stirs 24 hours with the rotating speed of 10000r/min, and zinc oxide is fully disperseed, and makes nano oxidized zinc solution.Get above-mentioned Chinese medicine drug microcapsule solution 30Kg, nano oxidized zinc solution 5Kg and the aqueous polyurethane solution 10Kg that makes, deionized water 55Kg, nano oxidized zinc solution, Chinese medicine drug microcapsule solution and aqueous polyurethane solution are put into agitator, stirred 2 hours, add deionized water then, stirred again 3 hours, and made nanometer Chinese medicine medicine antibacterial antiviral finishing agent.
By with the mass percent 3% of fabric, get nanometer Chinese medicine microcapsule antibacterial antiviral finishing agent, put into agitator, add water, evenly stir, form finish solution, the mass percent of this solution and required processing fabric is 70%; Adopt existing fabric dressing technology, the finish solution that makes is added in the dressing container, put into 100%32 cotton knit products then, be under 70 ℃ the condition in temperature, dipping 60min, fabric is soaked into and dressing, fabric after the dressing is placed on the conveyer belt of setting machine, the speed of conveyer belt is 9 meters/minute, and the baking room of setting machine sent into fabric by conveyer belt, be under 110 ℃ the condition in temperature, fabric is dried, and then, conveyer belt is sent into fabric in the room that cures that links to each other with baking room, in temperature is 150 ℃ environment, fabric is cured; Promptly fabric has been carried out the anti-bacteria and anti-virus arrangement.
Embodiment 2
Extracting honeysuckle 60Kg, capsule of weeping forsythia 20Kg and Radix Glycyrrhizae 20Kg put into medicinal herb grinder and pulverize respectively, and the drug particles granularity after the pulverizing is 400 orders.Press the mass percent of drug particles quality and ethanol quality 30%, place ethanol to soak 6 hours drug particles, then, put into ultrasonic machine, be under 60 ℃ the condition, to handle 1 hour, afterwards in temperature, filter, and ethanol evaporation is reclaimed, obtain the Chinese medicine drug extract.Get PLA, Chinese medicine drug extract and emulsifier op-10 respectively, place in the emulsion reactor, form mixed liquor, the concentration of controlling emulsifier op-10 in this mixed liquor is 3.0g/100ml, the mass ratio of Chinese medicine drug extract and PLA is 1: 2, and the ratio of oil phase and outer water is 10: 100, is that 60 ℃, reactor rotating speed are under the condition of 10000r/min in temperature, stir volatilization 48h, make solid content and be 50% Chinese medicine drug microcapsule solution.Getting commercially available granularity respectively is zinc oxide 20Kg, soil temperature-800.5Kg and the deionized water 79.5Kg of 10nm～80nm, puts into agitator, under the normal temperature, stirs 36 hours with the rotating speed of 12000r/min, and zinc oxide is fully disperseed, and makes nano oxidized zinc solution.Get above-mentioned Chinese medicine drug microcapsule solution 60Kg, nano oxidized zinc solution 20Kg and the aqueous polyurethane solution 10Kg that makes, deionized water 10Kg, nano oxidized zinc solution, Chinese medicine drug microcapsule solution and aqueous polyurethane solution are put into agitator, stirred 1 hour, add deionized water then, stirred again 1 hour, and made nanometer Chinese medicine medicine antibacterial antiviral finishing agent.
By with the mass percent 10% of fabric, get nanometer Chinese medicine microcapsule antibacterial antiviral finishing agent, put into agitator, add water, evenly stir, form finish solution, the mass percent of this solution and required processing fabric is 90%; Adopt existing fabric dressing technology, the finish solution that makes is added in the dressing container, put into pure wool tribute doskin cloth then, be under 50 ℃ the condition in temperature, dipping 40min, fabric is soaked into and dressing, fabric after the dressing is placed on the conveyer belt of setting machine, the speed of conveyer belt is 15 meters/minute, and the baking room of setting machine sent into fabric by conveyer belt, be under 130 ℃ the condition in temperature, fabric is dried, and then, conveyer belt is sent into fabric in the room that cures that links to each other with baking room, in temperature is 180 ℃ environment, fabric is cured; Promptly fabric has been carried out the anti-bacteria and anti-virus arrangement.
Embodiment 3
Extracting honeysuckle 30Kg, capsule of weeping forsythia 50Kg and Radix Glycyrrhizae 20Kg put into medicinal herb grinder and pulverize respectively, and the drug particles granularity after the pulverizing is 250 orders.Press the mass percent of drug particles quality and ethanol quality 28%, place ethanol to soak 3 hours drug particles, then, put into ultrasonic machine, be under 75 ℃ the condition, to handle 2 hours, afterwards in temperature, filter, and ethanol evaporation is reclaimed, obtain the Chinese medicine drug extract.Get PLA, Chinese medicine drug extract and emulsifier op-10 respectively, place in the emulsion reactor, form mixed liquor, the concentration of controlling emulsifier op-10 in this mixed liquor is 2.0g/100ml, the mass ratio of Chinese medicine drug extract and PLA is 1: 6, and the ratio of oil phase and outer water is 6: 100, is that 45 ℃, reactor rotating speed are under the condition of 5500r/min in temperature, stir 27h, make solid content and be 40% Chinese medicine drug microcapsule solution.Getting commercially available granularity respectively is zinc oxide 12.5Kg, soil temperature-800.3Kg and the deionized water 87.2Kg of 10nm～80nm, puts into agitator, under the normal temperature, stirs 30 hours with the rotating speed of 11000r/min, and zinc oxide is fully disperseed, and makes nano oxidized zinc solution.Get above-mentioned Chinese medicine drug microcapsule solution 45Kg, nano oxidized zinc solution 12.5Kg and the aqueous polyurethane solution 15Kg that makes, deionized water 27.5Kg, nano oxidized zinc solution, Chinese medicine drug microcapsule solution and aqueous polyurethane solution are put into agitator, stirred 1.5 hours, add deionized water then, stirred again 2 hours, and made nanometer Chinese medicine medicine antibacterial antiviral finishing agent.
By with the mass percent 7% of fabric, get nanometer Chinese medicine microcapsule antibacterial antiviral finishing agent, put into agitator, add water, evenly stir, form finish solution, the mass percent of this solution and required processing fabric is 80%; Adopt existing fabric dressing technology, the finish solution that makes is added in the dressing container, put into fabric then, be under 60 ℃ the condition in temperature, dipping 50min, fabric is soaked into and dressing, fabric after the dressing is placed on the conveyer belt of setting machine, the speed of conveyer belt is 12 meters/minute, and the baking room of setting machine sent into fabric by conveyer belt, be under 120 ℃ the condition in temperature, fabric is dried, and then, conveyer belt is sent into fabric in the room that cures that links to each other with baking room, in temperature is 165 ℃ environment, fabric is cured; Promptly fabric has been carried out the anti-bacteria and anti-virus arrangement.
Embodiment 4
Extracting honeysuckle 45Kg, capsule of weeping forsythia 35Kg and Radix Glycyrrhizae 20Kg put into medicinal herb grinder and pulverize respectively, and the drug particles granularity after the pulverizing is 175 orders.Press the mass percent of drug particles quality and ethanol quality 26%, place ethanol to soak 4 hours drug particles, then, put into ultrasonic machine, be under 70 ℃ the condition, to handle 2.5 hours, afterwards in temperature, filter, and ethanol evaporation is reclaimed, obtain the Chinese medicine drug extract.Get PLA, Chinese medicine drug extract and emulsifier op-10 respectively, place in the emulsion reactor, form mixed liquor, the concentration of controlling emulsifier op-10 in this mixed liquor is 1.5g/100ml, the mass ratio of Chinese medicine drug extract and PLA is 1: 4, and the ratio of oil phase and outer water is 4: 100, is that 40 ℃, reactor rotating speed are under the condition of 3500r/min in temperature, stir volatilization 16h, make solid content and be 35% Chinese medicine drug microcapsule solution.Getting commercially available granularity respectively is zinc oxide 8.8Kg, soil temperature-80 0.2Kg and the deionized water 91Kg of 10nm～80nm, puts into agitator, under the normal temperature, stirs 27 hours with the rotating speed of 10500r/min, and zinc oxide is fully disperseed, and makes nano oxidized zinc solution.Get above-mentioned Chinese medicine drug microcapsule solution 40Kg, nano oxidized zinc solution 12.5Kg and the aqueous polyurethane solution 12.5Kg that makes, deionized water 35Kg, nano oxidized zinc solution, Chinese medicine drug microcapsule solution and aqueous polyurethane solution are put into agitator, stirred 2 hours, add deionized water then, stirred again 1.5 hours, and made nanometer Chinese medicine medicine antibacterial antiviral finishing agent.
By with the mass percent 5% of fabric, get nanometer Chinese medicine microcapsule antibacterial antiviral finishing agent, put into agitator, add water, evenly stir, form finish solution, the mass percent of this solution and required processing fabric is 75%; Adopt existing fabric dressing technology, the finish solution that makes is added in the dressing container, put into 100%32 cotton knit products then, be under 55 ℃ the condition in temperature, dipping 45min soaks into and dressing fabric, and the clothing after adopting common roller dryer to dressing is dried, 80 ℃ of bake out temperatures, drying time 20 minutes; After the oven dry with clothes Gua in oven, be under 150 ℃ the condition, to cure 0.5 minute in temperature, promptly finished 35/65 cotton/the wash anti-bacteria and anti-virus arrangement of clothes.
Embodiment 5
Extracting honeysuckle 30Kg, capsule of weeping forsythia 20Kg and Radix Glycyrrhizae 50Kg put into medicinal herb grinder and pulverize respectively, and the drug particles granularity after the pulverizing is 400 orders.Press the mass percent of drug particles quality and ethanol quality 30%, place ethanol to soak 5 hours drug particles, then, put into ultrasonic machine, be under 80 ℃ the condition, to handle 1.5 hours, afterwards in temperature, filter, and ethanol evaporation is reclaimed, obtain the Chinese medicine drug extract.Get PLA, Chinese medicine drug extract and emulsifier op-10 respectively, place in the emulsion reactor, form mixed liquor, the concentration of controlling emulsifier op-10 in this mixed liquor is 2.5g/100ml, the mass ratio of Chinese medicine drug extract and PLA is 1: 8, and the ratio of oil phase and outer water is 8: 100, is that 50 ℃, reactor rotating speed are under the condition of 7000r/min in temperature, stir 37h, make solid content and be 45% Chinese medicine drug microcapsule solution.Getting commercially available granularity respectively is zinc oxide 16.5Kg, soil temperature-800.4Kg and the deionized water 83.1Kg of 10nm～80nm, puts into agitator, under the normal temperature, stirs 33 hours with the rotating speed of 11500r/min, and zinc oxide is fully disperseed, and makes nano oxidized zinc solution.Get above-mentioned Chinese medicine drug microcapsule solution 36Kg, nano oxidized zinc solution 17.5Kg and the aqueous polyurethane solution 14Kg that makes, deionized water 32.5Kg, nano oxidized zinc solution, Chinese medicine drug microcapsule solution and aqueous polyurethane solution are put into agitator, stirred 1 hour, add deionized water then, stirred again 2.5 hours, and made nanometer Chinese medicine medicine antibacterial antiviral finishing agent.
By with the mass percent 8% of fabric, get nanometer Chinese medicine microcapsule antibacterial antiviral finishing agent, put into agitator, add water, evenly stir, form finish solution, the mass percent of this solution and required processing fabric is 85%; Adopt existing fabric dressing technology, the finish solution that makes is added in the dressing container, put into 100%32 cotton knit products then, be under 65 ℃ the condition in temperature, dipping 55min soaks into and dressing fabric, and the clothing after adopting common roller dryer to dressing is dried, 90 ℃ of bake out temperatures, drying time 30 minutes; After the oven dry with clothes Gua in oven, be under 180 ℃ the condition, to cure 5 minutes in temperature, promptly finished 35/65 cotton/the wash anti-bacteria and anti-virus arrangement of clothes.
Adopt nanometer Chinese medicine microcapsule dressing agent of the present invention that fabric is put in order, the fabric after the arrangement has the effect of anti-bacteria and anti-virus.
According to standard GB/T 20944-2007 the antibacterial effect of the fabric after handling through the present invention is tested.The result shows, to the fabric effect after 1 hour after the arrangement, fabric to the average bacteriostasis rate of Staphylococcus aureus (AATCC6538) greater than 99%, to the average bacteriostasis rates of Escherichia coli (8099) greater than 95%, greater than 90%, and fabric bacteriostasis rate to each bacterial classification after 20 washings still is higher than 90% to the average bacteriostasis rate of Candida albicans (AATCC10231).
Require design according to antivirus test in Ministry of Public Health's " disinfection technology standard " 2002 editions and " the new Chinese medicine preclinical study guideline ", by external Virus culture experiment, the fabric of detection after finishing agent of the present invention is handled is to influenza virus (RNA viruses) and the antiviral drug effect of herpes simplex virus (dna virus), facts have proved, fabric after finishing agent of the present invention is handled has significant inhibitory effect to the virus of absorption: when virus concentration is high, fabric is higher than 80% to the inhibiting rate of virus, when virus concentration is low, fabric is higher than 95% to the inhibiting rate of virus, when virus concentration hanged down, fabric had the complete inhibition effect to virus.
Claims (9)
1. nanometer Chinese medicine microcapsule fabric finishing agent, by mass percentage, form by following component:
Chinese medicine drug microcapsule solution 30%～60%
Nano oxidized zinc solution 5%～20%
Aqueous polyurethane solution 10%～15%
Deionized water 10%～55%
Above-mentioned each component total amount 100%.
2. according to the described fabric finishing agent of claim 1, it is characterized in that, described Chinese medicine drug microcapsule solution, form by Chinese medicine drug extract, PLA and emulsifier op-10, the mass ratio of described Chinese medicine drug extract and PLA is 1: 2～10, and the concentration of emulsifier op-10 is 1.0g/100ml～3.0g/100ml.
3. according to the described fabric finishing agent of claim 2, it is characterized in that, described Chinese medicine drug extract is to be that 100 orders～400 purpose Chinese medicine drug particles are put into ethanol with granularity, and the mass ratio of control Chinese medicine drug particles and ethanol is 25%～30%, soak after 3 hours～6 hours, placing in the ultrasonic machine, is under 60 ℃～90 ℃ the condition, to handle 1 hour～3 hours in temperature, filtration, ethanol evaporation make then.
4. according to the described fabric finishing agent of claim 3, it is characterized in that described Chinese medicine drug particles by mass percentage, is made of each component total amount 100% honeysuckle 30%～60%, the capsule of weeping forsythia 20%～50% and Radix Glycyrrhizae 20%～50%.
5. the preparation method of the described fabric finishing agent of claim 1 is characterized in that, carries out according to the following steps:
Step 1: produce the Chinese medicine drug extract
By mass percentage, difference extracting honeysuckle 30%～60%, the capsule of weeping forsythia 20%～50% and Radix Glycyrrhizae 20%～50%, each component total amount 100%, putting into pulverizer pulverizes, obtaining granularity is 100 orders～400 purpose Chinese medicine drug particles, this Chinese medicine drug particles is put into ethanol, the mass ratio of control Chinese medicine drug particles and ethanol is 25%～30%, soaks after 3 hours～6 hours, places in the ultrasonic machine, under 60 ℃～90 ℃ temperature, handled 1 hour～3 hours, and then, filtered, ethanol evaporation is reclaimed, obtain the Chinese medicine drug extract;
Step 2: preparation Chinese medicine drug microcapsule solution
Get Chinese medicine drug extract and emulsifier op-10 that PLA, step 1 make respectively, place in the emulsion reactor, form mixed liquor, the ratio that control the mass ratio of Chinese medicine drug extract and PLA in this mixed liquor and be 1: 2～10, the concentration of emulsifier op-10 is 1.0g/100ml～3.0g/100ml, oil phase and outer water is 1～10: 100, in temperature is 30 ℃～60 ℃ environment, reactor rotating speed 1000r/min～10000r/min, stir 6h～48h, make solid content and be 30%～50% Chinese medicine drug microcapsule solution;
Step 3: prepare nano oxidized zinc solution
By mass percentage, getting granularity respectively is zinc oxide 5%～20%, soil temperature-800.1%～0.5% and the deionized water 79.5%～94.9% of 10hm～80nm, each component total amount 100%, put into agitator, under the normal temperature, rotating speed with 10000r/min～12000r/min stirred 24 hours～36 hours, made zinc oxide fully disperse, and obtained nano oxidized zinc solution;
Step 4: preparation nanometer Chinese medicine microcapsule dressing agent
By mass percentage, get the Chinese medicine drug microcapsule solution 30%～60% that step 2 makes, nano oxidized zinc solution 5%～20%, aqueous polyurethane solution 10%～15% and the deionized water 10%～55% that step 3 makes respectively, each component total amount 100%, nano oxidized zinc solution, Chinese medicine drug microcapsule solution are mixed with aqueous polyurethane solution, stirred 1 hour～2 hours, add deionized water and stirring 1 hour～3 hours, and made nanometer Chinese medicine microcapsule dressing agent.
6. a method of utilizing the described finishing agent of claim 1 to carry out textile finishing is characterized in that, specifically carries out according to the following steps:
A. by with the mass percent 3%～10% of fabric, get nanometer Chinese medicine microcapsule dressing agent, put into agitator, add water, stir, form finish solution, the mass percent of this solution and required finish fabric is 70%～90%;
B. adopting existing fabric dressing technology, the finish solution that the last step obtains is put into the dressing container, put into fabric then, is under 50 ℃～70 ℃ the condition in temperature, dipping 40min～60min;
C. will go up the fabric of step after the dressing and dry and cure, finish the anti-bacteria and anti-virus arrangement of fabric.
7. according to the described fabric finishing method of claim 6, it is characterized in that described nanometer Chinese medicine microcapsule dressing agent, preparation according to the following steps:
Step 1: produce the Chinese medicine drug extract
By mass percentage, difference extracting honeysuckle 30%～60%, the capsule of weeping forsythia 20%～50% and Radix Glycyrrhizae 20%～50%, each component total amount 100%, putting into pulverizer pulverizes, obtaining granularity is 100 orders～400 purpose Chinese medicine drug particles, this Chinese medicine drug particles is put into ethanol, soaked 3 hours～6 hours, the mass ratio of Chinese medicine drug particles and ethanol is 25%～30%, then, place in the ultrasonic machine, temperature is 60 ℃～90 ℃, handles 1 hour～3 hours, afterwards, filter, ethanol evaporation is reclaimed, obtain the Chinese medicine drug extract;
Step 2: preparation Chinese medicine drug microcapsule solution
Get Chinese medicine drug extract and emulsifier op-10 that PLA, step 1 make respectively, place in the emulsion reactor, form mixed liquor, control the mass ratio of Chinese medicine drug extract and PLA in this mixed liquor and be 1: 2～10, the concentration of emulsifier op-10 is 1.0g/100ml～3.0g/100ml, in temperature is 30 ℃～60 ℃ environment, reactor rotating speed 1000r/min～10000r/min stirs 6h～48h, makes solid content and be 30%～50% Chinese medicine drug microcapsule solution;
Step 3: prepare nano oxidized zinc solution
By mass percentage, getting commercially available granularity respectively is zinc oxide 5%～20%, soil temperature-800.1%～0.5% and the deionized water 79.5%～94.9% of 10nm～80nm, each component total amount 100%, put into agitator, under the normal temperature, rotating speed with 10000r/min～12000r/min stirred 24 hours～36 hours, obtained nano oxidized zinc solution;
Step 4: preparation nanometer Chinese medicine microcapsule dressing agent
By mass percentage, get the Chinese medicine drug microcapsule solution 30%～60% that step 2 makes, nano oxidized zinc solution 5%～20%, aqueous polyurethane solution 10%～15% and the deionized water 10%～55% that step 3 makes respectively, each component total amount 100%, nano oxidized zinc solution, Chinese medicine drug microcapsule solution are mixed with aqueous polyurethane solution, stir after 1 hour～2 hours, add deionized water and stirring again 1 hour～3 hours, and made nanometer Chinese medicine microcapsule dressing agent.
8. according to the described fabric finishing method of claim 6, it is characterized in that described oven dry is cured and is, the fabric after the dressing is placed in the common roller dryer, is under 80 ℃～90 ℃ the condition, to dry 20 minutes～30 minutes in temperature; Then with fabric Gua in oven, under 150 ℃～180 ℃ temperature, cured 0.5 minute～5 minutes.
9. according to the described fabric finishing method of claim 6, it is characterized in that, described oven dry is cured and is, fabric after the dressing is placed on the conveyer belt of setting machine, conveyer belt carries fabric, and to enter the typing built-in temperature be 110 ℃～130 ℃ baking room, fabric after conveyer belt will be dried is then brought temperature into and is 150 ℃～180 ℃ and cures the room, cures typing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810150440XA CN101324026B (en) | 2008-07-24 | 2008-07-24 | Nanometer traditional chinese medicine microcapsule fabric finishing agent, preparation and fabric finishing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810150440XA CN101324026B (en) | 2008-07-24 | 2008-07-24 | Nanometer traditional chinese medicine microcapsule fabric finishing agent, preparation and fabric finishing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101324026A true CN101324026A (en) | 2008-12-17 |
| CN101324026B CN101324026B (en) | 2011-01-12 |
Family
ID=40187716
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200810150440XA Expired - Fee Related CN101324026B (en) | 2008-07-24 | 2008-07-24 | Nanometer traditional chinese medicine microcapsule fabric finishing agent, preparation and fabric finishing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101324026B (en) |
Cited By (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101732745A (en) * | 2009-12-29 | 2010-06-16 | 西安工程大学 | Nano medicine antibacterial and antiviral finishing agent as well as preparation method and finishing method thereof |
| WO2011057536A1 (en) * | 2009-11-16 | 2011-05-19 | 香港理工大学 | Antibacterial and wrinkle-proof fabric with blumea oil microcapsule and producing method thereof |
| CN102330356A (en) * | 2011-07-28 | 2012-01-25 | 吴江兰瑞特纺织品有限公司 | Natural antibacterial textile containing honeysuckle extracts, and preparation method for the same |
| CN102330331A (en) * | 2011-07-28 | 2012-01-25 | 吴江征明纺织有限公司 | Finishing agent for ultraviolet-proof perfumed fabric |
| CN102330349A (en) * | 2011-07-28 | 2012-01-25 | 吴江征明纺织有限公司 | Finishing agent for anti-ultraviolet aromatized and skincare textile |
| CN102352552A (en) * | 2011-07-27 | 2012-02-15 | 吴江兰瑞特纺织品有限公司 | Natural antibacterial textile containing fructus forsythiae extractive and preparation method thereof |
| CN102352553A (en) * | 2011-07-29 | 2012-02-15 | 吴江兰瑞特纺织品有限公司 | Natural antimycotic textile containing tarragon extracts and preparation method thereof |
| CN102367635A (en) * | 2011-07-28 | 2012-03-07 | 吴江兰瑞特纺织品有限公司 | Natural antibacterial textile containing extract of Baikal skullcap root and preparation process thereof |
| CN102392350A (en) * | 2011-07-28 | 2012-03-28 | 吴江征明纺织有限公司 | Anti-mosquito and anti-ultraviolet fabric finishing agent |
| CN102405941A (en) * | 2011-08-10 | 2012-04-11 | 华南农业大学 | Isatis root oil microcapsule and functional fabric finishing agent |
| CN102774537A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Garment suite |
| CN102776781A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Aseptic nutrient-added home textile suite |
| CN102771941A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Shoes |
| CN102774536A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Home textile stuffing |
| CN102771901A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Clothing stuffing material |
| CN102772119A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Sterile nutrient- added door curtain |
| CN102772058A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Aseptic nutrient-added back cushion |
| CN103147311A (en) * | 2013-04-07 | 2013-06-12 | 江苏悦达纺织集团有限公司 | Tea tree oil microcapsule antibacterial healthcare fiber and preparation method thereof |
| CN103422345A (en) * | 2013-08-02 | 2013-12-04 | 吴江市七都镇庙港雅迪针织制衣厂 | Anti-bacteria shrinkage-resisting woolen sweater treating liquid containing sodium palmitate |
| CN103437191A (en) * | 2013-08-02 | 2013-12-11 | 南京天脉健康管理有限公司 | Nano cannabis sativa oil microcapsule, nano cannabis sativa oil microcapsule fabric, preparation method of nano cannabis sativa oil microcapsule fabric and prepared product |
| CN103469605A (en) * | 2013-09-13 | 2013-12-25 | 句容市后白镇迎瑞印花厂 | Production method of anti-ultraviolet fabric |
| CN104264485A (en) * | 2014-09-18 | 2015-01-07 | 张伟 | Preparation method of medical bandage coated with polyurethane resin prepolymer |
| CN104452275A (en) * | 2014-12-23 | 2015-03-25 | 常熟市中宏针织厂 | Finishing technology of home textile fabric |
| CN104562647A (en) * | 2015-01-28 | 2015-04-29 | 苏州爱立方服饰有限公司 | Antibacterial finishing method of cotton fabric |
| CN104746350A (en) * | 2015-03-13 | 2015-07-01 | 常州大学 | Polyacrylate adhesive containing traditional Chinese medicine oil microcapsule as well as preparation method and application |
| CN104878608A (en) * | 2015-06-08 | 2015-09-02 | 苏州威尔德工贸有限公司 | Degradable antibacterial microcapsule for textile use and preparation method thereof |
| CN105064010A (en) * | 2015-08-03 | 2015-11-18 | 湖州吉昌丝绸有限公司 | Novel natural antibacterial finishing agent, and preparation method thereof |
| CN105568671A (en) * | 2016-02-16 | 2016-05-11 | 渤扬复合面料科技(昆山)有限公司 | Processing method for quick-dried antibacterial dacron textile |
| CN106012551A (en) * | 2016-07-15 | 2016-10-12 | 义乌市麻尚生针织品有限公司 | Preparation method for blended yarns of hemp cotton and antibacterial fibers |
| CN106337277A (en) * | 2015-07-16 | 2017-01-18 | 昊纺股份有限公司 | Antibacterial Chinese herbal medicine and preparation methods for fiber and fabric using same |
| CN106367970A (en) * | 2016-10-10 | 2017-02-01 | 义乌市麻尚生针织品有限公司 | Preparation method of multi-element hemp and cotton yarn blended nonwoven cloth |
| CN106400504A (en) * | 2016-08-24 | 2017-02-15 | 杭州美高华颐化工有限公司 | Super hydrophilic finishing agent for nylon fabric and preparation method thereof |
| CN106498701A (en) * | 2016-10-20 | 2017-03-15 | 常州市鼎日环保科技有限公司 | A kind of preparation method of antibiotic property flame-retardant silk fabric |
| CN107034682A (en) * | 2017-04-13 | 2017-08-11 | 段体奎 | Silk quilt that a kind of microcapsules technology lifting amino acid is fully absorbed and preparation method thereof |
| CN108560253A (en) * | 2018-04-19 | 2018-09-21 | 河南纳美纺织科技有限公司 | A kind of Chinese medicine health-care leather shell material and application thereof |
| CN110499644A (en) * | 2019-08-27 | 2019-11-26 | 浙江理工大学 | A method of antibacterial type textile finshing agent is prepared using ursolic acid extract |
| CN111607970A (en) * | 2020-04-23 | 2020-09-01 | 苦蒲丹(山东)中药科技有限公司 | Preparation method of traditional Chinese medicine antibacterial mask material |
| CN114345019A (en) * | 2021-12-28 | 2022-04-15 | 河南省安克林滤业有限公司 | Antibacterial and antiviral composite filter material with flame retardant function and production process thereof |
| CN116356569A (en) * | 2023-04-26 | 2023-06-30 | 东华大学 | Antibacterial fabric and preparation method thereof |
-
2008
- 2008-07-24 CN CN200810150440XA patent/CN101324026B/en not_active Expired - Fee Related
Cited By (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011057536A1 (en) * | 2009-11-16 | 2011-05-19 | 香港理工大学 | Antibacterial and wrinkle-proof fabric with blumea oil microcapsule and producing method thereof |
| CN101732745B (en) * | 2009-12-29 | 2013-09-11 | 西安工程大学 | Nano medicine antibacterial and antiviral finishing agent as well as preparation method and finishing method thereof |
| CN101732745A (en) * | 2009-12-29 | 2010-06-16 | 西安工程大学 | Nano medicine antibacterial and antiviral finishing agent as well as preparation method and finishing method thereof |
| CN102771941A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Shoes |
| CN102774536A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Home textile stuffing |
| CN102772058A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Aseptic nutrient-added back cushion |
| CN102772119A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Sterile nutrient- added door curtain |
| CN102771901A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Clothing stuffing material |
| CN102776781A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Aseptic nutrient-added home textile suite |
| CN102774537A (en) * | 2011-05-09 | 2012-11-14 | 紫罗兰家纺科技股份有限公司 | Garment suite |
| CN102352552A (en) * | 2011-07-27 | 2012-02-15 | 吴江兰瑞特纺织品有限公司 | Natural antibacterial textile containing fructus forsythiae extractive and preparation method thereof |
| CN102330349A (en) * | 2011-07-28 | 2012-01-25 | 吴江征明纺织有限公司 | Finishing agent for anti-ultraviolet aromatized and skincare textile |
| CN102392350A (en) * | 2011-07-28 | 2012-03-28 | 吴江征明纺织有限公司 | Anti-mosquito and anti-ultraviolet fabric finishing agent |
| CN102330356A (en) * | 2011-07-28 | 2012-01-25 | 吴江兰瑞特纺织品有限公司 | Natural antibacterial textile containing honeysuckle extracts, and preparation method for the same |
| CN102330331A (en) * | 2011-07-28 | 2012-01-25 | 吴江征明纺织有限公司 | Finishing agent for ultraviolet-proof perfumed fabric |
| CN102367635A (en) * | 2011-07-28 | 2012-03-07 | 吴江兰瑞特纺织品有限公司 | Natural antibacterial textile containing extract of Baikal skullcap root and preparation process thereof |
| CN102352553A (en) * | 2011-07-29 | 2012-02-15 | 吴江兰瑞特纺织品有限公司 | Natural antimycotic textile containing tarragon extracts and preparation method thereof |
| CN102405941A (en) * | 2011-08-10 | 2012-04-11 | 华南农业大学 | Isatis root oil microcapsule and functional fabric finishing agent |
| CN103147311A (en) * | 2013-04-07 | 2013-06-12 | 江苏悦达纺织集团有限公司 | Tea tree oil microcapsule antibacterial healthcare fiber and preparation method thereof |
| CN103147311B (en) * | 2013-04-07 | 2015-07-15 | 江苏悦达纺织集团有限公司 | Tea tree oil microcapsule antibacterial healthcare fiber and preparation method thereof |
| CN103422345A (en) * | 2013-08-02 | 2013-12-04 | 吴江市七都镇庙港雅迪针织制衣厂 | Anti-bacteria shrinkage-resisting woolen sweater treating liquid containing sodium palmitate |
| CN103437191A (en) * | 2013-08-02 | 2013-12-11 | 南京天脉健康管理有限公司 | Nano cannabis sativa oil microcapsule, nano cannabis sativa oil microcapsule fabric, preparation method of nano cannabis sativa oil microcapsule fabric and prepared product |
| CN103437191B (en) * | 2013-08-02 | 2015-07-08 | 南京天脉健康管理有限公司 | Nano cannabis sativa oil microcapsule, nano cannabis sativa oil microcapsule fabric, preparation method of nano cannabis sativa oil microcapsule fabric and prepared product |
| CN103422345B (en) * | 2013-08-02 | 2015-06-17 | 苏州爱立方服饰有限公司 | Anti-bacteria shrinkage-resisting woolen sweater treating liquid containing sodium palmitate |
| CN103469605A (en) * | 2013-09-13 | 2013-12-25 | 句容市后白镇迎瑞印花厂 | Production method of anti-ultraviolet fabric |
| CN103469605B (en) * | 2013-09-13 | 2015-09-09 | 句容市后白镇迎瑞印花厂 | A kind of production method of anti-ultraviolet fabric |
| CN104264485A (en) * | 2014-09-18 | 2015-01-07 | 张伟 | Preparation method of medical bandage coated with polyurethane resin prepolymer |
| CN104452275A (en) * | 2014-12-23 | 2015-03-25 | 常熟市中宏针织厂 | Finishing technology of home textile fabric |
| CN104562647A (en) * | 2015-01-28 | 2015-04-29 | 苏州爱立方服饰有限公司 | Antibacterial finishing method of cotton fabric |
| CN104746350B (en) * | 2015-03-13 | 2016-08-17 | 常州大学 | A kind of palyacrylate binder containing Chinese medicine oil microcapsule and its preparation method and application |
| CN104746350A (en) * | 2015-03-13 | 2015-07-01 | 常州大学 | Polyacrylate adhesive containing traditional Chinese medicine oil microcapsule as well as preparation method and application |
| CN104878608A (en) * | 2015-06-08 | 2015-09-02 | 苏州威尔德工贸有限公司 | Degradable antibacterial microcapsule for textile use and preparation method thereof |
| CN106337277A (en) * | 2015-07-16 | 2017-01-18 | 昊纺股份有限公司 | Antibacterial Chinese herbal medicine and preparation methods for fiber and fabric using same |
| CN105064010A (en) * | 2015-08-03 | 2015-11-18 | 湖州吉昌丝绸有限公司 | Novel natural antibacterial finishing agent, and preparation method thereof |
| CN105568671A (en) * | 2016-02-16 | 2016-05-11 | 渤扬复合面料科技(昆山)有限公司 | Processing method for quick-dried antibacterial dacron textile |
| CN106012551A (en) * | 2016-07-15 | 2016-10-12 | 义乌市麻尚生针织品有限公司 | Preparation method for blended yarns of hemp cotton and antibacterial fibers |
| CN106400504A (en) * | 2016-08-24 | 2017-02-15 | 杭州美高华颐化工有限公司 | Super hydrophilic finishing agent for nylon fabric and preparation method thereof |
| CN106367970A (en) * | 2016-10-10 | 2017-02-01 | 义乌市麻尚生针织品有限公司 | Preparation method of multi-element hemp and cotton yarn blended nonwoven cloth |
| CN106498701A (en) * | 2016-10-20 | 2017-03-15 | 常州市鼎日环保科技有限公司 | A kind of preparation method of antibiotic property flame-retardant silk fabric |
| CN107034682A (en) * | 2017-04-13 | 2017-08-11 | 段体奎 | Silk quilt that a kind of microcapsules technology lifting amino acid is fully absorbed and preparation method thereof |
| CN108560253A (en) * | 2018-04-19 | 2018-09-21 | 河南纳美纺织科技有限公司 | A kind of Chinese medicine health-care leather shell material and application thereof |
| CN110499644A (en) * | 2019-08-27 | 2019-11-26 | 浙江理工大学 | A method of antibacterial type textile finshing agent is prepared using ursolic acid extract |
| CN111607970A (en) * | 2020-04-23 | 2020-09-01 | 苦蒲丹(山东)中药科技有限公司 | Preparation method of traditional Chinese medicine antibacterial mask material |
| CN114345019A (en) * | 2021-12-28 | 2022-04-15 | 河南省安克林滤业有限公司 | Antibacterial and antiviral composite filter material with flame retardant function and production process thereof |
| CN116356569A (en) * | 2023-04-26 | 2023-06-30 | 东华大学 | Antibacterial fabric and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101324026B (en) | 2011-01-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101324026B (en) | Nanometer traditional chinese medicine microcapsule fabric finishing agent, preparation and fabric finishing method | |
| Thilagavathi et al. | Microencapsulation of herbal extracts for microbial resistance in healthcare textiles | |
| CN105648646B (en) | Anti-mite antibacterial healthy knitted fabric of one kind and preparation method thereof | |
| CN101589853B (en) | Blumea oil microcapsule antibacterial mask and preparation method thereof | |
| CN107326685B (en) | The preparation of Korean pine phytocide finishing agent and its fabric and method for sorting arranged | |
| CN101591859A (en) | A kind of Blumea oil microcapsule textile composite finishing agent and application thereof | |
| CN103726312A (en) | Finishing technology of fragrant antibacterial cotton fabric | |
| CN109457474B (en) | Efficient antibacterial deodorizing socks and preparation method thereof | |
| CN102051812B (en) | Application of botanical antibacterial mothproof multifunctional composite preparation in wool product | |
| CN107587252A (en) | A kind of antibacterial socks not easy to fade and preparation method thereof | |
| CN102418267A (en) | Traditional Chinese medicinal antibacterial finishing agent | |
| CN107099167A (en) | A kind of wormwood dyestuff and its production and use | |
| CN101613929A (en) | A kind of preparation method of inorganic nano antibiotic cotton fiber and the application in home textile product thereof | |
| CN106729931A (en) | A kind of preparation method for carrying silver-colored chitosan medical dressing | |
| CN101886328B (en) | Antibacterial treatment process of worsted fabric | |
| CN103276591A (en) | Preparation method of antiallergic aroma type woolen sweater | |
| KR101037791B1 (en) | Fabric with silver nano powder applied for improving absorption and fast drying, and method of manufacturing thereof | |
| CN108504461A (en) | One kind containing diatomaceous antimicrobial laundry liquid and preparation method thereof | |
| CN106337277A (en) | Antibacterial Chinese herbal medicine and preparation methods for fiber and fabric using same | |
| CN102517914A (en) | Towel with effect of purifying skin and preparation method thereof | |
| Adnan et al. | Performance and Characterization of Aloe Vera Microcapsules on Silk/Lyocell Blended Fabric | |
| CN104213413B (en) | A kind of antibacterial silk wadding quilt and preparation method thereof | |
| CN109251256B (en) | Modified cyclodextrin and application thereof in composite antibacterial deodorant liquid | |
| CN108560253A (en) | A kind of Chinese medicine health-care leather shell material and application thereof | |
| CN117431651B (en) | Gentian lyocell fiber with anti-allergy and soothing effects and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110112 Termination date: 20130724 |