CN101288631B - Skin cleaning agent composite - Google Patents
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- CN101288631B CN101288631B CN 200810090802 CN200810090802A CN101288631B CN 101288631 B CN101288631 B CN 101288631B CN 200810090802 CN200810090802 CN 200810090802 CN 200810090802 A CN200810090802 A CN 200810090802A CN 101288631 B CN101288631 B CN 101288631B
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Abstract
A skin cleansing composition contains the following ingredients (A), (B) and (C): (A) a polyoxyethylene alkylether sulfate, (B) a polyoxyethylene alkylether carboxylate, and (C) a cationic group-containing polymer having a cationic charge density of not less than 4.5 meq/g, and/or polyvinylpyrrolidone. A weight ratio (A):(B) of the ingredient (A) to the ingredient (B) is from 85:15 to 25:75. A total content of the ingredients (A) and (B) based on the whole composition ranges from 5 to 25 wt %. A content of the ingredient (C) ranges from 0.05 to 1 wt %. The skin cleansing composition is excellent in foamability and foam quality, and provides a good stop feeling during rinsing and a refreshed touch feeling after towel blotting.
Description
Technical field
The present invention is relevant skin cleaning agent composite.
Background technology
In the middle of the many performances to skin cleaning agent that be used for to clean face and whole body, as the sensation during flushing in the use procedure, importantly have frictional resistance sense of touch (sense that pauses, stopfeeling).In when flushing, until feel that the time till this pauses sense is short, and its intensity can be given salubrious sense, therefore preferably when strong.
In the prior art, in this field the surfactant of extensive use be polyoxyethylene alkyl ether sulfate salt as the skin cleaning agent composite of host, although its foaming characteristic is good, when flushing, have the problem of residual slimy sensation.In patent documentation 1 and 2, put down in writing, in the agent compositions of removing ornaments and formal dress as the individual of host with the water soluble surfactant active of polyoxyethylene alkyl ether sulfate salt etc., by adding the water-insoluble oil of polyisobutylene and silicone wet goods, thus the flushing sense when giving the flushing of improvement.; if so the oiliness composition is added in the skin cleaning agent composite; particularly in the situation that use in order to clean whole body; pause sensation during flushing just becomes abundant not; give afterwards residual sense and the oiliness sense of skin stronger in flushing; so have sticky feeling, can not get salubrious sense of touch.
In patent documentation 3 and patent documentation 4, put down in writing the cleansing composition that contains specific surfactant and cation property copolymer.Such cation property copolymer is used the comb general character of finger when improving flushing as the adjusting agent that reduces crude sense in hair cleansing.In addition, in skin cleaning agent also as the adjusting agent of skin moisturizing is used.But these cleansing compositions are in the purposes that skin is cleaned, and the viewpoint of the pause sense during from flushing can not fully meet the demands.
Patent documentation 1: Japanese Unexamined Patent Application Publication 2001-513539 communique
Patent documentation 2: Japanese Unexamined Patent Application Publication 2001-513538 communique
Patent documentation 3: Japanese kokai publication hei 2-42013 communique
Patent documentation 4: Japanese kokai publication hei 9-165598 communique
Summary of the invention
The present invention provides a kind of skin cleaning agent composite, and it contains following ingredients (A), (B) and (C):
(A) polyoxyethylene alkyl ether sulfate salt
(B) polyoxyethylene alkyl ether carboxylate
(C) cationic charge density is the above polymer that contains cation radical and/or polyvinylpyrrolidone of 4.5meq/g,
Composition (A) and mass ratio (B) they are (A): (B)=85: 15～25: 75, composition (A) and total content (B) in all forming are 5～25 quality %, and the content of composition (C) is 0.05～1 quality %.
Skin cleaning agent composite of the present invention bubbles rapidly, foam volume and alveolar substance are remarkable, and the pause sense during flushing is good, and has salubrious sense after doing toweling off.In addition, owing to containing polyvinylpyrrolidone, further improved the pearly-lustre sense.Further, by containing higher fatty acids or higher alcohol, during bath towel after flushing is used and the defoaming in the gutter during flushing become good.
The specific embodiment
The invention relates to a kind of skin cleaning agent composite, the pause sense when it has remarkable foaming characteristic and alveolar substance, flushing is good, towel off and have salubrious sense after doing.
Present inventor's discovery, by polymer or the polyvinylpyrrolidone that is used in combination polyoxyethylene alkyl ether sulfate salt and polyoxyethylene alkyl ether carboxylate and specifically contains cation radical, the skin cleaning agent composite of the above-mentioned problem that just can be resolved.
As the polyoxyethylene alkyl ether sulfate salt of employed composition (A) in the present invention, preferably with the represented material of following formula.
R-O(CH
2CH
2O)
n-SO
3X
In the formula, R represents the alkyl or alkenyl of carbon number 10～18; N represents average, is 0.5～5 number; X represents hydrogen atom, alkali metal, alkaline-earth metal, ammonium or organic ammonium.
In the formula, as the alkyl of the preferred carbon number 12～14 of R.In addition, the average addition molal quantity of oxirane is 0.5～5, but is preferably 1～4.
In addition, can enumerate the alkali metal of sodium and potassium etc. as X; The alkaline-earth metal of calcium and magnesium etc.; Ammonium; The ammonium that comes from the alkanolamine of monoethanolamine, di-methylcarbinol amine and triethanolamine etc.; Come from the cation of the alkali type amino acids such as arginine and lysine etc.
Composition (A) can use more than a kind, is preferably containing 1～20 quality % in full group, and 3～13 quality % more preferably are because remarkable aspect the pause sense of this moment when lather quickness, foam volume and flushing.
As the polyoxyethylene alkyl ether carboxylate of composition (B), the material that preferably is expressed from the next.
R-O(CH
2CH
2O)
nCH
2-COOX
In the formula, R represents alkyl or the thiazolinyl of carbon number 10～18; N represents average, is 0.5～10 number; X represents hydrogen atom, alkali metal, alkaline-earth metal, ammonium or organic ammonium.
In the formula, as the R alkyl of carbon number 12～16 more preferably.In addition, the average addition molal quantity of oxirane is 0.5～10, but more preferably 1～6.
In addition, can enumerate the alkali metal of sodium and potassium etc. as X; The alkaline-earth metal of calcium and magnesium etc.; Ammonium; The ammonium that comes from the alkanolamine of monoethanolamine, di-methylcarbinol amine and triethanolamine etc.; Come from the cation of the alkali type amino acids such as arginine and lysine etc.
Composition (B) can use more than a kind, is preferably containing 1～20 quality % in full group, and 1.5～10 quality % more preferably are because remarkable aspect the pause sense of this moment when foam volume alveolar substance and flushing.
In the present invention, composition (A) and mass ratio (B) they are (A): (B)=85: 15～25: 75, be preferably 75: 25～35: 65.If in this scope, remarkable aspect the pause sense when foaming characteristic, foam volume and flushing so, so preferred.
In addition, composition (A) and total content (B) in all forming are 5～25 quality %, are preferably 7.5～20 quality %.If in this scope, remarkable aspect foaming characteristic, foam volume and alveolar substance so, so preferred.
In the present invention, use mentioned component (A) and (B) time, also being used in combination composition (C) cationic charge density is the above polymer that contains cation radical and/or polyvinylpyrrolidone of 4.5meq/g.
At this, so-called cationic charge density refers to consist of the equivalents (meq/g) of the cationic charge in the monomer unit of polymer.
The cationic charge density that contains the polymer of cation radical is more than the 4.5meq/g, and is preferred 4.5～7, more preferably 5～7, most preferably 5.5～6.5.If have the material of the high-cation charge density of this scope, the pause sense the during flushing of cleansing composition is good so.Especially preferably the amphiphilic polymers that except containing above-mentioned cation radical, also contains anion base.
Wherein, be the polymer that contains cation radical more than the 4.5meq/g as positive ion density, such as the homopolymer that can enumerate dimethyl diallyl ammonium chloride; The copolymer of the monomer of other of dimethyl diallyl ammonium chloride and (methyl) acrylic acid, (methyl) acrylate, (methyl) acrylamide etc.; Polymethyl acyl chlorides oxy-ethyl-trimethyl salmiac etc.
Particularly, can enumerate the homopolymer (Merquat100 of dimethyl diallyl ammonium chloride; Charge density 6.2meq/g), (Merquat 295 for dimethyl diallyl ammonium chloride and acrylic acid copolymer オ Application デ オ Na Le コ society system:; Charge density 5.9meq/g), dimethyl diallyl ammonium chloride and acrylic acid copolymer (Merquat280 オ Application デ オ Na Le コ society system:; Charge density 5.0meq/g), (Kao Corp makes polymethyl acyl chlorides oxy-ethyl-trimethyl salmiac: charge density 4.8meq/g) オ Application デ オ Na Le コ society system:.
Consider from the corrosion resistance aspect of manufacturing equipment, the homopolymer of preferred dimethyl diallyl ammonium chloride, with dimethyl diallyl ammonium chloride and acrylic acid copolymer, especially dimethyl diallyl ammonium chloride and acrylic acid copolymerization ratio be 95: 5 copolymer (above-mentioned Merquat295; オ Application デ オ Na Le コ society makes: the aspect of the pause sense during charge density 5.9meq/g) for flushing and the amount of bubble and preferred.
In addition, in composition (C), as polyvinylpyrrolidone, because the pause sense in when flushing is remarkable, so its K value is preferably 10～100, more preferably 15～90.At this, so-called K value is the intrinsic viscosity that derives as the formula of the Fikentscher of the function representation of concentration from the viscosity with polyvinylpyrrolidonesolution solution.The kind of polyvinylpyrrolidone is by this K value representation, and it becomes the supposition of the cardinal principle of molecular weight.
Composition (C) can use more than a kind, and also can be used in combination cationic charge density is the above polymer that contains cation radical and polyvinylpyrrolidone of 4.5meq/g.Composition (C) contains 0.05～1 quality % in full the composition, preferably contain 0.075～1 quality %.If in this scope, remarkable aspect the pause sense when flushing so, so preferred.
As composition (C), be used in combination in the situation that cationic charge density is the polymer that contains cation radical more than the 4.5meq/g and polyvinylpyrrolidone, pause sense and the good viewpoint of liquid appearance during from flushing, its mass ratio is preferred, cationic charge density is the above polymer that contains cation radical of 4.5meq/g: polyvinylpyrrolidone=90: 10～20: 80, more preferably 80: 20～25: 75.
Skin cleaning agent composite of the present invention can further contain (D) inorganic salt or the acylate of carbon number below 6.Can enumerate the salt of alkali metal, alkaline-earth metal and halogen, sulphuric acid, sulfurous acid and phosphoric acid etc. as inorganic salt.Particularly, can enumerate sodium chloride, potassium chloride, sodium bromide, magnesium chloride, sodium sulfate, potassium sulfate, sodium dihydrogen phosphate and sodium hydrogen phosphate etc.In addition, as acylate, can also enumerate acetic acid, the salt of the hydroxy acid of lactic acid, malic acid, citric acid, succinic acid etc. and polyprotic acid and alkali metal etc.In the middle of these, be preferably sodium chloride, natrium malicum, sodium lactate, sodium citrate and sodium succinate.
Composition (D) can use more than a kind in the scope of the foaming characteristic that does not hinder effect of the present invention and alveolar substance, from by composition (A), (B) and (C) complex of the slightly solubility that forms of 3 compositions of (particularly cationic charge density is the polymer that contains cation radical more than the 4.5meq/g) can be easily dissolved, improve the viewpoint of pausing sense and improving liquid appearance (transparency), the amount of composition (D) in full the composition is preferably 0.5～10 quality %, more preferably 0.5～6 quality %.
In the present invention, composition (A) and mass ratio (B) they are (A): (B)=85: 15～25: 75, the complex that is formed by composition (A), (B) and 3 compositions (C) in this case becomes and easily dissolves, (C)/[(A)+(B)] value is in the situation that 0.025～0.08, and complex becomes and is more prone to dissolving.
Also have, by containing (D) inorganic salt or the acylate of carbon number 6 below, the complex that is formed by composition (A), (B) and 3 compositions (C) becomes and is more prone to dissolve.Viewpoint from improving dissolubility, stability and easily embodying pearly luster etc., be more preferably (D)/value of [(A)+(B)+(C)] is in 0.19～0.34 scope.Skin is separated out and be adsorbed in to the complex of dissolving in the process of dilution, so satiny sensation disappears very soon, the sense that pauses also further is improved, so preferred.Particularly preferably (A), (B) and (C) cationic charge density be the above polymer that contains cation radical of 4.5meq/g and (D) combination of inorganic salt.
Skin cleaning agent composite of the present invention can further contain (E) higher fatty acids and/or higher alcohol.At this, higher fatty acids and higher alcohol are preferably respectively the material of the carbon number 10～18 of straight chain, the more preferably material of carbon number 12～15.
By containing these compositions, the amount that usually can suppress to steep in the situation of the dilution ratio more taller than the dilution ratio of the detergent of clean health all can become good so remain in the froth breaking easiness (broken bubble) that residues in the foam of discharge outlet behind the froth breaking easiness (broken bubble) of the foam on the bath towel after the use and the flushing health.
In addition, as aftermentioned, skin cleaning agent composite of the present invention preferably shows the pH value of faintly acid～neutral region.In said composition, higher fatty acids is not the fatty acid soaps of the form of salt, but is contained in the compositions with lipid (free fatty) form, usually, in cleaning the dilution ratio zone of health, think that it helps the raising of performance of the bubble of the texture of steeping etc.
Composition (E) can use more than a kind, also can be used in combination higher fatty acids and higher alcohol.Further, from the performance that improves bubble and the viewpoint that has simultaneously the effect of good froth breaking, preferred compositions is used lauric acid and myristyl alcohol.
Composition (E) preferably contains 0.3～3 quality % in full constituent, more preferably 0.5～2 quality %.
Skin cleaning agent composite of the present invention can further contain composition (F) pearly luster imparting agent.
Can enumerate the fatty acid of carbon number 16～22 and the ester of ethylene glycol (single, two), the ester of the fatty acid of carbon number 16～22 and the Polyethylene Glycol with polyoxyethylene (1～7) unit etc. as the pearly luster imparting agent.Also has the glycol ester of the fatty acid of preferred carbon number 16～18 (single, two).
More specifically, can enumerate ethylene glycol fatty acid ester such as ethylene glycol monostearate and glycol monomethyl behenic acid ester etc.; The ethylene glycol bis fatty acid ester of Ethylene Glycol Distearate and ethylene glycol bis behenic acid ester etc.
The pearly luster imparting agent can use more than a kind, from the good viewpoint of pearly luster sense, preferably contains 1～3 quality % in full constituent, more preferably 1.5～2.5 quality %.
Skin cleaning agent composite of the present invention in the scope that does not hinder effect of the present invention, can also contain other the surfactant that is generally used in the cleansing composition except above-mentioned composition.Particularly can enumerate the cationic surfactant such as alkylbenzenesulfonate, alpha-alkene sulfonate, alkane sulfonate, alpha-sulfo fatty acid ester salt, acylated amino salt, alkylphosphonate, acyl group-Pidolidone salt etc.; The non-ionic surface active agent of the two alkanolamides of polyoxyalkylene alkyl, alkyl polyglucoside, fatty acid monoalkylol amide or fatty acid, polyoxyalkylene type block copolymer, fatty acid glyceride, alkyl glycerylether etc.; The cationic surfactant of quaternary ammonium salt etc.; The amphoteric surfactant of carboxybetaine class, sulfobetaines class, imidazolinium betaine class, hydroxyl betaines, fatty acid amide betaines etc.
Skin cleaning agent composite of the present invention further can also contain the various compositions that are generally used in the cleansing composition according to necessity.Particularly, can enumerate wetting agent such as propylene glycol, dipropylene glycol, glycerol and Sorbitol etc.; The solvent of water and ethanol etc.; The viscosity modifier of methylcellulose etc.; The antibacterial of triclosan, triclocarban etc.; The anti-inflammatory agent of dipotaccium glycyrrhizate and alpha-tocopherol acetate etc.; The antiseptic of methyl parahydroxybenzoate, butyl p-hydroxybenzoate, phenyl phenol and benzoate etc.; Other pigment, spice, UV absorbent and antioxidant etc.
Skin cleaning agent composite of the present invention can be according to usual way, by weighing allotment composition, in any order it is mixed in water or with water as main body and comprise in the aqueous medium of other water-soluble solvents of alcohol etc. and make.Thereby can use as bathing shampoo, wash one's face agent and cleansing product etc.
Skin cleaning agent composite of the present invention preferably is adjusted to faintly acid, and this moment is little to the stimulation of skin, and remarkable cleaning strength can not be suffered damage and the foaming characteristic when clean becomes well, the pause sense when flushing and use brilliance aspect the sensation.
So-called faintly acid refers to that pH is 4.5～7, is preferably pH4.5～6.5.In the present invention, pH is the value under 25 ℃ of temperature conditions of expression when being diluted to 20 times of quality with ion exchange water.
Embodiment
Embodiment 1～32, comparative example 1～13
The skin cleaning agent composite of the composition shown in the manufacturing table 1～table 9, feel when estimating flushing pause speed till the sense, the pause sense when flushing finishes intensity, towel off salubrious sense after doing and the amount of bubble.In addition, in the embodiment of a part, dried smooth feeling, pearly-lustre sense, broken bubble and liquid appearance also are evaluated.At last with the result respectively combined statement be shown in table 1～table 9.
Manufacture method
Composition shown in the weighing table also joins it in ion exchange water, stirs fully under 50 ℃ temperature conditions, thereby obtains skin cleaning agent composite.Add an amount of sodium hydroxide or malic acid, the pH that is adjusted into 20 times diluent becomes faintly acid.At this, pH is diluted to 20 times and obtain after the aqueous solution of 5 quality % with ion exchange water with compositions, uses pH tester (HORIBA makes, model F-22) to measure.
Evaluation methodology
(1) when flushing felt the speed (front wrist cleaning evaluation) till the sense of pausing:
Get each cleansing composition 1.0g in one on hand, with tap water dilution and afterwash two wrists (from the elbow to the front end) that make it to bubble, wash with tap water.At this moment, while the two front wrists that rub are washed, measure until feel friction number of times when having till the sense of pausing.Standard is carried out classification according to following metewand to measurement result.
5: the friction number of times is less than 3 times.
4: the friction number of times is less than 6 times more than 3 times.
3: the friction number of times is less than 9 times more than 6 times.
2: the friction number of times is less than 12 times more than 9 times.
1: the friction number of times is more than 12 times.
The intensity (whole body cleaning evaluation) of the pause sense when (2) flushing finishes:
Use for 1 day 1 time each cleansing composition to clean whole body by 10 specialty evaluation persons.Continuous like this carrying out 3 days estimated the intensity of washing the pause sense when finishing, and represented the result of determination of 3 days overall merit by following benchmark.
◎: have the pause sense when 8 people are above to answer the flushing end strong.
Zero: the pause sense when having 5～7 people to answer the flushing end is strong.
△: the pause sense when having 2～4 people to answer the flushing end is strong.
*: nobody or the pause sense that has 1 people to answer when washing end are strong.
(3) towel off salubrious sense (whole body cleaning evaluation) after doing:
Use for 1 day 1 time each cleansing composition to clean whole body by 10 specialty evaluation persons.Continuous like this carrying out 3 days estimated the salubrious sense that towels off after doing, and represented the result of determination of 3 days sum total evaluation by following benchmark.
◎: have the above answer of 8 people to towel off dried aftersensation salubrious.
Zero: have 5～7 people's answers to towel off dried aftersensation salubrious.
△: have 2～4 people's answers to towel off dried aftersensation salubrious.
*: nobody or have 1 people to answer to towel off dried aftersensation salubrious.
(4) amount of bubble:
To be diluted to 150 times (conditions when being equivalent to clean health) as the sample aqueous solution with 4 degree hard water in the compositions of each embodiment and comparative example modulation.Band bottle stopper at 50mL also adds sample solution 7.5ml and covers bottle stopper in the graduated glass cylinder pipe, (IWAKI of Co., Ltd. industry is made to use vibrator, model universal shaking machine V-SX), vibrates 30 seconds with the speed of 300 strokes/minute, read the bubble amount after vibration finishes.
(5) dried smooth feeling:
Use for 1 day 1 time each cleansing composition to clean whole body by 10 specialty evaluation persons.Continuous like this carrying out 3 days estimated dried smooth feeling, represented the result of determination of 3 days overall merit by following benchmark.
◎: have the dry aftersensation of the above answer of 8 people smooth.
Zero: have 5～7 people to answer dry aftersensation smooth.
△: have 2～4 people to answer dry aftersensation smooth.
*: nobody or to have 1 people to answer dry aftersensation smooth.
(6) pearly-lustre sense:
Outward appearance when joining cleansing composition in the vial is particularly estimated with visual the pearly-lustre sense.Standard is carried out classification according to following benchmark to evaluation result.
A: the reflecting feel that Margarita is arranged.
B: the reflecting feel of Margarita a little less than a bit.
C: the reflecting feel that does not have Margarita.
(7) broken bubble:
The cleansing composition that to modulate in each embodiment and comparative example is diluted to the high magnification (400 times) of imagining the broken bubble after washing with 4 degree hard water, as the sample aqueous solution.The sample solution of 7.5mL is joined in 50mL band bottle stopper and the graduated glass cylinder pipe, (IWAKI of Co., Ltd. industry is made to use vibrator, model universal shaking machine V-SX), vibrates 30 seconds with the speed of 300 strokes/minute, read vibration bubble amount (cm) afterwards.
(8) liquid appearance:
Outward appearance when joining cleansing composition in the vial with visual valuation (transparent feel).Standard is carried out classification according to following benchmark to evaluation result.
A: transparent feel is arranged.
B: transparent feel a little less than a bit.
C: do not have transparent feel.
Embodiment 33
The method identical with embodiment 1～32 made the bathing shampoo of composition shown below.
Table 10
Embodiment 34
The method identical with embodiment 1～32 made the bathing shampoo of composition shown below.
Table 11
Embodiment 35
The method identical with embodiment 1～32 made the bathing shampoo of composition shown below.
Table 12
Embodiment 36
The method identical with embodiment 1～32 made the bathing shampoo of composition shown below.
Table 13
The bathing shampoo that obtains among the embodiment 33～36 all demonstrates good foaming characteristic and alveolar substance, and the pause sense in when flushing and the salubrious sense that towels off after doing are also all good.In addition, the pearly-lustre sense is also good.
Claims (12)
1. skin cleaning agent composite is characterized in that:
Contain following ingredients (A), (B) and (C):
(A) polyoxyethylene alkyl ether sulfate salt
(B) polyoxyethylene alkyl ether carboxylate
(C) cationic charge density is the polymer that contains cation radical and/or the polyvinylpyrrolidone of 4.5～7meq/g,
Described cationic charge density is that the polymer that contains cation radical of 4.5～7meq/g is selected from following polymer: the homopolymer of dimethyl diallyl ammonium chloride; Dimethyl diallyl ammonium chloride and the copolymer that is selected from the monomer of (methyl) acrylic acid, (methyl) acrylate, (methyl) acrylamide; Polymethyl acyl chlorides oxy-ethyl-trimethyl salmiac;
Composition (A) and mass ratio (B) they are (A): (B)=85: 15～25: 75, composition (A) and total content (B) in all forming are 5～25 quality %, and the content of composition (C) is 0.05～1 quality %.
2. the skin cleaning agent composite of putting down in writing such as claim 1 is characterized in that:
The polymer that contains cation radical of composition (C) is the homopolymer of dimethyl diallyl ammonium chloride, perhaps dimethyl diallyl ammonium chloride and acrylic acid copolymer.
3. the skin cleaning agent composite of putting down in writing such as claim 1 or 2 is characterized in that:
Also contain (D) inorganic salt or the acylate of carbon number below 6,
The amount of composition (D) in full the composition is 0.5～10 quality %,
Described inorganic salt is selected from the salt of alkali metal, alkaline-earth metal and halogen, sulphuric acid, sulfurous acid and phosphoric acid,
The acylate of described carbon number below 6 is to be selected from hydroxy acid and polyprotic acid and the alkali-metal salt of selecting from acetic acid, lactic acid, malic acid, citric acid, succinic acid.
4. the skin cleaning agent composite of putting down in writing such as claim 1 or 2 is characterized in that:
Also contain (E) higher fatty acids or higher alcohol,
The amount of composition (E) in full constituent is 0.3～3 quality %,
Described higher fatty acids and described higher alcohol are respectively the materials of the carbon number 10～18 of straight chain.
5. the skin cleaning agent composite of putting down in writing such as claim 3 is characterized in that:
Also contain (E) higher fatty acids or higher alcohol,
The amount of composition (E) in full constituent is 0.3～3 quality %,
Described higher fatty acids and described higher alcohol are respectively the materials of the carbon number 10～18 of straight chain.
6. the skin cleaning agent composite of putting down in writing such as claim 1 or 2 is characterized in that:
Also contain (F) pearly luster imparting agent,
The amount of composition (F) in full constituent is 1～3 quality %,
The fatty acid that described pearly luster imparting agent is carbon number 16～22 and monoesters or the dibasic acid esters of ethylene glycol.
7. the skin cleaning agent composite of putting down in writing such as claim 3 is characterized in that:
Also contain (F) pearly luster imparting agent,
The amount of composition (F) in full constituent is 1～3 quality %,
The fatty acid that described pearly luster imparting agent is carbon number 16～22 and monoesters or the dibasic acid esters of ethylene glycol.
8. the skin cleaning agent composite of putting down in writing such as claim 4 is characterized in that:
Also contain (F) pearly luster imparting agent,
The amount of composition (F) in full constituent is 1～3 quality %,
The fatty acid that described pearly luster imparting agent is carbon number 16～22 and monoesters or the dibasic acid esters of ethylene glycol.
9. the skin cleaning agent composite of putting down in writing such as claim 1 or 2 is characterized in that:
PH when being diluted to 20 quality times with ion exchange water is 4.5～7.
10. the skin cleaning agent composite of putting down in writing such as claim 3 is characterized in that:
PH when being diluted to 20 quality times with ion exchange water is 4.5～7.
11. the skin cleaning agent composite as claim 4 is put down in writing is characterized in that: the pH when being diluted to 20 quality times with ion exchange water is 4.5～7.
12. the skin cleaning agent composite as claim 6 is put down in writing is characterized in that: the pH when being diluted to 20 quality times with ion exchange water is 4.5～7.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007-111423 | 2007-04-20 | ||
| JP2007111423 | 2007-04-20 | ||
| JP2007111424 | 2007-04-20 | ||
| JP2007-111424 | 2007-04-20 |
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| Publication Number | Publication Date |
|---|---|
| CN101288631A CN101288631A (en) | 2008-10-22 |
| CN101288631B true CN101288631B (en) | 2013-01-02 |
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| CN 200810090802 Active CN101288631B (en) | 2007-04-20 | 2008-04-02 | Skin cleaning agent composite |
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| JP (1) | JP2008285480A (en) |
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5057337B2 (en) * | 2008-04-08 | 2012-10-24 | モアコスメティックス株式会社 | Hypoallergenic liquid cleaning composition |
| US20130039871A1 (en) * | 2010-04-27 | 2013-02-14 | Kao Corporation | Aqueous composition contained in container |
| JP5308491B2 (en) | 2011-09-02 | 2013-10-09 | 花王株式会社 | Skin cleanser composition |
| JP6121098B2 (en) * | 2012-03-07 | 2017-04-26 | 花王株式会社 | Skin cleanser composition |
| CN103800213B (en) * | 2012-11-08 | 2018-09-14 | 花王株式会社 | Cleanser compositions |
| JP6431304B2 (en) * | 2013-10-24 | 2018-11-28 | 花王株式会社 | Cleaning composition |
| JP6538343B2 (en) * | 2014-12-16 | 2019-07-03 | クラシエホームプロダクツ株式会社 | Pearl-like gloss composition |
| JP6538342B2 (en) * | 2014-12-16 | 2019-07-03 | クラシエホームプロダクツ株式会社 | Pearl-like gloss composition |
| JP6402024B2 (en) * | 2014-12-17 | 2018-10-10 | クラシエホームプロダクツ株式会社 | Pearl-like luster cleaning composition and method for producing the same |
| CN106473948B (en) * | 2015-09-02 | 2021-08-27 | 花王株式会社 | Detergent composition |
| CN106473938B (en) * | 2015-09-02 | 2021-09-03 | 花王株式会社 | Detergent composition |
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Also Published As
| Publication number | Publication date |
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| CN101288631A (en) | 2008-10-22 |
| JP2008285480A (en) | 2008-11-27 |
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