JP2000264821A - Composition for permanent wave or correcting curly hair - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain the subject composition improved in a touch such as smoothness of hair in a wet and a dry states after permanent waving or curly hair correcting treatment and moistness of the hair in a dry state by composing the composition of an agent containing a reducing agent, etc., and an agent containing an oxidizing agent, etc. SOLUTION: This composition is composed of (A) a first agent composition containing (i) a reducing agent such as ammonium thioglycolate in an amount of preferably 2-10 wt.% in the ingredient A and (ii) a copolymer of dimethyldiallylammonium chloride and acrylic acid in an amount of preferably 0.5-3.0 wt.% in the ingredient A and (B) a second agent containing (i) an oxidizing agent such as sodium bromate in an amount of preferably 1.5-10 wt.% in the ingredient B and (ii) an anionic surfactant such as sodium polyoxyethylene lauryl ether sulfate in an amount of preferably 0.5-3.0 wt.% in the ingredient B. The composition is useful as a cold two-bath type permanent waving agent, etc.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

FIELD OF THE INVENTION The present invention relates to a permanent wave or curly straightening composition. For more information,
A permanent wave comprising a first agent and a second agent, which significantly improve the feeling of the permanent wave and the smoothness of the hair in the wet and dry states after the hair straightening treatment and the moistness of the hair in the dry state, or The present invention relates to a composition for straightening hair.

[0002]

2. Description of the Related Art In the process of permanent waving and straightening of hair, various irreversible damages to hair are caused by reduction and oxidation. In particular, an increase in friction, a reduction in puffiness, and a reduction in gloss due to the disorder of the cuticle layer on the hair surface are serious factors that impair the beauty of hair, and many techniques have been tried to solve this.

[0003] For example, a technique of blending a cationic polymer in the first agent for permanent wave and an anionic surfactant in the second agent (Japanese Patent Publication No. 2-12927;
6-15099, JP-A-58-150506, JP-A-61-183214), and technology for applying a silicone polymer (JP-A-60-8216, JP-A-2-183214) Etc. have been proposed.

[0004]

However, in the former technique, when a complex of a cationic polymer and an anionic surfactant is formed on the hair surface, the hair becomes smooth when wet with water. Although it gives a feel, it is rather unpleasant in a dry state because it gives a rough feel.

[0005] In addition, the technology using a silicone polymer has a problem that the hair is somewhat insufficient in smoothness, and when it is in a dry state, the hair is too dry and hard and crisp and lacks moistness. there were.

[0006] The present inventors have conducted intensive studies to solve the problems of the prior art by the treatment of permanent wave and straightening hair from the above viewpoints. As a result, (A) a reducing agent,
(B) a first agent containing a copolymer of dimethyldiallylammonium chloride and acrylic acid, (C) an oxidizing agent,
(D) When a permanent wave and straightening treatment is performed using a composition comprising a second agent containing an anionic surfactant, both the dry state and the wet state have a remarkably smooth feel and are moist even in a dry state. The present inventors have found that a hair giving a soft feeling can be obtained, and have completed the present invention.

[0007] The present invention significantly improves the feel of the hair in a wet state after a permanent wave or straightening treatment, the smoothness of the hair in a dry state, and the moistness of the hair in a dry state. It is an object of the present invention to provide a permanent wave or curly straightening composition.

[0008]

That is, the present invention provides:
(A) a first agent containing a reducing agent and (B) a copolymer of dimethyldiallylammonium chloride and acrylic acid,
A permanent wave or curly straightening composition characterized by comprising (C) an oxidizing agent and (D) a second agent containing an anionic surfactant.

[0009] The present invention also provides the composition for correcting permanent hair or curly hair, wherein the composition further comprises (E) an anionic polymer in the second agent.

Further, the present invention is characterized in that said first agent further comprises (F) an amino-modified silicone polymer, a glycol-modified silicone polymer and a silicone oil, wherein said permanent wave or curly hair is used. The present invention provides a correction composition.

[0011] The present invention also provides the above-mentioned composition for permanent wave or hair straightening, wherein the second agent further comprises (G) a higher alcohol.

Further, the present invention is characterized in that the higher alcohol (G) is one or more higher alcohols selected from the group consisting of myristyl alcohol, cetyl alcohol, stearyl alcohol and behenyl alcohol. And a permanent wave or curly straightening composition.

[0013]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The configuration of the present invention will be described below in detail.

The reducing agent of the component (A) used in the first agent of the present invention is not particularly limited as long as it is a reducing agent usually used for a permanent waving agent. Salts, cysteine or salts thereof, N-acetylcysteine, sulfite, bisulfite and the like.

Specific preferred reducing agents include, for example, thioglycolic acid, ammonium thioglycolate, monoethanolamine thioglycolate, isopropanolamine thioglycolate, lysine thioglycolate, arginine thioglycolate, thiolactic acid, thiolactic acid, and thiolactic acid. Ammonium lactate, monoethanolamine thiolactate, isopropanolamine thiolactate, lysine thiolactate, arginine thiolactate, L-cysteine, DL-cysteine, L
-Cysteine hydrochloride, DL-cysteine hydrochloride, N-acetyl-L-cysteine, N-acetyl-DL-cysteine, sodium sulfite, sodium bisulfite, ammonium sulfite, ammonium bisulfite, monoethanolamine sulfite and monoethanol bisulfite Amines and the like.

These reducing agents can be used alone or in combination of two or more. The content of the reducing agent is 1 to 15% by weight, preferably 2 to 10% by weight in the first agent.

In order to adjust the reducing power of these reducing agents, it may be useful to add conjugated oxidizing agents such as dithiodiglycol-acid, dithiodilactic acid or salts thereof, L-cystine and cystine derivatives.

These reducing agents generally have a stronger action as the pH of the first agent is higher.
PH to 6.0 to 10.0, preferably 6.5 to 9.5
Is adjusted.

The copolymer of dimethyldiallylammonium chloride and acrylic acid as the component (B) of the first agent of the present invention has a number average molecular weight of 100,000 to 10,000,000,
Mercoat 280 (copolymer of about 80% dimethyldiallylammonium chloride and about 20% acrylic acid, number average molecular weight of about 2,000,000, manufactured by Calgon Corporation); Mercoat 295 (about 9% of dimethyldiallylammonium chloride)
5% and about 5% acrylic acid copolymer, number average molecular weight 5
Commercial products such as 0000 (manufactured by Calgon Corporation) can be used.

These copolymers can be used singly or in combination of two or more.
0.1-5.0% by weight, preferably 0.5-3.0% in the preparation
% By weight.

The oxidizing agent of the component (C) used in the second agent of the present invention is not particularly limited as long as it is an oxidizing agent usually used for a permanent waving agent, and examples thereof include sodium bromate, potassium bromate, and peroxidic acid. Examples include sodium borate and aqueous hydrogen peroxide.

These oxidizing agents can be used singly or in combination of two or more.
0.5 to 15% by weight, preferably 1.5 to 10% by weight of the composition.

As the anionic surfactant of the component (D) used in the second agent of the present invention, the anionic hydrophilic part is-
A surfactant containing at least one of an OSO ₃ ^— group, a —SO ₃ ^— group, or a —COO ⁻ group, for example, an alkyl sulfate, an alkyl ether sulfate, an alkyl sulfonate, an alkylbenzene sulfonate, an alkyl Taurate, alkyl N-methyl taurate, alkyl sulfosuccinate, alkyl ether sulfosuccinate,
Alkyl sarcosinate, alkyl ether carboxylate, alkyl phosphate, alkyl ether phosphate and the like can be mentioned.

Preferred anionic surfactants include, for example, sodium or ammonium lauryl sulfate, mono-, di-, triethanolamine, sodium polyoxyethylene lauryl ether sulfate, α-olefin sulfonate, coconut fatty acid methyl-N-taurine Sodium, N-myristoylmethyl N-taurine sodium, sodium lauryl sulfonate, sodium lauryl sulfocolacinate, sodium lauryl polyethylene glycol sulfosuccinate (1-3 ethylene oxide adduct), potassium N-cocoyl dultamate , Sodium, sodium sodium dodecane-1,2-diol phosphate, sodium lauryl phosphate, sodium lauryl ether phosphate, and the like.

These anionic surfactants can be used alone or in combination of two or more, and the content thereof is 0.1 to 5.0% by weight, preferably 0.5 to 5.0% by weight in the second agent.
3.0% by weight is blended.

The anionic polymer of component (E) used in the second agent of the present invention includes, for example, acrylic acid polymer;
Methacrylic acid polymer; acrylic acid / methacrylic acid copolymer; acrylic acid / alkyl methacrylate copolymer; maleic acid / butylene copolymer; alkylene maleate copolymer; carboxyvinyl polymer; carboxy-modified silicone polymerization Things.

These anionic polymers may be used alone or in combination.
More than one kind can be used in combination, and the content is 0.01 to 5.0% by weight in the second agent, preferably 0.05 to 1.0% by weight in the case of a vinyl polymer, In the case of a modified silicone oil or a carboxy-modified silicone polymer, the content is 0.05 to 4.0% by weight.

The amino-modified silicone polymer, glycol-modified silicone polymer or silicone oil of the component (F) used in the first agent of the present invention is blended as an emulsion or a microemulsion. 0.0% by weight,
Preferably, it is added in an amount of 0.5 to 5.0% by weight.

The higher alcohol of the component (G) used in the second agent of the present invention is not limited as long as it is a higher alcohol usually used in hair cosmetics, but is preferably myristyl alcohol, cetyl alcohol, stearyl alcohol. , Behenyl alcohol or a combination of two or more thereof.

The content of the higher alcohol is 0.1 in the second agent.
To 20% by weight, and preferably 0.
It is preferably 5 to 3.0% by weight, and in the case of two creams, preferably 3.0 to 15% by weight.

In order to blend these higher alcohols usefully and stably, it is preferable to further blend a nonionic surfactant in addition to the above-mentioned component (D).

Preferred nonionic surfactants include, for example, polyoxyethylene alkyl ether; (eg, polyoxyethylene lauryl ether, polyoxyethylene myristyl ether, polyoxyethylene cetyl ether, polyoxyethylene oleyl ether, polyoxyethylene stearyl) Ether, polyoxyethylene isostearyl ether), monofatty acid glycerin ester, monofatty acid sorbitan ester, fatty acid monoethanolamide, fatty acid diethanolamide and the like.

The permanent waving or curly hair straightening composition of the present invention contains components commonly used in hair cosmetics,
For example, water, alcohol, alkaline agent, fat, mineral oil,
Various synthetic ester oils, higher branched alcohols, higher unsaturated alcohols, silicone oils, emulsifiers, solubilizers, buffers, fragrances, dyes, preservatives, sequestering agents, pH adjusters, hair protectants such as amino acids and peptides And solvent, etc.
The compound can be appropriately compounded within a range that does not impair the effects of the present invention, and can be produced by a conventional method.

The permanent waving or curly hair straightening composition of the present invention can be used, for example, as a cold two-bath type, heated two-bath type permanent waving agent or hair straightening agent.

[0035]

EXAMPLES Next, the present invention will be described more specifically with reference to examples, but the present invention is not limited to only these examples.

"Examples 1 to 6, Comparative Examples 1 to 4""Table1"
And hair obtained by adjusting the first and second agents of the permanent wave composition shown in Table 2 according to a conventional method, and performing the permanent wave treatment with the combinations shown in Tables 3 and 4. The following tests were conducted to evaluate the effect of the present invention on the friction and the feel of the hair. Table 3 shows the results.
And "Table 4".

[Test Method for Friction of Hair] Hair: Undamaged hair which has not been chemically permed, colored and bleached is immersed in a 0.5% aqueous solution of sodium lauryl sulfate and allowed to stand at 40 ° C. for 30 minutes. After the placement, the plate was thoroughly washed in running water and air-dried by standing still in a room. This hair fiber 4
Zero hairs were aligned at the root and the direction of the hair tips were aligned, and the roots were bonded to form a hair bundle.

<Measurement of Hand Friction> A hair friction force measuring instrument, Model M430-M1 (manufactured by Nikki Denso Co., Ltd.) was used.
An NBR ring was mounted on the roller portion of the measuring instrument, the hair bundle was sandwiched between the rollers, and the tension applied to the hair bundle was measured while rotating the roller at 2 rpm. The measurement was performed before and after the perm treatment, and the measurement was made at four locations while shifting the hair bundle by 1 cm. Hair bundles are dry (24 ± 1 ° C, 60 ±
5% RH) and completely wet with water, and the hand friction was calculated by the following equation. Hand friction = [tension on hair bundle after perm treatment (g)] / [tension on hair bundle without perm treatment (g)] Hand friction = 1: No change in friction before and after perm treatment. Hand friction <1: When the friction is reduced by the perm agent treatment. Hand friction> 1: When friction increases due to perm agent treatment. When treating with a combination of one permanent agent and two agents, one agent is 30
At 10 ° C. for 10 minutes, two hairs were treated at 30 ° C. for 10 minutes, and 4 hair bundles were treated, and n = 4 sites × 4 = 16, and the average value was described in “Table 1”.

[Test Method for Feeling of Hair] Hair bundle: 3 g of the same hair as in the friction measurement, 20 cm was bundled, and the root of the hair was bonded to prepare a hair bundle. This hair bundle is treated with one agent at 30 ° C. for 10 minutes and two agents at 30 ° C. for 10 minutes.
The hair was subjected to the following sensory evaluation, and the treated hair was subjected to a sensory evaluation of smoothness (kisimi and comb) and feeling of moistness.

<Judgment of Smoothness (Kishimi and Comb)) For each of the dry state and the wet state of the hair bundle that has been subjected to the above-described perm agent treatment, four panels made a judgment of the kismi and comb states. went. As a criterion, a value obtained by rounding off the second decimal place of the average value of the following criteria of each panel was evaluated according to the following five grades. Rating 1: There is considerably more blemishes than untreated hair, and combing is much worse. Score 2: There is more blemishes than untreated hair and the comb is worse. Score 3: Slightly smoother than untreated hair and slightly better comb-through. Score 4: Smooth and more supple than untreated hair,
Katsu comb street is also good. Rating 5: Very smooth and supple than untreated hair, and very good combing. ×: Average score is less than 1.5 Δ: Average score is 1.5 or more and less than 2.5 ○: Average score is 2.5 or more and less than 3.5: Average score is 3.5 or more and 4. Less than 5 ☆: Average score is 4.5 or more

<Judgment of Moistness> After the determination of the kissiness and comb as described above, the hair bundle was immersed in hot water of 40 ° C. for 10 minutes, suspended in a room, and air-dried for 30 minutes (23 ° C., 55% RH).
The moistness was determined by four panels. As a criterion, a value obtained by rounding off the second decimal place of the average value of the following grading scores of each panel was evaluated according to the following four grades. Rating 1: The hair is considerably crisp and stiffer than untreated hair. Rating 2: Slightly flaky than untreated hair. Score 3: Felt slightly softer and softer than untreated hair. Rating 4: Moist and softer than untreated hair. ×: Average score is less than 1.5 Δ: Average score is 1.5 or more and less than 2.5 ：: Average score is 2.5 or more and less than 3.5 ５: Average score is 3.5 or more

[0042]

[Table 1] ---------------------------------------------- --------------- Composition of first agent (W / V%) No.1 No.2 No.3 No.4 ------------ ------------------------------------------------- Thio Ammonium glycolate (50%) 13.5 g 13.5 13.5 13.5 Monoethanolamine 2.0 2.0 2.0 2.0 Ammonium bicarbonate 1.0 1.0 1.0 1.0 Mercoat 100 (40%) ^* 1-2.0--Mercoat 295 (40%) ^* 2--2.0 2.0 Toray Silicone SM8704C ^{* 3} ---4.0 Purified water Residue Residue Residue Residue ----------------------------------- -------------------------- Total (mL) 100.0 100.0 100.0 100.0 ---------------- --------------------------------------------- * 1: Mercoat 100 (Polymer of diallyldimethylammonium chloride, about 40% aqueous solution: manufactured by Calgon Corporation, commercially available product) * 2: Mercoat 259 (copolymer of diallyldimethylammonium chloride and acrylic acid: about 40% aqueous solution: calgon Over poration Ltd., commercially available) * 3: Toray Silicone SM8704C (aqueous emulsion containing about 40% amino-modified silicone: Toray Dow Corning Co., commercially available)

[0043]

[Table 2] ---------------------------------------------- --------------- Composition of second agent (W / V%) No.1 No.2 No.3 No.4 No.5 No.6 ------ -------------------------------------------------- ----- Sodium bromate 6.0 6.0 6.0 6.0 6.0 6.0 Alscope AP-30 ^* 4-1.0 1.0 1.0 0.5 0.5 Hemulene TP-2 ^* 5--0.2-0.2-Toray silicone BY22-840 ^{* 6} ---2.0 -2.0 Cetostearyl alcohol 4060----0.2 0.2 Polyoxyethylene oleyl ether (20E.O.) 0.1 0.1 0.1 0.1 0.1 0.1 Purified water Residue Residue Residue Residue Residue Residue Total (mL) 100.0 100.0 100.0 100.0 100.0 100.0 --- -------------------------------------------------- -------- * 4: Alscope AP-30 (approximately 30% aqueous solution of sodium polyoxyethylene (3EO) lauryl ether sulfate: commercially available from Toho Chemical Co., Ltd.) * 5: Pemulen TR -2 (Acrylic acid / alkyl methacrylate copolymer, Nikko Chemicals Co., Ltd .: BF Goodrich, commercially available) * 6: Toray Silicone BY22-840 (Aqueous microemulsion containing 30% carboxy-modified silicone: Toray Dow Corning, commercial product)

"Evaluation by Combination of First Agent / Second Agent"

[Table 3] ---------------------------------------------- ------------------------- Comparative Example Comparative Example Comparative Example Example Example Example Example Example Example 1 2 3 1 2 3 4 5 6 ------------------------------------------------ ----------------------- First agent No.1 No.2 No.3 No.3 No.4 No.4 No.4 No.4 No.4 2nd agent No.1 No.2 No.1 No.2 No.2 No.3 No.4 No.5 No.6 ----------------- -------------------------------------------------- ---- Friction measurement [touch friction] [Wet] 1.57 0.91 1.03 0.80 0.73 0.55 0.50 0.48 0.37 [Tori] 1.35 1.21 1.07 0.88 0.82 0.60 0.64 0.52 0.44 ---------------- -------------------------------------------------- ----- Feeling judgment [sensory test] --------------------------------------- -------------------------------- Smoothness [Kisimi / Koshidori] [Wet] × ○ ○ ◎ ◎ ☆ ☆ ☆ ☆ [Triple] × △ △ ○ ◎ ◎ ◎ ◎ ◎ ------------------------------------ --------------------------- -------- Moisturizing [Dorai] × × × ○ ○ ◎ ◎ ◎ ◎ ---------------------------- -------------------------------------------

[0045]

[Table 4] ---------------------------------------------- --------------- Example Example Example Example Example 7 8 9 10 ----------------------- -------------------------------------- 1st agent No.3 No.3 No.3 No.3 2nd agent No.3 No.4 No.5 No.6 -------------------------------- ----------------------------- Friction measurement [touch friction] [Wet] 0.75 0.65 0.56 0.44 [Triple] 0.85 0.73 0.68 0.51- -------------------------------------------------- ---------- Feeling judgment [sensory test] ---------------------------------- --------------------------- Smoothness [Kisimi / Koshidori] [Wet] ◎ ☆ ☆ ☆ [Dry] ○ ◎ ◎ ◎- -------------------------------------------------- ---------- Moistness [Triple] ○ ◎ ◎ ◎ ------------------------------- ------------------------------

As can be seen from Tables 3 and 4,
In Examples of the present invention, touch friction [Wet], [Dry], smoothness [Wet], [Dry] and moistness [Dry] are remarkably improved as compared with Comparative Examples. By blending Mercoat 295 in the first part and Alscope AP-30 in the second part, the improvement in the feel and friction of the hair is clear, but the first part is Toray Silicone SM8704C and the second part is The results also show that the addition of Pemulen TR-2, Torre Silicone BY22-840 and cetostearyl alcohol further improves the feel and friction of the hair.

Example 11 The following first and second cold bath type permanent wave preparations were prepared. 1st agent ----------------------------------------------- ----------------- Composition Blended amount (W / V%) No.1 Ammonium thioglycollate (50%) 16.0g No.2 Siammonium dithiocyclocholate (40% %) 3.8g No.3 Ammonium water reagent special grade (28%) 1.5g No.4 Monoethanolamine 1.0g No.5 Ammonium hydrogen carbonate 1.5g No.6 Mercoat 280 2.0g No.7 Toray Silicone BY22-010 2.0 g No.8 EDTA-2Na 0.1g No.9 Polyoxyethylene (20E.O.) lauryl ether 0.3g No.10 Flavor 0.1g No.11 Purified water Remaining ------------ -------------------------------------------------- -Total 100.0 mL No. 6: Mercoat 280 (approximately 40% aqueous solution of a copolymer of diallyldimethylammonium chloride (80%) and acrylic acid (20%): commercially available from Calgon Corporation) No. 7: Toray Silicone BY22-010 (Hydrophilic containing polydimethylsiloxane Lee Black Emulsion: Toray Dow Corning Co., commercially available) [Preparation] successively added No.1,2,4,5,6,8 to No.11 about 50 g,
Separately, add No. 9 to about 10 g of No. 11 and dissolve by heating. Add No. 10 and stir until it becomes transparent. Then add this part to the previous main part, add No. 3 and No. 7 and stir evenly, then add No. 11 at the end to make the whole 100
mL. A transparent and stable first agent is obtained.

[0048] Second agent -------------------------------------------- -------------------- Composition Compounding amount (W / V%) No.1 Sodium bromate 7.0g No.2 Potassium phosphate 0.5g No.3 Caustic sorter 0.2g No.4 Alscoffe SP-40 1.5g No.5 Hi-Vis Wako 104 0.3g No.6 Polyoxyethylene (20E.O.) Oleyl ether 0.5g No.7 Purified water Residue -------- -------------------------------------------------- ------ Total 100.0 mL No. 4: Alscope SP-40 (aqueous solution containing about 40% sodium lauryl sulfate: commercially available from Toho Chemical Co., Ltd.) No. 5: Hibiswako 104 (carboxyvinyl polymer: (Wako Pure Chemical Industries, Ltd., commercially available product) [Production method] Add No. 1, 2, and 4 to about 50 g of No. 7 and stir evenly (Part 1). No. 5 was added to about 30 g of No. 7 and stirred.
And stir until the whole becomes a uniform gel (Part 2). Add No. 6 to about 10 g of No. 7 and stir while heating and dissolving (Part 3). Combine parts 1, 2, and 3 and stir until the whole becomes transparent and uniform. Finally, add the remainder of No. 7 to make the whole 100.0 mL, and stir again. A transparent and stable microviscous second agent is obtained.

[Effect] The first agent was used as a hair bundle (3 g, 20 cm)
And about 1 mL thereof was uniformly wound around an ever rod using a winding paper. Room temperature (24 ° C, 60% R
H) After the elapse of 10 minutes, 2 mL of the first agent was further applied and allowed to stand for 10 minutes. Rinse in running water of about 40 ° C for 3 minutes, lightly dry with a towel, apply 3 mL of the second agent uniformly, and add
Let stand for 0 minutes. The rod was removed, the hair bundle was washed in running water at about 40 ° C., lightly dried with a towel, suspended in a room, and air-dried. Uniform and elastic wave hair is obtained, wet,
The dry state was very smooth, flexible and moist.

Example 12 The following first and second cold double bath permanent wave preparations were prepared. 1st agent ----------------------------------------------- ----------------- Composition Blended amount (W / V%) No.1 Ammonium thiolactate (60%) 10.0g No.2 Monoethanolamine thiolactate (40%) 10.0g No.3 Diammonium dithiocyanate lactate (40%) 2.5g No.4 Monoethanolamine 2.0g No.5 L-alkydyne 1.0g No.6 Mercoat 295 3.0g No.7 Toray Silicone SM8704C 2.0g No.8 EDTA3Na 0.1g No.9 Polyoxyethylene (15E.O.) cetyl ether 0.3g No.10 Fragrance 0.2g No.11 Purified water Residue ------------------- --------------------------------------------- No.6: Marcote 295 (about 40% aqueous solution of a copolymer of diallyldimethylammonium chloride (95%) and acrylic acid (5%): commercially available from Calgon Corporation) No. 7: Toray Silicone SM8704C: Approx. 40 amino-modified silicone % Aqueous emulsion (Tore Dawco) Packaging Co., commercially available) [Preparation] was added to No.1,2,3,4,5,6,8 to No.11 about 60g uniformly stirred to dissolve. (Part 1) No. 9 is added to about 10 g of No. 11 and dissolved by heating, and No. 10 is added and stirred to dissolve transparently. (Part 2) Add Part 2 to Part 1 and add No.7 while stirring.
Finally, add the remainder of No. 11 to make the whole 100.0 mL, and stir again to make it uniform. A uniform and milky white stable first agent is obtained.

Second agent -------------------------------------------- -------------------- Composition Compounding amount (W / V%) No.1 Sodium bromate 8.0g No.2 Monopotassium phosphate 0.1g No.3 Phosphorus Disodium salt 0.2g No.4 Nikkor CMT-30 1.5g No.5 Purified water Residue ------------------------------ ---------------------------------- Total 100.0mL No.4: Nikkor CMT-30 (Methyl palm oil fatty acid) An aqueous solution containing about 30% sodium tauride: commercially available from Nikko Chemicals) [Production method] No. 1, 2, 3 and 4 are added to about 80 g of No. 6 and uniformly stirred to dissolve. No. 5 was further added, and the remainder of No. 6 was added and stirred, and the whole was adjusted to 100.0 mL. A milky and stable second agent is obtained.

[Effect] The first agent is applied to a hair bundle (3 g, 20 cm)
And about 1 mL, and uniformly wound around an ever rod using a winding paper. Room temperature (24 ° C, 63
% RH) After about 10 minutes have elapsed, 2 mL of the first agent is applied again,
It was left still for 10 minutes. After washing with running water of about 40 ° C. for 3 minutes, lightly towel-drying, 3 mL of the second agent was uniformly applied, and allowed to stand at room temperature for 10 minutes. The rod was removed, and the hair bundle was washed in running water at about 40 ° C., lightly towel-dried, suspended in a room, and air-dried. Uniform and elastic wavy hairs were obtained, very smooth and flexible in both wet and dry states, and moist and very shiny wavy hairs were obtained even when dry.

Example 13 The following first and second preparations for a heated two-bath type permanent wave shown below were prepared. 1st agent ----------------------------------------------- ----------------- Composition Blended amount (W / V%) No.1 DL-cysteine hydrochloride 6.5 g No.2 N-acetyl-L-cysteine 1.5 g No. 3 Ammonium thioglycolate (50%) 2.0g No.4 Monoethanolamine 3.5g No.5 Mercoat 295 1.0g No.6 EDTA-3Na 0.5g No.7 Purified water residue ---------- -------------------------------------------------- ---- 100.0 mL in total No.5: Mercoat 295 (Aqueous solution of about 40% copolymer of diallylmethylammonium chloride (95%) and acrylic acid (5%): commercially available from Calgon Corporation) No No. 1, 2, 3, 4, 5 and 6 were added to about 80 g of 0.7 and stirred to dissolve uniformly. The remainder of No. 7 was added to make the whole 100.0 mL to obtain a uniform, transparent and stable first agent (No. 9).

Second agent -------------------------------------------- -------------------- Composition Compounding amount (W / V%) No.1 Hydrogen peroxide solution (3.0%) 6.7g No.2 Phosphoric acid 0.1g No .3 Methyl alcohol 0.1 g No.4 Cetostearyl alcohol 4060 0.5 g No.5 Alscope SP-40 0.5 g No.6 Sarcosinate LN 0.2 g No.7 Polyoxyethylene (8E.O.) cetyl ether 0.2 g No.8 Hemulen TR-2 0.3g No.9 Purified water residue -------------------------------------- -------------------------- Total 100.0mL No.5: Alscope SP-40 (Aqueous solution containing about 40% sodium lauryl sulfate: Toho) No. 6: Sarcosinate LN (sodium sarcosine laurate: manufactured by Nikko Chemicals, commercial product) No. 8: Pemulen TR-2 (copolymer of acrylic acid and alkyl methacrylate: Nikko Chemicals) [Production method] No.1 and 2 in about 50g of No.9 Add 3 and 3 to dissolve uniformly (part 1). No. 9 was added to about 40 g of No. 9. 8 plus
After uniformly dissolving while stirring, add Nos. 4, 5, 6, and 7 and heat to about 80 ° C, and gradually cool to about 30 ° C while gently stirring (Part 2). Add Part 2 to Part 1 and mix gently. Add the rest of No. 9 and add 100.
The volume was adjusted to 0 mL, and the mixture was further stirred gently to obtain a uniform white, slightly viscous second agent.

[Effect] As a result of treating the hair bundle by the same method as in Examples 7 and 8 (however, it was heated to about 40 ° C. when the first agent was applied), a uniform and elastic wave was obtained. Thus, a wavy hair having a remarkably good feel in both wet and dry conditions was obtained.

Example 14 A first and second liquids of a heated two-bath curling agent shown below were prepared. 1st agent ----------------------------------------------- ----------------- Composition Compounding amount (W / V%) No.1 Sodium hydrosulfite 3.0g No.2 Urea 3.0g No.3 Monoethanolamine 3.0g No. 4 2-Amino-2-methylfluoroethanol 1.0g No.5 Mercoat 280 3.0g No.6 Cationic emulsion DCQ2-7224 1.0g No.7 Purified water Residue --------------- ------------------------------------------------- total 100.0 mL No.5: Mercoat 280 (Aqueous solution of about 40% copolymer of diallyldimethylammonium chloride (80%) and acrylic acid (20%): commercially available from Calgon Corporation) No.6: Cationic emulsion DCQ2-7224 (aqueous emulsion containing trimethylsilylicea modimethicone: commercially available from Dow Corning) [Production method] To about 80 g of No. 7, add No. 1, 2, 3, 4 and 5 and stir until homogeneously dissolved. . Next, add No. 6 and stir, and finally
Add the remainder of No. 7 to make the whole 100.0 mL. A milky white stable first liquid was obtained.

[0057] Second agent -------------------------------------------- -------------------- Composition Compounding amount (W / V%) No.1 Sodium bromate 1.00g No.2 Monopotassium phosphate 0.05g No.3 Phosphorus Disodium acid 0.10g No.4 Alicecope AP30 0.50g No.5 Sulfosuccinate L2Na 0.25g No.6 Hexenyl alcohol 0.30g No.7 Cetostearyl alcohol 1.50g No.8 Polyoxyethylene (50E.O.) oleyl Ether 0.20g No.9 Aron A-20P 0.05g No.10 Purified water residue -------------------------------- -------------------------------- Total 100.00mL No.4: Aliscope AP-30 (polyoxyethylene (3E .O.) Aqueous solution containing about 30 g of sodium lauryl sulfate: commercially available from Toho Chemical Co., Ltd. No. 5: Sulfosuccinate L2Na (sodium lauryl sulfosuccinate: commercially available from NOF Corporation) No. 9 : Aron A-20P (sodium polyacrylate) Toagosei Chemical Industry Co., commercially available) [Preparation] The No.1,2,3 and 9 in addition to No.10 about 30g, and stirred until uniformly dissolved (part 1). About 60g of No.10
No. 4, 5, 6, 7 and 8 are added to the mixture, and the mixture is heated to about 80 ° C. and gradually cooled with gentle stirring to about 30 ° C. (part 2). Add part 2 to part 1 and gently stir,
The remainder of No. 10 was added to make the whole 100.0 mL, and stirring was further continued to obtain a milky viscous second liquid.

[Effect] 1 mL of the first liquid was applied to a hair bundle (3 g, 20 cm), wound around an ever rod, and further 2 m long.
L is applied and left at 40 ° C. for 20 minutes. About 40
After washing for about 3 minutes in running water at
3 mL of the solution is applied and allowed to stand at room temperature (25 ° C., 52% RH) for about 5 minutes. The rod was removed, washed with running water of about 40 ° C., lightly towel-dried, suspended in a room, and air-dried. A loose but elastic soft wave was formed. Both the wet and dry were beautiful waves with a remarkably excellent feel.

Example 15 The following first and second warming two-bath hair straightening agents were prepared. 1st agent ----------------------------------------------- ----------------- Composition Compounding amount (W / W%) No.1 Ammonium thioglycolate (50%) 8.8g No.2 N, N'-diacetyl cystine 1.0 g No.3 Monoethanolamine 1.3g No.4 Hepenyl alcohol 3.0g No.5 Cetostearyl alcohol 4060 3.0g No.6 Stearyltrimethylammonium chloride (60%) 0.5g No.7 Polyoxyethylene (15E.O.) oil Lerether 0.5g No.8 Marcoat 295 5.0g No.9 Silicon SC1014M 0.5g No.10 Fragrance 0.1g No.11 Purified water Residue -------------------- -------------------------------------------- Total 100.0g No.8 : Mercoat 295 (aqueous solution containing about 40% copolymer of diallyldimethylammonium chloride (95%) and acrylic acid (5%): commercial product, manufactured by Calgon Corporation) No. 9: Silicon SC1014M (glycol-modified silicone: Shin-Etsu Chemical Co., Ltd. [Production method] No.1, No.2, No.3 and No.8 are added to about 30 g of No.11 and stirred until they are uniformly dissolved (part 1). No.11 about 40g N
Add o, 4, 5, 6, 7 and 9 and heat to about 80 ° C, slowly cool to about 40 ° C with stirring to obtain a creamy base, add No. 10 and stir for about 60 minutes ( Part 2). Parts 1, 2
While stirring well, add the remainder of No. 11 to make the whole 100.0 g. Finally, the mixture was degassed under reduced pressure to obtain a creamy first agent.

Second agent -------------------------------------------- -------------------- Composition Compounding amount (W / W%) No.1 Hydrogen peroxide solution (30%) 6.80 g No.2 Phenacetin 0.10 g No. 3 Phosphoric acid 0.20g No.4 Disodium phosphate 0.05g No.5 Methyl alcohol 0.05g No.6 Hepenyl alcohol 3.00g No.7 Cetostearyl alcohol 3.00g No.8 Myristyl alcohol 1.00g No.9 Nikkor MMT 1.00g No. 10 Polyoxyethylene (15E.O.) oleyl ether 0.50g No.11 Polymethylsiloxane (20cs) 3.00g No.12 Polyester OMR 1.00g No.13 Purified water residue ------------ -------------------------------------------------- -Total 100.0 g No. 9: Nikkor MMT (N-myristoylmethyl-N-taurine sodium salt: commercially available from Nikko Chemicals Co., Ltd.) No. 12: Polystar OMR (sodium salt of maleic acid / isobutylene copolymer) About 25% included The solution: NOF Corporation, and stirred until commercially available) [Preparation] dissolved No.1,2,3,4,5 and 12 were added uniformly to No.13 about 20 g (part 1). About 5 of No.13
No. 6, 7, 8, 9, 10 and 11 are added to 0 g, heated to about 80 ° C., homo-processed by a homo mixer, then gradually cooled while stirring the whole, and further added to part 1 to be uniform. Stirring is continued until the rest of No. 13 is added to make the whole 100.0 g, and stirring is continued. Finally, the mixture was degassed under reduced pressure to obtain a creamy second agent.

[Effect] Strong curly hair (3.0 g, 2 g
0 cm) to make a hair bundle. After washing with a commercially available shampoo, rinsing well and drying with a towel, 3.0 g of the first agent was evenly applied with a comb and thoroughly spread, and the hair was straightened and allowed to stand at 40 ° C. for 15 minutes while heating. . About 4
2. Wash with water for 3 minutes under running water at 0 ° C, dry with a towel,
Apply 0 g evenly while spreading well with a comb, straighten hair, let stand at room temperature (24 ° C, 65% RH) for 5 minutes, wash well under running water of about 40 ° C, and dry with towel After that, it was suspended in the room and air-dried. It was confirmed that the curly hair was straight straight hair, very smooth and flexible in both dry and wet conditions, and the gloss was improved.

[0062]

According to the present invention, a permanent wave having a significantly improved feel such as permanent wave, smoothness of hair in a wet and dry state after straightening treatment, and moistness in a dry state. A wave or curly straightening composition can be provided.

 ──────────────────────────────────────────────────続 き Continuing on the front page (72) Inventor Emiko Kawata 1050 Nippa-cho, Kohoku-ku, Yokohama-shi, Kanagawa F-term in Shiseido Daiichi Research Center Co., Ltd. 4C083 AB032 AB082 AB282 AB312 AB332 AB352 AB412 AC061 AC071 AC182 AC482 AC532 AC542 AC582 AC642 AC682 AC772 AC782 AC792 AD091 AD092 AD132 AD151 AD161 AD162 BB05 BB33 CC34 DD06 EE06 EE25

Claims (5)

[Claims] 1. A first agent containing (A) a reducing agent and (B) a copolymer of dimethyldiallylammonium chloride and acrylic acid, and (C) an oxidizing agent and (D) an anionic surfactant. A permanent wave or curly straightening composition, characterized in that it comprises a second agent. 2. The permanent waving or curly straightening composition according to claim 1, wherein the second agent further comprises (E) an anionic polymer. 3. The method according to claim 1, wherein the first agent further comprises (F) an amino-modified silicone polymer, a glycol-modified silicone polymer, and a silicone oil.
Or the composition for correcting permanent wave or curly hair according to item 2. 4. The permanent waving or curly straightening composition according to claim 1, wherein the second agent further comprises (G) a higher alcohol. 5. The method according to claim 4, wherein the higher alcohol (G) is one or more higher alcohols selected from the group consisting of myristyl alcohol, cetyl alcohol, stearyl alcohol and behenyl alcohol. A permanent wave or curly straightening composition.