CN101280471A - Fibre containing superfine calamine particle - Google Patents
Fibre containing superfine calamine particle Download PDFInfo
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- CN101280471A CN101280471A CNA2008100365081A CN200810036508A CN101280471A CN 101280471 A CN101280471 A CN 101280471A CN A2008100365081 A CNA2008100365081 A CN A2008100365081A CN 200810036508 A CN200810036508 A CN 200810036508A CN 101280471 A CN101280471 A CN 101280471A
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Abstract
The invention discloses a fiber comprising the ultra-fine calamine particles, which belongs to a functional fiber. Under a certain conditions, the calamine is processed into an ultra-fine product with the particle diameter of 1.0 to 0.1um, which is then infiltrated into the fiber. Therefore, a kind of fiber with health care function is produced, wherein the fiber includes natural and synthetic fibers of two main categories.
Description
Technical field
The invention belongs to a kind of functional fiber and preparation method thereof, be specifically related to a kind of functional fiber and preparation method who contains superfine calamine particle.
Background technology
Well-known calamine is that a kind of common Chinese medicine (sees Chinese medicine voluminous dictionary 1986 the 1st edition for details; the 1450th page of calamine bar record); originally be the ore of carbonate mineral, smithsonite; its Main Ingredients and Appearance is a zinc carbonate; the Powdered zinc oxide in calcining back; because it has anticorrosion, convergence, protective effect to the wound of skin, so medically Chang Zuowei treats dermopathic medicinal material and is used for preventing and treating skin disease and accidental skin wound.
Fiber mainly comprises natural fabric and synthetic fiber two big classes.Wherein natural fabric comprises the string with cotton representative, is the animal fiber etc. of representative with the cashmere; The general name of the synthetic fiber chemical fibre that to be classes made by synthetic macromolecular compound is (referring to chemical dictionary, the Shanghai Lexicographic Publishing House, in September, 1989 version-P322 " synthetic fibre strip "), mainly comprise: terylene (polyester fiber), polyamide fibre (polyamide fiber), acrylic fibers (polyacrylonitrile fibre), polyvinyl (vinylon), polypropylene fibre (polypropylene fibre) and polyvinyl chloride fibre (polyvinyl chloride fibre), and the soybean fiber of semi-synthetic character etc.
In addition, along with the progress and the development of science and technology of society, occur the functional fiber of a class in recent years, as contained the fiber of bamboo charcoal, contained the fiber of tourmaline (Tourmaline) etc.
As everyone knows; the largest organ of human body---skin; have many special functions, as have defencive function, sensory function, regulate body temperature, excretory function, absorption function, metabolic function, immunologic function, Gu this protection skin health also more and more causes people's attention.Thereby branch of industry and scientific worker abide by the development in science and technology of preventiveing treatment of disease very naturally and see diversion to the environment aspect of creating the protection skin health, optimizes people's quality of life, constantly carries out this piece of writing " surface " article of protection skin health.
Summary of the invention
The object of the present invention is to provide a kind of fiber that contains superfine calamine particle, because this fibrid has certain anticorrosion, anti-inflammatory properties to human body skin, so it also is a kind of functional fiber.After it is further processed into dress ornament, can optimize people's living environment, help the rehabilitation and the health care of dermatosis patient.The cotton fiber that contains superfine calamine particle in addition can also be directly as amenities, and it not only carries out anti-inflammatory and anticorrosion for the skin of trauma patient, but also for skin metabolism provides necessary zinc element, thereby healing acceleration.
Design of the present invention is such:
Select the raw material of Chinese medicine calamine (calamine after the calcining is a powder) as fibre modification, the peculiar function that has calamine through the fiber of modification, need calamine is carried out super-fine processing and surface treatment for this reason, calamine " is combined " well with fiber, form a kind of fiber that contains calamine ultrafine dust (nano_scale particle).
According to above-mentioned design, the present invention is achieved in that
At first calamine is carried out super-fine processing and surface treatment:
Experiment finds that calcining back its particle diameter of calamine powder is usually about 45 microns, when it is crushed to several microns, the calamine of this small particle has very strong agglomeration, calamine just is difficult to further pulverize in case reunite, so when super-fine processing, must be handled (or claiming surface modification) by surfactant, prevent the appearance of this agglomeration, make calamine by super-fine processing to 1.0～0.1 microns of particle diameters, and be dispersed in aqueous phase, form a kind of stable slurry.
Specific process is described below:
With commercially available particle diameter is that the calamine of 45 μ m places ball mill, press earlier 0.5～1.0% of calamine weight ratio and add surfactant, add entry again and be mixed with the mixture that solid content is 10～35% (wt), then the ball of making by aluminium oxide (or corundum) (sphere diameter 0.5～3.0mm) ball milling 24～48 hours; Taking-up is placed on along falling carries out hierarchical processing in the formula centrifugal classifying, with below standard component, promptly draw the outer ring of calamine particle from grader of particle diameter＞1 μ m, returns and proceeds ball milling processing in the ball mill; Component up to standard, promptly the calamine slurry of particle diameter＜1 μ m is drawn from the grader center, as intermediate products for next step use.Wherein said surfactant is to be a cationoid type surfactant of representative with the Si ion, or is a kind of among the class neutral surface active agent of representative with Si and Al ion, or their mixture.The maximum yield of the qualified products of classification gained is 60% (wt) of inventory (in calamine weight, together following).Experiment shows: the consumption of surfactant what, the yield of component up to standard is had bigger influence, be 0.2% o'clock as dosage of surfactant, under with same ball milling condition, the yield of the calamine that it is up to standard only is 20% (wt); When dosage of surfactant is 0.5% (wt), same ball milling 48 hours, the yield of calamine up to standard can reach 60% (wt), the visible surface activating agent is to the super-fine processing of calamine particle and be dispersed with bigger influence, if not having enough surfactants helps disperse, even the calamine particle that has been broken also can be agglomerated into bigger " particle " voluntarily, influence the yield of its certified products; When dosage of surfactant reached 1.0～1.5%, the dispersion thing can be more stable, but yield is constant substantially, so the consumption of surfactant suits with 0.5～1.0% (wt).
The length of ball milling time also has very big influence to the yield of product; When the ball milling time is 24 hours, even dosage of surfactant reaches 1.0%, its calamine product yield up to standard also only is about 30%.
As fully visible: the consumption of surfactant is 0.5～1.0%, the ball milling time be 48 hours be a kind of both economical suitable selection.If produce sector is ready to select the short ball milling time, as 24 hours, be to produce qualified slurry, but because below standard component proportion is bigger, more by the calamine material that returns reprocessing after the hierarchical processing, need expend more non-cutting time, all in all, economically may not be worthwhile.Secondly, with the calamine slurry of above-mentioned gained, with the active water dilution, making the content of calamine in the slurry after the dilution is 2～3% (wt), and it can be used as a kind of stable slurry for next step use (can be used as a kind of intermediate products supply the market).
Just contain the fiber preparation method of calamine ultrafine dust below, be described below respectively:
(1) contains the natural fabric of calamine ultrafine dust
Taking cotton fiber is weighed, and (other natural fabric also together in the back, is representative with cotton fiber as natural fabric for describing easy), slurry with above-mentioned calamine ultrafine dust, spray is gone in the cotton fiber, its spray flux control calamine content is 0.5～1.0% (wt%, with the cotton fiber is the percentage by weight of benchmark) for spending, sprayed back balance two hours, utilize the high penetrability of calamine ultrafine dust and active water, calamine is implanted in the micropore of fibr tissue, form a kind of metastable fiber that contains the calamine ultrafine dust, and then oven dry or dry, thereby a kind of natural fibre product of calamine ultrafine dust obtained.
Wherein said active water means " micromolecule " water of degree of association≤6.As everyone knows: the water that we are daily because the pollution of environment, its degree of association is all very high usually, usually reaches 46, it be a kind of " the inertia water of macoradical ", its penetrability and detergency all are very poor.Said active water among the present invention.Tie up in the experiment with daily water consumption by tourmaline purifier or popular ozone purification device activate and remove anhydrate in the pollutant of trace, obtain the water of a kind of degree of association less than 6 little group, we claim that it is an active water.Another of active water is characterized as, wherein PH is about 7.2, the high-quality water that occurring in nature exists, its degree of association is also less than 6, as NongFuShanQuan water be exactly in one degree of association less than the water of 6 little group, its pH value is about 7.2, so be about 7.2 to pure water such as its pH value, can think that it is exactly the active water of little group.
In addition, the preparation method who contains the natural fabric of calamine ultrafine dust also comprises the thing that natural fabric is processed into gauze, it is immersed in the slurry of ultrafine dust of above-mentioned calamine, and balance 4 hours, dry or dry after taking out then and get final product (it can be used as hospital gauze or sanitary underwear articles for use).The natural animal fiber that with the cashmere is representative in addition can make the fiber product that contains the calamine ultrafine dust equally as stated above.
(2) contain the synthetic fiber of calamine ultrafine dust
The synthetic fiber that contain the calamine ultrafine dust except comprising the synthetic fiber series products, also comprise the synthetic fiber master batch (as a kind of intermediate products, hereinafter to be referred as the calamine master batch) that contains the calamine ultrafine dust
(1) contains the preparation and the application thereof of the synthetic fiber master batch of calamine ultrafine dust
The calamine ultrafine dust slurry (referring to not use active water-reducible original slurry) of above-mentioned gained is dried, make calamine ultrafine dust powder product, it (is comprised terylene, polypropylene fibre or the section of other synthetic fiber in 10～35% (wt) ratios and synthetic fiber section, be whole fibre sections listed in the background technology) mix, then by conventional operations such as mixing, extrusion processes, make the synthetic fiber master batch that contains the calamine ultrafine dust, be called for short " calamine master batch ", it is as a kind of synthetic fiber processing intermediate products, supply the market.
When " calamine master batch " when using as intermediate products, system with above-mentioned " calamine master batch " again with synthetic fiber material section mixing ingredient, technology is made the synthetic fiber that a class contains the calamine ultrafine dust in wire drawing workshop section routinely then, comprise fine count fiber (≤1.0～1.5 dawn), middle dawn fiber (＞1.5 dawn), three-dimensional mesopore fiber and five holes and the seven apertures in the human head fiber of making terylene or polypropylene fibre etc., wherein the consumption of " calamine master batch " with the content of calamine ultrafine dust in the controlling fiber at 0.5～1.0% degree of being.
(2) contain the synthetic fiber preparation of calamine ultrafine dust
Except with " calamine master batch " as intermediate products, and then be processed into outside the synthetic fiber products, a lot of occasions are that calamine ultrafine dust slurry is directly joined in the former slurry of synthetic fiber, comprise common viscose glue, the former slurry of one class synthetic fiber such as acrylic fibers, and the former slurry made of semi-synthetic character soybean protein, the content of calamine is 0.5～1.0% (wt) in the control slurry, after fully being mixed, (can disperse) by auxiliary agent dispersed with stirring or sand mill, method is routinely made the synthetic fiber products that a class contains the calamine ultrafine dust in the wire drawing workshop section of chemical fibre factory then, be called for short by " calamine synthetic fiber ", become various goods for the dress ornament industrial processes, to satisfy market demand with health care.
Above-mentioned said synthetic fiber, except comprising polyester fiber (being terylene), polypropylene fibre (being polypropylene fibre), also comprise polyamide fiber (polyamide fibre), polyacrylonitrile fibre (acrylic fibers), vinylon (polyvinyl) and polyvinyl chloride fibre (polyvinyl chloride fibre), and the soybean fiber of semi-synthetic character.In addition, can also join together with the functional material of " bamboo charcoal ", " tourmaline " and so on and make a class multifunctional fibre product in the above-mentioned synthetic fiber, thereby make human living environment more rich and varied.
The specific embodiment
Further illustrate content of the present invention below in conjunction with embodiment, but these embodiment do not limit protection scope of the present invention.
Embodiment 1
The preparation of calamine ultrafine dust (particle diameter is 1.0～0.1 μ m) product
With commercially available particle diameter is 45 μ m calamines, 250 grams, place ball mill, add 2.5 gram surfactants (or claiming dispersant) and 500 milliliters of (being equivalent to solid content is 33.4%) water again, (sphere diameter is 0.5～3.0mm) ball milling 48 hours to the ball of making by aluminium oxide or corundum, obtain the calamine pasty material, taking-up is placed in the high speed centrifugation settling classifier, carry out hierarchical processing, component wherein up to standard (being the calamine slurry of particle diameter≤1 μ m) concentrates on the middle part of grader, deposit in the groove after drawing, below standard coarse granule calamine (pulp components of particle diameter＞1 μ m) returns after drawing and continues processing in the ball mill with the form concentrator outside of slurry.Above-mentioned said component up to standard can directly be used for next step processing with the form of slurry, but also drying, packing back as the powder product supply the market.
Said surfactant (or dispersant) for a kind of be the cationic surface active agent of representative with the Si ion, or a kind of be a kind of among the neutral surface active agent of representative with Si and Al ion, or their mixture, concrete because next step uses the difference of object and difference, branch of industry can select voluntarily according to own actual conditions.
Above-mentioned said its yield of component up to standard is 60% (wt), the calamine weight when testing to drop into.
Embodiment 2
Contain the preparation of the natural fabric of calamine ultrafine dust
At first the calamine slurry up to standard (particle diameter is 0.1～1.0 μ m) with embodiment 1 gained dilutes with active water, the content (concentration expressed in percentage by weight) of control calamine is 2～3% (wt), spray goes into to be weighed as in 1000 cotton fibers that restrain (is the natural fabric of representative with the cotton fiber) then, its spray flux is 0.5～1.0% (with cotton fiber weight) to contain calamine content in the control cotton fiber, and continued balance 2 hours, the calamine ultrafine dust is infiltrated with active water or implant in the tissue of cotton fiber, dry or dry cotton fiber (as the representative of the natural fabric) product that can obtain containing the calamine ultrafine dust at last.Experimental results show that:
Though be prepared into the natural fabric that contains the calamine ultrafine dust in the implantation mode, its calamine particle only is adsorbed on the fibr tissue, certain meeting desorption (when particularly washing) in use thereafter, but this feature, when it makes health cotton balls cleaning wound, can discharge zinc oxide, the effect of performance cleaning wound, anti-inflammatory purification and skin nutrition.
Embodiment 3
Contain the preparation of the synthetic fiber master batch (being called for short " calamine master batch ") of calamine ultrafine dust
The calamine superfine powder product of embodiment 1 gained is added in the synthetic fiber section of 2Kg, the addition of calamine can be chosen in 10～35% (wt) scope, a kind of in terylene, polypropylene fibre or other fibre section of said synthetic fiber section, place small-sized laboratory fully to mediate half an hour down in 160 ℃ with kneader, and then place the screw rod machine to become to contain the synthetic fiber master batch of calamine particle in 260 ℃ of following extruder grains, be called for short " calamine master batch ", can be used as the intermediate products supply the market.
Embodiment 4
A kind of preparation that contains the synthetic fiber (or abbreviation " calamine fiber ") of calamine ultrafine dust
" the calamine master batch " of embodiment 3 gained mixed according to a certain percentage with corresponding synthetic fiber section, wherein said synthetic fiber section comprises terylene, polypropylene fibre or the section of other synthetic fiber, said " certain proportion " means with corresponding synthetic fiber material by the gross weight timing, the content of control calamine is 0.5～1.0% (wt), make fiber product by the conventional drawing process of chemical fibre factory then after mixture fully mediated, as be processed into the thin dawn (≤1.0～1.5 dawn), the middle dawn (more than 1.5 dawn), three-dimensional mesopore fiber, functional fiber products such as five holes or seven apertures in the human head, as processing raw material of dress ornament industry, supply the market.
Embodiment 5
A kind of powder product of the calamine ultrafine dust with embodiment 1 gained directly adds the method that is prepared into fiber product in the former slurry of synthetic fiber.
The calamine superfine powder product of embodiment 1 gained is added directly in the synthetic fiber material slurries, comprise viscose glue, synthesising fibre raw slurry or other synthetic or narrow and become second nature raw slurries such as acrylic fibers, after conventional dispersing technology processing such as stirring, then the wire drawing workshop section of chemical fibre factory routinely processes become a class to have the functional fiber product of calamine characteristic, raw material as dress ornament industry, supply the market, wherein the addition of superfine calamine powder product should be controlled in 0.5～1.0% (wt) scope (in contained synthetic fiber material in the slurries); Said functional fiber product except referring to be processed into the embodiment 4 said products, can also be processed into fine denier filament, thereby further satisfy dress ornament industry to the requirement on the material choice.
In a word, as long as after having solved the technological difficulties of calamine ultra-fine grinding technically, just can be easily with calamine ultra-fine grain product (comprising slurry and powder), penetrate in the fiber-like raw material, make a class and have health care fiber product (or claiming the functional fiber product), be reprocessed into various functional article, improve and optimize people's living environment.
Claims (5)
1. fiber that contains the calamine ultrafine dust, it is characterized in that: the superfine product that at first calamine is processed into particle diameter 1.0～0.1 μ m, then with in before-mentioned products implantation or the infiltrated fiber, the content of the calamine in the controlling fiber (in the fiber net weight) is 0.5～1.0%, make the functional fiber that a class has the calamine characteristic, wherein said fiber comprises natural fabric and synthetic fiber two big classes.
2. fiber as claimed in claim 1 is characterized in that: wherein said natural fabric comprises with the cotton to be the natural plant fibre of representative and to be the natural animal fiber of representative with the cashmere.
3. fiber as claimed in claim 1, it is characterized in that: wherein said synthetic fiber comprise polyester fiber, polyamide fiber, polyacrylonitrile fibre, vinylon, polypropylene fibre and polyvinyl chloride fibre, and the soybean fiber of semi-synthetic character.
4. fiber as claimed in claim 1 is characterized in that: wherein said calamine superfine product comprises that the calamine particle diameter is that 1.0～0.1 μ m solid contents are that the slurry and the calamine particle diameter of 2～3% (wt) is the powder product of 1.0～0.1 μ m.
5. as claim 1 or 4 described fibers, it is characterized in that: wherein said calamine superfine product, for a kind of be that raw material places ball mill with the Chinese medicine calamine, add surfactant and water, be made into the system that solid content is 10～35% (wt), a kind of particle diameter of 24～48 hours gained of ball milling is the slurry of 1.0～0.1 μ m again, further to be mixed with solid content then be the slurry of 2～3% (wt) or be dried into powder product, wherein said surfactant is to be a cationoid type surfactant of representative with the Si ion, or with Si and Al ion a kind of among the class neutral surface active agent of representative, or their mixture, its consumption is 0.5～1.0% (wt) of calamine.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2008100365081A CN101280471B (en) | 2008-04-23 | 2008-04-23 | Fibre containing superfine calamine particle |
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| CN2008100365081A CN101280471B (en) | 2008-04-23 | 2008-04-23 | Fibre containing superfine calamine particle |
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| CN101280471A true CN101280471A (en) | 2008-10-08 |
| CN101280471B CN101280471B (en) | 2011-09-28 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101851803A (en) * | 2010-05-28 | 2010-10-06 | 新乡化纤股份有限公司 | Health-care function viscose fiber and preparation method thereof |
| CN103355749A (en) * | 2013-08-06 | 2013-10-23 | 太仓市珠江线带厂 | Cold-proof heat-preservation fabric |
| CN107361413A (en) * | 2017-09-05 | 2017-11-21 | 句容躬行创客管理咨询有限公司 | One kind adult's underwear temperature indicating colour development material |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1302900C (en) * | 2003-08-25 | 2007-03-07 | 华东理工大学 | Processing method of bamboo carbon ultrafine powder and its application in synthetic fiber |
| CN100348790C (en) * | 2005-12-26 | 2007-11-14 | 天津市赛远保健品有限公司 | Calamine functional fiber and manufacturing method thereof |
| CN100507100C (en) * | 2006-06-29 | 2009-07-01 | 福建众和股份有限公司 | Calamine viscose fiber and preparation method and application thereof |
| CN101158115A (en) * | 2007-11-08 | 2008-04-09 | 天津市赛远保健品有限公司 | Method for manufacturing multifunctional comfortable textile face fabric |
-
2008
- 2008-04-23 CN CN2008100365081A patent/CN101280471B/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101851803A (en) * | 2010-05-28 | 2010-10-06 | 新乡化纤股份有限公司 | Health-care function viscose fiber and preparation method thereof |
| CN101851803B (en) * | 2010-05-28 | 2012-08-08 | 新乡化纤股份有限公司 | Health-care function viscose fiber and preparation method thereof |
| CN103355749A (en) * | 2013-08-06 | 2013-10-23 | 太仓市珠江线带厂 | Cold-proof heat-preservation fabric |
| CN107361413A (en) * | 2017-09-05 | 2017-11-21 | 句容躬行创客管理咨询有限公司 | One kind adult's underwear temperature indicating colour development material |
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| CN101280471B (en) | 2011-09-28 |
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Application publication date: 20081008 Assignee: Hualisuofei Science and Technology Co., Ltd., Shanghai Assignor: East China University of Science and Technology Contract record no.: 2013310000007 Denomination of invention: Fibre containing superfine calamine particle Granted publication date: 20110928 License type: Exclusive License Record date: 20130129 |
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