CN100469827C - Aeration running water composite and its preparation method - Google Patents
Aeration running water composite and its preparation method Download PDFInfo
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- CN100469827C CN100469827C CNB2007100572566A CN200710057256A CN100469827C CN 100469827 C CN100469827 C CN 100469827C CN B2007100572566 A CNB2007100572566 A CN B2007100572566A CN 200710057256 A CN200710057256 A CN 200710057256A CN 100469827 C CN100469827 C CN 100469827C
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Abstract
A composition for enriching O2, activating water, generating ultra-strong infrared ray, strong magnetic field and negative ions, and releasing trace elements is proportionally prepared from bioactive ceramics, sepiolite-family ore, and water glass as adhesive through proportional mixing, shaping and drying.
Description
Technical field
Technical scheme of the present invention relates to material for water treatment.Specifically, be a kind of aeration running water composite and preparation method thereof.
Background technology
Biological in process of growth, often need to depend on surrounding environment and constantly supply with its multiple life condition, sometimes also need the artificial various conditions of setting up, as soak seed, irrigate, spray insecticide, to fertilize, with radiation exposure etc. biological growth to be got faster and better, reaches the agricultural produce purpose.And these people are that the condition of setting up is still among continuous research and development.Recently, there is the expert tentatively to promote agriculture production, obtained unusual effect with the running water technology.Different fully with the mode of traditional chemical medicament, the running water technology is safe and reliable nuisanceless physics mode, to improving crop yield, quality, reduces the use of medicaments such as fertilizer and pesticide and various hormones, and alleviating agricultural pollution all has very positive meaning.
The technology such as magnetic field, far infrared rays, microwave that it is found that can change the association state of water molecules, reach the running water purpose.Can influence the physiologically active of organism again with such running water.Solvency power, seepage force, metabolism power, diffusive force, the emulsifying power of water after the activated processing in organism all strengthens, and can strengthen the metabolism of organism.On agricultural, activated water can be used for improving rate of emergence, promotes plant-growth, promotes growing of feeding animals.
The water activating device function that the initial first-generation is used for agriculture field is all more single.CN 2074534U discloses a kind of seed magnetization device, running water makes inner some activation of component of seed under the action of a magnetic field, thereby raising rate of emergence, strengthen germinating energy, promotion is grown, and premature ripening finally improves output, but there is shortcoming in it is function singleness, does not possess functions such as oxygenation antibiosis; CN 2570256Y discloses the biological device that encourages of a kind of nano ceramics, make it to become active-energy water by material radiating far infrared rayss such as silicon oxide, titanium oxide activation water molecules, but not explanation be used for activating cells, enhance metabolism, thereby improve the ability of crop disease-resistant, drought resisting, reach the concrete effect of increasing both production and income purpose, and function singleness.
S-generation water activating device product possesses two kinds of functions simultaneously, but also just simply compound.CN 1440656A discloses a kind of nano-antibacterial composite granule, form by magnesium oxide, silicon carbide, titanium oxide, aluminum oxide, silicon oxide, water glass, collection far infrared function and special antibacterial are one, its middle infrared (Mid-IR) emission wavelength reaches 2～18 μ m, normal direction whole radiation rate is greater than 83%, but do not mention the oxygenation function, adsorption function and useful ion transport function; CN 1616356A discloses a kind of oxygenation activated water treatment agent, form by magnesium oxide, silicon oxide, aluminum oxide, titanium oxide, titanium carbide, water glass, can reach the purpose of aeration running water, but it just utilizes metal oxide own radiation far infrared rays, macromolecular mass water broken be small-micelle water, the degree of breaking is not high, and the dissolved oxygen content in therefore can dissolved air is also lower; CN 1883269A discloses a kind of a kind of composite nano-catalyst antibiotic, radiation infrared function that has, the photocatalyst material of wherein being introduced decomposes objectionable impurities and the seed metabolic waste of eliminating in the water, reach antibiotic purpose, meanwhile produce far infrared rays and negative ion, water clusters is diminished, improve the water activity, be used for seed soaking, promote the seed growth of sprouting, but the not raising of its infrared emittance, and do not possess the oxygenation function.
Third generation water activating device product is a multifunctional type.CN 1392115A discloses a kind of multifunctinoal health ceramic material and preparation method thereof,, activated water antibiotic for having simultaneously, the superpower far infrared rays of radiation, produces multiple functions such as negative ion and stripping trace element, but not mentioned oxygenation function and adsorption function; CN 1636942A discloses a kind of diverse in function, collect antibiotic, radiation infrared, preserve moisture, the plant-growth comprehensive regulation micropore ceramic ball of multiple functions such as nutritive substance such as damping, slow-release nitrogen phosphorus potassium and trace element, but also not mentioned oxygenation function and adsorption function.
In a word, the function of above-mentioned water activating device is still complete inadequately, and performance is still not good enough.
Summary of the invention
Technical problem to be solved by this invention is: a kind of aeration running water composite and preparation method thereof is provided, producing with this running water composite in the process of activated water, because the superpower far infrared rays of this material energy radiation, generation high-intensity magnetic field, generation negative ion and stripping trace element, therefore processed water is had antibiotic, higher oxygenation function and adsorption function simultaneously, the performance of gained activated water is also more good.
The present invention solves this technical problem the technical scheme that is adopted: a kind of aeration running water composite, form by following weight percent prescription: bioactivation ceramic material 50～85%, sepiolite group mineral 5～30%, with sodium silicate binder 10～30%, each component sum is 100%, described bioactivation ceramic material is a tourmalinite 5～30% by weight percent, ferrite 10～30%, kaolin 10～20%, silicon oxide 5～20%, aluminum oxide 5～20%, calcium oxide 5～20%, Mierocrystalline cellulose 2～5%, polyacrylic acid 2～5%, Viscotrol C 2～5%, form with rare earth 1～5%, each component sum is 100%.
Above-mentioned a kind of aeration running water composite, its middle-weight rare earths are the mixtures of cerous nitrate or cerous nitrate and neodymium nitrate arbitrary proportion.
Above-mentioned a kind of aeration running water composite, wherein the sepiolite group mineral are meant one or more the arbitrary combination in sepiolite, polygorskite, the attapulgite.
A kind of preparation method of aeration running water composite, its technology is:
(1) batching: above-mentioned bioactivation ceramic material is milled to median size≤15 μ m, the sepiolite group mineral respectively through acid concentration be 5～15%, the solid-liquid mass ratio is that 1: 10, time are that 10 hours acid activation is handled and 100-250 ℃, 8 hours thermal activation treatment and be milled to median size≤10.7 μ m, water glass is made into is enough to make the moistening aqueous solution of above-mentioned dosage batch mixing, standby;
(2) batch mixing: earlier (1) is gone on foot bioactivation ceramic material and sepiolite group mineral uniform mixing in the composition of raw materials, and add the water glass of described composition of raw materials gross weight 10～20%, stirred 1～2 hour;
(3) moulding: the batch mixing that (2) step is made adopts mould slip casting to become the blank of needed shape;
(4) drying: just the blank of (3) one-step forming is dry under 80～95 ℃ temperature, makes product.
Among the preparation method of above-mentioned a kind of aeration running water composite, the shape that (3) one-step forming technology makes blank is spherical, sheet, bar-shaped or block.
The invention has the beneficial effects as follows:
Compared with prior art, producing with this running water composite in the process of activated water, because the superpower far infrared rays of this material energy radiation, generation high-intensity magnetic field, generation negative ion and stripping trace element, therefore processed water is had antibiotic, higher oxygenation function and adsorption function simultaneously, the performance of gained activated water is also more good.Its reason is as follows:
1) running water composite of the present invention has added the sepiolite component in the composition of raw materials again, utilize its natural nano pore passage structure, through certain activation treatment, make it have excellent adsorptivity and ion exchangeable, heavy metal ion in the water, radioactive substance, hydrocarbon polymer, ammonia, carbonic acid gas, sulfurous gas are adsorbed to fall, promote that again the water clusters clustering architecture is descending, transport simultaneously goes out the ion of useful plants growth;
2) appropriate design bioactivation ceramic material middle-weight rare earths, tourmalinite and ferritic component ratio, utilize tourmalinite to have emitting far-infrared function, rare earth has the performance of appraising at the current rate, the effect of synergism ferrimagnetism ripple, make that the far-infrared radiation rate of 5-8 μ m is higher than the commercial like product, emittance can be up to more than 0.90, reach as high as 0.97, the sub-cluster structure of large quantity of moisture is diminished, be far superior to the oxygenation function of the disclosed a kind of oxygenation activated water treatment agent of CN 1616356A, thereby increased oxygen in water, and improving antibacterial, concrete comparative result is seen embodiment 1 and accompanying drawing 5,6.
Handle the active water that obtains with running water composite of the present invention, can cause the physiological effect of the series of active of organism, can promote its metabolism, improve the body-internal-circulation system, make that its growth is full of leaves, body strong, the effect of plentiful, quality better, specifically relatively see embodiment 1 and accompanying drawing 7,8.
The preparation method's of aeration running water composite of the present invention characteristics are that the function ingredients grain composition is reasonable, the nano particle that optionally prepares a certain particle size range of feed composition, obtain easily purity height, good uniformity, chemical constitution precise control, respond well multi-functional running water material product, and it is simple to have the preparation method, cost is low, is suitable for the characteristics of industrial applications.
Description of drawings
The present invention is further described below in conjunction with drawings and Examples.
Fig. 1 is the scanning electron microscopy analysis photo figure before the scpiolitc activation treatment among the embodiment 1.
Fig. 2 is the scanning electron microscopy analysis photo figure after the scpiolitc activation treatment among the embodiment 1.
Fig. 3 is the scanning electron microscopy analysis photo figure of bioactivation ceramic material among the embodiment 1.
Fig. 4 is the scanning electron microscopy analysis photo figure of embodiment 1 obtained aeration running water composite.
Fig. 5 is the far-infrared radiation rate comparison diagram of embodiment 1 obtained aeration running water composite and commercially available water-activating material.
Fig. 6 is the dissolved oxygen content comparison diagram in the water of handling respectively with embodiment 1 obtained aeration running water composite and with commercially available water-activating material.
Fig. 7 is for influencing comparison diagram with embodiment 1 obtained aeration running water composite and the water of handling respectively with commercially available water-activating material to the junge Erbsen rate of emergence.
Fig. 8 is for influencing comparison diagram with embodiment 1 obtained aeration running water composite and the water of handling respectively with commercially available water-activating material to the broad bean rate of emergence.
Embodiment
Embodiment 1
Composition of raw materials 1: bioactivation ceramic material 50%, sepiolite 30%, sodium silicate binder 20%, wherein the bioactivation ceramic material is that tourmalinite 5～30%, ferrite 10～30%, kaolin 10～20%, silicon oxide 5～20%, aluminum oxide 5～20%, calcium oxide 5～20%, Mierocrystalline cellulose 2～5%, polyacrylic acid 2～5%, Viscotrol C 2～5% and cerous nitrate 1～5% are formed by weight percent, and each component sum is 100%.
The preparation method of aeration running water composite is as follows:
(1) batching: according to composition of raw materials 1, the bioactivation ceramic material is milled to median size 10.5 μ m, sepiolite respectively through acid concentration be 15%, the solid-liquid mass ratio is 1: 10, the time is that 10 hours acid activation is handled and 150 ℃, 8 hours thermal activation treatment and be milled to median size 5.5 μ m; Water glass is made into is enough to make the moistening aqueous solution of above-mentioned dosage batch mixing, standby, and ball mill adopts common industrial ball mill;
(2) batch mixing: earlier (1) is gone on foot bioactivation ceramic material and sepiolite uniform mixing in the composition of raw materials, and add the water glass of described composition of raw materials gross weight 20%, stirred 1 hour;
(3) moulding: the blank that the batch mixing that makes of (2) step is adopted mould slip casting glomeration, sheet, bar-shaped or block shape;
(4) drying: the blank of (3) one-step forming is dry under 80 ℃ temperature, make product.
Carry out observable scanning electron microscopy analysis photo figure with Philips XL30-TMP type scanning electronic microscope before the raw material scpiolitc activation treatment of Fig. 1 for embodiment 1; Fig. 2 carries out observable scanning electron microscopy analysis photo figure through after the activation treatment with Philips XL30-TMP type scanning electronic microscope for the raw material scpiolitc of embodiment 1.Comparing result finds that through after the activation treatment, the fiber of sepiolite and fibrous bundle just can shorten, and attenuates, and it is many that the quantity in duct obviously becomes.
The surface topography of raw material bioactivation ceramic material used among the embodiment 1 is observed with Philips XL30-TMP type scanning electronic microscope, obtained microstructural scanning electron microscopy analysis photo figure shown in Figure 3.Found that its powder granule is spherical in shape substantially, size does not wait from several microns to tens microns, and no agglomeration occurs between particle.Composite granule chemical constitution with its preparation is even, moulding process is good, and has excellent infrared radiation property and anti-microbial property.
Fig. 4 is the scanning electron microscopy analysis photo figure that observes embodiment 1 obtained aeration running water composite with Philips XL30-TMP type scanning electronic microscope, find out that thus gained running water composite product of the present invention is a grey, smooth surface, the quality densification.
Embodiment 1 obtained aeration running water composite is processed into the water activating device sample of Φ 101mm and thick 10mm, with best Φ 101mm that produces by Tianjin enterprise of commercially available effect and the water activating device sample of thick 10mm, the 5DX Fourier transformation infrared spectrometer of using America NI COLET company to produce respectively is at the infrared emittance of 100 ℃ of following working samples.Fig. 5 shows that after tested, water activating device sample of the present invention is 0.86 in 8～15 μ m far infrared band normal direction radiant ratios.Contrast as can be known, up to 0.91, and commercially available water activating device sample emittance mean value has only 0.82 to water activating device sample of the present invention at the far infrared transmissivity mean value of 5-8 μ m.This wave band has all comprised the 6-8 μ m far infrared band that mates fully with human body, the far infrared transmissivity of this explanation aeration running water composite of the present invention is than commercially available prod height, more responsive, handle the physiological effect that the running water obtain more helps causing the series of active of organism with its, the activated plant cytoactive, strengthen metabolism, improve immunologic function.
The aeration running water composite of making among the embodiment 1 is used to detect it to oxygen in water content influence situation, entrusts chemical engineering institute of University Of Tianjin to carry out dissolved oxygen test (report number 2006HW-BJ-0051).Fig. 6 shows, found that aeration running water composite of the present invention at different time dissolved oxygen content (among Fig. 6 shown in the curve a) apparently higher than the oxygen in water content of commercially available prod (among Fig. 6 shown in the curve b) and blank water sample (among Fig. 6 shown in the curve c), that is to say that water activating device of the present invention is to the oxygenation function.
The aeration running water composite of making among the embodiment 1 is used for activated water, and detecting gained influences situation to the activated water rate of emergence, entrusts Tianjin Cucumber Inst. to carry out the percentage of germination testing experiment.Fig. 7 and Fig. 8 show that junge Erbsen, the broad bean seed germination rate of handling the activated water processing that obtains with aeration running water composite of the present invention are improved significantly.
Composition of raw materials 2: bioactivation ceramic material 85%, attapulgite 5%, sodium silicate binder 10%, wherein the bioactivation ceramic material is that the mixture 1～5% of tourmalinite 5～30%, ferrite 10～30%, kaolin 10～20%, silicon oxide 5～20%, aluminum oxide 5～20%, calcium oxide 5～20%, Mierocrystalline cellulose 2～5%, polyacrylic acid 2～5%, Viscotrol C 2～5% and cerous nitrate and neodymium nitrate arbitrary proportion is formed by weight percent, and each component sum is 100%.
The preparation method of aeration running water composite is as follows:
(1) batching: according to composition of raw materials 1, the bioactivation ceramic material is milled to median size 7.5 μ m, sepiolite respectively through acid concentration be 10%, the solid-liquid mass ratio is 1: 10, the time is that 10 hours acid activation is handled and 100 ℃, 8 hours thermal activation treatment and be milled to median size 9.6 μ m; Water glass is made into is enough to make the moistening aqueous solution of above-mentioned dosage batch mixing, standby, and ball mill adopts common industrial ball mill;
(2) batch mixing: earlier will (1) go on foot bioactivation ceramic material and sepiolite uniform mixing in the composition of raw materials, and add the described content of described composition of raw materials the aqueous solution of water glass, stirred 1.5 hours;
(3) moulding: the blank that the batch mixing that makes of (2) step is adopted mould slip casting glomeration, sheet, bar-shaped or block shape;
(4) drying: the blank of (3) one-step forming is dry under 95 ℃ temperature, make product.
Embodiment 3
Composition of raw materials 1: bioactivation ceramic material 50%, polygorskite 30%, sodium silicate binder 20%, wherein the bioactivation ceramic material is that tourmalinite 5～30%, ferrite 10～30%, kaolin 10～20%, silicon oxide 5～20%, aluminum oxide 5～20%, calcium oxide 5～20%, Mierocrystalline cellulose 2～5%, polyacrylic acid 2～5%, Viscotrol C 2～5% and cerous nitrate 1～5% are formed by weight percent, and each component sum is 100%.
The preparation method of aeration running water composite is as follows:
(1) batching: according to composition of raw materials 1, the bioactivation ceramic material is milled to median size 1 μ m, sepiolite respectively through acid concentration be 5%, the solid-liquid mass ratio is 1: 10, the time is that 10 hours acid activation is handled and 250 ℃, 8 hours thermal activation treatment and be milled to median size 1 μ m; Water glass is made into is enough to make the moistening aqueous solution of above-mentioned dosage batch mixing, standby, and ball mill adopts common industrial ball mill;
(2) batch mixing: bioactivation ceramic material and sepiolite uniform mixing in earlier will (1) step composition of raw materials, and adding described content the aqueous solution of water glass, stirred 1 hour;
(3) moulding: the blank that the batch mixing that makes of (2) step is adopted mould slip casting glomeration, sheet, bar-shaped or block shape;
(4) drying: the blank of (3) one-step forming is dry under 85 ℃ temperature, make product.Embodiment 4
Composition of raw materials 4: the sepiolite/attapulgite 15% of bioactivation ceramic material 65%, arbitrary proportion, sodium silicate binder 20%, wherein the bioactivation ceramic material is that tourmalinite 5～30%, ferrite 10～30%, kaolin 10～20%, silicon oxide 5～20%, aluminum oxide 5～20%, calcium oxide 5～20%, Mierocrystalline cellulose 2～5%, polyacrylic acid 2～5%, Viscotrol C 2～5% and cerous nitrate 1～5% are formed by weight percent, and each component sum is 100%.The preparation method of aeration running water composite makes product with embodiment 1.
Composition of raw materials 5: the sepiolite/polygorskite 5% of bioactivation ceramic material 85%, arbitrary proportion, sodium silicate binder 10%, wherein the bioactivation ceramic material is that tourmalinite 5～30%, ferrite 10～30%, kaolin 10～20%, silicon oxide 5～20%, aluminum oxide 5～20%, calcium oxide 5～20%, Mierocrystalline cellulose 2～5%, polyacrylic acid 2～5%, Viscotrol C 2～5% and cerous nitrate 1～5% are formed by weight percent, and each component sum is 100%.
The preparation method of aeration running water composite makes product with embodiment 1.
Composition of raw materials 6: the sepiolite/attapulgite of bioactivation ceramic material 85%, arbitrary proportion/polygorskite 5%, sodium silicate binder 10%, wherein the bioactivation ceramic material is that tourmalinite 5～30%, ferrite 10～30%, kaolin 10～20%, silicon oxide 5～20%, aluminum oxide 5～20%, calcium oxide 5～20%, Mierocrystalline cellulose 2～5%, polyacrylic acid 2～5%, Viscotrol C 2～5% and cerous nitrate 1～5% are formed by weight percent, and each component sum is 100%.
The preparation method of aeration running water composite makes product with embodiment 1.
Claims (5)
1. aeration running water composite, it is characterized in that: form by following weight percent prescription: bioactivation ceramic material 50～85%, sepiolite group mineral 5～30%, with sodium silicate binder 10～30%, each component sum is 100%, described bioactivation ceramic material is a tourmalinite 5～30% by weight percent, ferrite 10～30%, kaolin 10～20%, silicon oxide 5～20%, aluminum oxide 5～20%, calcium oxide 5～20%, Mierocrystalline cellulose 2～5%, polyacrylic acid 2～5%, Viscotrol C 2～5%, form with rare earth 1～5%, each component sum is 100%.
2. according to the described a kind of aeration running water composite of claim 1, it is characterized in that: its middle-weight rare earths is the mixture of cerous nitrate or cerous nitrate and neodymium nitrate arbitrary proportion.
3. according to the described a kind of aeration running water composite of claim 1, it is characterized in that: wherein the sepiolite group mineral are meant one or more the arbitrary combination in sepiolite, polygorskite, the attapulgite.
4. the preparation method of the described a kind of aeration running water composite of claim 1, it is characterized in that: its technology is:
(1) batching: above-mentioned bioactivation ceramic material is milled to median size≤15 μ m, the sepiolite group mineral respectively through acid concentration be 5～15%, the solid-liquid mass ratio is that 1: 10, time are that 10 hours acid activation is handled and 100-250 ℃, 8 hours thermal activation treatment and be milled to median size≤10.7 μ m, water glass is made into is enough to make the moistening aqueous solution of above-mentioned dosage batch mixing, standby;
(2) batch mixing: earlier (1) is gone on foot bioactivation ceramic material and sepiolite group mineral uniform mixing in the composition of raw materials, and add the water glass of described composition of raw materials gross weight 10～20%, stirred 1～2 hour;
(3) moulding: the batch mixing that (2) step is made adopts mould slip casting to become the blank of needed shape;
(4) drying: just the blank of (3) one-step forming is dry under 80～95 ℃ temperature, makes product.
5. among the preparation method according to the described a kind of aeration running water composite of claim 4, it is characterized in that: the shape that moulding process makes blank is spherical, sheet, bar-shaped or block.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101693626B (en) * | 2009-10-09 | 2012-01-04 | 河北工业大学 | Bone china and preparation method thereof |
| CN101857311B (en) * | 2010-05-13 | 2012-02-01 | 厦门利得新环保科技有限公司 | Multifunctional filter material for circulating water treatment and preparation method thereof |
| CN102557162A (en) * | 2012-01-14 | 2012-07-11 | 毕庆凡 | Biological activating water treatment agent |
| CN105597679B (en) * | 2016-02-15 | 2018-06-19 | 苏州中材非金属矿工业设计研究院有限公司 | A kind of method that high-performance sorbing material is prepared with low-quality staple fiber sepiolite |
| CN109928478A (en) * | 2019-03-19 | 2019-06-25 | 固安天天一泉环保科技有限公司 | A kind of water purification PH adjusts filtrate and preparation method thereof |
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