CN100507100C - Calamine viscose fiber and preparation method and application thereof - Google Patents
Calamine viscose fiber and preparation method and application thereof Download PDFInfo
- Publication number
- CN100507100C CN100507100C CNB2006100363443A CN200610036344A CN100507100C CN 100507100 C CN100507100 C CN 100507100C CN B2006100363443 A CNB2006100363443 A CN B2006100363443A CN 200610036344 A CN200610036344 A CN 200610036344A CN 100507100 C CN100507100 C CN 100507100C
- Authority
- CN
- China
- Prior art keywords
- calamine
- viscose
- fiber
- spinning
- mother liquor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
- D01F2/10—Addition to the spinning solution or spinning bath of substances which exert their effect equally well in either
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
Abstract
The invention discloses a calamine cellulose viscose and its process for preparing and application, in which the said fiber contains 1%-6% calamine powder measuring by the gross dry group. The calamine cellulose viscose of this invention not only has the advantages including pure nature, degradability, flexibility and champion dyeing behavior of the cellulose viscose, but also is entitled medicinal and health function, and has multiple physiological activities, which is good for improving the cell vitality and can remove fog and red and can constrict moisture and tumefaction, and simultaneously has distinctive effects including resistance to ultraviolet rays, bacterial inhibition and skin maintenance.
Description
Technical field
The invention belongs to the textile industry field, relate to a kind of calamine viscose fiber, also relate to the preparation method and its usage of calamine viscose fiber.
Background technology
Viscose belongs to regenerated celulose fibre, and general molecular formula is (C
6H
10O
5) n, n is the degree of polymerization.It is to be raw material with native celluloses such as natural timber, reed, cotton linters, makes the soluble cellulose xanthate acid through operations such as alkalization, aging, yellows, is dissolved in sig water again to make viscose glue, makes through wet spinning.It is one of chemical fibre that drops into the earliest in the world suitability for industrialized production.Viscose divides two kinds on long filament and staple fibre.Viscose filament yarn claims artificial silk or viscose again; And viscose staple fibre has cotton type (claiming artificial cotton), wool type (title artificial wool) and medium-length fibre.Because the character of viscose approaches natural fabric, good hygroscopicity, moisture percentage meets the physiological requirement of human body skin most, have smooth nice and cool, ventilative, antistatic, dyeing characteristic such as gorgeous, dress is soft, comfortable, and spinnability is good, so, can carry out pure spinning, or with cotton, hair or various synthetic fiber blending, interweave, be used for all kinds of clothes and decorative textile product.And, after the fabric of viscose is discarded, can biodegradation, can not cause the influence of characteristic of concentration to environment.
Calamine has very high medicinal and health care and is worth, and the medicinal function of calamine is all on the books on multiple successive dynasties medicine ancient books and modern drug encyclopedia.Calamine is natural simply medicinal material, medication name: calamine, English name: luganshi, nature and flavor: sweet, flat.Return liver, the stomach warp.The calamine main component is zinc carbonate (ZnCO
3), aqueous carbonic acid zinc (ZnCO
32Zn (OH)
2H
2O), zinc oxide (ZnO).The calamine effect: detoxifcation makes eye bright, and removes the screen hygroscopic, and with controlling red eye, swell pain, order is given birth to screen film, belepharitis ciliaris eye; Hygroscopic is antipruritic, and regenerating tissue to heal wond is with controlling the wet sore of eczema, unhealing ulcer.The clinical treatment that can be used for multiple contact dermatitis-skin disorder, in particular for unhealing ulcer, pus is dripping, wet sore, treatment of conditions such as pruitus.
Although viscose and calamine differ from one another,, still unmanned with viscose and calamine combination up to now, make a kind of product have the advantage of two kinds of materials simultaneously.The inventor after understanding, grasping the characteristic of viscose and calamine, research through great efforts, the health care with viscose textiles and calamine combines finally, this case produces thus.
Summary of the invention
The object of the present invention is to provide a kind of calamine viscose fiber, make it except that the advantages such as dyeability of the pure natural with viscose, degradable, softness, excellence, also to give medicinal and health care function, improve material quality.
Another object of the present invention is to a kind of preparation method and application thereof of calamine viscose fiber.
In order to reach above-mentioned purpose, solution of the present invention is:
Calamine viscose fiber contain the calamine powder of 1%-6% with the total butt restatement of fiber in fiber, and the calamine powder is dispersed in the inside and the top layer of fiber.
Above-mentioned viscose is viscose filament yarn or viscose staple fibre.
Above-mentioned calamine powder is the micro-size particles of average grain diameter≤1 micron.
The preparation method of calamine viscose fiber is mixed with mother liquor with calamine, contains the consumption and the mixing of viscose blend of 1%-6% calamine powder in fiber butt gross weight, mixture filters, after the vacuum defoamation through fully stirring, through the long filament production line, the calamine viscose filament yarn that makes; Perhaps through the staple fibre production line, the calamine viscose staple fibre that makes.
The preparation method of calamine viscose fiber, calamine is mixed with mother liquor, contain the consumption of 1%-6% calamine powder and spinning viscose glue by the direct blend of syringe device before spinning in fiber butt gross weight,, promptly obtain the calamine viscose filament yarn then through the long filament production line; Perhaps through the staple fibre production line, the calamine viscose staple fibre that makes.
Above-mentioned calamine mother liquor prescription is: calamine 5%-15%, water 85%-95%.
The range of application of calamine viscose fiber is: but calamine viscose filament yarn direct spinning, or interweave with cotton, chemical fibre doubling twisting, staple fibre can spin with short fiber blendings such as cotton, acrylic fibers, terylene, is used for underwear, T-shirt, nightwear, shirt, skirt, bedding etc.
The present invention is owing to be dispersed in calamine powder particulate among the fiber, powder in the inside of fiber and top layer and fiber become one securely.Calamine powder compatibility, favorable dispersibility, wash resistant, fast light photograph, high temperature resistant, the dyeability of viscose and good spinnability.Make calamine viscose fiber by said method, have broad-spectrum antiseptic, antibiotic dauer effect.Staphylococcus aureus, Escherichia coli, Candida albicans etc. there is significant anti-(pressing down) bacterium effect.Health care and medical assistance effect are played in multiple contact dermatitis-skin disorder patient's treatment.
This calamine viscose fiber, be to add the functional form fiber, except that the advantages such as dyeability of the pure natural with viscose, degradable, softness, excellence, also give medicinal and health care function, have multiple physiologically active, help to strengthen cell viability, can play the effect of conditioning skin, body beautification health, and calamine viscose fiber also has significant uvioresistant performance, has improved material quality.
Experimental results show that: calamine viscose filament yarn quality of the present invention meets GB/T13758-92 Grade A standard; Calamine viscose staple fibre quality meets GB/T14463-93 Grade A standard.
The specific embodiment
Calamine viscose fiber has wide range of applications, and following example is not a limitation of the present invention.
Specific embodiment 1:
Preparation-ton content is 4% calamine viscose filament yarn, at first prepares the calamine mother liquor.
The preparation prescription of calamine mother liquor:
Calamine (average grain diameter≤1.0 μ m): 5%-15%, water: 85%-95%.
The mother liquor preparation method who contains calamine 10.0wt%: in the stainless steel still, add calamine 40Kg, add water 360Kg, stir, mixing, standby.
With above-mentioned mother liquor, with the blend continuously in the syringe before spinning of spinning viscose glue, the blend ratio is 1: 0.04 by the weight ratio that contains the calamine powder in the weight of α-Cell in the total weight of fiber (alpha cellulose) and the mother liquor, enters R535A spinning machine (or R535, R535A semi-continuous spinning machine and continuous spinning machine) simultaneously and carries out spinning.Spinning cake that falls behind the spinning moulding carries out desulfurization, washing, pickling, bleaching, washes, oils, dewaters, dries through compressing and washing (or drip washing) post processing again, becomes tube, promptly obtains desired above-mentioned calamine viscose filament yarn.
Specific embodiment 2:
Preparing one ton of content is 4% calamine viscose staple fibre, at first prepares the calamine mother liquor.
The preparation prescription of calamine mother liquor:
Calamine (≤1.0 μ m): 5%-15%, water 85%-95%.
The mother liquor preparation method who contains calamine 10.0wt%: in the stainless steel still, add calamine 40Kg, add water 360Kg, stir, mixing, standby.
With above-mentioned mother liquor, with mixing of viscose in the dissolving machine blend, the blend ratio is 1:0.04 by the weight ratio that contains the calamine powder in the weight of α-Cell in the total weight of fiber (alpha cellulose) and the mother liquor, blend is through stirring, filtration, vacuum defoamation, maturation enters the viscose staple fibre spinning machine and carries out spinning.Tow behind the spinning moulding passes through staple fibre post processing carrying out desulfurization, washing, pickling, bleaching again, washes, oils, cuts off, dries, and packing promptly obtains desired above-mentioned calamine viscose staple fibre.
Experimental results show that: the calamine viscose fiber of 4% calamine content, the uvioresistant effect is remarkable, compares with common viscose fiber, and Ultraviolet Protection Factor UPF can be enhanced about more than once.Bacteriostasis rate is not less than 90%, but effective to itching of skin.
Specific embodiment 3:
Preparing one ton of content is 2% calamine viscose filament yarn, at first prepares the calamine mother liquor.
The preparation prescription of calamine mother liquor:
Calamine (average grain diameter≤1.0 μ m): 5%-15%, water: 85%-95%.
The mother liquor preparation method who contains calamine 10.0wt%: in the stainless steel still, add calamine 20Kg, add water 180Kg, stir, mixing, standby.
With above-mentioned mother liquor, with the blend continuously in the syringe before spinning of spinning viscose glue, the blend ratio is 1:0.02 by the weight ratio that contains the calamine powder in the weight of α-Cell in the total weight of fiber (alpha cellulose) and the mother liquor, enters R535A spinning machine (or R535, R535A semi-continuous spinning machine and continuous spinning machine) simultaneously and carries out spinning.Spinning cake that falls behind the spinning moulding carries out desulfurization, washing, pickling, bleaching, washes, oils, dewaters, dries through compressing and washing (or drip washing) post processing again, becomes tube, promptly obtains desired above-mentioned calamine viscose filament yarn.
Specific embodiment 4:
Preparing one ton of content is 2% calamine viscose staple fibre, at first prepares the calamine mother liquor.
The preparation prescription of calamine mother liquor:
Calamine (≤1.0 μ m): 5%-15%, water 85%-95%.
The mother liquor preparation method who contains calamine 10.0wt%: in the stainless steel still, add calamine 20Kg, add water 180Kg, stir, mixing, standby.
With above-mentioned mother liquor, with mixing of viscose in the dissolving machine blend, the blend ratio is 1:0.02 by the weight ratio that contains the calamine powder in the weight of α-Cell in the total weight of fiber (alpha cellulose) and the mother liquor, blend is through stirring, filtration, vacuum defoamation, maturation enters the viscose staple fibre spinning machine and carries out spinning.Tow behind the spinning moulding passes through staple fibre post processing carrying out desulfurization, washing, pickling, bleaching again, washes, oils, cuts off, dries, and packing promptly obtains desired above-mentioned calamine viscose staple fibre.
Experimental results show that: the calamine viscose fiber of 2% calamine content, the uvioresistant effect is remarkable, compares with common viscose fiber, and Ultraviolet Protection Factor UPF can improve more than 0.6 times.Bacteriostasis rate is not less than 80%, but effective to itching of skin.
In a word, fiber of the present invention is soft, and close skin exquisiteness can play antibiotic, mildew-resistant, deodorization, conditioning skin, the effect of body beautification health.This invention combines the health care of calamine with taking textiles, have vast potential for future development.
Claims (11)
1, calamine viscose fiber is characterized in that: contain 1%-6% calamine powder with the total butt restatement of fiber in fiber.
2, calamine viscose fiber as claimed in claim 1 is characterized in that: the calamine powder is scattered in the inside and the top layer of fiber.
3, calamine viscose fiber as claimed in claim 1 is characterized in that: viscose is viscose filament yarn or viscose staple fibre.
4, calamine viscose fiber as claimed in claim 1 is characterized in that: the calamine powder is the micro-size particles of average grain diameter≤1 micron.
5, the preparation method of calamine viscose fiber, it is characterized in that: calamine is mixed with mother liquor, contain the consumption and the mixing of viscose blend of 1%-6% calamine powder in fiber butt gross weight, mixture is through fully stirring, filter, after the vacuum defoamation,, make the calamine viscose filament yarn through the long filament production line.
6, the preparation method of calamine viscose fiber, it is characterized in that: calamine is mixed with mother liquor, contain the consumption and the mixing of viscose blend of 1%-6% calamine powder in fiber butt gross weight, mixture is through fully stirring, filter, after the vacuum defoamation,, make the calamine viscose staple fibre through the staple fibre production line.
7, the preparation method of calamine viscose fiber, it is characterized in that: calamine is mixed with mother liquor, contain the consumption of 1%-6% calamine powder and spinning viscose glue by the direct blend of syringe device before spinning in fiber butt gross weight, through the long filament production line, promptly obtain the calamine viscose filament yarn then.
8, the preparation method of calamine viscose fiber, it is characterized in that: calamine is mixed with mother liquor, contain the consumption of 1%-6% calamine powder and spinning viscose glue by the direct blend of syringe device before spinning in fiber butt gross weight, through the staple fibre production line, promptly obtain the calamine viscose staple fibre then.
9, as the preparation method of calamine viscose fiber as described in the claim 5 to 8 any, it is characterized in that: calamine mother liquor prescription is: calamine 5%-15%, water 85%-95%.
10, the calamine viscose filament yarn is used for direct spinning, or the application that interweaves with cotton, chemical fibre doubling twisting.
11, the calamine viscose staple fibre is used for the application with short fiber blending spinning.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006100363443A CN100507100C (en) | 2006-06-29 | 2006-06-29 | Calamine viscose fiber and preparation method and application thereof |
PCT/CN2007/002027 WO2008003243A1 (en) | 2006-06-29 | 2007-06-28 | Calamine viscose fiber, its process for preparing and application |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006100363443A CN100507100C (en) | 2006-06-29 | 2006-06-29 | Calamine viscose fiber and preparation method and application thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1876905A CN1876905A (en) | 2006-12-13 |
CN100507100C true CN100507100C (en) | 2009-07-01 |
Family
ID=37509455
Family Applications (1)
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CNB2006100363443A Expired - Fee Related CN100507100C (en) | 2006-06-29 | 2006-06-29 | Calamine viscose fiber and preparation method and application thereof |
Country Status (2)
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CN (1) | CN100507100C (en) |
WO (1) | WO2008003243A1 (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100507100C (en) * | 2006-06-29 | 2009-07-01 | 福建众和股份有限公司 | Calamine viscose fiber and preparation method and application thereof |
CN101280471B (en) * | 2008-04-23 | 2011-09-28 | 华东理工大学 | Fibre containing superfine calamine particle |
SG162687A1 (en) | 2008-12-24 | 2010-07-29 | Millipore Corp | Caustic stable chromatography ligands |
CN101851803B (en) * | 2010-05-28 | 2012-08-08 | 新乡化纤股份有限公司 | Health-care function viscose fiber and preparation method thereof |
CN101985781B (en) * | 2010-10-19 | 2012-03-28 | 山东海龙股份有限公司 | Preparation method of calamine cellulose fiber |
CN102383223B (en) * | 2011-09-22 | 2014-05-07 | 福建众和股份有限公司 | High-strength calamine seaweed fiber and preparation method and application thereof |
CN102828298A (en) * | 2012-08-20 | 2012-12-19 | 肖晖 | Hetian jade yarn and preparation method thereof |
CN116602820B (en) * | 2023-05-23 | 2023-10-13 | 江苏宝姿实业有限公司 | Soft and breathable adult nursing pad and preparation process thereof |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0465510A (en) * | 1990-07-02 | 1992-03-02 | Bio Giken:Kk | Production of antibacterial rayon material |
JP2579600B2 (en) * | 1994-08-22 | 1997-02-05 | 信秀 前田 | Method for producing rayon having antibacterial properties and deodorizing properties and having far-infrared radiation characteristics |
JP2876309B2 (en) * | 1995-10-09 | 1999-03-31 | 信秀 前田 | Method for producing rayon having antibacterial properties, deodorizing properties and insect repellent properties and having far-infrared radiation characteristics |
JP2909028B2 (en) * | 1995-11-27 | 1999-06-23 | 信秀 前田 | A method for producing a processed yarn in which a composite rayon having antibacterial properties, deodorizing properties and insect repellent properties, and far-infrared radiation properties, and mixed or twisted with a milk protein fiber are spun. |
JP2836020B2 (en) * | 1996-03-18 | 1998-12-14 | 信秀 前田 | Process for producing a processed yarn in which a composite rayon and silk fiber having anti-bacterial, deodorizing, mold-proof and insect-proof properties and far-infrared radiation properties are mixed or twisted and spun. |
CN1401831A (en) * | 2001-08-27 | 2003-03-12 | 武汉纳宝新技术有限责任公司 | Functional rayon staple comprising nanopowder material |
CN100348790C (en) * | 2005-12-26 | 2007-11-14 | 天津市赛远保健品有限公司 | Calamine functional fiber and manufacturing method thereof |
CN100507100C (en) * | 2006-06-29 | 2009-07-01 | 福建众和股份有限公司 | Calamine viscose fiber and preparation method and application thereof |
-
2006
- 2006-06-29 CN CNB2006100363443A patent/CN100507100C/en not_active Expired - Fee Related
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2007
- 2007-06-28 WO PCT/CN2007/002027 patent/WO2008003243A1/en active Application Filing
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WO2008003243A1 (en) | 2008-01-10 |
CN1876905A (en) | 2006-12-13 |
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