CN101263812A - Sterilization disinfectant and preparation - Google Patents
Sterilization disinfectant and preparation Download PDFInfo
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- CN101263812A CN101263812A CNA200810047477XA CN200810047477A CN101263812A CN 101263812 A CN101263812 A CN 101263812A CN A200810047477X A CNA200810047477X A CN A200810047477XA CN 200810047477 A CN200810047477 A CN 200810047477A CN 101263812 A CN101263812 A CN 101263812A
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- ozone
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- reaction
- oxygen
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- 238000002360 preparation method Methods 0.000 title claims abstract description 33
- 238000004659 sterilization and disinfection Methods 0.000 title claims description 19
- 239000000645 desinfectant Substances 0.000 title abstract description 11
- 230000001954 sterilising effect Effects 0.000 title description 7
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 51
- 238000006243 chemical reaction Methods 0.000 claims abstract description 25
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 16
- 239000003549 soybean oil Substances 0.000 claims abstract description 13
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 13
- 230000003647 oxidation Effects 0.000 claims abstract description 11
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 10
- 239000008158 vegetable oil Substances 0.000 claims abstract description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 33
- 229910052760 oxygen Inorganic materials 0.000 claims description 33
- 239000001301 oxygen Substances 0.000 claims description 33
- 239000003595 mist Substances 0.000 claims description 15
- 150000001735 carboxylic acids Chemical class 0.000 claims description 11
- 150000002148 esters Chemical class 0.000 claims description 11
- 238000001914 filtration Methods 0.000 claims description 8
- 230000008014 freezing Effects 0.000 claims description 8
- 238000007710 freezing Methods 0.000 claims description 8
- GHUXAYLZEGLXDA-UHFFFAOYSA-N 8-azido-5-ethyl-6-phenylphenanthridin-5-ium-3-amine;bromide Chemical compound [Br-].C12=CC(N=[N+]=[N-])=CC=C2C2=CC=C(N)C=C2[N+](CC)=C1C1=CC=CC=C1 GHUXAYLZEGLXDA-UHFFFAOYSA-N 0.000 claims description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 4
- 235000019483 Peanut oil Nutrition 0.000 claims description 4
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 4
- 239000000312 peanut oil Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- GYFUWKFMILQVDR-UHFFFAOYSA-N butyl 2-methylprop-2-enoate;ethene Chemical compound C=C.CCCCOC(=O)C(C)=C GYFUWKFMILQVDR-UHFFFAOYSA-N 0.000 claims description 3
- 235000012343 cottonseed oil Nutrition 0.000 claims description 3
- 239000002385 cottonseed oil Substances 0.000 claims description 3
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 claims description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 3
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 3
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 3
- 235000019486 Sunflower oil Nutrition 0.000 claims description 2
- 239000002600 sunflower oil Substances 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 201000010099 disease Diseases 0.000 abstract description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 3
- 230000036541 health Effects 0.000 abstract description 3
- 230000000855 fungicidal effect Effects 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 230000002421 anti-septic effect Effects 0.000 abstract 5
- 210000004877 mucosa Anatomy 0.000 abstract 1
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- 235000013311 vegetables Nutrition 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- 230000002411 adverse Effects 0.000 description 6
- 239000004006 olive oil Substances 0.000 description 6
- 235000008390 olive oil Nutrition 0.000 description 6
- 238000006385 ozonation reaction Methods 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 241000700605 Viruses Species 0.000 description 4
- 239000003899 bactericide agent Substances 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 239000003242 anti bacterial agent Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- WURFKUQACINBSI-UHFFFAOYSA-M ozonide Chemical compound [O]O[O-] WURFKUQACINBSI-UHFFFAOYSA-M 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 244000052616 bacterial pathogen Species 0.000 description 2
- 239000012567 medical material Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 229940098465 tincture Drugs 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 206010016717 Fistula Diseases 0.000 description 1
- 206010052428 Wound Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000003890 fistula Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 150000002496 iodine Chemical class 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000002640 oxygen therapy Methods 0.000 description 1
- 230000002980 postoperative effect Effects 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicinal Preparation (AREA)
Abstract
The invention relates to an antiseptic disinfectant and the preparation method of the antiseptic disinfectant, belonging to the field of medical health, which is characterized in that, vegetable oil, unsaturated carboxylic and ozone are added to a reaction column for oxidation, and then the antiseptic disinfectant is prepared; wherein the addition amount of the vegetable oil is 2kg to 4kg; the addition amount of the unsaturated carboxylic is 10ml to 25ml; the flow rate of the ozone is 120m3/h to 1803/h. The antiseptic disinfectant and the preparation method of the antiseptic disinfectant have the advantages that, the material adopted by the invention is the frequently used vegetable soybean oil; the preparation method is simple and the cost is low; the invention has no toxicity and side effect; ozone has broad spectrum bactericidal effect and good antibacterial activity and fungicidal activity to various aerobic microbes and anaerobic microbes of skin and mucosa diseases.
Description
Technical field
The present invention relates to relate to medicine and hygiene fields, specifically a kind of disinfection sanitizer and preparation method thereof.
Background technology
Usually will use disinfection sanitizer in a large number in medical and health industry, existing disinfection sanitizer is generally alcohol and tincture of iodine series bactericidal agent.The alcohol and the tincture of iodine have bactericidal effect preferably, but it has resting period shortcoming short, that volatilize easily, therefore only is suitable as liquid fungicide, can not be used for medical material as bactericide.Publication number is CN1723778, open day be that the application for a patent for invention on January 25th, 2006 discloses a kind of silver-containing antibacterial material and its production and application, its is coated on the medical material after adopting silver oxide and chitin chelating.Because silver can combine with the DNA base in the pathogenic bacteria, duplicate thereby cause the dna structure sex change of germ to suppress it, reach the purpose of sterilization.Therefore it has the good advantage of bactericidal effect.But because heavy metal silver is harmful, it also has other useful cell of human body in killing pathogenic bacteria causes harm.Therefore the disinfectant of argentiferous or mercury is banned use of by the health organization of many countries.People are studying disinfectant ozoniferous always in recent years, carry out the sterilization safety non-toxic by ozone.Japan takes the photograph Nanjing University and learns the researcher recently in the basic research of ozonisation olive oil, prepares the ozonisation olive oil as disinfection sanitizer in order to olive oil, ozone.Be used for the postoperative difficult healing fistula of environment and medical field application and the treatment of wound, it is prepared as follows:
(1), in the cold house of hospital, by allowing ozone gas in olive oil, inject, obtain the ozonisation oil product of oneself.
(2), when olive oil mixes with ozone, produce a large amount of bubbles, bubble could disappear after 2 days, was able to the ozonisation finish after ozone is immobilized.
(3), the oxidation potential of ozone olive oil is stable continues seven months.
This invention has the good sterilization effect, and safety non-toxic, but should invent the storage time weak point, thereby has limited its scope of application.
Summary of the invention
The object of the invention is exactly the defective at existing disinfectant, and a kind of ozone sterilization disinfectant and preparation method thereof is provided, and it has the bactericidal action of wide spectrum, and the various aerobic and anaerobe of skin, membrane disease is all had good antibacterial, bactericidal activity.
Technical scheme of the present invention is achieved in that it is to be prepared from carrying out oxidation reaction in vegetable oil, esters of unsaturated carboxylic acids and the ozone adding reaction column.
Wherein the addition of vegetable oil is 2kg～4kg, and the esters of unsaturated carboxylic acids addition is 10ml～25ml, and the ozone flow velocity is 120m3/h～180m3/h.
Wherein the time of oxidation reaction is 2.5～4.5 hours, and pressure is 0.6Pa～0.7Pa, and reaction temperature is 20 ℃～30 ℃.
Wherein said vegetable oil is one or more in soybean oil, cottonseed oil, rape seed oil, sunflower oil or the peanut oil.
Wherein said esters of unsaturated carboxylic acids is ethyl acetoacetate, ethylene methacrylic acid butyl ester, ethylethylene acid butyl ester, EMA, butyl methacrylate or acrylic acid glyceride.
Optimized technical scheme of the present invention is soybean oil 4kg, and esters of unsaturated carboxylic acids 25ml, ozone flow velocity are with 180Nm3/h, and pressure is 0.7Pa; Oxidizing reaction temperature is 25 ℃, and oxidation reaction needs 4.5 hours;
Preparation method of the present invention follows these steps to carry out:
(1) oxygen preparation: the mist with oilless air compressor obtains, the mist filtration is obtained oxygen, after the freezing type drier dehumidifying, be input to the oxygen hold-up tank and preserve stand-by;
(2) ozone preparation: use the high-frequency electrical solution, oxygen is decomposed generate active free body ozone;
(3) vegetable oil is inserted in the reaction pillar, ozone flow velocity 120m3/h～180m3/h, with in the counter-current input reaction pillar, ozone flow velocity 120m3/h～180m3/h slowly adds esters of unsaturated carboxylic acids again, obtains the present invention through reaction with ozone.Pressure 0.6Pa～0.7Pa pressure when wherein reacting, temperature are at 20 ℃～30 ℃, and oxidation time is 2.5～4.5 hours.
Ozonide antibacterial agent of the present invention is to follow the Henry law: the dissolving of ozone in carrier oil is when temperature and ozone air pressure keep relative stability, and obtains the ozonide finish.When soybean oil mixes by ozone, in the carrier esters of unsaturated carboxylic acids, do not produce bubble, directly be able to the ozonisation finish.The oxidation potential of ozone soybean oil is stable to continue 2 years.Be that at present unique in the world ozonide that can make is preserved the longest disinfectant.
The present invention adopts raw material to be the plant soybean oil that people use always, and the preparation method is simple, cost is low.Esters of unsaturated carboxylic acids is medical intermediate, has no side effect.Ozone has the bactericidal action of wide spectrum, and the various aerobic and anaerobe of skin, membrane disease is all had good antibacterial, bactericidal activity.The present invention facts have proved to have good antibacterial action with organically combination of raw materials used effect, its role is to:
1) quick sterilization: can kill various bacteriums, virus, be a kind of oxidoreduction bactericide;
2) have no drug resistance: ozone is DNA and the RNA that it directly acts on bacterium and virus to the effect of bacterium and virus, and bacterium and virus are killed, and this is the outstanding advantage of ozone.
3) sterilization oxygen therapy: the product behind the ozone reaction is an oxygen, a kind of safe bactericide of non-secondary pollution;
Embodiment:
The invention will be further described below in conjunction with embodiment:
Embodiment 1
The preparation method is as follows:
1, oxygen preparation: the mist with no oily pneumatics obtains, the mist filtration is obtained oxygen, after the freezing type drier dehumidifying, be input to the oxygen hold-up tank and preserve stand-by;
2, ozone preparation: use 0.5Pa pressure, temperature prepares oxygen with the air source in the high-frequency electrical solution in the time of 20 ℃;
3, soybean oil 2kg inserts in the reaction pillar; Ozone adds with the 120m3/h flow velocity, in the adverse current input reaction pillar; Slowly add acrylic acid glyceride 15ml;
4, oxidation time is 2.5 hours;
5, obtaining the ozone oil concentration is 25mg/L the present invention, preserves ten months under the normality.
Embodiment 2
The preparation method is as follows:
1, oxygen preparation: the mist with no oily pneumatics obtains, the mist filtration is obtained oxygen, after the freezing type drier dehumidifying, be input to the oxygen hold-up tank and preserve stand-by;
2, ozone preparation: use 0.6Pa pressure, temperature prepares oxygen with the air source in the high-frequency electrical solution in the time of 23 ℃;
3, soybean oil 3kg inserts in the reaction pillar, and ozone adds with the 150m3/h flow velocity, in the adverse current input reaction pillar; Slowly add EMA 20ml;
4, oxidation time is 3.5 hours;
5, obtain the antibacterial agent of the present invention that the ozone oil concentration is 40mg/L, preserved 15 months under the normality.
Embodiment 3
Its preparation method is as follows:
1, oxygen preparation: the mist with pneumatics obtains, obtain oxygen after the filtration, after the freezing type drier dehumidifying, be input to the oxygen hold-up tank and preserve stand-by;
2, ozone preparation: at 25 ℃, in the high-frequency electrical solution, prepare oxygen with the air source with 0.7Pa pressure;
3, soybean oil 4kg inserts in the reaction pillar, and ozone adds with the 180m3/h flow velocity, in the adverse current input reaction pillar, slowly adds EMA 25ml;
4, oxidation time is 4.5 hours;
5, obtain the antibacterial agent of the present invention that the ozone oil concentration is 54mg/L, preserved 24 months under the normality.
Embodiment 4
The preparation method is as follows:
1, oxygen preparation: the mist with no oily pneumatics obtains, the mist filtration is obtained oxygen, after the freezing type drier dehumidifying, be input to the oxygen hold-up tank and preserve stand-by;
2, ozone preparation: use 0.5Pa pressure, temperature prepares oxygen with the air source in the high-frequency electrical solution in the time of 20 ℃;
3, insert in reaction column after soybean oil 2kg, cottonseed oil 2kg mix; Ozone adds with the 120m3/h flow velocity, in the adverse current input reaction pillar; Slowly add ethylethylene acid butyl ester 20ml;
4, oxidation time is 2.5 hours;
5, obtaining the ozone oil concentration is 25mg/L the present invention, preserves 20 months under the normality.
Embodiment 5
The preparation method is as follows:
1, oxygen preparation: the mist with no oily pneumatics obtains, the mist filtration is obtained oxygen, after the freezing type drier dehumidifying, be input to the oxygen hold-up tank and preserve stand-by;
2, ozone preparation: use 0.5Pa pressure, temperature prepares oxygen with the air source in the high-frequency electrical solution in the time of 20 ℃;
3, insert in reaction column after soybean oil 1kg, peanut oil 1kg, rape seed oil 1kg mix; Ozone adds with the 120m3/h flow velocity, in the adverse current input reaction pillar; Slowly add ethyl acetoacetate 25ml;
4, oxidation time is 4.5 hours;
5, obtaining the ozone oil concentration is 40mg/L the present invention, preserves 20 months under the normality.
Embodiment 6
The preparation method is as follows:
1, oxygen preparation: the mist with no oily pneumatics obtains, the mist filtration is obtained oxygen, after the freezing type drier dehumidifying, be input to the oxygen hold-up tank and preserve stand-by;
2, ozone preparation: use 0.5Pa pressure, temperature prepares oxygen with the air source in the high-frequency electrical solution in the time of 20 ℃;
3, insert in reaction column after soybean oil 1kg, peanut oil 1kg, rape seed oil 1kg mix; Ozone adds with the 120m3/h flow velocity, in the adverse current input reaction pillar; Slowly add ethylene methacrylic acid butyl ester 15ml;
4, oxidation time is 4.5 hours;
5, obtaining the ozone oil concentration is 40mg/L the present invention, preserves 20 months under the normality.
Claims (7)
1, a kind of disinfection sanitizer, it is to be prepared from carrying out oxidation reaction in vegetable oil, esters of unsaturated carboxylic acids and the ozone adding reaction column.
2, a kind of disinfection sanitizer according to claim 1, wherein the addition of vegetable oil is 2kg～4kg, and the esters of unsaturated carboxylic acids addition is 10ml～25ml, and the ozone flow velocity is 120m3/h～180m3/h.
3, a kind of disinfection sanitizer according to claim 1, wherein the time of oxidation reaction is 2.5～4.5 hours, and pressure is 0.6Pa～0.7Pa, and reaction temperature is 20 ℃～30 ℃.
4, a kind of disinfection sanitizer according to claim 1, wherein said vegetable oil is one or more in soybean oil, cottonseed oil, rape seed oil, sunflower oil or the peanut oil.
5, a kind of disinfection sanitizer according to claim 1, wherein said esters of unsaturated carboxylic acids are ethyl acetoacetate, ethylene methacrylic acid butyl ester, ethylethylene acid butyl ester, EMA, butyl methacrylate or acrylic acid glyceride.
6, a kind of preparation method of disinfection sanitizer, it follows these steps to carry out:
(1) oxygen preparation: the mist with oilless air compressor obtains, the mist filtration is obtained oxygen, after the freezing type drier dehumidifying, be input to the oxygen hold-up tank and preserve stand-by;
(2) ozone preparation: use the high-frequency electrical solution, oxygen is decomposed generate active free body ozone;
(3) vegetable oil is inserted in the reaction pillar, ozone flow velocity 120m3/h～180m3/h, with in the counter-current input reaction pillar, ozone flow velocity 120m3/h～180m3/h slowly adds esters of unsaturated carboxylic acids again, obtains the present invention through reaction with ozone.
7, according to the preparation method of a kind of disinfection sanitizer of claim 6, pressure 0.6Pa～0.7Pa pressure when wherein reacting, temperature is at 20 ℃～30 ℃, and oxidation time is 2.5～4.5 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810047477XA CN101263812B (en) | 2008-04-28 | 2008-04-28 | Sterilization disinfectant and preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810047477XA CN101263812B (en) | 2008-04-28 | 2008-04-28 | Sterilization disinfectant and preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101263812A true CN101263812A (en) | 2008-09-17 |
| CN101263812B CN101263812B (en) | 2010-10-20 |
Family
ID=39986699
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200810047477XA Expired - Fee Related CN101263812B (en) | 2008-04-28 | 2008-04-28 | Sterilization disinfectant and preparation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101263812B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102834012A (en) * | 2010-04-12 | 2012-12-19 | 狮王株式会社 | Disinfection aid for ozone disinfection and method for ozone disinfection |
| CN103262856A (en) * | 2013-05-22 | 2013-08-28 | 杨风广 | Plant disinsecting and sterilizing solution and special sprayer for preparing and spraying same |
| CN105920075A (en) * | 2016-06-02 | 2016-09-07 | 陈泽鑫 | Externally-used drug of ozone antibacterial agent |
| CN106881055A (en) * | 2017-04-10 | 2017-06-23 | 安徽嘉宝诺生物科技有限公司 | Ozone solidifies emulsifier unit and the sterilized agent and process for producing same of ozone solidification emulsification |
| CN110559189A (en) * | 2019-08-20 | 2019-12-13 | 安徽氧趣生物科技有限公司 | Preparation method of dimer and polymer ozone ointment |
| CN110663700A (en) * | 2019-09-12 | 2020-01-10 | 河北众成七星生物科技有限公司 | Ozone disinfectant and preparation method thereof |
-
2008
- 2008-04-28 CN CN200810047477XA patent/CN101263812B/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102834012A (en) * | 2010-04-12 | 2012-12-19 | 狮王株式会社 | Disinfection aid for ozone disinfection and method for ozone disinfection |
| CN102834012B (en) * | 2010-04-12 | 2015-03-25 | 狮王株式会社 | Disinfection aid for ozone disinfection and method for ozone disinfection |
| CN103262856A (en) * | 2013-05-22 | 2013-08-28 | 杨风广 | Plant disinsecting and sterilizing solution and special sprayer for preparing and spraying same |
| CN103262856B (en) * | 2013-05-22 | 2015-06-24 | 山东惠生现代农业有限公司 | Plant disinsecting and sterilizing solution and special sprayer for preparing and spraying same |
| CN105920075A (en) * | 2016-06-02 | 2016-09-07 | 陈泽鑫 | Externally-used drug of ozone antibacterial agent |
| CN106881055A (en) * | 2017-04-10 | 2017-06-23 | 安徽嘉宝诺生物科技有限公司 | Ozone solidifies emulsifier unit and the sterilized agent and process for producing same of ozone solidification emulsification |
| CN110559189A (en) * | 2019-08-20 | 2019-12-13 | 安徽氧趣生物科技有限公司 | Preparation method of dimer and polymer ozone ointment |
| CN110663700A (en) * | 2019-09-12 | 2020-01-10 | 河北众成七星生物科技有限公司 | Ozone disinfectant and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101263812B (en) | 2010-10-20 |
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Effective date of registration: 20170621 Address after: South Industrial Park, 438800 Huanggang city of Hubei province Tuanfeng County Patentee after: GAUKE HEALTHCARE Co.,Ltd. Address before: 4, building 436, central Washington, No. 430032, Jianshe Avenue, Hubei, Wuhan Patentee before: WUHAN CENSHENG OZONE PHARMACEUTICAL SCIENCE AND TECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20210804 Address after: 430027 No. 83-105, Baofeng 1st Road, Qiaokou District, Wuhan City, Hubei Province Patentee after: Wuhan green oxygen technology development Co.,Ltd. Address before: 438800 Chengnan Industrial Park, Huanggang City, Hubei Province Patentee before: GAUKE HEALTHCARE Co.,Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20101020 |