CN101255671A - Regenerated cellulose fibrous environment protection type wallpaper - Google Patents

Regenerated cellulose fibrous environment protection type wallpaper Download PDF

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Publication number
CN101255671A
CN101255671A CNA2007100485572A CN200710048557A CN101255671A CN 101255671 A CN101255671 A CN 101255671A CN A2007100485572 A CNA2007100485572 A CN A2007100485572A CN 200710048557 A CN200710048557 A CN 200710048557A CN 101255671 A CN101255671 A CN 101255671A
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China
Prior art keywords
fibre
wallpaper
6660dtex
environment protection
protection type
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CNA2007100485572A
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Chinese (zh)
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CN101255671B (en
Inventor
冯涛
廖周荣
吴忠东
孙毅
周宗平
罗开云
闵家春
向世君
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Yibin Haisite Fiber Co Ltd
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Yibin Haisite Fiber Co Ltd
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Priority to CN2007100485572A priority Critical patent/CN101255671B/en
Publication of CN101255671A publication Critical patent/CN101255671A/en
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Publication of CN101255671B publication Critical patent/CN101255671B/en
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Abstract

Disclosed is an environment-friendly energy wallpaper of regenerated cellulose fiber. The wallpaper includes decoration layer and base, and is made by the adhesion of decoration fibrous layer that is formed by interweaving the man-made flat rayons with a denier being 167 to 6660 dtex to the base. The wallpaper made of regenerated cellulose fiber-man-made flat rayon has properties of bright color, variation, stereoscopic sense, and elegant and luxury decorative effect. The product has a good permeability without any chemical toxicity to the body.

Description

A kind of environment protection type wallpaper of regenerated celulose fibre
Technical field:
The present invention relates to a kind of wallpaper, a kind of employing regenerated celulose fibre material, the wallpaper that artificial flat viscose fibre is made, this wallpaper have characteristics such as degradable, good permeability, nontoxic, environmental protection, and product is called artificial raffia wallpaper, has another name called the Ya Feite wallpaper.
Background technology:
Wallpaper is the indispensable main material of modern architecture.Modern wallpaper is of a great variety, fancy is different, the pace of product renewal is very fast, product mainly is divided into PVC wallpaper, stationery wallpaper, natural braiding class wallpaper and Metal wall paper etc., the most common on the market wallpaper, the material therefor overwhelming majority is polyvinyl chloride or polyethylene, be called for short the PVC plastic wall paper, several types such as this wallpaper branch is made the zero diopter stamp, the light stamp is arranged, monochromatic embossing, printing and embossing.
In recent years, because the rapid high concentration of urban population, City Building begins to high-rise and superelevation stratification development, thereby also has higher requirement for the performance of house decorative material.Popular in the market wallpaper product mainly is the PVC series wallpaper that adopts gravure printing technique, though this class wallpaper has characteristics such as pattern grace, good hand touch, permeability is poor, paper has shortcomings such as residual smell, little poison but also exist, and is difficult to satisfy the demand of people at aspects such as material, environmental protection.
Patent Office of the People's Republic of China disclosed at present " preparation method and its usage of flax fibre " (publication number CN1526860) mainly is that the rattan of the fiber crops of wild or tame kind such as flax, Pueraria lobota fiber crops, jute, hemp, ramie, bluish dogbane etc. is made paper, is used as wallpaper again." a kind of production technology of polychrome string establishment wallpaper " (publication number CN1580458), its production stage is to select the plant long fibered raw material for use, dye, after the drying, choose the fibrous raw material of 2-4 kind different colours, with its mixed bundle that is set to, through manually combing repeatedly, be placed in the long shuttle cavity to fully mixing, in weaving process, take out some fibers at random; Be woven into polychrome wallpaper decoration layer, and be bonded into one with the base stock of wallpaper, but above-mentioned disclosed two technology contents, all do not relate to the application that fiber number is the artificial flat viscose fibre of 167-6660dtex, and, fiber number has different performances because being the artificial flat viscose fibre of 167-6660dtex itself, its method and structure that forms wallpaper is different with existing wallpaper product, particularly at aspects such as gas permeability, degradabilities, has possessed existing wallpaper product and can't reach corresponding effects.
Summary of the invention:
The objective of the invention is to remedy the deficiency of existing wallpaper product on the market, a kind of regenerated celulose fibre material of using be provided---the high-quality wallpaper that artificial flat viscose fibre is made with characteristics such as permeability is good, nontoxic, odorlessness, environmental protections.Wallpaper is beautiful in colour, changeableization, have three-dimensional texture, decorative effect gracefulness, luxurious; Product is encroached on without any chemistry human body simultaneously, and permeability is good, has satisfied current people to needs such as building interior trim market Green Products.
Concrete technology contents of the present invention is as follows:
A kind of environment protection type wallpaper of regenerated celulose fibre comprises decorative layer and basic unit, it is characterized in that: by fiber number is to be organized into after the artificial flat viscose fibre of 167-6660dtex interweaves to decorate fibrage and base adhesive is made.
Invent described decoration fibrage by warp and parallel intersection organizational composition, warp is the parallel composition of sub-thread strand or 2-5 thigh strand, and parallel is made up of sub-thread strand or 2-5 thigh strand.
Invent described decoration fibrage and comprise that at least one deck is that twist thread viscose glue thread layers that the back horizontal organization arranges and one deck of the artificial flat viscose fibre of 167-6660dtex is the artificial flat viscose fibre of the 167-6660dtex viscose glue thread layers that back longitudinal tissue arranges of twisting thread by fiber number by fiber number, and whenever adopt line ball mode, bonding way or the mode of laminating to connect between two-layer.
Invent described fiber number and be 167-6660dtex artificial flat viscose fibre bar vertically to do fracture strength be 1.00-2.00CN/dtex, vertically wet breaking strength is 0.5-1CN/dtex.
The cross section of inventing described artificial flat viscose glue sub-thread strand is pancake, trilobal, quatrefoil, " L " shape, " V " shape or " X " shape, and the fibrolaminar cross section of described decoration is rectangle or continuous " recessed " font.
Invent described tissue and comprise plain weave mode, twill-weave mode or satin weave mode, fiber number is that the artificial flat viscose fibre of 167-6660dtex is through the parallel feeding braiding machine braiding in the back of twisting thread or interweave.
Invent described basic unit and mainly comprise ply of paper or layer of cloth etc.
Inventing described bonding agent is PVA (polyvinyl alcohol)
The preparation method who invents the environment protection type wallpaper of described a kind of regenerated celulose fibre is:
A, preparation fiber number are the method for the artificial flat viscose fibre of 167-6660dtex: be raw material with the cotton linter, make colloid substance through dissolving, respin into silk;
B, preparation fiber number are the artificial flat viscose fibre method of yarn of 167-6660dtex: the equipment through comprising friction spinning machine, open-end spinning frame, ring spinning frame, special twisting machine and loom is made artificial flat viscose fibre yarn after with fiber number being the artificial flat viscose fibre skeining, washing, oven dry, damping, twisting, anti-strand of 167-6660dtex;
The method of C, tissue fibers decorative layer: with fiber number is the artificial flat viscose fibre yarn of 167-6660dtex, after warping technology is handled warp, parallel are interweaved, every two-layer employing line ball mode, bonding way or the mode of laminating connect between the graticule;
The method of D, tissue fibers wallpaper: comprise that the input, gluing of yarn and fabric, compound, pressurization, heat dries by the fire, cools off, cuts, batches.
The high-quality wallpaper that the present invention is made by artificial flat viscose fibre with characteristics such as permeability is good, nontoxic, odorlessness, environmental protections.Wallpaper is beautiful in colour, changeableization, have three-dimensional texture, decorative effect gracefulness, luxurious; Product is encroached on without any chemistry human body simultaneously, and permeability is good, has satisfied current people to needs such as building interior trim market Green Products.
Description of drawings:
Fig. 1 layer structure schematic diagram of the present invention
Wherein: decorative layer 1, adhesive-layer 2, basic unit 3.
The specific embodiment:
A kind of environment protection type wallpaper of regenerated celulose fibre---artificial raffia wallpaper, comprise decorative layer 1, adhesive linkage 2 and basic unit 3, it is characterized in that: by fiber number is to make with base adhesive after the artificial flat viscose fibre of 167-6660dtex is organized into decorative layer, and the wallpaper of making thus has following technical indicator:
1, stretch-proof tearing strength
Moistening intensity vertically is not less than 4N/1.5cm, laterally is not less than 2N/1.5cm, and the transverse breakage percentage elongation is not less than 8%;
2, COLOR FASTNESS is wiped in colour fastness to rubbing, dry friction COLOR FASTNESS, wet-milling, color fastness to light is not less than 4 grades;
3, opacity is not less than 90%.
4, limits of harmful substances value (unit: mg/kg)
Heavy metal (or other) element: barium≤100, cadmium≤25, chromium≤60, plumbous≤90, arsenic≤8, mercury≤20, selenium≤165, antimony≤20.
Vinyl Chloride Monomer≤1.0
Formaldehyde discharges and is not higher than 2mg/L
Satisfy standard GB 18585-2001 (whether containing above-mentioned heavy metal substance)
Organizational composition after decoration fibrage of the present invention is interweaved by warp and parallel, warp are the parallel composition of sub-thread strand or 2-5 thigh strand, and parallel is walked abreast by sub-thread strand or 2-5 thigh strand and forms.
Decoration fibrage of the present invention comprises that at least one deck is that twist thread viscose glue thread layers that the back horizontal organization arranges and one deck of the artificial flat viscose fibre of 167-6660dtex is the artificial flat viscose fibre of the 167-6660dtex viscose glue thread layers that back longitudinal tissue arranges of twisting thread by fiber number by fiber number, and whenever adopts line ball mode, bonding way or the mode of laminating to connect between two-layer.
Fiber number of the present invention is that the vertically dried fracture strength of the artificial flat viscose fibre bar of 167-6660dtex is 1.00-2.00CN/dtex, and vertically wet breaking strength is 0.5-1CN/dtex.
The cross section of artificial flat viscose glue sub-thread strand of the present invention is pancake, trilobal, quatrefoil, " L " shape, " V " shape or " X " shape, and described decoration fibrage cross section is rectangle or continuous " recessed " font.
Tissue of the present invention comprises plain weave mode, twill-weave mode or satin weave mode, and fiber number is that the artificial flat viscose fibre of 167-6660dtex is through the parallel feeding braiding machine braiding in the back of twisting thread or interweave.
Basic unit of the present invention comprises ply of paper or layer of cloth.
Bonding agent of the present invention is PVA (polyvinyl alcohol)
The preparation method of the environment protection type wallpaper of a kind of regenerated celulose fibre of the present invention is:
A, preparation fiber number are the method for the artificial flat viscose fibre of 167-6660dtex: be raw material with the cotton linter, make colloid substance through dissolving, respin into silk.
A, preparation fiber number are the artificial flat viscose fibre method of yarn of 167-6660dtex: utilize novel friction spinning machine, open-end spinning frame, ring spinning frame, special twisting machine and loom etc. with fiber number for the artificial flat viscose fibre skeining of 167-6660dtex, washing, oven dry, damping, twisting, anti-strand after, make artificial flat viscose fibre yarn.Also utilize handicraft braided fabric or
The method of B, tissue fibers decorative layer: with fiber number is the artificial flat viscose fibre yarn of 167-6660dtex, after warping technology is handled warp, parallel are interweaved, every two-layer employing line ball mode, bonding way or the mode of laminating connect between the graticule
The method of C, tissue fibers wallpaper: comprise that the input, gluing of yarn and fabric, compound, pressurization, heat technical process such as dries by the fire, cools off, cuts, batches.
Embodiment 1:
Artificial flat viscose fibre 2000D/1F footpath latitude after openpore or the dyeing is woven into decorative layer, passes through bondingly at last, PROCESS FOR TREATMENT such as film is made the artificial raffia wallpaper of 2000D;
1, stretch-proof tearing strength
Moistening intensity vertically is not less than 4N/1.5cm, laterally is not less than 2N/1.5cm
The transverse breakage percentage elongation is not less than 8%;
2, COLOR FASTNESS is wiped in colour fastness to rubbing, dry friction COLOR FASTNESS, wet-milling, color fastness to light is not less than 4 grades;
3, opacity is not less than 90%.
4, limits of harmful substances value (unit: mg/kg)
Heavy metal (or other) element: barium≤100, cadmium≤25, chromium≤60, plumbous≤90, arsenic≤8, mercury≤20, selenium≤165, antimony≤20 Vinyl Chloride Monomer≤1.0
Formaldehyde discharges and is not higher than 2mg/L
Satisfy standard GB 18585-2001
Embodiment 2
Artificial flat viscose fibre 1100D/1F footpath latitude after openpore or the dyeing is woven into decorative layer, passes through bondingly at last, PROCESS FOR TREATMENT such as film is made the artificial raffia wallpaper of 1100D;
1, stretch-proof tearing strength
Moistening intensity vertically is not less than 4N/1.5cm, laterally is not less than 2N/1.5cm
The transverse breakage percentage elongation is not less than 8%;
2, COLOR FASTNESS is wiped in colour fastness to rubbing, dry friction COLOR FASTNESS, wet-milling, color fastness to light is not less than 4 grades;
1, opacity is not less than 90%.
4, limits of harmful substances value (unit: mg/kg)
Heavy metal (or other) element: barium≤100, cadmium≤25, chromium≤60, plumbous≤90, arsenic≤8, mercury≤20, selenium≤165, antimony≤20.
Vinyl Chloride Monomer≤1.0
Formaldehyde discharges and is not higher than 2mg/L
Satisfy standard GB 18585-2001
Embodiment 3
Artificial flat viscose fibre 600D/1F footpath latitude after openpore or the dyeing is woven into decorative layer, passes through bondingly at last, PROCESS FOR TREATMENT such as film is made the artificial raffia wallpaper of 600D;
1, stretch-proof tearing strength
Moistening intensity vertically is not less than 4N/1.5cm, laterally is not less than 2N/1.5cm
The transverse breakage percentage elongation is not less than 8%;
2, COLOR FASTNESS is wiped in colour fastness to rubbing, dry friction COLOR FASTNESS, wet-milling, color fastness to light is not less than 4 grades;
3, opacity is not less than 90%.
4, limits of harmful substances value (unit: mg/kg)
Heavy metal (or other) element: barium≤100, cadmium≤25, chromium≤60, plumbous≤90, arsenic≤8, mercury≤20, selenium≤165, antimony≤20.
Vinyl Chloride Monomer≤1.0
Formaldehyde discharges and is not higher than 2mg/L
Satisfy standard GB 18585-2001 (whether containing above-mentioned heavy metal substance)
Embodiment 4
Artificial flat viscose fibre 300D/1F footpath latitude after openpore or the dyeing is woven into decorative layer, passes through bondingly at last, PROCESS FOR TREATMENT such as film is made the artificial raffia wallpaper of 300D;
1, stretch-proof tearing strength
Moistening intensity vertically is not less than 4N/1.5cm, laterally is not less than 2N/1.5cm
The transverse breakage percentage elongation is not less than 8%;
2, COLOR FASTNESS is wiped in colour fastness to rubbing, dry friction COLOR FASTNESS, wet-milling, color fastness to light is not less than 4 grades;
3, opacity is not less than 90%.
4, limits of harmful substances value (unit: mg/kg)
Heavy metal (or other) Elements Barium≤100, cadmium≤25, chromium≤60, plumbous≤90, arsenic≤8, mercury≤20, selenium≤165, antimony≤20.
Vinyl Chloride Monomer≤1.0
Formaldehyde discharges and is not higher than 2mg/L
Satisfy standard GB 18585-2001 (whether containing above-mentioned heavy metal substance)
Embodiment 5
Artificial flat viscose fibre 150D/1F footpath latitude after openpore or the dyeing is woven into decorative layer, passes through bondingly at last, PROCESS FOR TREATMENT such as film is made the artificial raffia wallpaper of 150D.
1, stretch-proof tearing strength
Moistening intensity vertically is not less than 4N/1.5cm, laterally is not less than 2N/1.5cm
The transverse breakage percentage elongation is not less than 8%;
2, COLOR FASTNESS is wiped in colour fastness to rubbing, dry friction COLOR FASTNESS, wet-milling, color fastness to light is not less than 4 grades;
3, opacity is not less than 90%.
4, limits of harmful substances value (unit: mg/kg)
Heavy metal (or other) element: barium≤100, cadmium≤25, chromium≤60, plumbous≤90, arsenic≤8, mercury≤20, selenium≤165, antimony≤20.
Vinyl Chloride Monomer≤1.0
Formaldehyde discharges and is not higher than 2mg/L
Satisfy standard GB 18585-2001.
The present invention has characteristics such as permeability is good, nontoxic, odorlessness, environmental protection by what artificial flat viscose fibre was made The high-quality wallpaper. Wallpaper is beautiful in colour, changeableization, have three-dimensional texture, decorative effect gracefulness, luxurious; Produce simultaneously Product are encroached on without any chemistry human body, and permeability is good, have satisfied current people to building interior trim market green Environment-friendly products etc. need.

Claims (9)

1. the environment protection type wallpaper of a regenerated celulose fibre comprises decorative layer and basic unit, it is characterized in that: by fiber number is to be organized into after the artificial flat viscose fibre of 167-6660dtex interweaves to decorate fibrage and base adhesive is made.
2. the environment protection type wallpaper of the described a kind of regenerated celulose fibre of invention according to claim 1, it is characterized in that: described decoration fibrage is by warp and parallel intersection organizational composition, warp is the parallel composition of sub-thread strand or 2-5 thigh strand, and parallel is made up of sub-thread strand or 2-5 thigh strand.
3. the environment protection type wallpaper of the described a kind of regenerated celulose fibre of invention according to claim 1 and 2, it is characterized in that: described decoration fibrage comprises that at least one deck is that twist thread viscose glue thread layers that the back horizontal organization arranges and one deck of the artificial flat viscose fibre of 167-6660dtex is the artificial flat viscose fibre of the 167-6660dtex viscose glue thread layers that back longitudinal tissue arranges of twisting thread by fiber number by fiber number, and whenever adopts line ball mode, bonding way or the mode of laminating to connect between two-layer.
4. the environment protection type wallpaper of the described a kind of regenerated celulose fibre of invention according to claim 1 and 2, it is characterized in that: described fiber number is that the vertically dried fracture strength of the artificial flat viscose fibre bar of 167-6660dtex is 1.00-2.00CN/dtex, and vertically wet breaking strength is 0.5-1CN/dtex.
5. the environment protection type wallpaper of the described a kind of regenerated celulose fibre of invention according to claim 1 and 2, it is characterized in that: the cross section of described artificial flat viscose glue sub-thread strand is pancake, trilobal, quatrefoil, " L " shape, " V " shape or " X " shape, and the fibrolaminar cross section of described decoration is rectangle or continuous " recessed " font.
6. the environment protection type wallpaper of the described a kind of regenerated celulose fibre of invention according to claim 1, it is characterized in that: described tissue comprises plain weave mode, twill-weave mode or satin weave mode, and fiber number is that the artificial flat viscose fibre of 167-6660dtex is through the parallel feeding braiding machine braiding in the back of twisting thread or interweave.
7. the environment protection type wallpaper of the described a kind of regenerated celulose fibre of invention according to claim 1 is characterized in that: described basic unit mainly comprises ply of paper or layer of cloth.
8. according to the environment protection type wallpaper of claim 1 or the described a kind of regenerated celulose fibre of 3 described inventions, it is characterized in that: described bonding agent is PVA (polyvinyl alcohol)
9. the environment protection type wallpaper of the described a kind of regenerated celulose fibre of invention according to claim 1 is characterized in that: described preparation method is:
A, preparation fiber number are the method for the artificial flat viscose fibre of 167-6660dtex: be raw material with the cotton linter, make colloid substance through dissolving, respin into silk;
B, preparation fiber number are the artificial flat viscose fibre method of yarn of 167-6660dtex: the equipment through comprising friction spinning machine, open-end spinning frame, ring spinning frame, special twisting machine and loom is made artificial flat viscose fibre yarn after with fiber number being the artificial flat viscose fibre skeining, washing, oven dry, damping, twisting, anti-strand of 167-6660dtex;
The method of C, tissue fibers decorative layer: with fiber number is the artificial flat viscose fibre yarn of 167-6660dtex, after warping technology is handled warp, parallel are interweaved, every two-layer employing line ball mode, bonding way or the mode of laminating connect between the graticule;
The method of D, tissue fibers wallpaper: comprise that the input, gluing of yarn and fabric, compound, pressurization, heat dries by the fire, cools off, cuts, batches.
CN2007100485572A 2007-03-01 2007-03-01 Regenerated cellulose fibrous environment protection type wallpaper Active CN101255671B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN101255671B CN101255671B (en) 2011-05-04

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101792989A (en) * 2010-03-20 2010-08-04 浙江沃莱菲装饰材料有限公司 Non-woven silk composite wallpaper and production process thereof
CN103978760A (en) * 2014-05-22 2014-08-13 安徽华邦特种材料有限公司 Preparation technology of hybrid fiber paper multifilament
CN113550063A (en) * 2021-07-14 2021-10-26 台州市黄岩喜金擦纱有限公司 Manufacturing process of packing paper of melt direct spinning strong polyester filament yarn
US11639316B2 (en) 2018-09-26 2023-05-02 3M Innovative Properties Company Fiber tows with a heat-activated sizing

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1328634A (en) * 1969-12-12 1973-08-30 Ici Ltd Decorative wall covering material
CN2369882Y (en) * 1999-04-21 2000-03-22 刘森 Pollutionless green environment protection decorative wall cloth
US6410140B1 (en) * 1999-09-28 2002-06-25 Basf Corporation Fire resistant corespun yarn and fabric comprising same
CN1094158C (en) * 2001-07-27 2002-11-13 宜宾丝丽雅股份有限公司 Once coagulating bath type prodn. of flat viscose fiber and its prpen. method
JP2003053868A (en) * 2001-08-22 2003-02-26 Kyosei:Kk Non-combustible wall material
CN1631627A (en) * 2004-12-29 2005-06-29 陈玉强 Bamboo wallpaper weaving method
CN1654717A (en) * 2005-03-14 2005-08-17 蔡增先 Adhesive raffia prepared by using secondary coagulating bath and its manufacturing method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101792989A (en) * 2010-03-20 2010-08-04 浙江沃莱菲装饰材料有限公司 Non-woven silk composite wallpaper and production process thereof
CN103978760A (en) * 2014-05-22 2014-08-13 安徽华邦特种材料有限公司 Preparation technology of hybrid fiber paper multifilament
CN103978760B (en) * 2014-05-22 2016-08-24 安徽华邦特种材料有限公司 A kind of production technology of composite fibre paper multifilament
US11639316B2 (en) 2018-09-26 2023-05-02 3M Innovative Properties Company Fiber tows with a heat-activated sizing
CN113550063A (en) * 2021-07-14 2021-10-26 台州市黄岩喜金擦纱有限公司 Manufacturing process of packing paper of melt direct spinning strong polyester filament yarn
CN113550063B (en) * 2021-07-14 2022-08-19 台州市黄岩喜金擦纱有限公司 Manufacturing process of packing paper of melt direct spinning strong polyester filament yarn

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