CN1012553B - Formulation of series products of seed coating agent and processing - Google Patents
Formulation of series products of seed coating agent and processingInfo
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- CN1012553B CN1012553B CN 86100095 CN86100095A CN1012553B CN 1012553 B CN1012553 B CN 1012553B CN 86100095 CN86100095 CN 86100095 CN 86100095 A CN86100095 A CN 86100095A CN 1012553 B CN1012553 B CN 1012553B
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Abstract
A seed coating agent is a novel product combined with the integral control of pests and diseases and used for seed coatings for standardizing qualified seeds. The former seed treatment agents used by the present invention can not solve the problem that seed coat can only swell after absorbing water without dissolving in the water. Seed germination can not be influenced, and the present invention also has key formulas which have the advantages of long efficiency, broad spectrum and low residue. The sixteen formulas of the present invention are respectively formed by compounding different pesticide components or seed fertilizers in a dyadic or multi-element way and confecting water with tens of matched auxiliary agents, such as film forming agents, etc. after ultramicro grinding. The formulas can be widely used for seed coating for difference crops, vegetables, Chinese medicinal herbs, flowers, etc. in different areas, the quality of fine seeds is raised, and the present invention is mainly used for treating different insect pests.
Description
Technical field: plant clothing agent system and be used for the seed treatment that seed pelleting improves breeding quality and integrated control seedling stage diseases and pests.
Background of invention: in the world the medicament and the fertilizer of seed are handled at present, seed dressing or the seed soaking modes of adopting are taken medicine fertilizer, when taking a lot of work more.Some countries of the U.S. and Russia, day and West Europe have adopted seed pelleting to handle new technology more widely in recent years.
Handle for cotton seeds, the U.S. at first in 1962 with puddling (Slurry) dressing, middle nineteen seventies Olin company uses kobam (Terrazole, C again
5H
5Cl
3N
2OS) and pcnb (PCNB, C
6Cl
5NO
2) be processed into Terracat number of products processing ginning cotton seed, prevent and treat sprout term disease.U.S. Texas experiment station had developed with sorbose (Sorbose C in 1978
6H
12O
6) add the adhesive acetate fiber cotton seed is carried out Cotton seeds, prevent and treat damping off.The Soviet Union had developed with high molecular polymer and has made adhesive in 1982, with growth regulator A-1 and trichlorophenol copper (Copper2,4,5-Trichlorophenolate, C
12H
4O
2CuCl
6) compositely be processed into the gel coat agent and handle cotton seed, but the Soviet Union is many with the wet-millings seed dressing to the chemicals treatment of seed before this.
On other crop, the United States Department of Agriculture research center was processed into seed coating medicine dressing soybean in 1982 with high molecular polymer and agriculture chemical compounding, had improved big germination of bean situation.SUMITOMO CHEMICAL KCC has set up vegetable seeds dressing factory in some places.Adopt natural material be material as seed coating medicine, carry out the vegetable seeds dressing, make big granulation of small-sized seed or pillization, be convenient to machine sowing and reduce seeding quantity.In addition, also useful natural material adds trace element and is processed into seed coating medicine and carries out the slurry type dressing.
But to kind of a clothing agent, also solve in the world at present prescription with composite film former and auxiliary aid make kind of clothing agent in soil, meet water can only imbibition and dissolved hardly, to guarantee that seed normally germinates, medicament slowly discharges, thereby prolongs critical formulations and the technology of drug effect phase.
Goal of the invention: the present invention is intended to overcome existing seed treatment diseases and pests controlling and composes the narrow shortcomings such as chance water easily dissolves loss in soil, and the drug effect phase is short that reach.The present invention uses emulsification, suspension, moistening the reaching in the surface of the seed film forming principle of colloid-stabilised principle and interfacial active component and high molecular polymer.Select for use long-acting systemic activity agricultural chemicals and different seed manure and hormone to make binary or Recompounded multielement.Make and can adapt to different regions, Different Crop needs, and can cure mainly the kind clothing agent series products of different damage by disease and insect and nutritional deficiency disease.
Summary of the invention:
One, plants the forming principle and the action principle of clothing agent
(1) forming principle:
The basic principle of this kind clothing agent series products moulding is to adopt the ionic dissociation equilibrium of the hydrophobic group of high molecular polymer colloid dispersant and carboxyl etc. and what form is the colloidal dispersion of carrier with water; The fertile active principle of medicine is dispersed in wherein through the slip of superfine grinding, carries out the product modulation with film forming agent and other kinds clothing agent auxiliary aid again and form.
(2) action principle:
Kind clothing on the seed at first plays disinfective action, allocates and transports and its spread in china with improved variety popularization to prevent some germ; During capsuled seed is broadcast and buried, plant clothing and around seed, form one deck protection barrier, can avoid the invasion and attack of sick worm in the soil; Behind the seed sprouting, plant clothing and play " little Drug Storage " effect, the medicament of interior absorption slowly discharges from " little Drug Storage ", is transmitted to not dispenser position by seed and plant absorption, has continued the preventing disease pest control effect.The trace element or the hormone of planting in the clothing then play the seed manure effect or stimulate root growth, strengthen resistance.
(3) to kind of the requirement of clothing agent:
The agent of kind of clothing is different from general seed dressing, requires when it is enclosed on the seed immediately that film-forming is kind of a clothing, does not need airing and dry the processing, broadcast plant clothing chance water in the soil can only imbibition, and dissolved hardly loss; Simultaneously, harmless to seed safety, thereby the normal suction that guarantees seed is germinateed and growth, the medicine fertilizer slow-release, and the lasting period is long, increase operation rate, thereby require kind of a clothing agent to answer the following characteristics of tool: high-purity, superfine particle diameter, suitable pH value, good storage-stable, and to the tight security of seed with to higher biologically active of controlling object etc.
Two, plant clothing agent effective ingredient, auxiliary aid and prescription, the scope of application:
(1) active constituent
The agent of 16 kind clothing of the present invention is made up of following agricultural chemicals active princlple respectively: carbofuran (Carbofuran); thimet (Phorate); acetyl group acephatemet (Acephate); phoxim (Phoxim); chlopyrifos (Chlorpyrifos); carbendazim (Carbendazim); pcnb (Quintozene), aliette (Aliette); tpn (Daconil), zinc methyl-arsenate (Zincmethyl arsonate); mancozeb (Manconeb); ziram (Ziram), tmtd (Thiram), fenaminosulf (Dexon); triazolone (Bayleton); Triadimenol (Baytan), succinic acid copper (Copper succinate), drazoxolon (Drazoxolon); metalaxyl (Metalaxyl), chemical constitution sees table 1 for details.(annotate: the furans pellet is the trade name of carbofuran)
The present invention some the prescription used trace element be zinc, copper, iron, manganese, boron, calcium and magnesium etc. as seed manure, used plant hormone is naphthenate, heteroauxin, methyl.
The selected main auxiliary agent classification of (two) ten six all clothing agent prescriptions is as follows:
1, colloid dispersant: keep the key assistant of stable colloid system, the present invention has selected for use following several:
The polymer of A, polyvinyl acetate and polyvinyl alcohol:
White bag solid tablet, alcoholysis degree is 88%, the tool colloid dispersion.
The polymer of B, ethyl acrylate and vinyl acetate:
White solid, tool different polymerization degree and molecular weight have colloid dispersion.
2, film forming agent: be the key assistant that kind of clothing agent has good filming and kind clothing fastness, that selects for use has:
A. polyvinyl acetate (Polyvinyl acetate, be called for short PVAC)
Homopolymers (Homopolymer) is a solid during low temperature, melts during high temperature to be dense emulsus.The tool film forming, moist again, the epithelium softness is wear-resisting, and fastness is strong.
B. polyvinyl resin (Polyvinyl resin is called for short PVRN)
White solid, tool different polymerization degree and molecular weight.Tool film forming on the thing table, the epithelium after the curing only can swellings in cold water, and dissolving hardly.Have the character such as esterification, etherificate and acetalation of the many alcohol of long-chain, chemical stability is good.
C, polymethylacrylic acid glycol ester (Polyglycol methylacrylate).
White solid, the tool different polymerization degree is also had a film forming, to institute's adhesive material, has strong bond properties, and it is also wettable to meet water, imbibition, but dissolved hardly.
D, polyethylene glycol (Polyvinyl Glycol)
3, bleeding agent: A, iso-octyl sodium sulfosuccinate, B, " peregal ".
A, be colourless light yellow thick liquid.B, be nonionic penetrant, industrial goods are that white solid is to promote behind the seed germination to inhale in the active ingredient to be penetrated into the inner key assistant that plays bactericidal action of seed, own simultaneously kind of a clothing agent product are also played moistening suspension effect.
4, emulsified wetting suspending agent: play emulsification, moistening and suspension effect.
A, phenethyl phenol polyoxy ethyl ether
Being nonionic, is the addition product of styrene, phenol and oxirane, and outward appearance is light yellow thick liquid, is the wax shape during winter low temperature, cloud point 93-95 ℃.
B, alkylphenol formaldehyde resin polyoxy ethyl ether.
N=30-80 m=2-4 R=C8-9 alkyl
Be nonionic, be the addition product of alkyl phenol, formaldehyde and oxirane.Cloud point 85-95 ℃, PH5-6, moisture 0.5%, degree of polymerization 10-15.Except that the tool emulsification, suspension effect is stronger.
C. calcium dodecyl benzene sulfonate
Be the anionic interfacial agent, white is insoluble in water to light yellow solid, generally uses 75% methanol solution.
Above-mentioned A and C are two monomers, and generally the two is made into compound auxiliary agent use according to prescription.Also available A or B and iso-octyl sodium sulfosuccinate (anionic) form compound auxiliary agent and use, and when the latter existed, A can use separately, and the two in fact also constitutes compound and works, and without C.Selecting for use the B monomer mainly to play suspension does to have.
5, colloid protective agent (claiming stabilizing agent again):
A:25% sulfuric acid.
B: dextrin.
6, other kinds clothing agent auxiliary aid:
1. antifreezing agent: ethylene glycol; 2. preservative (bactericide): A, Sodium Benzoate, B, potassium sorbate, C, sorbic acid; 3. diffusant: A, NNO(naphthalene sulfonic acid formaldehyde polymer), B, draw back powder; 4. viscosity stabiliser: A. phenol, B, butanols, C, sodium sulfocyanate, D, calcium thiocyanate; 5. defoamer: A, octanol, B, dimethicone, C, tributyl phosphate; 6. warning colouration: A, Ruo Daming-B(Rhodamine-B), B, Acid Brilliant Scarlet GR, C, Acid Red G, D, Acid Red B, E, F-3B, F, S-130 be pH value levelling agent 7.: hydrochloric acid and sodium hydroxide and sodium sulphate; 8. dressing filler: humus and peat; 9. adhesive: A, methylcellulose, B, carboxymethyl cellulose; (10) colloid water absorbing agent.16 kind clothing agent prescriptions see Table 2.
Table 2 kind of clothing agent prescription
Continuous table 2
Continuous table 2
Continuous table 2
(4) physical index and the scope of application of the agent of kind clothing:
1, physical index: planting the clothing agent is pasty state or newborn pasty state in appearance; Particle diameter≤2 micron particles are more than 92%, and≤4 micron particles are more than 95%; PH value 6.5-7.2; Dynamic viscosity 200-400 centipoise; Bin stability is more than 2 years; Film formation time is in 20 minutes in nylon braided bag; Plant clothing and vibrated 1 hour down, plant the clothing expulsion rate and be lower than 0.70% at 1200 rev/mins.
2, the scope of application: the agent of this kind clothing is to be applicable to Different Crop, and different regions cure mainly different damage by disease and insect.The scope of application such as the table 3 of of the present invention 16 all clothing agent products.
The table 3 series of products scope of application and controlling object
Planting the clothing agent is used for the crop controlling object and adapts to the area
The sterilization of cotton spoting verticillium wilt infected seeds such as No. 1 cotton, soybean, cotton in seedling stage anthracnose,
Damping off etc.Cotton aphid, thrips, soil insect.Soybean
The Cyst nematode disease, root rot etc.
No. 2 cottons, see taste plant be mainly used in northern cotton region, controlling object is the same, but it is withered to oppose
Sick special efficacy such as thing.Bright to ornamental plants damping off and soil insect effect
Show
No. 3 cottons, peanut, big national cotton region are general, and controlling object is wide than the former two.To flowers
Root diseases such as beans ornamental plants are effective with the insect pest in early stage.To roots such as southern peanut stem rot
Effectively sick.
No. 4 cottons, peanut, jade are used for northern cotton region, anti-ly eliminate aphis, thrips and soil insect.
Control of maize, grain mythimna separata and soil insects such as rice, grain, sweet potato, control grain nematodosis
And sweep stem nematode.
No. 5 vegetables, beet, western vegetables fusarium wilt and verticillium wilt fungus, damping off etc.;
Root rot of sugar beet such as melon, cotton, damping off; Watermelon blight and anthracnose;
The anthracnose in cotton region, south, eqpidemic disease etc.
Continuous table 3
Planting the clothing agent is used for the crop controlling object and adapts to the area
No. 6 vegetables, American Ginseng, vegetables and American Ginseng damping offs, anthracnose, damping off etc.; Yellow,
Bluish dogbane anthracnose such as crudefiber crop, withered rotten disease, fusarium wilt, damping off and relevant
Crop nutritional deficiency disease etc.
No. 7 vegetables, watermelon, sesame vegetables, watermelon blight, anthracnose etc., sesame anthracnose,
Sclerotinia rot of colzas such as fiber crops, rape and nutritional deficiency disease etc.
No. 8 vegetables, beet, flower vegetables, beet fusarium wilt, root rot, anthracnose and nutritional deficiency disease
Grass, nursery stock or the like.
Watermelons such as No. 9 watermelon vegetables and vegetables anthracnose, fusarium wilt, damping off, angular leaf spot,
Damping off and nutritional deficiency disease etc.
No. 10 vegetables, watermelon, sweet above-mentioned crop soil insect, angular leaf spot, fusarium wilt, verticillium wilt,
Anthracnose such as dish and physiological disease etc. still have the growth of promotion effect.
No. 11 cottons, paddy rice etc. are mainly used in southern cotton region, to prevent and treat anthracnose, damping off, epidemic disease
Sick and damping off is main, double eliminating aphis and soil insect, control
Achlya spp and the early stage other damage by disease and insect.
No. 12 cottons, paddy rice, numb object is the same substantially and to red, jute yarn parasitosis, anthracnose etc.
Special efficacys such as class.
Control of maize such as No. 13 corns, jowar, jowar head smut, soil insect, mythimna separata and
Nutritional deficiency disease etc.
Continuous table 3
Planting the clothing agent is used for the crop controlling object and adapts to the area
Control cereal class rust and powdery mildews such as No. 14 cereal classes, sunflower, smut, arbovirus
Disease, soil insect.Prevent and treat rust of sunflower and soil insect etc.
No. 15 floods and droughts rice, sweet corn control rice make double leafhopper, plant hopper, the snout moth's larvas controlled such as bakanae disease, continuous corruption
Worm, soil insect and nutritional deficiency disease etc.The mythimna separata of sweet corn,
Following insect etc.
No. 16 flowers, vegetables, herd and make the big granulation of small-sized seed, pillization, be convenient to sowing and save and use
Kind amounts such as grass etc.
Three, the technological process of production:
(1) technological process of production:
According to the characteristics of kind of clothing agent active princlple toxicity and the required rerum natura of kind clothing agent, the sealed wet processing flow process of sand milling still superfine grinding, product modulation, last test package is adopted in technological process of the present invention, and flow chart is attached.Brief description of the process is as follows.
1, wet type sand milling still superfine grinding operation
According to 1: 1.5 material sand than (volume ratio); drop into a certain amount of abrasive body bead in the sand milling still earlier; by the requirement of 16 kinds of different formulations, respectively effective ingredients such as the red female powder of furans, thimet, acetyl group acephatemet, phoxim, chlopyrifos, carbendazim, pcnb, aliette, tpn, the swollen sour zinc of methyl, mancozeb, tmtd, succinic acid copper, fenaminosulf are dropped in the sand milling still again.Add interfacial agent, antifreezing agent, diffusant etc. by the prescription requirement, open and stir, carry out wet grinding.In process of lapping, add defoamer according to circumstances, and when the slip face outdos oneself interface 20cm, just need to add defoamer, be ground to certain hour, the sampling and measuring granularity is when granularity meets standard (≤2 microns account for more than 92%, ≤ 4 microns account for more than 95%) after, be grinding endpoint, ground the back static 30 minutes, make the bead landing.With vacuum tube slip is sucked in the elevated dosing vessel then, measure, change next step operation then over to.
2, product modulating process
Through measuring qualified slip, utilize potential difference to put into modulation kettle, start stirring, measure the slip pH value again, and be transferred to 6.5-7.2, observe the slip color with pH value levelling agent, according to the different formulations requirement, according to the auxiliary agents such as colloid dispersant, film forming agent, stabilizing agent, preservative and warning colouration of slip quantity adding some, modulate repeatedly, carry out metering packing again up to after the assay was approved.
3, test package operation
With the modulating process close fit, after adding above-mentioned various modulation auxiliary agent, technical indicators such as sample analysis product active constituent content, proportion, centrifugal stability, dry matter content, viscosity, film formation time, after meeting product standard, product is put into packing tube and is carried out metering packing, adopts the double-layer seal container package.
4, technical target of the product and assay method
(1) granularity: granularity is kind of the basis of clothing agent film forming, and the particle of qualified kind of clothing agent≤4 micron accounts for more than 95% of sum, and≤2 microns particle accounts for more than 92% of sum.
(2) viscosimetric analysis: viscosity is one of kind of clothing agent key rerum natura, and with art for coating, coating quality and kind clothing fastness are in close relations.The viscosity of qualified kind of clothing agent: generally be used for the kind clothing agent product of cotton, wheat, coating paddy seeds, viscosity is between the 200-400 centipoise.
(3) pH value: this is influence kind of a clothing developing agent storage stability, especially directly influences the main rerum natura that capsuled seed germinates.The pH value of qualified products is 6.5-7.2.
(4) mensuration of ethyl acetate insolubles content: in order to check exotic impurity such as machinery, qualified index: ethyl acetate insolubles content≤0.5%.
(5) Su Cunliang on the sieve: as the investigation of control milling time reference index and storage back flocculation situation.
In process of lapping,, measured once every one hour, to be advisable less than 1% as the control physical index.
(6) centrifugal stability: this rerum natura is relevant with bin stability, divides three grades:
Excellent: elutriation goes out volume≤3%;
Very: elutriation goes out volume≤6%;
Difference: elutriation goes out volume＞6%-9%.
Qualified its centrifugal stability of kind clothing agent should be more than well.
(7) planting clothing agent film forming measures: one of film forming system kind of clothing agent key, and directly related with coating quality.The film-forming time of criterion of acceptability in nylon braided bag should be 10-20 minute.The mutual adhesion of the seed of dressing does not lump for qualified.
(8) the seed expulsion rate is measured: purpose is to measure the fastness of kind of clothing.Qualified kind of clothing expulsion rate should be lower than the 0.5-0.7% of total kind of clothing dry weight.
(2) capital equipment
Capital equipment
According to the technological process requirement, generally need following capital equipment:
1, sand milling still
The sand milling still is the key equipment of superfine grinding operation, is the vavuum pump that the water measuring tank is arranged and measure storage tanks and use for the former powder vacuum feed of agricultural chemicals for six grinding aids that different product needs of its service, and auxiliary agent vacuum feed pipeline.The storage tank that has that cooperates the former powder charging of agricultural chemicals, and dust catching jar also have vacuum buffer tank.
2, modulation kettle
Modulation kettle is a product modulating process capital equipment, and the equipment that cooperates it is that vavuum pump and vacuum intake pipe, the high-order metering of slip storage tank, two auxiliary agents are modulated little still, three auxiliary agents metering storage tanks and water yield jar etc.
From this technological process and selected device: 1. technological process is short, a complete set of equipment channelization.Sealed wet production, the no three wastes, no dust, no evaporating, emitting, dripping or leaking of liquid or gas problem.Working condition is good; 2. equipment interoperability is strong, and a set of equipment can be produced multiple series of products, the utilization rate of equipment and installations height, and cost is low; 3. the red female powder of more malicious furans is taked vacuum feed, is furnished with the dust catching jar, will catch the use that feeds intake again of female powder.
Four, the present invention and prior art compare the good effect that is had:
1, the present invention plants the clothing agent and is different from general seed treatment, is to be used for seed pelleting, makes the breeding standardization, improves seeding quality, the special-purpose formulation of prevention and elimination of disease and pests.Film-forming is kind of a clothing when it is enclosed on the seed immediately, broadcasts to bury, and meeting water can only imbibition and dissolved hardly; thereby guarantee normal germinating growth of seed and medicine fertilizer slow-release, prolong the lasting period, save medicine fertilizer; reduce area spray, protection natural enemy, protection environment.
What 2, the present invention planted that clothing agent system forms with group's ionic dissociation equilibrium such as the hydrophobic group of high molecular polymer colloid dispersant and carboxyl is the colloidal dispersion of carrier with water, agricultural chemicals or seed manure are dispersed in wherein through the slip of superfine grinding, modulate with film forming agent and other auxiliary aids again and form, to form after the storage not tackify, do not condense the kind clothing agent of tool film forming.Adopt composite film former to make the kind clothing on the seed can absorbent ventilate, guarantee seed sprouting, can make the critical formulations and the technology of medicine fertilizer slow-release again.
3, the present invention plants clothing agent system according to China's chief crop breeding dressing needs with to the requirement and the main diseases worm kind of nutrition, through the multiple years test, the kind clothing agent series products prescription of designing is tasted propagating materials dressing needs such as plant to adapt to cotton, oil crop, cereal crop, vegetables, medicinal material, sight, different regions, the needs of different controlling objects.Factory can use a set of equipment according to agricultural demand and local raw material, produces multiple product, and small investment brings notable results.
4, the present invention plants the clothing agent and adopts binary or multi-pesticide active princlple composite, is intended to the sick worm of integrated control, overcomes pesticide resistance.The fertile composite seed coating agent of medicine can improve the planting seed quality, double infectious disease and the physiological disturbance controlled.Medicine is fertile composite with natural material, makes the big granulation of small-sized seed, pillization, saves sowing quantity, makes in air seeding.
5, the present invention plants the clothing agent and makes the breeding standardization, improves seeding quality, realizes precision drilling, helps stock breeding and popularization, saves with planting, and the dressing cotton seed drops to 2-5 jin by every mu of original 10-15 jin.Make valuable watermelon, after seed pelletings such as American Ginseng and flowers are handled, economize to plant and save money, income is big.
6, the present invention plants the clothing agent to be used for seed pelleting is hidden dispenser, but integrated control damage by disease and insect and physiological disease guarantee that one broadcasts full stand.Full stand and healthy seedling can also promote to grow, and increases output, improves quality.Increase gined cotton about 15%, invest and take in than being about 1: 30, economic benefit and social benefit are obvious.
Description of drawings
Sequence number device name specification material
1 vavuum pump W3
2 vavuum pump W4
300 liters of A3 of 3 W4 surge tanks
300 liters of A3 of 4 dust catching jars
300 liters of A3 of 5 dust catching jars
300 liters of A3 of 6 W3 surge tanks
100 liters of A3 of 7 water measuring tanks
100 liters of A3 of No. 1 measuring tank of 8 auxiliary agents
100 liters of A3 of No. 2 measuring tanks of 9 auxiliary agents
100 liters of A3 of No. 3 measuring tanks of 10 auxiliary agents
100 liters of A3 of 11 defoamer measuring tanks
100 liters of A3 of 12 auxiliary agent measuring tanks
100 liters of A3 of 13 auxiliary agents, 600 measuring tanks
200 liters of A3 of the red female powder basin of 14 furans
500 liters of enamel of 15 sand milling stills
600 liters of A3 of 16 high-order feed liquid metering storage tanks
50 liters of A3 of 17 water measuring tanks
50 liters of A3 of 18 preservative basins
50 liters of A3 of 19 stabilizing agent basins
50 liters of A3 of 20 pH values levelling agent jar
50 liters of enamel of 21 warning colouration modulation kettles
20 liters of enamel of 22 film forming agent modulation kettles
1000 liters of enamel of 23 kinds of clothing agent modulation kettles
Claims (17)
1, be used for the series kind clothing agent that seed pelleting improves breeding quality and integrated pest prevention and control effect, comprise 16 different prescriptions altogether--plant clothing agent No. 1 to No. 16, the invention is characterized in: the material that constitutes this series kind clothing agent prescription comprises following a few class:
(1) pesticide activity component comprises: 20 kinds of carbofuran (furans pellet), thimet, acetyl group acephatemet, phoxim, chlopyrifos, carbendazim, pcnb, aliette, tpn, methyl Shen acid zinc, mancozeb, ziram, tmtd, fenaminosulf, succinic acid copper, Seedvax, Triadimenol, triazolone, drazoxolon, metalaxyls etc.
(2) seed manure and plant hormone comprise: zinc, copper, iron, manganese, boron, calcium, magnesium, naphthenate, heteroauxin, methyl
(3) film forming agent comprises: A, polyvinyl acetate, B, polyvinyl resin, C, polymethylacrylic acid glycol ester, D, polyethylene glycol
(4) colloid dispersant comprises: the polymer of A, polyvinyl acetate and polyvinyl alcohol, the polymer of B, ethyl acrylate and vinyl acetate
(5) bleeding agent comprises: A, iso-octyl sodium sulfosuccinate, B, " peregal "
(6) emulsified wetting suspending agent comprises: A, phenethyl phenol polyoxy ethyl ether, B, alkylphenol-formaldehyde resin polyoxy ethyl ether, C, calcium dodecyl benzene sulfonate
(7) colloid protective agent comprises: A, 25% sulfuric acid, B, dextrin
(8) viscosity stabiliser comprises: A, phenol, B, butanols, C, sodium sulfocyanate, D, sulphur hydracid calcium
(9) diffusant comprises: A, NNO (naphthalene sulfonic acid formaldehyde polymer), B, draw back powder
(10) defoamer comprises: A, octanol, B, dimethicone, C, phosphotriester
(11) antifreezing agent: ethylene glycol
(12) preservative comprises: A, Sodium Benzoate, B, potassium sorbate, C, sorbic acid
(13) warning colouration comprises: A, Ruo Daming-B, B, Acid Brilliant Scarlet GR, C, Acid Red G, D, Acid Red B, E, F-3B, F, S-130
(14) colloid water absorbing agent
(15) carrier comprises: peat and water.
2, by described kind of clothing agent series of claim 1 prescription, the concrete prescription that it is characterized in that No. 1, kind of clothing agent, be by weight percentage: furans pellet 20.00, carbendazim 10.00, the polymer (B) 1.50 of the polymer of polyvinyl acetate and polyvinyl alcohol (A)+ethyl acrylate and vinyl acetate, phenethyl phenol polyoxy ethyl ether (A) 1.50, polyvinyl acetate (A)+polyvinyl resin (B) 1.50-2.00(8:2), iso-octyl sodium sulfosuccinate (A)+" peregal " (B) 1.50,25% sulfuric acid (A) 0.30, phenol (A) 0.20, octanol (A) 0.02, ethylene glycol 5.00, potassium sorbate (B) 0.02, Acid Brilliant Scarlet GR (B) 0.70, all the other are water.
3, by described kind of clothing agent series of claim 1 prescription, the concrete prescription that it is characterized in that No. 2, kind of clothing agent, be by weight percentage: furans pellet 10.00, pcnb 15.00, seed manure 5.00, the polymer (B) 1.50 of polyvinyl acetate and polyvinyl alcohol polymer (A)+ethyl acrylate and vinyl acetate, phenethyl phenol polyoxy ethyl ether (A)+alkylphenol-formaldehyde resin polyoxy ethyl ether (B) 1.50(6:4), colloid water absorbing agent 0.10-1.00, polyvinyl acetate (A)+polyvinyl resin (B) 0.80-1.20(6:4), " peregal " be 2.00,25% sulfuric acid (A) 0.25 (B), phenol (A) 0.10, octanol (A) 0.05, ethylene glycol 5.00, Sodium Benzoate (A) 0.50, Ruo Daming-B(A)+Acid Brilliant Scarlet GR (B) 0.60, all the other are water.
4, by described kind of clothing agent series of claim 1 prescription, the concrete prescription that it is characterized in that No. 3, kind of clothing agent, be by weight percentage: furans pellet 20.00, carbendazim 5.00, pcnb 5.00, the polymer (B) 1.50 of polyvinyl acetate and polyvinyl alcohol polymer (A)+ethyl acrylate and vinyl acetate, colloid water absorbing agent 0.2-0.80, phenethyl phenol polyoxy ethyl ether (A)+alkylphenol-formaldehyde resin polyoxy ethyl ether (B)+calcium dodecyl benzene sulfonate (C) 1.50(4:5:1), polyvinyl acetate (A)+polyvinyl resin (B) 1.20-1.50(7:3), iso-octyl sodium sulfosuccinate (A)+" peregal " (B) 2.00, dextrin (B) 0.10.Benzene powder (A) 0.15, octanol (A) 0.10, ethylene glycol 5.00, Sodium Benzoate (A) 0.10, Acid Red G (C) 0.50, all the other are water.
5, by described kind of clothing agent series of claim 1 prescription, the concrete prescription that it is characterized in that No. 4, kind of clothing agent, be by weight percentage: furans pellet 20.00, thimet 10.00, polyvinyl acetate and polyvinyl alcohol polymer (A) 1.00, phenethyl phenol polyoxy ethyl ether (A)+calcium dodecyl benzene sulfonate (C) 5.50, polyvinyl acetate (A)+polyvinyl resin (B) 1.80-2.50(2:8), dextrin (B) 0.30, benzene powder (A) 0.10, ethylene glycol 5.00, Sodium Benzoate (A) 0.10, Acid Red B (D) 0.50, all the other are water.
6, by described kind of clothing agent series of claim 1 prescription, the concrete prescription that it is characterized in that No. 5, kind of clothing agent, be by weight percentage: carbendazim 20.00, aliette 5.00, the polymer (B) 1.20 of the polymer of polyvinyl acetate and polyvinyl alcohol (A)+ethyl acrylate and vinyl acetate, phenethyl phenol polyoxy ethyl ether (A)+calcium dodecyl benzene sulfonate (C) 2.00(5: 5), polyvinyl acetate (A)+polymethylacrylic acid ethanol ester (C) 1.50(5: 5), bleeding agent 2.00, dextrin (B) 0.10, butanols (B) 0.05, NNO(A) 2.50, dimethicone (B)+tributyl phosphate (C) 0.10, ethylene glycol 5.00, potassium sorbate (B) 0.05, Ruo Daming-B(A) 0.50, and all the other are water.
7, by described kind of clothing agent series of claim 1 prescription, the concrete prescription that it is characterized in that No. 6, kind of clothing agent, be by weight percentage: carbendazim 10.00, pcnb 10.00, ziram 5.00, seed manure 5.00, the polymer (B) 1.50 of the polymer of polyvinyl acetate and polyvinyl alcohol (A)+ethyl acrylate and vinyl acetate, phenethyl phenol polyoxy ethyl ether (A)+alkylphenol-formaldehyde resin polyoxy ethyl ether (B)+calcium dodecyl benzene sulfonate (C) 1.50-2.20(3: 3: 4), polyvinyl acetate (A)+polyvinyl resin (B) 0.80-1.20(6:4), bleeding agent 2.50, dextrin (B) 0.10, phenol (A) 0.20, octanol (B) 0.10, ethylene glycol 5.00, potassium sorbate (B) 0.10, S-130(F) 0.30, all the other are water.
8, by described kind of clothing agent series of claim 1 prescription, the concrete prescription that it is characterized in that No. 7, kind of clothing agent, be by weight percentage: carbendazim 9.00, mancozeb 10.00, seed manure 6.00, the polymer of polyvinyl acetate and polyvinyl alcohol (A) 1.00-1.20, phenethyl phenol polyoxy ethyl ether (A)+calcium dodecyl benzene sulfonate (C) 1.80-2.00(2:8), polyvinyl acetate (A)+polyethylene glycol (D) 0.80-1.50(5:5), bleeding agent 2.50, dextrin (B) 0.15, phenol (A) 0.15, draw back powder (B) 1.00, dimethicone (B)+tributyl phosphate (C) 0.10, ethylene glycol 5.00, potassium sorbate (B) 0.10, F-3B(E) 0.30, all the other are water.
9, by described kind of clothing agent series of claim 1 prescription, the concrete prescription that it is characterized in that No. 8, kind of clothing agent, be by weight percentage: carbendazim 15.00, Seedvax 5.00, seed manure 10.00, the polymer (B) 1.20 of the polymer of polyvinyl acetate and polyvinyl alcohol (A)+ethyl acrylate and vinyl acetate, phenethyl phenol polyoxy ethyl ether (A)+calcium dodecyl benzene sulfonate (C) 1.50-2.00(5:5), polyvinyl acetate (A)+polyvinyl resin (B) 0.80-1.20(6:4), bleeding agent 2.50, dextrin (B) 0.15, phenol (A) 0.05, draw back powder (B) 0.50, dimethicone (B)+tributyl phosphate (C) 0.10, ethylene glycol 5.00, potassium sorbate (B) 0.05, Ruo Daming-B(A)+Acid Brilliant Scarlet GR (C) 0.50, all the other are water.
10, by described kind of clothing agent series of claim 1 prescription, the concrete prescription that it is characterized in that No. 9, kind of clothing agent, be by weight percentage: carbendazim 7.50, pcnb 7.50, tmtd 5.00, succinic acid copper 5.00, seed manure 5.00, the polymer (B) 1.50 of the polymer of polyvinyl acetate and polyvinyl alcohol (A)+ethyl acrylate and vinyl acetate, phenethyl phenol polyoxy ethyl ether (A)+alkylphenol-formaldehyde resin polyoxy ethyl ether (B)+calcium dodecyl benzene sulfonate (C) 1.70-2.00(3:5:2), polyvinyl acetate (A)+polyvinyl resin (B) 0.80-1.50(5:5), bleeding agent 1.80-2.50, dextrin (B) 0.20, phenol (A) 0.13, NNO(A) 2.00, octanol (A) 0.15, ethylene glycol 5.00, Sodium Benzoate (A) 0.50, Acid Brilliant Scarlet GR (B) 0.50, all the other are water.
11; by described kind of clothing agent series of claim 1 prescription; the concrete prescription that it is characterized in that No. 10, kind of clothing agent; be by weight percentage: furans pellet 3.00; acetyl group acephatemet 5.00; carbendazim 4.50, pcnb 4.50, tmtd 3.00; metalaxyl 2.00; seed manure 7.00, the polymer of polyvinyl acetate and polyvinyl alcohol (A) 1.20, phenethyl phenol polyoxy ethyl ether (A)+calcium dodecyl benzene sulfonate (C) 2.50-3.00(7:3); polyvinyl acetate (A)+polymethylacrylic acid glycol ester 0.70-1.20(8:2); bleeding agent 1.20-1.80,25% sulfuric acid (A) 0.30, sodium sulfocyanate (C) 0.05; draw back powder (B) 1.50; octanol (A) 0.15, ethylene glycol 5.00, Sodium Benzoate (A) 0.05; Acid Red B (D) 0.70, all the other are water.
12, by described kind of clothing agent series of claim 1 prescription, the concrete prescription that it is characterized in that No. 11, kind of clothing agent, be by weight percentage: furans pellet 7.00, carbendazim 5.00, tmtd 5.00, dijuntong 5.00, seed manure 8.00, the polymer (B) 1.50 of the polymer of polyvinyl acetate and polyvinyl alcohol (A)+ethyl acrylate and vinyl acetate, phenethyl phenol polyoxy ethyl ether (A) 2.00-2.50, polyvinyl acetate (A)+polyvinyl resin (B) 0.70-1.20(7:3), bleeding agent 1.50-2.20,25% sulfuric acid (A) 0.30, calcium thiocyanate (D) 0.05, tributyl phosphate (C) 0.03, ethylene glycol 5.00, potassium sorbate (B) 0.02, Ruo Daming-B(A) 0.70, and all the other are water.
13, by described kind of clothing agent series of claim 1 prescription, the concrete prescription that it is characterized in that No. 12, kind of clothing agent, be by weight percentage: furans pellet 5.00, carbendazim 7.50, zinc methyl-arsenate 7.50, seed manure 10.00, the polymer (B) 1.30 of the polymer of polyvinyl acetate and polyvinyl alcohol (A)+ethyl acrylate and vinyl acetate, phenethyl phenol polyoxy ethyl ether (A)+calcium dodecyl benzene sulfonate (C) 1.20-1.80(5:5), polyvinyl acetate (A)+polymethylacrylic acid glycol ester (C) 0.80-1.50(6:4), bleeding agent 0.80-1.00, dextrin (B) 0.10, butanols (B) 0.05, dimethicone (B)+tributyl phosphate (C) 0.10, ethylene glycol 5.00, potassium sorbate (B) 0.05, Ruo Daming-B(A) 0.30, and all the other are water.
14, by described kind of clothing agent series of claim 1 prescription, the concrete prescription that it is characterized in that No. 13, kind of clothing agent, be by weight percentage: phoxim 12.00, triazolone (alcohol) 10.00, seed manure hormone 12.00, colloid water absorbing agent 0.10-1.20, the polymer of polyvinyl acetate and polyvinyl alcohol (A) 1.00, phenethyl phenol polyoxy ethyl ether (A)+calcium dodecyl benzene sulfonate (C) 6.50, polyvinyl resin (B) 1.00, iso-octyl sodium sulfosuccinate (A)+" peregal " (B) 4.00, tributyl phosphate (C) 0.25, ethylene glycol 5.00, Sodium Benzoate (A) 0.05, Ruo Daming-B(A) 0.40, and all the other are water.
15, by described kind of clothing agent series of claim 1 prescription, the concrete prescription that it is characterized in that No. 14, kind of clothing agent, be by weight percentage: phoxim 10.00, triazolone (alcohol) 6.00, Seedvax 4.00, seed manure hormone 6.00, the colloid water absorbing agent is 10-1.40 both, the polymer of polyvinyl acetate and polyvinyl alcohol (A) 1.50, phenethyl phenol polyoxy ethyl ether (A)+calcium dodecyl benzene sulfonate (C) 2.00, polyvinyl acetate (A)+polyvinyl resin (B) 1.20, iso-octyl sodium sulfosuccinate (A)+" peregal " (B) 4.00, octanol (A) 0.10, ethylene glycol 5.00, sorbic acid (C) 0.04, F-3B(E) 0.50, all the other are water.
16, by described kind of clothing agent series of claim 1 prescription, the concrete prescription that it is characterized in that No. 15, kind of clothing agent, be by weight percentage: furans pellet 3.00, chlopyrifos 3.00, carbendazim 6.00, fenaminosulf 6.00, seed manure hormone 6.00, colloid water absorbing agent 0.10-2.50, the polymer (B) 1.20 of the polymer of polyvinyl acetate and polyvinyl alcohol (A)+ethyl acrylate and vinyl acetate, phenethyl phenol polyoxy ethyl ether (A) 1.50, polyvinyl acetate (A)+polyvinyl resin (B) 1.50, iso-octyl sodium sulfosuccinate (A) 2.50, dimethicone (B) 0.08, ethylene glycol 5.00, sorbic acid (C) 0.06, Acid Brilliant Scarlet GR (B) 0.25, all the other are water.
17, by described kind of clothing agent series of claim 1 prescription, the concrete prescription that it is characterized in that No. 16, kind of clothing agent, be by weight percentage: furans pellet 5.00, carbendazim 5.00, triazolone (alcohol) 1.00, tmtd 5.00, seed manure hormone 3.00, colloid water absorbing agent 6.00, humus and peat 72.00, methylcellulose (A)+carboxymethyl cellulose (B) 3.00.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 86100095 CN1012553B (en) | 1986-01-09 | 1986-01-09 | Formulation of series products of seed coating agent and processing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 86100095 CN1012553B (en) | 1986-01-09 | 1986-01-09 | Formulation of series products of seed coating agent and processing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN86100095A CN86100095A (en) | 1987-10-07 |
| CN1012553B true CN1012553B (en) | 1991-05-08 |
Family
ID=4800884
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 86100095 Expired CN1012553B (en) | 1986-01-09 | 1986-01-09 | Formulation of series products of seed coating agent and processing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1012553B (en) |
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| CN1965595B (en) * | 2004-04-21 | 2010-09-22 | 阿尔卡特无线技术公司 | Restrictive and preferential routing in a distributed mobile switching center environment |
| CN102187873A (en) * | 2010-03-03 | 2011-09-21 | 利民化工有限责任公司 | Ternary compound wettable powder and preparation method and application thereof |
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-
1986
- 1986-01-09 CN CN 86100095 patent/CN1012553B/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1965595B (en) * | 2004-04-21 | 2010-09-22 | 阿尔卡特无线技术公司 | Restrictive and preferential routing in a distributed mobile switching center environment |
| CN102187873A (en) * | 2010-03-03 | 2011-09-21 | 利民化工有限责任公司 | Ternary compound wettable powder and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN86100095A (en) | 1987-10-07 |
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