CN1038011C - Composite packaging agent for drought resistance seed and its preparation - Google Patents
Composite packaging agent for drought resistance seed and its preparation Download PDFInfo
- Publication number
- CN1038011C CN1038011C CN94114270A CN94114270A CN1038011C CN 1038011 C CN1038011 C CN 1038011C CN 94114270 A CN94114270 A CN 94114270A CN 94114270 A CN94114270 A CN 94114270A CN 1038011 C CN1038011 C CN 1038011C
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- Prior art keywords
- absorbent resin
- super absorbent
- water
- drought
- coating agent
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- Agricultural Chemicals And Associated Chemicals (AREA)
- Pretreatment Of Seeds And Plants (AREA)
Abstract
The drought-resistant seed compound coating agent provided by the present invention contains pesticides, trace elements, plant growth hormones and 1.8 to 2.8% of super absorbent resin. The drought-resistant seed compound coating agent has the advantages of drought resistance, pesticide lasting effect increase, emergence rate enhancement, increase in yield, etc. Compared with the prior art, the preparation method of the coating agent, which is provided by the present invention, greatly reduces equipment investment, simplifies operating step and greatly lowers the processing cost of finished products; the preparation method is favorable to popularization and application.
Description
The present invention relates to the mixture of anti-drought water-retaining agent, agricultural chemicals, little fertilizer and multiple auxiliary agent, exactly is a kind of seed coating medicine that the plant breeding is handled that is used for.
Existing coating agent for seed; the fertile composite type seed seed coating medicine of medicine (patent publication No. is CN86100095A) as Beijing Agricultural University's invention contains agricultural chemicals, little fertilizer, trace element, auxin and other auxiliary aids; can around seed, form the protection barrier of prevention and elimination of disease and pests; control soil passes, kind passes sick the erosion; after treating that seed sprouting is unearthed; medicine is fertile slowly to be discharged, and continues preventing disease pest control and fertilizer efficiency effect.Its deficiency is to lack drought resistance function.Be head it off, on April 14th, 1993 disclosed a kind of " drought-resistant seed compound coating agent " (CN1070799) by Patent Office of the People's Republic of China.This coating agent for seed " contains agricultural chemicals, little fertilizer, trace element, auxin, colloid dispersant and water.It is characterized in that also containing the super absorbent resin of 3%-4.5% (percentage by weight)." wherein " said agricultural chemicals is certain two kinds in tpn, carbendazim, furans pellet, triazolone, the Isofenphos methyl, said little fertilizer is diammonium hydrogen phosphate, said trace element is at least two kinds in zinc sulphate, potassium sulphate, potassium dihydrogen phosphate, borax, the ammonium molybdate, said auxin is α-Nai Yisuanna or heteroauxin, said colloid dispersant is the polymer of polyvinyl acetate and polyvinyl alcohol, and its content adopts following percentage by weight when selecting above-mentioned each material for use:
Tpn 0.3-0.35
Carbendazim 1.0-1.5
The red 0.25-0.3 of furans
Triazolone 1.25-1.5
Isofenphos methyl 1.05-1.25
Diammonium hydrogen phosphate 0.5-1.0
Potassium sulphate 0.2-0.25
Zinc sulphate 0.08-0.23
Potassium dihydrogen phosphate 0.08-0.13
Borax 0.08-0.13
Ammonium molybdate 0.05-0.10
α-Nai Yisuanna or heteroauxin 0.001-0.10
The polymer of the polymer of polyvinyl acetate and polyvinyl alcohol or ETHYL CYANOACRYLATE and vinyl acetate
0.015-0.2
Surplus is a water.
This technology is in use planted the interior super absorbent resin of clothing and can be absorbed moisture content on every side in a large number, becomes " the little reservoir of soil ", after this slowly disengages, and has strengthened crop drought control and drought resistance ability widely.Plant the agricultural chemicals in the clothing, little fertilizer, plant growing simultaneously and swash growth and the prevention and elimination of disease and pests ability that compositions such as rope have promoted crop effectively.
Because the super absorbent resin that above-mentioned technology adopted is in main chemical reactions after the manufactured goods of granulation, oven dry, pulverizing, in the preparation of seed coating medicine, need under hot conditions, to be reduced into liquid state, composite with other effective ingredients again, therefore this technology has the following disadvantages: at first in a series of physical refining processes that back segment adopted of preparation process of super absorbent resin, not only equipment investment is big, and labour intensity is high and influence product quality---make its water absorbent rate reduction; Secondly, in seed coating medicine composite, because super absorbent resin will be reduced into liquid state (pasty state) under hot conditions, and the temperature-fall period after its reduction is slow, so the quality to other effective ingredients of seed coating medicine such as agricultural chemicals, plant growth promoter, trace element etc. will cause remarkable reduction in practice, simultaneously, intensification in the reduction process and cooling also cause the raising of cost.
The deficiency of above-mentioned technology is that also the consumption of super absorbent resin is higher, thereby the gas permeability of seed is had certain influence.The consumption of part agricultural chemicals and trace element also has in addition needs to adjust part.
The objective of the invention is the above-mentioned not enough compound proportion of adjusting effective ingredient in the seed coating medicine, and improve complex process in the hope of further improving effect of increasing production and significantly reducing composite cost at prior art.
Drought-resistant seed compound coating agent provided by the present invention, contain certain proportion agricultural chemicals, trace element, auxin, colloid dispersant, super absorbent resin and water, it is characterized in that: the content of super absorbent resin is 1.8%-2.8% (percentage by weight).
The employed super absorbent resin of the composite above-mentioned seed coating medicine of the present invention is that aqueous dispersion is made (by weight percentage) by following material: acrylic acid 23.26-33.53, sodium hydroxide 11.53-15.27, methene base bisacrylamide 0.0083-0.017, Si Ban-600.0333-0.0415, ammonium persulfate 0.0332-0.0415, anhydrous sodium sulfite 0.0332-0.0415 contains gasoline 1-1.53 simultaneously, and surplus is a water.
A kind of embodiment of above-mentioned seed coating medicine is: contain (percentage by weight) super absorbent resin 1.8-2.8, triazolone 1.25-1.3, phosfolan_methyl 1.05-1.25, zinc sulphate 0.18-0.23, potassium sulphate 0.2-0.25, α-Nai Yisuanna 0.001-0.01, the polymer 0.1-0.15 of ETHYL CYANOACRYLATE and vinyl acetate, surplus is a water.
Second kind of embodiment of above-mentioned seed coating medicine contains (percentage by weight) super absorbent resin 1.8-2.6, tpn 0.3-0.35, Isofenphos methyl 1.0-1.5, zinc sulphate 0.18-0.23, potassium sulphate 0.2-0.25, α-Nai Yisuanna 0.005-0.01, the polymer 0.1-0.17 of ETHYL CYANOACRYLATE and vinyl acetate, surplus is a water.
The third embodiment of above-mentioned seed coating medicine contains (percentage by weight) super absorbent resin 1.6-2.4, carbendazim 1.0-1.5, the red 2.8-4.8 of furans, potassium dihydrogen phosphate 0.08-0.13, borax 0.08-0.13, heteroauxin 0.001-0.01, the polymer 0.15-0.2 of polyvinyl acetate and polyvinyl alcohol, surplus is a water.
The 4th kind of embodiment of above-mentioned seed coating medicine contains (percentage by weight) super absorbent resin 2.0-2.6, tpn 0.3-0.35, Isofenphos methyl 1.05-1.25, borax 0.08-0.13, heteroauxin 0.001-0.01, ammonium molybdate 0.005-0.008, the polymer 0.15-0.2 of polyvinyl acetate and polyvinyl alcohol, surplus is a water.
The preparation method of drought-resistant seed compound coating agent provided by the present invention, its key step comprises: the aqueous dispersion of preparation super absorbent resin; The mixed liquor or the aqueous dispersion of preparation agricultural chemicals, trace element, auxin, colloid dispersant, behind the cleaning reaction still, the aqueous dispersion of super absorbent resin is added wherein, implement to stir, add simultaneously the mixed liquor or the moisture content prose style free from parallelism of agricultural chemicals, trace element, auxin, colloid dispersant at normal temperatures successively, abundant mixed seed coating medicine mixed liquor is milled to the 150-180 order by colloid mill; Sample examination, packing, labeling, storage.
In above-mentioned preparation technology, the aqueous dispersion of super absorbent resin prepares by following key step: the acrylic acid and the aqueous solvent of certainty ratio are added in the reactor, start reactor and implement to stir, the while is injected cooling water in the reactor interlayer; Dropping sodium solution in reactor, control still interior reaction temperature adds the mixed liquor of the methene base bisacrylamide aqueous solution and Si Ban-60 and gasoline below 35 ℃, stirs 5-10 minute; Add ammonium persulfate aqueous solution and sodium sulfite aqueous solution, stir and drop in the storage pool after 2 minutes; Leave standstill after 8 hours and in storage pool, add water to certainty ratio, soak and make after 24 hours.
The chemical structural formula of the used agricultural chemicals of the present invention is as follows:
Tpn (Daconil):
Carbendazim (Cafbendazim):
α-naa sodium: C
10H
7CH
2COONa
Furans pellet (Carbofurcln):
Triazolone (Bayltron):
Isofenphos methyl:
Phosfolan_methyl
The present invention has following outstanding advantage compared with prior art:
1, owing to adjusted the composite amount of super absorbent resin, not only reduces the seed coating medicine cost, also improved emergence rate effectively.
2, at the growth characteristic of Different Crop adjusted the part agricultural chemicals and the trace element composite amount after further improved emergence rate.
3, adopt new complex process to avoid of the reduction of physical refining processes such as granulation, baking effectively, improved quality high-hydroscopicity resin water absorbent rate.
4, owing to adopted the normal temperature complex process, overcome the reduction of high temperature to active princlple effects such as agricultural chemicals, trace elements.
5, the highly effective requirement that has simplified production equipment of adopting new technology reduces equipment investment more than 50%, and has simplified the operation requirement.Can reduce by 1/4 through experiment statistics seed coating medicine price, use the input-output ratio of seed coating medicine to reach more than 1: 40.
The seed coating medicine that table one is made by new proportioning for adopting new technology is opposed than the synthesis result table of comparisons of test with the old technology product.Test at agrotechnique center, Shandong Province, ground (city) such as the Chinese Academy of Agricultural Sciences base, agricultural weather center, Shandong, Qingdao, Weifang, Dezhou carries out respectively.
Table one
| Crop | Classification | Increase emergence rate (%) | Volume increase (%) |
| Corn | New technology | 16.1 | 18.8 |
| Old technology | 15.8 | 13.8 | |
| Wheat | New technology | 17.2 | 17.0 |
| Old technology | 10.8 | 12.1 | |
| Cotton | New technology | 20.5 | 15.7 |
| Old technology | 10.1 | 10.0 | |
| Peanut | New technology | 18.3 | 22.5 |
| Old technology | 13.1 | 15.2 |
Table two has provided the percentage by weight of three embodiment of the present invention (being used for winter wheat) table numerical value for each composition.
Table two
| The material title | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Super absorbent resin | 1.8 | 2.4 | 2.8 |
| Triazolone | 1.25 | 1.5 | 1.3 |
| Phosfolan_methyl | 1.05 | 1.25 | 1.2 |
| Zinc sulphate | 0.18 | 0.23 | 0.2 |
| Potassium sulphate | 0.2 | 0.25 | 0.23 |
| α-Nai Yisuanna | 0.001 | 0.01 | 0.005 |
| The polymer of ETHYL CYANOACRYLATE and vinyl acetate | 0.1 | 0.15 | 0.1 |
| Water | Surplus is a water | Surplus is a water | Surplus is a water |
Table three has provided three embodiment of the present invention (being used for corn), and numerical value is the percentage by weight of each composition in the table.
Table three
| The material title | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Super absorbent resin | 1.8 | 2.2 | 2.6 |
| Tpn | 0.3 | 0.35 | 0.33 |
| Isofenphos methyl | 1.00 | 1.25 | 1.5 |
| Zinc sulphate | 0.18 | 0.23 | 0.2 |
| Potassium sulphate | 0.2 | 0.25 | 0.23 |
| α-Nai Yisuanna | 0.005 | 0.01 | 0.008 |
| The polymer of ETHYL CYANOACRYLATE and vinyl acetate | 0.1 | 0.17 | 0.13 |
| Water | Surplus is a water | Surplus is a water | Surplus is a water |
Table four has provided three embodiment of the present invention (being used for cotton), and numerical value is the percentage by weight of each composition in the table.
Table four
| The material title | Embodiment 7 | Embodiment 8 | Embodiment 9 |
| Super absorbent resin | 1.6 | 2.0 | 2.4 |
| Carbendazim | 1.0 | 1.5 | 1.25 |
| The furans pellet | 2.8 | 3.6 | 4.8 |
| Potassium dihydrogen phosphate | 0.08 | 0.13 | 0.1 |
| Borax | 0.08 | 0.13 | 0.1 |
| Heteroauxin | 0.001 | 0.01 | 0.005 |
| The polymer of polyvinyl acetate and polyvinyl alcohol | 0.15 | 0.2 | 0.18 |
| Water | Surplus is a water | Surplus is a water | Surplus is a water |
Table five has provided the percentage by weight of three embodiment of the present invention (being used for peanut) table numerical value for each composition.
Table five
| The material title | Embodiment 10 | Embodiment 11 | Embodiment 12 |
| Super absorbent resin | 2.0 | 2.2 | 2.6 |
| Tpn | 0.3 | 0.35 | 0.32 |
| Isofenphos methyl | 1.05 | 1.25 | 1.1 |
| Heteroauxin | 0.001 | 0.01 | 0.005 |
| Borax | 0.08 | 0.13 | 0.1 |
| Potassium dihydrogen phosphate | 0.08 | 0.13 | 0.1 |
| Ammonium molybdate | 0.005 | 0.006 | 0.008 |
| The polymer of polyvinyl acetate and polyvinyl alcohol | 0.15 | 0.2 | 0.18 |
| Water | Surplus is a water | Surplus is a water | Surplus is a water |
The production method of drought-resistant seed compound coating agent provided by the invention is specified by following embodiment: as produce 1000Kg the foregoing description 12 said drought-resistant seed compound coating agents, and its processing step is:
A, weigh acrylic acid 19.31kg by certainty ratio, sodium hydroxide 7.47kg, methene base bisacrylamide 0.0099kg, 120# gasoline 0.594kg, Si Ban-600.0248kg, Ammonium Persulfate 98.5 0.0248Kg, anhydrous sodium sulfite 0.0248Kg, tpn 3.2Kg, Isofenphos methyl 11Kg, potassium dihydrogen phosphate 1kg, borax 1kg, heteroauxin 0.05kg, ammonium molybdate 0.08kg, the polymer 1.8kg of polyvinyl acetate and polyvinyl alcohol, water 955.41kg;
B, with dissolution of sodium hydroxide in 13.6kg water, methene base bisacrylamide is dissolved in the 1.2kg water, Si Ban-60 is dissolved among the gasoline, Ammonium Persulfate 98.5 and anhydrous sodium sulfite are dissolved in respectively in the water of 0.8kg;
C, acrylic acid 19.31kg and 12.16kg water are added in the reactor, sodium hydroxide solution is sucked in the gravity tank;
D, startup reactor stir, water flowing cooling in reacting kettle jacketing, and dropping sodium solution notices that temperature is below 35 ℃ in the control reactor;
E, sodium hydroxide solution add drip off finish after, treat to add when temperature in the kettle is reduced to 18 ℃-22 ℃ the aqueous solution of methene base bisacrylamide and the gasoline solution of Si Ban-60, the aqueous solution that stirs the aqueous solution that solution mixed in 5-10 minute to add Ammonium Persulfate 98.5 again and anhydrous sodium sulfite stirs after 2 minutes and adds suitable quantity of water, soaked 24 hours, and made the aqueous dispersion of super absorbent resin;
F, will tpn, Isofenphos methyl adds in the proper amount of clear water and stirs; Heteroauxin, ammonium molybdate, potassium dihydrogen phosphate and boric acid are put into an amount of water respectively be stirred to whole dissolvings;
G, remaining water added all the aqueous dispersion with super absorbent resin stirs in the reactor, the aqua that in reactor, adds heteroauxin, potassium dihydrogen phosphate, ammonium molybdate, tpn and Isofenphos methyl while stirring successively, the mixture that adds polyvinyl acetate and polyvinyl alcohol at last stirred 15-20 minute;
H, the gained material is fed colloid mill, be milled to the 150-180 order and make the compound seed coating medicine of seed, stand-by in the packing material of packing into.
Claims (7)
1, drought-resistant seed compound coating agent contains certainty ratio agricultural chemicals, trace element, auxin, colloid dispersant, super absorbent resin and water, it is characterized in that: the content of super absorbent resin is 1.8%-2.8% (percentage by weight); Super absorbent resin is an aqueous dispersion, and its effective ingredient is (by weight percentage); Acrylic acid 23.26-33.53, sodium hydroxide 11.53-15.27, methene base bisacrylamide 0.0083-0.017, one 600.0333-0.0415 of class of department, ammonium persulfate 0.0332-0.0415, anhydrous sodium sulfite 0.0332-0.0415, contain gasoline 1-1.53 simultaneously, surplus is a water.
2, drought-resistant seed compound coating agent according to claim 1, it is characterized in that: contain (percentage by weight) super absorbent resin 1.8-2.8, triazolone 1.25-1.3, phosfolan_methyl 1.05-1.25, zinc sulphate 0.18-0.23, potassium sulphate 0.2-0.25, α-Nai Yisuanna 0.001-0.01, the polymer 0.1-0.15 of ETHYL CYANOACRYLATE and vinyl acetate, surplus is a water.
3, the drought-resistant seed compound coating agent of stating according to claim 1, it is characterized in that: contain (percentage by weight) super absorbent resin 1.8-2.6, tpn 0.3-0.35, Isofenphos methyl 1.0-1.50, zinc sulphate 0.18-0.23, potassium sulphate 0.2-0.25, α-Nai Yisuanna 0.005-0.01, the polymer 0.1-0.17 of ethyl acrylate and vinyl acetate, surplus is a water.
4, drought-resistant seed compound coating agent according to claim 1, it is characterized in that: contain (percentage by weight) super absorbent resin 1.6-2.4, carbendazim 1.0-1.5, the red 2.8-4.8 of furans, potassium dihydrogen phosphate 0.08-0.13, borax 0.08-0.13, heteroauxin 0.001-0.01, the polymer 0.15-0.2 of polyvinyl acetate and polyvinyl alcohol, surplus is a water.
5, drought-resistant seed compound coating agent according to claim 1, it is characterized in that containing (percentage by weight) super absorbent resin 2.0-2.6, tpn 0.3-0.35, Isofenphos methyl 1.05-1.25, borax 0.08-0.13, heteroauxin 0.001-0.01, ammonium molybdate 0.005-0.008, the polymer 0.15-0.2 of polyvinyl acetate and polyvinyl alcohol, surplus is a water.
6, a kind of preparation method of drought-resistant seed compound coating agent, poly-comprising in main step:
6-1 prepares the aqueous dispersion of super absorbent resin as claimed in claim 1;
6-2 prepares the mixed liquor or the aqueous dispersion of agricultural chemicals, trace element, auxin, colloid dispersant;
Behind the 6-3 cleaning reaction still, the aqueous dispersion adding of super absorbent resin is wherein implemented to stir, add the mixed liquor or the aqueous dispersion of agricultural chemicals, trace element, auxin, colloid dispersant simultaneously successively, whole process is carried out at normal temperatures;
The abundant mixed seed coating medicine mixed liquor of 6-4 is milled to the 150-180 order by colloid mill;
6-5 sample examination, packing, labeling, storage.
7, the preparation method of drought-resistant seed compound coating agent according to claim 6 is characterized in that: the aqueous dispersion of super absorbent resin prepares by following key step:
7-1 adds startup reactor enforcement stirring in the reactor with the acrylic acid and the aqueous solvent of certainty ratio, injects cooling water simultaneously in the reactor interlayer;
7-2 dropping sodium solution, the control reaction temperature is in below 35 ℃;
The mixed liquor that 7-3 adds the methene base bisacrylamide aqueous solution and Si Ban-60 and gasoline stirred 5-10 minute;
7-4 adds ammonium persulfate aqueous solution and sodium sulfite aqueous solution, stirs and drops in the storage pool after 2 minutes;
7-5 adds water to certainty ratio in storage pool after 8 hours, soak and made in 24 hours.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94114270A CN1038011C (en) | 1994-12-29 | 1994-12-29 | Composite packaging agent for drought resistance seed and its preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94114270A CN1038011C (en) | 1994-12-29 | 1994-12-29 | Composite packaging agent for drought resistance seed and its preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1108878A CN1108878A (en) | 1995-09-27 |
| CN1038011C true CN1038011C (en) | 1998-04-15 |
Family
ID=5037166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94114270A Expired - Fee Related CN1038011C (en) | 1994-12-29 | 1994-12-29 | Composite packaging agent for drought resistance seed and its preparation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1038011C (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1053552C (en) * | 1996-08-28 | 2000-06-21 | 江苏里下河地区农业科学研究所 | Wrapping agent for strengthening seedlings and their roots by means of dry breeding |
| CN1058135C (en) * | 1997-11-06 | 2000-11-08 | 江苏省烟叶生产购销公司 | Tobacco pill-type high water absorbing seed's coating agent and its prepn. tech. |
| CN1077771C (en) * | 1998-06-03 | 2002-01-16 | 王树禹 | Plant drought-resisting agent preparation |
| CN104473251B (en) * | 2014-12-01 | 2016-08-24 | 黎明 | A kind of liquid for improveing Herba Herminii |
| CN105027747A (en) * | 2015-09-21 | 2015-11-11 | 山西省农业科学院谷子研究所 | Pelletized millet seeds and preparation method thereof |
| CN106386350A (en) * | 2016-09-08 | 2017-02-15 | 海南大学 | Method for improving drought resistance of Dalbergia odorifera, and growth regulator and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86100095A (en) * | 1986-01-09 | 1987-10-07 | 北京农业大学 | Plant clothing agent series products prescription and production technology thereof |
-
1994
- 1994-12-29 CN CN94114270A patent/CN1038011C/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86100095A (en) * | 1986-01-09 | 1987-10-07 | 北京农业大学 | Plant clothing agent series products prescription and production technology thereof |
Non-Patent Citations (1)
| Title |
|---|
| 国内精细化工产品手册 1982.8.1 化学工业部科学技术情报站编辑出版 * |
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| Publication number | Publication date |
|---|---|
| CN1108878A (en) | 1995-09-27 |
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