CN101220233A - Emulsified acrylic acid modified asphalt cement group waterproof coating material and method for producing the same - Google Patents
Emulsified acrylic acid modified asphalt cement group waterproof coating material and method for producing the same Download PDFInfo
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- CN101220233A CN101220233A CNA2008100467511A CN200810046751A CN101220233A CN 101220233 A CN101220233 A CN 101220233A CN A2008100467511 A CNA2008100467511 A CN A2008100467511A CN 200810046751 A CN200810046751 A CN 200810046751A CN 101220233 A CN101220233 A CN 101220233A
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Abstract
The invention relates to an acrylic acid modified asphalt cement-based and water-proof coating and a preparation method. The emulsified acrylic acid modified asphalt cement-based and water-proof coating consists of component A and component B; wherein, the mixture ratio of the component A to the component B is from 1 : 0.5 to 1.5 (in weight); wherein, the raw materials of component A and the weight percentage thereof are respectively as follows: acrylic emulsion or amphetamine emulsion accounting for 40 to 70 percent, emulsified asphalt accounting for 10 to 50 percent, filler accounting for 8 to 20 percent, accessory ingredient accounting for 0.1 to 3 percent and water accounting for 1 to 19.0 percent; the raw materials of component B and the weight percentage thereof are as follows respectively: cement accounting for 70 to 100 percent and filler accounting for 0 to 30 percent. The acrylic acid modified asphalt cement-based and water-proof coating has the advantages of strong binding power with the base, high tensile strength, large unit extension, low cost and environment protection.
Description
Technical field
The present invention relates to a kind of emulsified acrylic acid modified asphalt cement group waterproof coating material that is used for buildings, structures, road and bridge, tunnel, culvert waterproof, antiseepage, leakproof and preparation method thereof.
Background technology
Present coating water-proof technology and material, main following several technology and the material of adopting:
1, solvent-type waterproofing paint.Mainly contain polyurethane water-proof paint, polyurethane-modified asphalt waterproofing paint, SBS modified waterproof asphalt material, SBR modified waterproof asphalt material, rubber-like waterproof paint, silicon rubber waterproof coating etc.Its common feature is to be carrier and thinner with the organic solvent, generally has the advantage that intensity is big, unit elongation is high, anti-permeability performance is good.But, be inevitable to the pollution of environment, to producers and the healthy influence of workmen owing to adopted organic solvent.Organic solvent has inflammable and explosive property, and the fire prevention in production, storage, transportation, use, requirement of explosion proof are than higher, and safety in production requires high.In addition, as solvent based coating, than higher, this has brought bigger difficulty for the waterproof construction under wet environment, when rainy season construction, also can cause disadvantageous effect to the duration to the requirement of basic degree of drying.
2, at the existing problem of solvent-type waterproofing paint, nearly more than ten years aqueous waterproofing paint development is very fast.Mainly contain water-proof acrylic acid paint, aqueous polyurethane waterproof paint, emulsification chloroprene rubber waterproof coating etc.Except the general characteristic with solvent-type waterproofing paint, its principal feature is environmental protection, safe, pollution-free, strong to basic adaptability.
3, cement-base waterproof coating.Being that what to grow up in recent years is consolidating material with the oleic series emulsion, is the special aqueous waterproofing paint of a class that main active filler is formed with cement.Except characteristic, owing to added active filler cement, the bonding strength on itself and concrete or sand-cement slurry basis is obviously improved with general aqueous waterproofing paint.
Summary of the invention
The object of the present invention is to provide a kind of cohesive strength height, tension set is big, adaptability is strong, with low cost emulsified acrylic acid modified asphalt cement group waterproof coating material and preparation method thereof.
To achieve these goals, technical scheme of the present invention is: emulsified acrylic acid modified asphalt cement group waterproof coating material, and it is made up of first component and second component, the first component: the proportioning of second component is 1: 0.5~1.5 (weight);
Wherein each raw material and shared first weight percentages of components are respectively in the first component:
ACRYLIC EMULSION or benzene emulsion 40~70%,
Emulsified bitumen 10~50%,
Filler 8~20%,
Auxiliary agent 0.1~3%,
Water 1~19.0%;
Each raw material and shared second weight percentages of components are respectively in the second component:
Cement 70~100%,
Filler 0~30%.
Described ACRYLIC EMULSION is any one or any polymkeric substance or the copolymer emulsion more than two kinds in vinylformic acid, methyl acrylate, ethyl propenoate, butyl acrylate, methacrylic acid, methyl methacrylate, Jia Jibingxisuanyizhi, the butyl methacrylate, and any is any proportioning when mixing more than two kinds; F-400 emulsion as BASF AG.
Described benzene emulsion is the styrene-propene yogurt liquid that vinylbenzene and vinylformic acid or acrylic ester polymerization form; As the R-601 emulsion of national starch or the R106 emulsion of Union Carbide Corporation.
Described cement is any one or any mixing more than two kinds in ordinary Portland cement, silicate cement, perhafnate cement, extraordinary white cement, trass cement, the pulverized fuel ash cement, and any is any proportioning when mixing more than two kinds.
Described filler is any one or any mixing more than two kinds in lime carbonate, mica powder, flyash, kaolin, talcum powder, wollastonite, terra alba, rhombspar, the silica powder, and any is any proportioning when mixing more than two kinds.
Described auxiliary agent is any one or any mixing more than two kinds in sanitas, wetting agent, dispersion agent, the defoamer, and any is any proportioning when mixing more than two kinds.
Described sanitas is Sodium Benzoate, Zinc Pyrithione mould inhibitor or sodium pentachlorophenate; Described wetting agent is the T-731 wetting dispersing agent of CF-10 wetting agent, GR-5M wetting agent, the BYK-181 of Bi Ke company wetting dispersing agent or ROHM AND HASS company of SN-5040, the ROHM AND HASS company of the big auspicious company of the U.S.; Described dispersion agent is the T-731 wetting dispersing agent of TeogD-750W dispersion agent, the BYK-181 of Bi Ke company wetting dispersing agent or the ROHM AND HASS company of Degussa company; Described defoamer (aqueous solution defoamer) is the BYK-33 of Bi Ke company, BYK-22 defoamer, modest 082 defoamer of moral, the SPA-202 defoamer of Shanghai coating institute or the HX-5010 defoamer of China company.
The preparation method of above-mentioned emulsified acrylic acid modified asphalt cement group waterproof coating material is characterized in that it comprises the steps:
1) preparation of first component: 1. be respectively: ACRYLIC EMULSION or benzene emulsion 40~70% by each raw material in the first component and shared first weight percentages of components, emulsified bitumen 10~50%, filler 8~20%, auxiliary agent 0.1~3%, water 1~19.0% is chosen each raw material in the first component; 2. earlier with being heated to 70~90 ℃ in ACRYLIC EMULSION or benzene emulsion and the water adding reactor, slowly add emulsified bitumen while stirring, added follow-up continuation of insurance temperature stirring reaction 10~20 minutes, reduce to room temperature then, add auxiliary agent and filler then, the back packing that stirs gets the first component;
2) preparation of second component: 1. be respectively by each raw material in the second component and shared second weight percentages of components: cement 70~100%, filler 0~30% is chosen each raw material in the second component; 2. cement, filler are mixed the back packing in dry powder blender, get the second component;
3) when construction, by the first component: (weight) proportioning of second component is 1: 0.5~1.5, chooses first component and second component; Mix at the construction field (site) and stir, emulsified acrylic acid modified asphalt cement group waterproof coating material.After the mixing, emulsified acrylic acid modified asphalt cement group waterproof coating material must use up in three hours.
The present invention passes through the emulsified acrylic acid modified emulsifying asphalt earlier, and then organically combines with cement.Can improve the alkali resistance of emulsified bitumen like this, avoid the demulsification of cement emulsified bitumen.This waterproof paint and existing vinylformic acid cement-base waterproof coating relatively have characteristics such as cohesive strength height, tension set is big, good with the base bond performance, adaptability is strong, cost is low.
Embodiment
In order to understand the present invention better, further illustrate content of the present invention below in conjunction with embodiment, but content of the present invention not only is confined to the following examples.
Embodiment 1:
Emulsified acrylic acid modified asphalt cement group waterproof coating material, it is by the first component, and the second component is formed, first component: second component (weight)=1: 0.8.
Each raw material and shared first weight percentages of components are respectively in the first component:
Benzene emulsion (R-601 emulsion) 65.0%,
Emulsified bitumen (commercially available, anionic) 23.0%,
Filler (flyash and mica powder respectively account for 1/2) 8.0%,
Auxiliary agent (sodium pentachlorophenate and BYK-22 defoamer respectively account for 1/2) 0.8%,
Water (tap water) 3.2%,
Each raw material and shared second weight percentages of components are respectively in the second component:
Cement (white cement) 95.0%,
Filler (lime carbonate) 5.0%.
The preparation method, at first will be heated to 70~90 ℃ in R-601 emulsion and the water adding reactor by said ratio, slowly add the anionic emulsified bitumen while stirring, added follow-up continuation of insurance temperature stirring reaction 10~20 minutes, reduce to room temperature, add auxiliary agent sodium pentachlorophenate and BYK-22 defoamer and filler flyash and mica powder then, the back packing that stirs is as the first component.Be packaged as the second component after cement, filler-calcium carbonate mixed in dry powder blender.During construction first, second component is used by 1: 0.8 mixed and the back that stirs at the construction field (site), mixed waterproof paint must use up in three hours.
Embodiment 2:
Each raw material and shared first weight percentages of components are respectively in the first component:
ACRYLIC EMULSION (F-400 emulsion) 70.0%,
Emulsified bitumen (commercially available, anionic) 10.0%,
Filler (flyash) 12.0%,
Auxiliary agent (BYK-33 defoamer and T-731 wetting dispersing agent respectively account for 1/2) 0.6%,
Water (tap water) 7.4%,
Each raw material and shared second weight percentages of components are respectively in the second component:
Cement (ordinary Portland cement) 100.0%,
First component: second component=1: 1.25.
The preparation method, at first will be heated to 70~90 ℃ in F-400 emulsion and the water adding reactor by said ratio, slowly add the anionic emulsified bitumen while stirring, added follow-up continuation of insurance temperature stirring reaction 10~20 minutes, reduce to room temperature, add auxiliary agent B YK-33 defoamer and T-731 wetting dispersing agent and filler flyash then, the back packing that stirs is as the first component.Cement is packed as the second component.During construction first, second component is used by 1: 1.25 mixed and the back that stirs at the construction field (site), mixed waterproof paint must use up in three hours.
Embodiment 3:
Each raw material and shared first weight percentages of components are respectively in the first component:
Benzene emulsion (R106 emulsion) 42.0%,
Emulsified bitumen (negatively charged ion and nonionic mixing and emulsifying respectively account for 1/2) 45.0%,
Filler (mica powder and kaolin respectively account for 1/2) 9.0%,
Auxiliary agent (082 defoamer, BYK-181 wetting dispersing agent and sodium pentachlorophenate respectively account for 1/3) 2.5%,
Water (tap water) 1.5%,
Each raw material and shared second weight percentages of components are respectively in the second component:
Cement (white cement) 70.0%,
Filler (lime carbonate and silica powder respectively account for 1/2) 30.0%.
First component: second component=1: 1.2.
The preparation method, at first will be heated to 70~90 ℃ in R106 emulsion and the water adding reactor by said ratio, slowly add emulsified bitumen while stirring, added follow-up continuation of insurance temperature stirring reaction 10~20 minutes, reduce to room temperature, add auxiliary agent 082 defoamer, BYK-181 wetting dispersing agent and sodium pentachlorophenate and filler mica powder and kaolin then, the back packing that stirs is as the first component.Be packaged as the second component after cement, filler-calcium carbonate and silica powder mixed in dry powder blender.During construction first, second component is used by 1: 1.2 mixed and the back that stirs at the construction field (site), mixed waterproof paint must use up in three hours.
Embodiment 4:
Each raw material and shared first weight percentages of components are respectively in the first component:
Benzene emulsion (R106 emulsion) 50.0%,
Emulsified bitumen (commercially available, anionic) 25.0%,
Filler (flyash and mica powder respectively account for 1/2) 18.0%,
Auxiliary agent (BYK-33 defoamer, BYK-181 wetting dispersing agent and Zinc Pyrithione mould inhibitor respectively account for 1/3) 3.0%,
Water (tap water) 4.0%,
Each raw material and shared second weight percentages of components are respectively in the second component:
Cement (silicate cement) 85.0%,
Filler (lime carbonate and silica powder respectively account for 1/2) 15.0%.
First component: second component=1: 0.6
The preparation method, at first will be heated to 70~90 ℃ in R106 emulsion and the water adding reactor by said ratio, slowly add the anionic emulsified bitumen while stirring, added follow-up continuation of insurance temperature stirring reaction 10~20 minutes, reduce to room temperature, add auxiliary agent B YK-33 defoamer, BYK-181 wetting dispersing agent and Zinc Pyrithione mould inhibitor and filler flyash and mica powder then, the back packing that stirs is as the first component.Be packaged as the second component after cement, filler-calcium carbonate and silica powder mixed in dry powder blender.During construction first, second component is used by 1: 0.6 mixed and the back that stirs at the construction field (site), mixed waterproof paint must use up in three hours.
Embodiment 5:
Each raw material and shared first weight percentages of components are respectively in the first component:
Benzene emulsion (R-601 emulsion) 45.0%,
Emulsified bitumen (commercially available, anionic) 25.0%,
Filler (flyash, mica powder and talcum powder respectively account for 1/3) 10.0%,
Auxiliary agent (CF-10 wetting agent, D-750W dispersion agent, HX-5010 defoamer respectively account for 1/3) 1.0%,
Water (underground water) 19.0%,
Each raw material and shared second weight percentages of components are respectively in the second component:
Cement (white cement) 95.0%,
Filler (lime carbonate) 5.0%.
First component: second component=1: 1.
The preparation method, at first will be heated to 70~90 ℃ in R-601 emulsion and the water adding reactor, slowly add emulsified bitumen while stirring, added follow-up continuation of insurance temperature stirring reaction 10~20 minutes, reduce to room temperature, add auxiliary agent CF-10 wetting agent, D-750W dispersion agent, HX-5010 defoamer and filler flyash, mica powder and talcum powder then, the back packing that stirs is as the first component.Be packaged as the second component after cement, filler-calcium carbonate mixed in dry powder blender.During construction first, second component is used by 1: 1 the mixed and the back that stirs at the construction field (site), mixed waterproof paint must use up in three hours.
Embodiment 6:
Each raw material and shared first weight percentages of components are respectively in the first component:
ACRYLIC EMULSION (F-400 emulsion) 50.0%,
Emulsified bitumen (commercially available, anionic) 28.0%,
Filler (flyash and mica powder respectively account for 1/2) 9.0%,
Auxiliary agent (BYK-33 defoamer, BYK-181 wetting dispersing agent respectively account for 1/2) 0.6%,
Water (deionized water) 12.4%,
Each raw material and shared second weight percentages of components are respectively in the second component:
Cement (white cement) 100.0%,
First component: second component=1: 1.2.
The preparation method of aforesaid propylene acid modified asphalt cement-base waterproof coating, at first will be heated to 70~90 ℃ in F-400 emulsion and the water adding reactor, slowly add emulsified bitumen while stirring, added follow-up continuation of insurance temperature stirring reaction 10~20 minutes, reduce to room temperature, add auxiliary agent B YK-33 defoamer, BYK-181 wetting dispersing agent and filler flyash and mica powder then, the back packing that stirs is as the first component.Cement is as the second component.During construction first, second component is used by 1: 1.2 the mixed and the back that stirs at the construction field (site), mixed waterproof paint must use up in three hours.
Embodiment 7:
Each raw material and shared first weight percentages of components are respectively in the first component:
Benzene emulsion (R-601 emulsion) 55.0%,
Emulsified bitumen (commercially available, anionic) 30.0%,
Filler (flyash and mica powder respectively account for 1/2) 9.5%,
Auxiliary agent (T-731 wetting dispersing agent, 082 defoamer, Sodium Benzoate respectively account for 1/3) 1.2%,
Water (tap water) 4.3%,
Each raw material and shared second weight percentages of components are respectively in the second component:
Cement (white cement) 85.0%,
Filler (wollastonite, silica powder respectively account for 1/2) 15.0%.
First component: second component=1: 1.
The preparation method of aforesaid propylene acid modified asphalt cement-base waterproof coating, at first will be heated to 70~90 ℃ in R-601 emulsion and the water adding reactor, slowly add emulsified bitumen while stirring, added follow-up continuation of insurance temperature stirring reaction 10~20 minutes, reduce to room temperature, add auxiliary agent T-731 wetting dispersing agent, 082 defoamer, Sodium Benzoate and filler flyash and mica powder then, the back packing that stirs is as the first component.Cement and filler wollastonite and silica powder are mixed the back in dry powder blender pack as the second component.During construction first, second component is used by 1: 1 the mixed and the back that stirs at the construction field (site), mixed waterproof paint must use up in three hours.
Embodiment 8
Each raw material and shared first weight percentages of components are respectively in the first component:
Benzene emulsion (R-601 emulsion) 60.0%,
Emulsified bitumen (commercially available, anionic) 25.0%,
Filler (flyash and mica powder respectively account for 1/2) 10.0%,
Auxiliary agent (082 defoamer, T-731 wetting dispersing agent respectively account for 1/2) 1.0%,
Water 4.0%,
Each raw material and shared second weight percentages of components are respectively in the second component:
Cement (white cement) 90.0%,
Filler (silica powder) 10.0%.
First component: second component=1: 1.
Preparation method: at first will be heated to 70~90 ℃ in R-601 emulsion and the water adding reactor, slowly add emulsified bitumen while stirring, added follow-up continuation of insurance temperature stirring reaction 10~20 minutes, reduce to room temperature, add auxiliary agent T-731 wetting dispersing agent, 082 defoamer and filler flyash and mica powder then, packing after stirring is as the first component.Cement and filler silica powder are mixed the back in dry powder blender pack as the second component.During construction first, second component is used by 1: 1 the mixed and the back that stirs at the construction field (site), mixed waterproof paint must use up in three hours.
Embodiment 9:
With the benzene emulsion (R-601 emulsion) in ACRYLIC EMULSION (F-400 emulsion) alternative embodiment 8, rest part is identical with embodiment 8.
Embodiment 10:
Emulsified acrylic acid modified asphalt cement group waterproof coating material, it is made up of first component and second component, the first component: (weight) proportioning of second component is 1: 0.5;
Wherein each raw material and shared first weight percentages of components are respectively in the first component:
ACRYLIC EMULSION 40%,
Emulsified bitumen 50%,
Filler 8.9%,
Auxiliary agent 0.1%,
Water 1%;
Each raw material and shared second weight percentages of components are respectively in the second component:
Cement 70%,
Filler 30%.
Described ACRYLIC EMULSION is the methyl acrylate emulsion; Described cement is ordinary Portland cement; Described filler is a lime carbonate; Described auxiliary agent is a preservative sodium benzoate.
The preparation method of above-mentioned emulsified acrylic acid modified asphalt cement group waterproof coating material, it comprises the steps:
1) preparation of first component: 1. be respectively by each raw material in the first component and shared first weight percentages of components: ACRYLIC EMULSION or benzene emulsion 40%, emulsified bitumen 50%, filler 8.9%, auxiliary agent 0.1%, water 1% is chosen each raw material in the first component; 2. earlier with being heated to 70 ℃ in ACRYLIC EMULSION and the water adding reactor, slowly add emulsified bitumen while stirring, added follow-up continuation of insurance temperature stirring reaction 10 minutes, reduce to room temperature then, add auxiliary agent and filler then, the back packing that stirs gets the first component;
2) preparation of second component: 1. be respectively by each raw material in the second component and shared second weight percentages of components: cement 70%, filler (lime carbonate) 30% is chosen each raw material in the second component; 2. cement, filler are mixed the back packing in dry powder blender, get the second component;
3) when construction, by the first component: (weight) proportioning of second component is 1: 0.5, chooses first component and second component; Mix at the construction field (site) and stir, emulsified acrylic acid modified asphalt cement group waterproof coating material.After the mixing, emulsified acrylic acid modified asphalt cement group waterproof coating material must use up in three hours.
Embodiment 11:
Emulsified acrylic acid modified asphalt cement group waterproof coating material, it is made up of first component and second component, the first component: (weight) proportioning of second component is 1: 1.5;
Wherein each raw material and shared first weight percentages of components are respectively in the first component:
ACRYLIC EMULSION 60%,
Emulsified bitumen 10%,
Filler 20%,
Auxiliary agent 3%,
Water 7%;
Each raw material and shared second weight percentages of components are respectively in the second component:
Cement 99%,
Filler 1%.
Described ACRYLIC EMULSION is the copolymer emulsion of ethyl propenoate and butyl acrylate; Described cement is silicate cement; Described filler is a kaolin; Described auxiliary agent is a wetting agent---the BYK-181 of Bi Ke company wetting dispersing agent.
The preparation method of above-mentioned emulsified acrylic acid modified asphalt cement group waterproof coating material, it comprises the steps:
1) preparation of first component: 1. be respectively by each raw material in the first component and shared first weight percentages of components: ACRYLIC EMULSION 60%, emulsified bitumen 10%, filler 20%, auxiliary agent 3%, water 7% is chosen each raw material in the first component; 2. earlier with being heated to 90 ℃ in ACRYLIC EMULSION and the water adding reactor, slowly add emulsified bitumen while stirring, added follow-up continuation of insurance temperature stirring reaction 20 minutes, reduce to room temperature then, add auxiliary agent and filler then, the back packing that stirs gets the first component;
2) preparation of second component: 1. be respectively by each raw material in the second component and shared second weight percentages of components: cement 99%, filler 1% is chosen each raw material in the second component; 2. cement, filler are mixed the back packing in dry powder blender, get the second component;
3) when construction, by the first component: (weight) proportioning of second component is 1: 1.5, chooses first component and second component; Mix at the construction field (site) and stir, emulsified acrylic acid modified asphalt cement group waterproof coating material.After the mixing, emulsified acrylic acid modified asphalt cement group waterproof coating material must use up in three hours.
The bound value and the interval value of ACRYLIC EMULSION of the present invention or benzene emulsion, emulsified bitumen, filler, cement, auxiliary agent, water raw material can both be realized the present invention, and the concrete raw material of oleic series emulsion, emulsified bitumen, filler, cement, auxiliary agent, water can both realize the present invention, just do not enumerate embodiment one by one at this.
Claims (9)
1. emulsified acrylic acid modified asphalt cement group waterproof coating material, it is made up of first component and second component, the first component: the proportioning of second component is 1: 0.5~1.5 (weight);
Wherein each raw material and shared first weight percentages of components are respectively in the first component:
ACRYLIC EMULSION or benzene emulsion 40~70%,
Emulsified bitumen 10~50%,
Filler 8~20%,
Auxiliary agent 0.1~3%,
Water 1~19.0%;
Each raw material and shared second weight percentages of components are respectively in the second component:
Cement 70~100%,
Filler 0~30%.
2. emulsified acrylic acid modified asphalt cement group waterproof coating material according to claim 1 is characterized in that: the first component: the proportioning of second component is 1: 1 (weight);
Each raw material and shared first weight percentages of components are respectively in the first component:
ACRYLIC EMULSION or benzene emulsion 60.0%,
Emulsified bitumen 25.0%,
Filler 10.0%,
Auxiliary agent 1.0%,
Water 4.0%,
Each raw material and shared second weight percentages of components are respectively in the second component:
Cement 90.0%.
Filler 10.0%.
3. emulsified acrylic acid modified asphalt cement group waterproof coating material according to claim 1 and 2, it is characterized in that: described ACRYLIC EMULSION is any one or any polymkeric substance or the copolymer emulsion more than two kinds in vinylformic acid, methyl acrylate, ethyl propenoate, butyl acrylate, methacrylic acid, methyl methacrylate, Jia Jibingxisuanyizhi, the butyl methacrylate, and any is any proportioning when mixing more than two kinds.
4. emulsified acrylic acid modified asphalt cement group waterproof coating material according to claim 1 and 2 is characterized in that: described benzene emulsion is the styrene-propene yogurt liquid that vinylbenzene and vinylformic acid or acrylic ester polymerization form.
5. emulsified acrylic acid modified asphalt cement group waterproof coating material according to claim 1 and 2, it is characterized in that: described cement is any one or any mixing more than two kinds in ordinary Portland cement, silicate cement, perhafnate cement, extraordinary white cement, trass cement, the pulverized fuel ash cement, and any is any proportioning when mixing more than two kinds.
6. emulsified acrylic acid modified asphalt cement group waterproof coating material according to claim 1 and 2, it is characterized in that: described filler is any one or any mixing more than two kinds in lime carbonate, mica powder, flyash, kaolin, talcum powder, wollastonite, terra alba, rhombspar, the silica powder, and any is any proportioning when mixing more than two kinds.
7. emulsified acrylic acid modified asphalt cement group waterproof coating material according to claim 1 and 2, it is characterized in that: described auxiliary agent is any one or any mixing more than two kinds in sanitas, wetting agent, dispersion agent, the defoamer, and any is any proportioning when mixing more than two kinds.
8. emulsified acrylic acid modified asphalt cement group waterproof coating material according to claim 7 is characterized in that: described sanitas is Sodium Benzoate, Zinc Pyrithione mould inhibitor or sodium pentachlorophenate; Described wetting agent is the T-731 wetting dispersing agent of CF-10 wetting agent, GR-5M wetting agent, the BYK-181 of Bi Ke company wetting dispersing agent or ROHM AND HASS company of SN-5040, the ROHM AND HASS company of the big auspicious company of the U.S.; Described dispersion agent is the T-731 wetting dispersing agent of TeogD-750W dispersion agent, the BYK-181 of Bi Ke company wetting dispersing agent or the ROHM AND HASS company of Degussa company; Described defoamer is modest 082 defoamer of BYK-33, BYK-22 defoamer, moral of Bi Ke company, the SPA-202 defoamer of Shanghai coating institute or the HX-5010 defoamer of China company.
9. the preparation method of emulsified acrylic acid modified asphalt cement group waterproof coating material as claimed in claim 1 is characterized in that it comprises the steps:
1) preparation of first component: 1. be respectively: ACRYLIC EMULSION or benzene emulsion 40~70% by each raw material in the first component and shared first weight percentages of components, emulsified bitumen 10~50%, filler 8~20%, auxiliary agent 0.1~3%, water 1~19.0% is chosen each raw material in the first component; 2. earlier with being heated to 70~90 ℃ in ACRYLIC EMULSION or benzene emulsion and the water adding reactor, slowly add emulsified bitumen while stirring, added follow-up continuation of insurance temperature stirring reaction 10~20 minutes, reduce to room temperature then, add auxiliary agent and filler then, the back packing that stirs gets the first component;
2) preparation of second component: 1. be respectively by each raw material in the second component and shared second weight percentages of components: cement 70~100%, filler 0~30% is chosen each raw material in the second component; 2. cement, filler are mixed the back packing in dry powder blender, get the second component;
3) when construction, by the first component: the proportioning of second component is 1: 0.5~1.5 (weight), chooses first component and second component; Mix at the construction field (site) and stir, emulsified acrylic acid modified asphalt cement group waterproof coating material.
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2008
- 2008-01-22 CN CNA2008100467511A patent/CN101220233A/en active Pending
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CN101928518A (en) * | 2009-06-19 | 2010-12-29 | 深圳市卓宝科技股份有限公司 | Formula, preparation method and using method of bi-component fast-setting high polymer waterborne coating |
CN101633573B (en) * | 2009-08-14 | 2012-12-26 | 武汉广益交通科技股份有限公司 | Water-emulsion organic silicon composited acrylic acid modified asphalt cement-base waterproof coating and preparation method thereof |
CN102219446A (en) * | 2011-03-28 | 2011-10-19 | 湖南盛林建材科技有限公司 | Modified emulsified bitumen cement waterproof coating and preparation method thereof |
CN103508709A (en) * | 2012-06-15 | 2014-01-15 | 北京金隅加气混凝土有限责任公司 | Method for preparing steel bar antirust paint for autoclaved aerated concrete slabs |
CN103508709B (en) * | 2012-06-15 | 2016-08-03 | 北京金隅加气混凝土有限责任公司 | The autoclaved aerated concrete slab preparation method of reinforced steel bar rust preventing coating |
CN102850013A (en) * | 2012-08-13 | 2013-01-02 | 吴江市万事达防水建材有限公司 | Method for producing asphalt-modified polymer cement waterproof coating |
CN103242010A (en) * | 2012-08-13 | 2013-08-14 | 吴江市万事达防水建材有限公司 | Polymer cement waterproof paint |
CN103694804B (en) * | 2012-09-27 | 2017-01-18 | 湖北中科博策新材料研究院 | Two-component aqueous antirust quick-drying paint |
CN103694804A (en) * | 2012-09-27 | 2014-04-02 | 湖北中科博策新材料研究院 | Two-component aqueous antirust quick-drying paint |
CN102898091A (en) * | 2012-11-12 | 2013-01-30 | 吴江市万事达防水建材有限公司 | Asphalt modified polymer cement waterproof paint |
CN102977716A (en) * | 2012-12-25 | 2013-03-20 | 上海齐东昕防水工程有限公司 | Pure acrylic-acid elastic environment-friendly waterproof paint |
CN103043958A (en) * | 2013-01-10 | 2013-04-17 | 马千里 | Cement waterproof coating containing acrylic ester and preparation method of cement waterproof coating |
CN103468138A (en) * | 2013-08-16 | 2013-12-25 | 安徽快来防水防腐有限公司 | Waterproof coating for bridge floors, roofs and culverts |
CN103553452B (en) * | 2013-09-30 | 2015-05-20 | 潍坊市宏源防水材料有限公司 | Flexible waterproof mortar and production method thereof |
CN103553452A (en) * | 2013-09-30 | 2014-02-05 | 潍坊市宏源防水材料有限公司 | Flexible waterproof mortar and production method thereof |
CN103756476A (en) * | 2013-12-27 | 2014-04-30 | 安徽省美域节能环保技术应用有限公司 | Exterior wall insulating coating |
CN104109433A (en) * | 2014-05-09 | 2014-10-22 | 长兴泗安科林植保专业合作社 | Polymer-modified asphalt waterproof paint |
CN104109433B (en) * | 2014-05-09 | 2016-08-24 | 长兴泗安科林植保专业合作社 | A kind of polymer modified asphalt water-repellent paint |
CN104087171A (en) * | 2014-06-18 | 2014-10-08 | 安徽先锋门业科技有限公司 | Preparation method for water-emulsion-type acrylic-acid-modified asphalt waterproof coating |
CN104194630A (en) * | 2014-09-15 | 2014-12-10 | 重庆罗兹沃柯交通科技有限公司 | Novel waterproof bonding coating and preparation method thereof |
CN104478342A (en) * | 2014-12-23 | 2015-04-01 | 咸阳东方雨虹建筑材料有限公司 | Wet base surface treating agent |
CN104494226A (en) * | 2014-12-30 | 2015-04-08 | 南通福伦利新材料有限公司 | Waterproof heat-insulating fireproof layered material and construction technology thereof |
CN104652812B (en) * | 2014-12-30 | 2017-02-01 | 南通福伦利新材料有限公司 | Construction process of energy-saving luminescent artistic modeling engineering material |
CN104652812A (en) * | 2014-12-30 | 2015-05-27 | 南通福伦利新材料有限公司 | Construction process of energy-saving luminescent artistic modeling engineering material |
CN104893581A (en) * | 2015-05-26 | 2015-09-09 | 柳州市亿廷贸易有限责任公司 | Waterproof coating |
CN105440950A (en) * | 2015-12-16 | 2016-03-30 | 盘锦辽河油田金宇建筑材料有限公司 | Coating for anticorrosion and waterproofing, and preparation technology thereof |
CN105670432A (en) * | 2016-04-08 | 2016-06-15 | 苏州捷德瑞精密机械有限公司 | Environment-friendly waterproof aging-resistant coating and preparation method thereof |
CN106495620A (en) * | 2016-11-29 | 2017-03-15 | 安徽美琳建筑材料有限公司 | A kind of building water-proof paint |
CN106854066A (en) * | 2016-12-27 | 2017-06-16 | 慎思(天津)科技股份有限公司 | A kind of building intelligent installs decorative engineering polymer cement waterproof paint |
CN107383958A (en) * | 2017-07-31 | 2017-11-24 | 合肥泓定科技有限公司 | A kind of polymer cement waterproof paint and preparation method thereof |
CN107841203A (en) * | 2017-11-27 | 2018-03-27 | 安徽太基建设有限公司 | A kind of building water-proof paint and preparation method thereof |
CN108774417A (en) * | 2018-05-10 | 2018-11-09 | 镇江市江冠电器有限公司 | A kind of PRTV long-acting and anti-fouling flashing coatings with high hydrophobic and corrosion resistance |
CN109135666A (en) * | 2018-07-24 | 2019-01-04 | 南通科顺建筑新材料有限公司 | A kind of aqueous high solids content waterproof sealing cream and preparation method thereof |
CN109135666B (en) * | 2018-07-24 | 2020-10-27 | 南通科顺建筑新材料有限公司 | Water-based high-solid-content waterproof sealant and preparation method thereof |
CN110655864A (en) * | 2018-10-19 | 2020-01-07 | 湖南鲁班治水防水工程有限公司 | Cement-based polymer modified asphalt waterproof coating and preparation method thereof |
CN110105834B (en) * | 2019-06-04 | 2021-04-06 | 浙江欣苗化工有限公司 | Water-based acrylic asphalt anticorrosive paint and preparation process thereof |
CN110105834A (en) * | 2019-06-04 | 2019-08-09 | 浙江欣苗化工有限公司 | A kind of water soluble acrylic acid bitumastic and its preparation process |
CN111621231A (en) * | 2020-03-12 | 2020-09-04 | 苏州佳固士新材料科技有限公司 | Waterproof material for back surface with soft outer surface and rigid inner surface as well as preparation method and application of waterproof material |
CN111621204A (en) * | 2020-04-16 | 2020-09-04 | 西卡(上海)管理有限公司 | Liquid sound insulation coating |
CN111621204B (en) * | 2020-04-16 | 2021-11-09 | 西卡(上海)管理有限公司 | Liquid sound insulation coating |
CN112934647A (en) * | 2021-01-27 | 2021-06-11 | 佛山优尼凯新材料有限公司 | Environment-friendly high-elasticity high-strength heavy-corrosion-resistant coating process |
CN113801488A (en) * | 2021-10-13 | 2021-12-17 | 江苏西尔玛道路环保材料有限公司 | Asphalt-based concentrated sealing fabric, preparation method thereof and sand-containing fog seal |
CN114276085A (en) * | 2021-12-29 | 2022-04-05 | 山西中涂交通科技股份有限公司 | Special water-based primer for road markings |
CN115491058A (en) * | 2022-09-19 | 2022-12-20 | 深圳琼霸防水科技有限公司 | Multifunctional acrylic acid modified cement-based coating |
CN117532977A (en) * | 2024-01-09 | 2024-02-09 | 新大运防水科技(唐山)有限公司 | Asphalt waterproof coiled material and preparation method thereof |
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