CN107383958A - A kind of polymer cement waterproof paint and preparation method thereof - Google Patents

A kind of polymer cement waterproof paint and preparation method thereof Download PDF

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Publication number
CN107383958A
CN107383958A CN201710638201.8A CN201710638201A CN107383958A CN 107383958 A CN107383958 A CN 107383958A CN 201710638201 A CN201710638201 A CN 201710638201A CN 107383958 A CN107383958 A CN 107383958A
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percentage
weight
concentration
alumina silicate
superfine alumina
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汪琦
汪泽维
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Hefei Hong Ding Technology Co Ltd
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Hefei Hong Ding Technology Co Ltd
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Priority to CN201710638201.8A priority Critical patent/CN107383958A/en
Publication of CN107383958A publication Critical patent/CN107383958A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C09D1/06Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances cement
    • C09D1/08Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances cement with organic additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D195/00Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of polymer cement waterproof paint and preparation method thereof, wherein, the water-repellent paint includes the composition of following percentage by weight:High polymer emulsified asphalt 10%~16%;Silicone acrylic emulsion 6%~10%;Cement 12%~20%;Binary vinyl chloride-vinyl acetate resin 1.2%~2.8%;Silica flour 5%~15%;Superfine alumina silicate 2.5%~6.9%;Superfine alumina silicate polyalcohol 5.5%~9.2%;Coalescents 1.2%~2.6%;Remaining is deionized water.The water-repellent paint of the offer of the present invention is from high polymer emulsified asphalt, cement, binary vinyl chloride-vinyl acetate resin, silica flour, superfine alumina silicate and superfine alumina silicate polyalcohol according to being formed with special ratios, it has stronger water-proof function, and ageing-resistant performance is excellent, bonding force is strong, material ductility is good, application property is good, material safety and environmental protection, has no toxic side effect.

Description

A kind of polymer cement waterproof paint and preparation method thereof
Technical field
The present invention relates to a kind of polymer cement waterproof paint and preparation method thereof.
Background technology
As the continuous development and refinement of domestic coating industry, market are also more next to the requirement with special functional coating It is more prominent, wherein more increasing for the performance requirement such as anti-aging, water-fast, acid-alkali-corrosive-resisting, fire-retardant, in order to meet every profession and trade to anti- The requirement of water paint, produces high-performance, and widely used water-repellent paint is necessary.
Also there is poor water resistance in traditional polymer cement-based waterproof material, service life is short, it is impossible to be used in two level and with Upper water-proof roofing and important waterproofing work.During liquid material of the acrylate polymer emulsion as polymer cement waterproof paint, The shortcomings of poor water resistance be present, influence the water-proof function of polymer waterproof coating material.Pitch has that material source is extensive, price is low The advantages that honest and clean, ability low concentration inorganic acid, alkali and salt corrosion, and its own waterproof, there is certain self-healing.
The content of the invention
The defects of the present invention seeks to exist for prior art, provides a kind of polymer cement waterproof paint and its preparation Method.
The present invention to achieve the above object, adopts the following technical scheme that:A kind of polymer cement waterproof paint, including it is following The composition of percentage by weight:
Preferably, the composition of following percentage by weight is included:
Preferably, the composition of following percentage by weight is included:
Preferably, the composition of following percentage by weight is included:
Preferably, the concentration of the high polymer emulsified asphalt is 82~89% (percentage by weights);The silicone acrylic emulsion Concentration be 72~89% (percentage by weights);The concentration of the cement is 85~95% (percentage by weights);The binary chlorine The concentration of vinegar resin is 90~98% (percentage by weights);The concentration of the silica flour is 85~95% (percentage by weights);Institute The concentration for stating superfine alumina silicate is 76~88% (percentage by weights);The concentration of the superfine alumina silicate polyalcohol is 79~87% (percentage by weight);The concentration of the coalescents is 98.8~99.9% (percentage by weights).
Preferably, the concentration of the high polymer emulsified asphalt is 82% (percentage by weight);The silicone acrylic emulsion it is dense Spend for 79% (percentage by weight);The concentration of the cement is 85% (percentage by weight);The concentration of the binary vinyl chloride-vinyl acetate resin For 90% (percentage by weight);The concentration of the silica flour is 85% (percentage by weight);The concentration of the superfine alumina silicate is 76% (percentage by weight);The concentration of the superfine alumina silicate polyalcohol is 79% (percentage by weight);The coalescents Concentration is 98.8% (percentage by weight).
Preferably, the concentration of the high polymer emulsified asphalt is 86% (percentage by weight);The silicone acrylic emulsion it is dense Spend for 82% (percentage by weight);The concentration of the cement is 90% (percentage by weight);The concentration of the binary vinyl chloride-vinyl acetate resin For 94% (percentage by weight);The concentration of the silica flour is 90% (percentage by weight);The concentration of the superfine alumina silicate is 82% (percentage by weight);The concentration of the superfine alumina silicate polyalcohol is 82% (percentage by weight);The coalescents Concentration is 99.5% (percentage by weight).
Preferably, the concentration of the high polymer emulsified asphalt is 89% (percentage by weight);The silicone acrylic emulsion it is dense Spend for 89% (percentage by weight);The concentration of the cement is 95% (percentage by weight);The concentration of the binary vinyl chloride-vinyl acetate resin For 98% (percentage by weight);The concentration of the silica flour is 95% (percentage by weight);The concentration of the superfine alumina silicate is 88% (percentage by weight);The concentration of the superfine alumina silicate polyalcohol is 87% (percentage by weight);The coalescents Concentration is 99.9% (percentage by weight).
A kind of preparation method of polymer cement waterproof paint, comprises the following steps:
Automatical feeding system is first passed through by high polymer emulsified asphalt and weight of the weight percentage for 10%~16% The silicone acrylic emulsion that percentage composition is 6%~10% is added slowly to be loaded with the reactor of deionized water, and is sufficiently stirred, Whipping temp is 60-70 degree, and stirring air pressure is 1.2-2.3Mpa, and mixing time is 10~15 minutes, and the speed of stirring is 75-85 Rev/min;
It is 12%~20% cement, again to next proceed through automatical feeding system and slowly add weight percentage successively Measure percentage composition be 1.2%~2.8% binary vinyl chloride-vinyl acetate resin, weight percentage be 5%~15% the dilute base n-butyl ether of second, Coalescents that superfine alumina silicate that weight percentage is 2.5%~6.9%, weight percentage are 0.2%~0.6%, Superfine alumina silicate polyalcohol and the deionized water that weight percentage is 1.5%~3.2%, and be sufficiently stirred, whipping temp is 30-40 degree, stirring air pressure are 2.2-3.3Mpa, and mixing time is 15~25 minutes, and the speed of stirring is 55-75 revs/min;
Membrane pump is finally started, obtained mixture is first passed through into 0.2um filters circulating filtration 2~3 hours, then pass through 0.12 μm of filter filtering, to remove the unwanted particles that particle diameter in mixture is more than 0.12 μm, produces water-repellent paint.
Beneficial effects of the present invention:The water-repellent paint of the offer of the present invention is by high polymer emulsified asphalt, cement, binary chlorine Vinegar resin, silica flour, superfine alumina silicate and superfine alumina silicate polyalcohol coordinate according to special ratios to be formed, and it has stronger anti- Water function, and ageing-resistant performance is excellent, bonding force is strong, material ductility is good, application property is good, material safety and environmental protection, nontoxic pair Effect.
Brief description of the drawings
Fig. 1 is the process chart of the present invention.
Embodiment
The invention is further illustrated by the following examples, but is not limited to lifted embodiment.
Embodiment 1, the high polymer emulsified asphalt and 6kg silicone acrylic emulsions for weighing 10kg, then pass through automatical feeding system It is added slowly to be loaded with the reactor of appropriate deionized water, and is sufficiently stirred, whipping temp is 40 degree, and stirring air pressure is 1.2Mpa, mixing time are 10 minutes, and the speed of stirring is 45 revs/min;
Then 12kg cement, 1.2kg binary vinyl chloride-vinyl acetate resin, 5kg silica flour, 2.5kg isopropyl sulfuric is weighed Ether, 0.2kg coalescents, 1.5%kg superfine alumina silicate polyalcohol and appropriate deionized water, and be sufficiently stirred, stirring temperature Spend for 30 degree, stirring air pressure is 2.2Mpa, and mixing time is 15 minutes, and the speed of stirring is 55 revs/min;
Membrane pump is finally started, obtained mixture is first passed through into 0.2um filters circulating filtration 2 hours, then through 0.12 μ M filter filtering, to remove the unwanted particles that particle diameter in mixture is more than 0.12 μm, produces aluminium film water system photoresistance stripper.
Wherein, the concentration of the high polymer emulsified asphalt is 82% (percentage by weight);The concentration of the silicone acrylic emulsion For 72% (percentage by weight);The concentration of the cement is 85% (percentage by weight);The concentration of the binary vinyl chloride-vinyl acetate resin is 90% (percentage by weight);The concentration of the silica flour is 85% (percentage by weight);The concentration of the superfine alumina silicate is 76% (percentage by weight);The concentration of the coalescents is 98.8% (percentage by weight);The superfine alumina silicate polyalcohol Concentration be 79% (percentage by weight).
Embodiment 2, the high polymer emulsified asphalt and 8kg silicone acrylic emulsions for weighing 13kg, then pass through automatical feeding system It is added slowly to be loaded with the reactor of appropriate deionized water, and is sufficiently stirred, whipping temp is 50 degree, and stirring air pressure is 1.7Mpa mixing time is 12 minutes, the speed of stirring is 45 revs/min;
Then 17kg cement, 2.2kg binary vinyl chloride-vinyl acetate resin, 10kg silica flour, 4.5kg isopropyl sulfuric is weighed Ether, 0.4kg coalescents, 2.5%kg superfine alumina silicate polyalcohol and appropriate deionized water, and be sufficiently stirred, stirring temperature Spend for 35 degree, stirring air pressure is 2.9Mpa, and mixing time is 20 minutes, and the speed of stirring is 65 revs/min;
Membrane pump is finally started, obtained mixture is first passed through into 0.2um filters circulating filtration 2.5 hours, then pass through 0.12 μm of filter filtering, to remove the unwanted particles that particle diameter in mixture is more than 0.12 μm, produce the stripping of aluminium film water system photoresistance Chaotropic.
Wherein, the concentration of the high polymer emulsified asphalt is 86% (percentage by weight);The concentration of the silicone acrylic emulsion For 82% (percentage by weight);The concentration of the cement is 90% (percentage by weight);The concentration of the binary vinyl chloride-vinyl acetate resin is 94% (percentage by weight);The concentration of the silica flour is 90% (percentage by weight);The concentration of the superfine alumina silicate is 82% (percentage by weight);The concentration of the superfine alumina silicate polyalcohol is 82% (percentage by weight);The coalescents Concentration is 99.5% (percentage by weight).
Embodiment 3, the high polymer emulsified asphalt and 10kg silicone acrylic emulsions for weighing 16kg, then pass through automatical feeding system It is added slowly to be loaded with the reactor of appropriate deionized water, and is sufficiently stirred, whipping temp is 60 degree, and stirring air pressure is 2.3Mpa, mixing time are 15 minutes, and the speed of stirring is 45 revs/min;
Then 20kg cement, 2.8kg binary vinyl chloride-vinyl acetate resin, 15kg silica flour, 6.9kg isopropyl sulfuric is weighed Ether, 0.6kg coalescents, 3.2%kg superfine alumina silicate polyalcohol and appropriate deionized water, and be sufficiently stirred, stirring temperature Spend for 40 degree, stirring air pressure is 3.3Mpa, and mixing time is 25 minutes, and the speed of stirring is 75 revs/min;
Membrane pump is finally started, obtained mixture is first passed through into 0.2um filters circulating filtration 3 hours, then through 0.12 μ M filter filtering, to remove the unwanted particles that particle diameter in mixture is more than 0.12 μm, produces aluminium film water system photoresistance stripper.
Wherein, the concentration of the high polymer emulsified asphalt is 89% (percentage by weight);The concentration of the silicone acrylic emulsion For 89% (percentage by weight);The concentration of the cement is 95% (percentage by weight);The concentration of the binary vinyl chloride-vinyl acetate resin is 98% (percentage by weight);The concentration of the silica flour is 95% (percentage by weight);The concentration of the superfine alumina silicate is 88% (percentage by weight);The concentration of the coalescents is 99.9% (percentage by weight);The superfine alumina silicate polyalcohol Concentration be 87% (percentage by weight).
Understood in Fig. 1 technique, the water-repellent paint of offer of the invention is by high polymer emulsified asphalt, cement, binary chlorine Vinegar resin, silica flour, superfine alumina silicate and superfine alumina silicate polyalcohol coordinate according to special ratios to be formed, and it has stronger anti- Water function, and ageing-resistant performance is excellent, bonding force is strong, material ductility is good, application property is good, material safety and environmental protection, nontoxic pair Effect.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.

Claims (9)

1. a kind of polymer cement waterproof paint, it is characterised in that include the composition of following percentage by weight:
2. a kind of polymer cement waterproof paint as claimed in claim 1, it is characterised in that including following percentage by weight Composition:
3. a kind of polymer cement waterproof paint as claimed in claim 1, it is characterised in that including following percentage by weight Composition:
4. a kind of polymer cement waterproof paint as claimed in claim 1, it is characterised in that including following percentage by weight Composition:
5. polymer cement waterproof paint as claimed in claim 1, it is characterised in that the high polymer emulsified asphalt it is dense Spend for 82~89% (percentage by weights);The concentration of the silicone acrylic emulsion is 72~89% (percentage by weights);The cement Concentration is 85~95% (percentage by weights);The concentration of the binary vinyl chloride-vinyl acetate resin is 90~98% (percentage by weights);It is described The concentration of silica flour is 85~95% (percentage by weights);The concentration of the superfine alumina silicate is 76~88% (weight percents Than);The concentration of the superfine alumina silicate polyalcohol is 79~87% (percentage by weights);The concentration of the coalescents is 98.8 ~99.9% (percentage by weight).
6. polymer cement waterproof paint as claimed in claim 5, it is characterised in that the high polymer emulsified asphalt it is dense Spend for 82% (percentage by weight);The concentration of the silicone acrylic emulsion is 79% (percentage by weight);The concentration of the cement is 85% (percentage by weight);The concentration of the binary vinyl chloride-vinyl acetate resin is 90% (percentage by weight);The concentration of the silica flour is 85% (percentage by weight);The concentration of the superfine alumina silicate is 76% (percentage by weight);The superfine alumina silicate polyalcohol Concentration be 79% (percentage by weight);The concentration of the coalescents is 98.8% (percentage by weight).
7. polymer cement waterproof paint as claimed in claim 5, it is characterised in that the high polymer emulsified asphalt it is dense Spend for 86% (percentage by weight);The concentration of the silicone acrylic emulsion is 82% (percentage by weight);The concentration of the cement is 90% (percentage by weight);The concentration of the binary vinyl chloride-vinyl acetate resin is 94% (percentage by weight);The concentration of the silica flour is 90% (percentage by weight);The concentration of the superfine alumina silicate is 82% (percentage by weight);The superfine alumina silicate polyalcohol Concentration be 82% (percentage by weight);The concentration of the coalescents is 99.5% (percentage by weight).
8. polymer cement waterproof paint as claimed in claim 5, it is characterised in that the high polymer emulsified asphalt it is dense Spend for 89% (percentage by weight);The concentration of the silicone acrylic emulsion is 89% (percentage by weight);The concentration of the cement is 95% (percentage by weight);The concentration of the binary vinyl chloride-vinyl acetate resin is 98% (percentage by weight);The concentration of the silica flour is 95% (percentage by weight);The concentration of the superfine alumina silicate is 88% (percentage by weight);The superfine alumina silicate polyalcohol Concentration be 87% (percentage by weight);The concentration of the coalescents is 99.9% (percentage by weight).
9. a kind of preparation method of polymer cement waterproof paint, it is characterised in that comprise the following steps:
Automatical feeding system is first passed through by high polymer emulsified asphalt and weight percent of the weight percentage for 10%~16% The silicone acrylic emulsion that content is 6%~10% is added slowly to be loaded with the reactor of deionized water, and is sufficiently stirred, and stirs Temperature is 60-70 degree, and stirring air pressure is 1.2-2.3Mpa, and mixing time is 10~15 minutes, the speed of stirring turns for 75-85/ Point;
It is 12%~20% cement, weight hundred to next proceed through automatical feeding system and slowly add weight percentage successively The dilute base n-butyl ether of second that binary vinyl chloride-vinyl acetate resin that point content is 1.2%~2.8%, weight percentage are 5%~15%, weight Coalescents that superfine alumina silicate that percentage composition is 2.5%~6.9%, weight percentage are 0.2%~0.6%, weight Superfine alumina silicate polyalcohol and the deionized water that percentage composition is 1.5%~3.2%, and be sufficiently stirred, whipping temp 30-40 Degree, stirring air pressure are 2.2-3.3Mpa, and mixing time is 15~25 minutes, and the speed of stirring is 55-75 revs/min;
Membrane pump is finally started, obtained mixture is first passed through into 0.2um filters circulating filtration 2~3 hours, then through 0.12 μm Filter filtering, to remove the unwanted particles that particle diameter in mixture is more than 0.12 μm, produce water-repellent paint.
CN201710638201.8A 2017-07-31 2017-07-31 A kind of polymer cement waterproof paint and preparation method thereof Pending CN107383958A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108034287A (en) * 2017-12-04 2018-05-15 佛山杰致信息科技有限公司 A kind of polymeric silicate cement waterproof paint and preparation method thereof
CN112409926A (en) * 2020-11-26 2021-02-26 丽天防水科技有限公司 Silicon modified asphalt rubber waterproof coating and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101220233A (en) * 2008-01-22 2008-07-16 武汉阳光建筑新材料有限公司 Emulsified acrylic acid modified asphalt cement group waterproof coating material and method for producing the same
CN106010058A (en) * 2016-06-30 2016-10-12 广西梧州龙鱼漆业有限公司 Superhigh-elasticity water-resistant paint and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101220233A (en) * 2008-01-22 2008-07-16 武汉阳光建筑新材料有限公司 Emulsified acrylic acid modified asphalt cement group waterproof coating material and method for producing the same
CN106010058A (en) * 2016-06-30 2016-10-12 广西梧州龙鱼漆业有限公司 Superhigh-elasticity water-resistant paint and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108034287A (en) * 2017-12-04 2018-05-15 佛山杰致信息科技有限公司 A kind of polymeric silicate cement waterproof paint and preparation method thereof
CN112409926A (en) * 2020-11-26 2021-02-26 丽天防水科技有限公司 Silicon modified asphalt rubber waterproof coating and preparation method and application thereof

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Application publication date: 20171124