Long-acting slow release type aluminum foil paper and preparation method thereof
Technical field
The invention belongs to the cigarette material technical field, relate to cigarette packaging material, particularly relate to a kind of long-acting slow release type aluminum foil paper and preparation method thereof.
Background technology
Cigarette package is an important component part of production of cigarettes, is last procedure of whole process of production.In the overall process of production of cigarettes, circulation and consumption, the quality of packaging material has important function to safeguarding cigarette product quality, promotion, consumption guidance.Relative other commodity have certain particularity to the requirement of cigarette packaging material, and for example: peculiar smell can not be arranged, and the reply human body is nontoxic, should possess certain moisture resistance and isolated property etc.
The cigarette aluminium-foil paper is to be combined with each other by adhesive by aluminium foil and interior lining paper, and its effect mainly is that the cigarette that is used for wrapping up in the cigarette case props up, and keep cigarette Zhi Suoxu the preservation environment, keep cigarette Zhi Shuifen, delay the cigarette flavor component and scatter and disappear.Along with improving constantly of the development of tobacco business, scientific and technological level, cigarette enterprise is had higher requirement to the use of aluminium-foil paper.How to utilize aluminium-foil paper directly to prop up the characteristics that contact, make it the cigarette Zhi Chixu real estate of packaging is given birth to effect,, become the focus of each cigarette enterprise research and development of present stage, but do not see as yet in the prior art that solution is well arranged to optimize the suction quality of cigarette with cigarette.
Summary of the invention
The objective of the invention is at the deficiencies in the prior art, a kind of long-acting slow release type aluminum foil paper is provided, utilize aluminium-foil paper directly to prop up the characteristics that contact, constantly cigarette is propped up the suction flavor and modify and improve with cigarette.
Another object of the present invention is to provide a kind of method for preparing described long-acting slow release type aluminum foil paper.
Purpose of the present invention is achieved by following technical proposals.
Except as otherwise noted, percentage of the present invention is percetage by weight.
A kind of long-acting slow release type aluminum foil paper comprises aluminium foil, interior lining paper and adhesive, it is characterized in that: its air permeability of lining paper is 10~30000CU in described, is added with cigarette property-modifying additive or fumet in described in lining paper surface or the adhesive.
The air permeability of lining paper is preferably 3000~10000CU in described.
Described cigarette property-modifying additive can be any known be used for the cigarette modification or commercially available prod that cigarette odor-absorbing is had facilitation.
Described fumet can be any known commercially available prod that is used for the cigarette flavouring.Wherein preferred by having the outstanding fragrance material of strong volatility and feature and cigarette being propped up the fumet that the suction flavor has the plant extracts of facilitation to be mixed and to form.
The described fragrance material that has than volatility and feature are outstanding by force is selected from the ketone monomer, aldehydes monomer, esters monomer, alcohols monomer, acids monomer, one or more in phenolic monomers and the essential oil series products.Described cigarette is propped up inhaled flavor and had the plant extracts of facilitation to be selected from tobacco extract, one or more in fruits and vegetables class extract and the Chinese herbal medicine extract.
Wherein, described tobacco extract is selected from a kind of in Yunnan tobacco, Zimbabwe tobacco, Brazilian tobacco, U.S. tobacco and the Turkish tobacco.Described fruits and vegetables class extract is selected from a kind of in tomato, date, strawberry, plum, mango, the pineapple.Described Chinese herbal medicine extract is selected from a kind of in Radix Glycyrrhizae, peppermint, cloves, pseudo-ginseng, the root of Dahurain angelica and the Radix Angelicae Sinensis.Described ketone monomer is selected from a kind of in damascenone, Megastigmatrienone, violet ketone, acetophenone, geranyl acetone and the oxidation isophorone.Described aldehydes monomer is selected from a kind of in furfural, vanillic aldehyde, benzaldehyde, phenylacetaldehyde and the citral.Described esters monomer is selected from a kind of in ethyl acetate, propyl ester ethyl ester, phenylethyl phenylacetate, benzyl acetate, gaultherolin and the ethyl palmitate.Described alcohols monomer is selected from a kind of in phenmethylol, geraniol, leaf-alcohol, menthol and the nerolidol.Described acids monomer is selected from a kind of in acetate, 3 Methylbutanoic acid, butyric acid, formic acid, propionic acid valeric acid, laurate and the myristic acid.Described phenolic monomers is selected from a kind of in eugenol, guaiacol, the chlorogenic acid.Described essential oil series products is selected from a kind of in stone forest tobacco essential oil, Rosa Damascana, clove oil, tree moss essential oil, peppermint essential oil and the refined jasmine oil.
A kind of preparation method of long-acting slow release type aluminum foil paper may further comprise the steps:
1, selecting air permeability is that the interior lining paper of 10~30000CU is standby;
2, described cigarette property-modifying additive or fumet are coated in the surface of lining paper, or add described cigarette property-modifying additive or fumet to existing aluminium-foil paper according to 0.01%~5% ratio and stick with glue in the agent;
3, with aluminium foil with ventilative in lining paper routinely technology carry out bondingly, after cutting, eliminating the unusual smell, obtain described long-acting slow release type aluminum foil paper.
Preparation has the interior lining paper method of described air permeability: adopt laser boring or static punch device, punch on the lining paper in common; Or in existing, in the lining paper production technology,, make the interior lining paper of required air permeability by regulating the consumption of filler.
The method for preparing described cigarette perfuming agent is inhaled various cigarette is propped up flavor and is had the plant extracts of facilitation to mix, and stirs 90min under 60 ℃ of conditions, and raw material is fully dissolved, and is cooled to 20~25 ℃ then; Have strong volatile various fragrance materials earlier with 95% ethanol dilution, add after being mixed with 1%~10% uniform solution; Barrelling behind the interpolation propylene glycol stirring 5min places lucifuge, shady and cool place, deposits and makes required fumet in 24~72 hours;
Compared with prior art, the present invention has the following advantages:
1, the present invention takes the lead in having realized that cigarette packaging material promotes the cigarette interior quality, for the molding product personal characteristics, highlight style, has opened up new method and approach.
2, the utilization of this technology, given full play to aluminium-foil paper and directly propped up the characteristics that contact with cigarette, in adhesive or interior lining paper surface add functional additive, use interior lining paper simultaneously with suitable air permeability, make the material of interpolation can continue to discharge fragrance matter between the warehouse-in storage life at cigarette, and prop up generation physics, chemical action with cigarette effectively, and promote the lifting of its interior quality, make the suction flavor pureer and milder, comfortable;
3, by adjusting the prescription of additive, can satisfy the design requirement of different product pointedly; By selecting the interior lining paper of different air permeabilities, can regulate the effect degree of fragrance matter easily according to the designing requirement of different product;
4, prepared cigarette perfuming agent can be covered the bad breath that has aluminium-foil paper itself now well;
5, this long-acting slow release type aluminum foil paper, one to two year the best use of time, the term of validity 3 years, and before the deadline, cigarette interior quality and the storage time relation of being proportionate; For the fragrant not enough cigarette product of old cigarette, by the storage of a period of time, can effectively improve and inhale flavor, the outstanding better pure and mild property of product;
6, adopt this long-acting slow release type aluminum foil paper after, than mill run open the bag fragrance on feature more outstanding, lasting is more lasting, can promote to aspirate the desire for consumer goods well;
7, this technology can be connected well with existing cigarette process and equipment, need not existing equipment is adjusted, and can realize producing.
The specific embodiment
Below in conjunction with embodiment and Application Example the present invention is described in further detail, but they are not limitation of the invention.
Embodiment 1
Preparation long-acting slow release type aluminum foil paper: aluminium foil grammes per square metre: 20 ± 5g/m
2, thickness: 0.006~0.008mm, interior lining paper grammes per square metre: 30~80g/m
2The target setting air permeability is 10CU, adopts laser drilling device, punches on the lining paper in common.Take by weighing Yunnan tobacco extract 10g, tomato extract 5g, licorice 5g, damascenone 1% solution 0.5g, furfural 0.2g, ethyl acetate 10% solution 3g, phenmethylol 0.5g, acetate 0.1g, eugenol 10% solution 5g, stone forest tobacco essential oil 1% solution 5g, propylene glycol 65.7g, 100g altogether.Stone forest tobacco essential oil, damascenone be with 95% ethanol dilution, is mixed with concentration and is 1% uniform solution.Ethyl acetate, eugenol are mixed with 10% uniform solution with 95% ethanol dilution.All the other raw materials are mixed the back under 60 ℃ of conditions, stir 90min, raw material is fully dissolved, be cooled to 20~25 ℃ then, add stone forest tobacco essential oil solution, damascenone solution, ethyl acetate solution, eugenol solution, barrelling behind the stirring 5min.Place lucifuge, shady and cool place, deposit and promptly obtained required fumet in 24~48 hours.The surface of lining paper in described cigarette perfuming agent is coated on, coating weight is 0.1%.With aluminium foil with ventilative in lining paper routinely technology fit, after cutting, eliminating the unusual smell, obtain described long-acting slow release type aluminum foil paper.This aluminium-foil paper is applied to red certain brand cigarette of group that converges, makes the storage of sample warehouse-in after 6 months, deliver the judging panel of group and carry out organoleptic quality relatively.Under the standard environment condition of group, the strictness of smokeing panel test is carried out in accordance with regulations, and has 19 judging panels and participates in.The statistics smoking result shows, uses this aluminium-foil paper can give the breath of Yunnan tobacco feature effectively, the outstanding cigarette personal characteristics of strengthening, and effect is more remarkable.This aluminium-foil paper stresses to be used for that feature is outstanding, the relatively poor cigarette product of fragrance matter.
Embodiment 2
Repeat embodiment 1, following difference is arranged: the target setting air permeability is 100CU, adopts the static punch device to punch on interior lining paper.The fumet raw material consists of Zimbabwe tobacco extract 10g, Fructus Jujubae extract 10g, peppermint oil 1% solution 0.2g, Megastigmatrienone 1% solution 0.2g, vanillic aldehyde 0.2g, ethyl propionate 10% solution 2g, geraniol 0.01g, 3 Methylbutanoic acid 0.05g, guaiacol 10% solution 5g, Rosa Damascana 1% solution 0.01g, propylene glycol 72.33g, 100g altogether.Wherein peppermint oil, Megastigmatrienone, ethyl propionate, guaiacol, Rosa Damascana are all used 95% ethanol dilution, add after being mixed with the uniform solution of described concentration.The statistics smoking result shows that this aluminium-foil paper can promote the pipe tobacco alcoholization effectively, and the old cigarette fragrance breath of outstanding cigarette stresses to be used for the cigarette product that pipe tobacco refines cycle deficiency, perfume quantity deficiency.
Embodiment 3
Repeat embodiment 1, following difference is arranged: the target setting air permeability is 1000CU, adopts the static punch device to punch on interior lining paper.The fumet raw material consists of Turkish tobacco extract 5g, Fragaia ananassa Duchesne extract 10g, caryophyllus oil 1% solution 2g, violet ketone 1% solution 0.5g, benzaldehyde 0.2g, phenylethyl phenylacetate 10% solution 3g, leaf-alcohol 1% solution 0.2g, butyric acid 10% solution 0.5g, chlorogenic acid 10% solution 2g, tree moss essential oil 1% solution 1g, propylene glycol 75.6g, 100g altogether.Wherein caryophyllus oil, violet ketone, phenylethyl phenylacetate, leaf-alcohol, butyric acid, chlorogenic acid, tree moss essential oil add after all becoming uniform solution with 95% ethanol dilution.The statistics smoking result shows that this aluminium-foil paper can be covered, remove cigarette effectively and give birth to blue foreign smell, improves aroma quality, stresses to be used for the assorted cigarette product that gas is heavier, fragrance matter is relatively poor.
Embodiment 4
Repeat embodiment 1, following difference is arranged: the target setting air permeability is 3000CU, the fumet raw material consists of U.S. tobacco extract 5g, plum extract 10g, pseudo-ginseng tincture 5g, acetophenone 1% solution 0.5g, citral 0.5g, ethyl palmitate 10% solution 2g, nerolidol 1% solution 0.5g, laurate 5g, eugenol 10% solution 5g, refined jasmine oil 1% solution 2g, propylene glycol 64.5g, 100g altogether.Wherein acetophenone, ethyl palmitate, nerolidol, eugenol, refined jasmine oil add after all becoming uniform solution with 95% ethanol dilution.The statistics smoking result shows that it is rich that this aluminium-foil paper can improve cigarette perfume (or spice) effectively, promotes and sucks comfortableness, stresses to be used for the cigarette product that fragrance is thiner, comfortableness is relatively poor.
Embodiment 5
Embodiment 1 gained fumet is mixed by 0.01% consumption and adhesive, and selecting air permeability for use is the interior lining paper of 3000CU.Resulting long-acting slow-release aluminium-foil paper is applied to red certain brand cigarette of group that converges, and makes the storage of sample warehouse-in after 6 months, delivers the judging panel of group and carries out organoleptic quality relatively.Under the standard environment condition of group, the strictness of smokeing panel test is carried out in accordance with regulations, and has 19 judging panels and participates in.The statistics smoking result shows that this aluminium-foil paper can be given the breath of Yunnan tobacco feature effectively, the outstanding cigarette personal characteristics of strengthening, and effect is more remarkable, stresses to be used for that feature is outstanding, the relatively poor cigarette product of fragrance matter.
Embodiment 6
Embodiment 2 gained fumet are mixed by 0.1% consumption and aluminium-foil paper adhesive, and selecting air permeability for use is the interior lining paper of 6000CU, and other is with embodiment 5.The statistics smoking result shows that this long-acting slow-release aluminium-foil paper can promote the pipe tobacco alcoholization effectively, and the old cigarette fragrance breath of outstanding cigarette stresses to be used for the cigarette product that pipe tobacco refines cycle deficiency, perfume quantity deficiency.
Embodiment 7
Embodiment 3 gained fumet are mixed by 1% consumption and aluminium-foil paper adhesive, and selecting air permeability for use is the interior lining paper of 10000CU, and other is with embodiment 5.The statistics smoking result shows that this aluminium-foil paper can be covered, remove cigarette effectively and give birth to blue foreign smell, improves aroma quality, stresses to be used for the assorted cigarette product that gas is heavier, fragrance matter is relatively poor.
Embodiment 8
Embodiment 4 gained fumet are mixed by 5% consumption and aluminium-foil paper adhesive, and selecting air permeability for use is the interior lining paper of 30000CU, and other is with embodiment 5.The statistics smoking result shows that it is rich that this aluminium-foil paper can improve cigarette perfume (or spice) effectively, promotes and sucks comfortableness, stresses to be used for the cigarette product that fragrance is thiner, comfortableness is relatively poor.
Application Example 1
1, sample design
(1) in adhesive for alfoils, mix 0.01% functional additive, use lining paper in the air permeability 40CU, be combined into the long-acting slow-release aluminium-foil paper after, carry out cigarette and prop up packing, sample number into spectrum a;
(2) mix 0.5% functional additive, use lining paper in the air permeability 2000CU, be combined into the long-acting slow-release aluminium-foil paper after, carry out cigarette and prop up packing, sample number into spectrum b;
(3) mix 2% functional additive, use lining paper in the air permeability 10000CU, be combined into the long-acting slow-release aluminium-foil paper after, carry out cigarette and prop up packing, sample number into spectrum c;
(4) mix 5% functional additive, use lining paper in the air permeability 30000CU, be combined into the long-acting slow-release aluminium-foil paper after, carry out cigarette and prop up packing, sample number into spectrum d.
Above-mentioned sample does not carry out big change to equipment in manufacturing process, equipment operation condition is good.
2, organoleptic quality relatively
With certain brand product is subjects, is undertaken by a red production technical standard that converges, and wherein sample a, b, c, d adopt long-acting slow release type aluminum foil paper.After warehouse-in stores 6 months, deliver the judging panel of group and carry out organoleptic quality relatively.Under the standard environment condition of group, the strictness of smokeing panel test is carried out in accordance with regulations, and has 19 judging panels and participates in.The statistics smoking result wherein has 17 judging panels to think that sample a, b, c, d will obviously be better than standard specimen, and wherein the effect of d sample is particularly remarkable, and 2 judging panels think that difference is not obvious.The statistical average score value the results are shown in Table 1:
Table 1 sample organoleptic quality score contrast table
Sample |
Gloss (5) |
Fragrance (32) |
Harmony (6) |
Assorted gas (12) |
Excitant (20) |
Pleasant impression (25) |
Add up to (100) |
Standard specimen |
?5 |
30.22 |
5.30 |
10.00 |
18.27 |
22.33 |
91.12 |
A |
?5 |
30.87 |
5.30 |
10.50 |
18.29 |
22.47 |
92.43 |
B |
?5 |
30.92 |
5.30 |
10.50 |
18.28 |
22.51 |
92.51 |
C |
?5 |
30.88 |
5.30 |
10.50 |
18.29 |
22.49 |
92.46 |
D |
?5 |
30.95 |
5.30 |
10.50 |
18.31 |
22.56 |
92.62 |