CN101210385A - Treating agent for synthetic fiber and method for treating synthetic fiber - Google Patents
Treating agent for synthetic fiber and method for treating synthetic fiber Download PDFInfo
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- CN101210385A CN101210385A CNA2007101608461A CN200710160846A CN101210385A CN 101210385 A CN101210385 A CN 101210385A CN A2007101608461 A CNA2007101608461 A CN A2007101608461A CN 200710160846 A CN200710160846 A CN 200710160846A CN 101210385 A CN101210385 A CN 101210385A
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Abstract
Provided are a treating agent and a treating method which can suppress the generation of yarn waving, fluff and tar in a yarn-making step and prevent the decrease of yarn strength even when the yarn is made under severe conditions of high temperature and high contact pressure, such as synthetic fibers for industrial materials. As the synthetic fiber treatment agent, a synthetic fiber treatment agent containing a lubricant, an emulsifier and an antistatic agent at a predetermined ratio and containing an isocyanuric acid derivative as at least a part of the lubricant at a predetermined ratio is used, the isocyanuric acid derivative is selected from 1 or more than 2 of a partial or complete ester compound of tris (hydroxymethyl) isocyanuric acid and an organic monocarboxylic acid, a partial or complete ester compound of tris (2-hydroxyethyl) isocyanuric acid and an organic monocarboxylic acid, a partial or complete ester compound of tris (2-hydroxypropyl) isocyanuric acid and an organic monocarboxylic acid, a partial or complete ester compound of bis (2-hydroxypropyl) isocyanuric acid and an organic monocarboxylic acid, a partial or complete ester compound of tris (2-carboxyethyl) isocyanuric acid and a monovalent aliphatic hydroxyl compound, and a partial or complete ester compound of bis (2-carboxyethyl) isocyanuric acid and a monovalent aliphatic hydroxyl compound.
Description
Technical field
The present invention relates to the processing method (hereinafter referred be processing method) of synthetic fiber with finishing agent (hereinafter referred is a finishing agent) and synthetic fiber.For synthetic fiber such as polyamide fiber or polyester fibers, it is important not producing fine hair etc. in its throwing step on these synthetic fiber.Wherein, be used for tire cord, band (ベ Le ト), flexible pipe (ホ one ス), safety belt (シ one ト ベ Le ト), airbag (エ ア one バ Star グ) etc., because the relation of such use requires high-intensity industrial materials (Chan Ye Capital material) use synthetic fiber, because throwing under the harsh conditions of high temperature and high contact pressure, in the throwing step, easily produce pendulum wire (yarn shakes れ), fine hair and tar ( one Le), silk intensity reduces as a result, is particular importance so do not produce above-mentioned pendulum wire, fine hair and tar.Therefore, for the finishing agent that is attached on the synthetic fiber,, thereby prevent the finishing agent that an intensity reduces even require these synthetic fiber under high temperature and high contact pressure, also can suppress the generation of above-mentioned pendulum wire, fine hair and tar during throwing.The present invention relates to finishing agent and processing method corresponding to above-mentioned requirements.
Background technology
Even in the past as under high temperature and high contact pressure, also giving flatness to synthetic fiber, the finishing agent of inhibition generation fine hair etc., proposed 1) contain alkylene oxide addition product with the ester compounds of polyalcohol and hydroxyl monocarboxylic acid serve as must composition pure composition, with with the maleic acid be carboxylic acid composition that must composition ester compounds finishing agent (for example, with reference to patent documentation 1), 2) comprise the carboxylic acid composition who constitutes by dicarboxylic acids that does not have hydroxyl or monocarboxylic acid, the finishing agent of the ester compounds of the pure composition that constitutes with alkylene oxide addition product by castor oil or rilanit special (for example, with reference to patent documentation 2), 3) comprise the glycol component that the atactic polymer by oxolane and alkylene oxide constitutes, with the finishing agent of the ester compounds of dicarboxylic acids composition or monocarboxylic acid composition (for example, with reference to patent documentation 3), 4) contain the finishing agent (for example, with reference to patent documentation 4) etc. of the compound that has the polytetramethylene glycol residue in the molecule.In addition, even as under high temperature and high contact pressure, also giving heat resistance to synthetic fiber, the finishing agent of the generation of inhibition tar etc., known 5) contain the polybasic esterification compound, the finishing agent of anion surfactant and two kinds of hindered phenol anti-oxidants (for example, with reference to patent documentation 5), 6) contain sulfur-bearing diester compounds such as thio-2 acid dialkyl, the finishing agent of phosphate compound and hindered phenol anti-oxidants (for example, with reference to patent documentation 6), 7) contain the polybasic esterification compound, ester compounds with thioether group, the secondary sulphonic acid ester, the finishing agent of organophosphorus compounds and hindered phenol anti-oxidants (for example, with reference to patent documentation 7), 8) contain sulfur-bearing diester compounds such as thio-2 acid dialkyl, the finishing agent of two kinds of hindered phenol anti-oxidants and phosphate slaine (for example, with reference to patent documentation 8), 9) finishing agent that contains polybasic esterification compound and hindered phenol anti-oxidants (for example, with reference to patent documentation 9), 10) contain the aromatic ester compound, the finishing agent of organic carboxyl acid and various antioxidants (for example, with reference to patent documentation 10) etc.
But, in these existing finishing agents,,, prevent that from there is obvious inadequate problem in the reduction aspect of an intensity suppressing to produce above-mentioned pendulum wire, fine hair and tar for the synthetic fiber that throwing obtains under exacting terms more in recent years.
[patent documentation 1] Japanese kokai publication sho 59-223368 communique
[patent documentation 2] Japanese kokai publication sho 63-50572 communique
[patent documentation 3] Japanese kokai publication sho 63-235576 communique
[patent documentation 4] Japanese kokai publication sho 59-59978 communique
[patent documentation 5] Japanese kokai publication sho 59-211680 communique
[patent documentation 6] Japanese kokai publication hei 7-216735 communique
[patent documentation 7] Japanese kokai publication hei 8-120563 communique
[patent documentation 8] Japanese kokai publication hei 10-325074 communique
[patent documentation 9] Japanese kokai publication hei 5-140870 communique
[patent documentation 10] TOHKEMY 2004-292961 communique
Summary of the invention
The objective of the invention is to, provide as industrial materials with synthetic fiber, even under the harsh conditions of high temperature and high contact pressure, during throwing, also can suppress the generation of pendulum wire, fine hair and tar in the throwing step, thereby prevent the finishing agent and the processing method of the reduction of an intensity.
The inventor studies in order to address the above problem, found that ratio with regulation contains lubricant (level and smooth drug), emulsifying agent and antistatic additive and contains specific isocyanuric acid derivative with the ratio of regulation is suitable as the finishing agent of at least a portion of lubricant, in addition, it is suitable making above-mentioned finishing agent be attached to the synthetic fiber filament strand that supplies to heat treatment step with the amount of stipulating.
Promptly, the present invention relates to a kind of finishing agent, it contains lubricant, emulsifying agent and antistatic additive, it is characterized in that, contain the antistatic additive of 0.1～10 quality % of the emulsifying agent of 21～94 quality % of lubricant, finishing agent total amount of 5～75 quality % of finishing agent total amount and finishing agent total amount, and the following isocyanuric acid derivative of 5～45 quality % that contains the finishing agent total amount is as at least a portion of lubricant.
Isocyanuric acid derivative: the partially or completely ester compounds that is selected from three (hydroxymethyl) isocyanuric acids and organic monocarboxylic acid, the partially or completely ester compounds of three (2-hydroxyethyl) isocyanuric acids and organic monocarboxylic acid, the partially or completely ester compounds of three (2-hydroxypropyl) isocyanuric acids and organic monocarboxylic acid, the partially or completely ester compounds of isocyanuric acid two (2-hydroxypropyl) (イ ソ シ ア ヌ Le acid PVC ス (2-ヒ De ロ キ シ プ ロ ピ Le)) and organic monocarboxylic acid, the partially or completely ester compounds of three (2-carboxy ethyl) isocyanuric acids and univalent aliphatic series hydroxy compounds, and in the partially or completely ester compounds of isocyanuric acid two (2-carboxy ethyl) (イ ソ シ ア ヌ Le acid PVC ス (2-カ Le ボ キ シ エ チ Le)) and univalent aliphatic series hydroxy compounds more than a kind or 2 kinds.
In addition, the present invention relates to processing method, it is characterized in that, the finishing agent that the invention described above is related to is attached to the synthetic fiber filament strand that supplies to heat treatment step with 0.1～3 quality %.
The specific embodiment
At first the finishing agent that the present invention relates to is described.The finishing agent that the present invention relates to contains lubricant, emulsifying agent and antistatic additive, contains specific isocyanuric acid derivative at least a portion as lubricant.
Isocyanuric acid derivative as the lubricant of the finishing agent that is used for the present invention relates to, can enumerate and be selected from 1) the partially or completely ester compounds of three (hydroxymethyl) isocyanuric acids and organic monocarboxylic acid, 2) the partially or completely ester compounds of three (2-hydroxyethyl) isocyanuric acids and organic monocarboxylic acid, 3) the partially or completely ester compounds of three (2-hydroxypropyl) isocyanuric acids and organic monocarboxylic acid, 4) the partially or completely ester compounds of isocyanuric acid two (2-hydroxypropyl) and organic monocarboxylic acid, 5) the partially or completely ester compounds of three (2-carboxy ethyl) isocyanuric acids and univalent aliphatic series hydroxy compounds, 6) in the partially or completely ester compounds of isocyanuric acid two (2-carboxy ethyl) and univalent aliphatic series hydroxy compounds more than a kind or 2 kinds, all be preferably complete ester compounds, wherein more preferably 2) complete ester compounds and 5) complete ester compounds.
In the isocyanuric acid derivative of the lubricant of the finishing agent that is used for the present invention relates to, organic monocarboxylic acid as its raw material, can enumerate 1) acetate, propionic acid, butyric acid, valeric acid, caproic acid, sad, capric acid, hendecanoic acid, dodecylic acid, tridecanoic acid, tetradecanoic acid, pentadecanoic acid, palmitic acid, stearic acid, palmitoleic acid, oleic acid, isooctyl acid, isohexadecane acid, carbon numbers such as isostearic acid are 2～22 aliphatic monocarboxylic acid, 2) benzoic acid, 3,5-two (1, the 1-dimethyl ethyl)-aromatic monocarboxylates such as 4-hydroxy phenylpropionic acid, 3) malonic acid, maleic acid, itaconic acid, adipic acid, decanedioic acid, carbon numbers such as ten pentaene base butanedioic acids are 3～22 the aliphatic dicarboxylic acid and the aliphatic monoesters monocarboxylic acid of univalent aliphatic series hydroxy compounds, 4) phthalic acid, M-phthalic acid, carbon numbers such as terephthalic acid (TPA) are 8～22 the aromatic binary carboxylic acid and the aliphatic monoesters list aromatic carboxylic acid of univalent aliphatic series hydroxy compounds, 5) thio-2 acid, sulfo-two is sad, sulfo-two laurate, carbon numbers such as sulfo-distearyl acid are 3～22 sulfur-bearing aliphatic dicarboxylic acid and sulfur-bearing aliphatic monoesters monocarboxylic acid of univalent aliphatic series hydroxy compounds etc., wherein, preferred carbon number is 2～22 aliphatic monocarboxylic acid, and more preferably carbon number is 3～18 aliphatic monocarboxylic acid.
In addition, in the isocyanuric acid derivative of the lubricant of the finishing agent that is used for the present invention relates to, univalent aliphatic series hydroxy compounds as its raw material, can enumerate 1) butanols, amylalcohol, hexanol, enanthol, octanol, nonyl alcohol, decyl alcohol, tip-nip, dodecanol, tridecanol, 2-methyl-amylalcohol, 2-ethyl-hexanol, 2-propyl group-enanthol, carbon numbers such as 2-butyl-octanol are 1～26 aliphatic monobasic alcohol, 2) 1, the 4-butanediol, 1, the 6-hexylene glycol, neopentyl glycol, glycerine, trimethylolpropane, aliphatic monoesters monohydric alcohol of aliphatic polyols such as anhydro sorbitol and organic monocarboxylic acid etc., wherein, preferred carbon number is 1～26 aliphatic monobasic alcohol, and more preferably carbon number is 4～18 aliphatic monobasic alcohol.
The isocyanuric acid derivative of the lubricant of the finishing agent that is used for the present invention relates to can be synthetic with any known method.For example, the partially or completely ester compounds of three (hydroxymethyl) isocyanuric acids and organic monocarboxylic acid can followingly synthesize: with respect to 1 mole of pure composition three (hydroxymethyl) isocyanuric acid, use 3～5 moles of organic monocarboxylic acids, add acid compounds such as sulfuric acid, while heating the esterification of dewatering, or add alkali compounds such as pyridine, in atent solvents such as chloroform, carry out esterification while heat, synthesize above-claimed cpd thus.The partially or completely ester compounds of three (2-hydroxyethyl) isocyanuric acids and organic monocarboxylic acid, except using three (2-hydroxyethyl) isocyanuric acid, can use the method identical synthetic with the partially or completely ester compounds of above-mentioned three (hydroxymethyl) isocyanuric acids and organic monocarboxylic acid as the pure composition.The partially or completely ester compounds of the partially or completely ester compounds of three (2-hydroxypropyl) isocyanuric acids and organic monocarboxylic acid and isocyanuric acid two (2-hydroxypropyl) and organic monocarboxylic acid also can be synthetic with identical method.
In addition, for example, the partially or completely ester compounds of three (2-carboxy ethyl) isocyanuric acids and univalent aliphatic series hydroxy compounds can followingly synthesize: with respect to 1 mole of sour composition three (2-carboxy ethyl) isocyanuric acid, use 3～5 moles of univalent aliphatic series hydroxy compounds, add acid compound such as sulfuric acid, while heating the esterification of dewatering, or add alkali compounds such as pyridine, in atent solvents such as chloroform, carry out esterification while heat, synthesize above-claimed cpd thus.The partially or completely ester compounds of isocyanuric acid two (2-carboxy ethyl) and univalent aliphatic series hydroxy compounds, except using isocyanuric acid two (2-carboxy ethyl), can use the method identical synthetic with the partially or completely ester compounds of above-mentioned three (2-carboxy ethyl) isocyanuric acids and univalent aliphatic series hydroxy compounds as the sour composition.
As the lubricant outside the isocyanuric acid derivative that is used for finishing agent of the present invention, can enumerate organic esterified compound, mineral oil, polyethers, silicone compounds etc., be preferably organic esterified compound, wherein, be preferably aliphatic ester compound, aromatic ester compound and vegetable and animals oils lipid.As above-mentioned aliphatic ester compound, can enumerate 1) the octyl group stearate, the oil base laurate, the ester compounds of 1 yuan of alcohols and fatty monocarboxylic acids of aliphatic such as oil base oleate, 2) 1,6-hexylene glycol dicaprate, the complete ester compounds of aliphatic polyols such as trimethylolpropane monoleate dilaurate and aliphatic monocarboxylic acid, 3) dilauryl adipate ester, two oil base azelates, complete ester compounds of aliphatic monobasic alcohols such as trioctylphosphine trimellitate and aliphatic polybasic carboxylic acid etc., in addition, as the aromatic ester compound, can enumerate 4) the benzyl stearate, the ester compounds of aromatic series monohydric alcohols such as benzyl laurate and aliphatic monocarboxylic acid, 5) the complete ester compounds of aromatic polyol such as bisphenol-A dilaurate and aliphatic monocarboxylic acid, 6) two iso stearyl isophthalic acid esters, complete ester compounds of aliphatic monobasic alcohols such as trioctylphosphine trimellitate and aromatic series polybasic carboxylic acid etc., further, as vegetable and animals oils lipid, can enumerate 7) coconut oil, rapeseed oil, sunflower oil, soybean oil, castor oil, sesame oil, fish oil, tallow etc.Wherein, be preferably complete ester compounds, aliphatic monobasic alcohol and the binary of complete ester compounds, binary or ternary aromatic polyol and aliphatic monocarboxylic acid of complete ester compounds, aliphatic monobasic alcohol and the binary of binary or ternary aliphatic family polyalcohol and aliphatic monocarboxylic acid or ternary aliphatic family polybasic carboxylic acid or the complete ester compounds and the grease class of ternary aromatic series polybasic carboxylic acid.
As the emulsifying agent that is used for finishing agent of the present invention, can enumerate various non-ionic surface active agents.As above-mentioned non-ionic surface active agent, can enumerate 1) the polyoxyalkylene Octyl Ether, polyoxyalkylene Octyl Ether laurate, the polyoxyalkylene nonylplenyl ether, the polyoxyalkylene oleate, polyoxyalkylene lauryl amino ethers, the ether type non-ionic surface active agent that has polyoxy alkylidene in the polyoxyalkylene lauroyl amidogen ether equimolecular, 2) Arlacel-20, sorbitan trioleate, D-sorbite four oleates, glycerin mono-fatty acid ester, glyceryl monolaurate, polyol moiety ester type non-ionic surface active agents such as two dilaurins, 3) polyoxyalkylene sorbitan trioleate, the polyoxyalkylene glyceryl monolaurate, polyoxyalkylene bisphenol-A dilaurate, the polyoxyalkylene castor oil, the polyoxyalkylene rilanit special, polyoxyalkylene rilanit special dilaurate, polyoxyalkylene polyol fatty acid ester type non-ionic surface active agents such as polyoxyalkylene rilanit special three caprylates, 4) diethanol amine list lauramide, diethanol amine list oleamide, acid amide type non-ionic surface active agents such as diethylenetriamines dioctyl acid amides, 5) polyoxyethylene diethanol amine list oil base acid amides, polyoxyalkylene fatty acid amide type non-ionic surface active agents such as polyoxyethylene diethylenetriamines dilauryl acid amides etc.Wherein, be preferably polyol moiety ester type non-ionic surface active agent, polyoxyalkylene polyol fatty acid ester type non-ionic surface active agent, this polyalcohol is selected from glycerine, castor oil, rilanit special, anhydro sorbitol and D-sorbite, more preferably glycerine part ester, anhydro sorbitol part ester, D-sorbite part ester, polyoxyalkylene Isosorbide Dinitrate, polyoxyalkylene sorbitol ester, polyoxyalkylene castor oil, polyoxyalkylene rilanit special, polyoxyalkylene rilanit special Arrcostab.
As the antistatic additive that is used for finishing agent of the present invention, can enumerate various arbitrarily anion surfactants, cationic surfactant, amphoteric surfactant etc.Wherein, be preferably anion surfactant, as above-mentioned anion surfactant, can enumerate 1) the tridecyl sodium sulfonate, organic sulfonates such as neopelex, 2) organo-sulfate salt such as polyoxyethylene lauryl sulfate ester sodium, 3) octyl phosphate sodium salt, polyoxyethylene Tryfac 5573 sylvite, oil base phosphate triethanolamine salt, polyoxyethylene Tryfac 5573-organophosphorus ester salt such as polyoxyethylene lauryl amine salt, 4) potassium octanoate, enuatrol, organic fatty hydrochlorates such as alkenyl succinic acid potassium etc., wherein, be preferably organophosphorus ester salt, more preferably be selected from carbon number and be 4～26 aliphatic list or dialkyl phosphate slaine, carbon number is 4～26 polyoxyalkylene aliphatic list or dialkyl phosphate slaine, carbon number be 4～26 aliphatic list or dialkyl phosphate organic amine salt and carbon number be in 4～26 polyoxyalkylene aliphatic list or the dialkyl phosphate organic amine salt more than a kind or 2 kinds.
The finishing agent that the present invention relates to comprises the above-mentioned lubricant that contains the isocyanuric acid derivative, emulsifying agent and antistatic additive, the content of isocyanuric acid derivative is 5～45 quality % of finishing agent total amount, be preferably 7～35 quality % of finishing agent total amount, 9～27 quality % of finishing agent total amount more preferably, the content that contains the lubricant of above-mentioned isocyanuric acid derivative is 5～75 quality % of finishing agent total amount, be preferably 7～75 quality % of finishing agent total amount, 9～75 quality % of finishing agent total amount more preferably, the content of emulsifying agent is 21～94 quality % of finishing agent total amount, be preferably 40～85 quality % of finishing agent total amount, 49～80 quality % of finishing agent total amount more preferably, antistatic additive is 0.1～10 quality % of finishing agent total amount, be preferably 0.3～6 quality % of finishing agent total amount, 0.4～4 quality % of finishing agent total amount more preferably.
When making the finishing agent that the present invention relates to be attached to synthetic fiber, can be with the finishing agent that the present invention relates to, according to purpose and with other composition, for example, outward appearance is adjusted agent, antioxidant, heat resistance improving agent, defoamer, preservative agent, rust inhibitor etc., and also consumption is the least possible for it.
Then the processing method that the present invention relates to is described.In the processing method that the present invention relates to, the finishing agent that the invention described above is related to is attached to the synthetic fiber filament strand that supplies to heat treatment step with 0.1～3 quality %, preferred 0.5～1.5 quality %.As making the finishing agent that the present invention relates to be attached to step on the synthetic fiber, can enumerate spinning step, stretching step, carry out the step etc. of spinning and stretching simultaneously.In addition, as making the finishing agent that the present invention relates to be attached to method on the synthetic fiber, can enumerate oil process on the roller, use on the deflector roll of measuring pump on oil process, the dipping in oil process, the spraying oil process etc.Further as making the finishing agent that the present invention relates to be attached to mode on the synthetic fiber, can enumerate water-based liquid (water-based liquid), organic solvent solution, pure material (ニ one ト) etc., be preferably water-based liquid, 5～30 quality % water-based liquid of the finishing agent that more preferably the present invention relates to.When adhering to the water-based liquid of the finishing agent that the present invention relates to,, adhere to finishing agent 0.1～3 quality % that the present invention relates to, preferred 0.5～1.5 quality % for the synthetic fiber filament strand that supplies to heat treatment step.
Synthetic fiber as the applicable object of the processing method that the present invention relates to, can enumerate 1) polyethylene terephthalate, polytrimethylene terephthalate, polyester fibers such as poly-lactic acid ester, 2) nylon 6, polyamide-based fibers such as nylon 66,3) polyacrylic acid, modacrylic polyacrylic acid fibrids such as (モ ダ ア Network リ Le), 4) polyethylene, TPO fibers such as polypropylene, 5) polyurethanes fiber etc., its kind or purposes are not added qualification, but be applicable to when industrial materials under the harsh conditions that are in high temperature and high contact pressure in the throwing step are used synthetic fiber, the effect height that shows, the effect height that shows when wherein, especially being applicable to polyester fiber or polyamide fiber.
More than among Shuo Ming the present invention, have as industrial materials with synthetic fiber, even under the harsh conditions of high temperature and high contact pressure, during throwing, also can suppress the generation of pendulum wire, fine hair and tar in the throwing step, thereby prevent the effect that an intensity reduces.
Though hereinafter for structure of the present invention and effect are carried out specific description and enumerated embodiment, the present invention is not limited by these embodiment.And among hereinafter the embodiment and comparative example, part refers to parts by mass, % refers to quality %.
[embodiment]
Test classification 1 (preparation of finishing agent)
The preparation of embodiment 1{ finishing agent (P-1) }
10 parts in following isocyanuric acid derivative (K-1), 20 parts of following lubricants (L-1), 10 parts of following lubricants (L-2), 50 parts of following emulsifying agents (E-1), 10 parts of following emulsifying agents (E-2), following antistatic additive (S-3) are evenly mixed the finishing agent (P-1) of preparation embodiment 1 for 1 part.
Isocyanuric acid derivative (K-1): three (2-hydroxyethyl) isocyanuric acid tripropionate
Lubricant (L-1): two oil base thiodipropionates
Lubricant (L-2): bisphenol-A dilaurate
Emulsifying agent (E-1): the polyoxyalkylene aliphatic polybasic esterification compound that obtains with respect to 20 moles of rilanit special 1 moles of added ethylene oxide (hereinafter referred is EO).
Emulsifying agent (E-2): the ester compounds that 1 mole of polyoxyalkylene castor oil that obtains with respect to castor oil 1 mole of addition EO40 mole and capric acid are 3 moles.
Antistatic additive (S-3): oil base phosphate triethanolamine salt
The preparation of embodiment 2～68 and comparative example 1～17{ finishing agent (P-2)～(P-68) and finishing agent (R-1)～(R-17) }
Similarly operate preparation finishing agent (P-2)～(P-68) and finishing agent (R-1)～(R-17) with finishing agent (P-1).The content of employed composition is shown in table 1～table 5 in the preparation of above-mentioned each routine finishing agent, and the content of the finishing agent of above-mentioned in addition each example preparation is shown in table 6～table 14.
[table 1]
| The isocyanuric acid derivative | |
| Kind | The compound title |
| K-1 | Three (2-hydroxyethyl) isocyanuric acid tripropionate |
| K-2 | Three (2-hydroxyethyl) isocyanuric acid trioleate |
| K-3 | Trioctylphosphine three (2-carboxy ethyl) isocyanuric acid ester |
| K-4 | Three oil bases three (2-carboxy ethyl) isocyanuric acid ester |
| K-5 | Three (hydroxymethyl) isocyanuric acid trilaurin |
| K-6 | Three (2-hydroxypropyl) isocyanuric acid, three decylates |
| K-7 | Isocyanuric acid two (2-hydroxypropyl) three decylates |
| K-8 | Three (2-hydroxyethyl) isocyanuric acid, three single octylsulfo dipropionates |
| K-9 | Didecyl isocyanuric acid two (2-carboxy ethyl) |
| K-10 | Three monomethyl polyethylene glycol three (2-carboxy ethyl) isocyanuric acid ester |
| K-11 | Three (2-hydroxyethyl) isocyanuric acid dioleate |
| K-12 | Three (2-hydroxyethyl) isocyanuric acid monoleate |
| K-13 | Two oil bases three (2-carboxy ethyl) isocyanuric acid ester |
| K-14 | Single oil base three (2-carboxy ethyl) isocyanuric acid ester |
[table 2]
| Lubricant outside the isocyanuric acid derivative | |
| Kind | The compound title |
| L-1 | Two oil base thiodipropionates |
| L-2 | The bisphenol-A dilaurate |
| L-3 | Trioctyl trimellitate (TOTM) |
| L-4 | Rapeseed oil |
| L-5 | The oil base oleate |
| L-6 | Pentaerythrite four pelargonates |
| L-7 | 30 ℃ viscosity is 3.2 * 10 -5m 2The mineral oil of/s |
[table 3]
| Emulsifying agent | |
| Kind | The compound title |
| E-1 | The polyoxyalkylene aliphatic polybasic esterification compound that obtains with respect to rilanit special 1 mole of addition EO20 mole |
| E-2 | The ester compounds that 1 mole of polyoxyalkylene castor oil that obtains with respect to castor oil 1 mole of addition EO40 mole and capric acid are 3 moles |
| E-3 | Addition EO25 mole on 1 mole of D-sorbite four oleate and the polyoxyethylene polyols partial esterification compound that obtains |
| E-4 | The ester compounds that 1 mole of 2 moles of polyoxyalkylene rilanit specials, maleic acid that obtains with respect to rilanit special 1 mole of addition EO20 mole and stearic acid are 3 moles |
| E-5 | Sorbitan trioleate |
| E-6 | Diolein |
| E-7 | Addition EO14 mole on 1 mole of Arlacel-80 and the polyoxyethylene polyols partial esterification compound that obtains |
| E-8 | Addition EO8 mole on 1 mole of octanol and the ether monohydric alcohol that obtains |
| E-9 | On ethylene glycol with the ratio of 50/50 (mass ratio) random shape addition EO and PO and the PTMEG (number-average molecular weight is 1400) that obtains |
| E-10 | Addition EO10 mole on 1 mole of oleyl alcohol and the ether monohydric alcohol that obtains |
| E-11 | The ester compounds that 1 mole of polyoxyethylene addition product of the bisphenol-A that obtains with respect to bisphenol-A 1 mole of addition EO4 mole and laurate are 2 moles |
| E-12 | With respect to 1, the ester compounds that 6-hexylene glycol 1 mole of addition EO10 mole and 1 mole of the polyoxyethylene addition product that obtains and laurate are 2 moles |
| E-13 | Diethanol amine list oleamide |
| E-14 | The EO15 mole addition product of diethanol amine list oleamide |
| E-15 | Addition EO7 mole on 1 mole of nonyl phenol and the ether monohydric alcohol that obtains |
In the table 3, the number-average molecular weight of compound is the value of the HLC-8120GPC mensuration of producing with eastern ソ one Co., Ltd..
[table 4]
| Antistatic additive | |
| Kind | The compound title |
| S-1 | Polyoxyethylene (EO=3) Tryfac 5573 sylvite |
| S-2 | Polyoxyethylene (EO=6) oil base phosphate diethanolamine salt |
| S-3 | Oil base phosphate triethanolamine salt |
| S-4 | The oil base phosphoric acid ester sodium |
| S-5 | Three decyl sodium sulfonates |
| S-6 | The dodecenyl succinic potassium succinate |
| S-7 | 2-heptadecene base-hydroxyethyl imidazoles ethyl-sulfate (2-ヘ プ デ セ ニ Le-ヒ De ロ キ シ エ チ Le イ ミ ダ ゾ リ ウ system エ ト サ Le Off エ one ト) |
| S-8 | The octyldimethyl ammonium acetate |
[table 5]
| Using ingredient | |
| Kind | The compound title |
| T-1 | Oleyl alcohol |
| T-2 | Ethylene glycol |
| T-3 | 2,2 '-methylene two (4-methyl-6-tert butyl phenol) |
| T-4 | The polyoxyethylene modified siloxane |
| T-5 | Stearic acid |
[table 6]
| Classification | Embodiment | ||||||||||
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | ||
| Kind | P-1 | P-2 | P-3 | P-4 | P-5 | P-6 | P-7 | P-8 | P-9 | P-10 | |
| The isocyanuric acid derivative | K-1 K-2 K-3 K-4 K-5 K-6 K-7 K-8 K-9 K-10 K-11 K-12 K-13 K-14 | 10 | 24.5 | 24.5 | 20 | 14 | 15 | 18 | 7 | 30 | 10 |
| Other lubricant | L-1 L-2 L-3 L-4 L-5 L-6 L-7 | 20 9 | 5 | 9.5 15 | 5 20 | 15 | 10 15 | 18 10 10 | 5 5 | 15 12 10 | |
| Emulsifying agent | E-1 E-2 E-3 E-4 E-5 E-6 E-7 E-8 E-9 E-10 E-11 E-12 E-13 E-14 E-15 | 50 10 | 10 14 32 14 5 | 14 10 26 6 14 | 20 7 13 15 | 25 3 10 6 10 6 | 30 8 6 14 10 | 20 5 10 20 | 20 16 8 10 | 20 5 10 14 10 | 20 4 18 10 |
| Antistatic additive | S-1 S-2 S-3 S-4 S-5 S-6 S-7 S-8 | 1 | 0.5 | 0.5 | 0.5 | 1 | 2 | 2 | 1 | 1 | 1 |
| Using ingredient | T1 T2 T3 T4 T-5 | ||||||||||
[table 7]
| Classification | Embodiment | ||||||||||
| 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 | 20 | ||
| Kind | P-11 | P-12 | P-13 | P-14 | P-15 | P-16 | P-17 | P-18 | P-19 | P-20 | |
| The isocyanuric acid derivative | K-1 K-2 K-3 K-4 K-5 K-6 K-7 K-8 K-9 K-10 K-11 K-12 K-13 K-14 | 24 | 10 | 27 | 17 | 24 | 20 | 22 | 20 | 14 6 | 8 12 |
| Other lubricant | L-1 L-2 L-3 L-4 L-5 L-6 L-7 | 9 20 | 20 8 6 10 | 10 30 | 10 36 | 17 6 | 10 17 | 10 15 | 12 20 | 20 12 | 8 12 12 |
| Emulsifying agent | E-1 E-2 E-3 E-4 E-5 E-6 E-7 E-8 E-9 E-10 E-11 E-12 E-13 E-14 E-15 | 20 6 16 | 14 17 14 | 13 10 8 | 8 10 12 | 20 5 10 6 10 | 15 10 10 6 10 | 15 10 16 10 | 10 10 10 10 5 | 10 15 10 10 | 13 6 10 10 7 |
| Antistatic additive | S-1 S-2 S-3 S-4 S-5 S-6 S-7 S-8 | 4 1 | 1 | 2 | 3 4 | 2 | 1 1 | 2 | 1 1 1 | 1 1 1 | 1 1 |
| Using ingredient | T-1 T-2 T-3 T-4 T-5 | 1 | 2 | ||||||||
[table 8]
| Classification | Embodiment | ||||||||||
| 21 | 22 | 23 | 24 | 25 | 26 | 27 | 28 | 29 | 30 | ||
| Kind | P-21 | P-22 | P-23 | P-24 | P-25 | P-26 | P-27 | P-28 | P-29 | P-30 | |
| The isocyanuric acid derivative | K-1 K-2 K-3 K-4 K-5 K-6 K-7 K-8 K-9 K-10 K-11 K-12 K-13 K-14 | 10 12 | 20 | 16 | 10 | 10 | 17.8 | 24 | 16 8 | 14 6 | 10 4 |
| Other lubricant | L-1 L-2 L-3 L-4 L-5 L-6 L-7 | 22 10 | 20 4 10 | 8 14 10 | 34 10 | 20 12 12 | 20 6 20 | 23 | 10 18 | 24 16 | |
| Emulsifying agent | E-1 E-2 E-3 E-4 E-5 E-6 E-7 E-8 E-9 E-10 E-11 E-12 E-13 E-14 E-15 | 20 15 10 | 10 10 10 10 5 | 20 2 12 14 | 16 16 12 | 20 10 14 | 16 6 14 | 20 10 15 6 | 20 10 18 20 6 | 20 30 | 20 2 12 10 |
| Antistatic additive | S-1 S-2 S-3 S-4 S-5 S-6 S-7 S-8 | 1 | 1 | 1 2 1 | 2 | 1 1 | 0.2 | 2 | 1 1 | 2 | 2 |
| Using ingredient | T-1 T-2 T-3 T-4 T-5 | 1 | 0.5 | ||||||||
[table 9]
| Classification | Embodiment | ||||||||||
| 31 | 32 | 33 | 34 | 35 | 36 | 37 | 38 | 39 | 40 | ||
| Kind | P-31 | P-32 | P-33 | P-34 | P-35 | P-36 | P-37 | P-38 | P-39 | P-40 | |
| The isocyanuric acid derivative | K-1 K-2 K-3 K-4 K-5 K-6 K-7 K-8 K-9 K-10 K-11 K-12 K-13 K-14 | 15.9 | 6 6 | 12 | 8 8 | 10 4 | 12 | 10 4 | 6 6 | 10.9 5 | 15.9 |
| Other lubricant | L-1 L-2 L-3 L-4 L-5 L-6 L-7 | 45 | 5 20 13 | 10 23 5 | 5 33 | 5 5 30 | 4 12 16 | 16 18 | 8 30 | 10 20 15 | 16 20 10 |
| Emulsifying agent | E-1 E-2 E-3 E-4 E-5 E-6 E-7 E-8 E-9 E-10 E-11 E-12 E-13 E-14 E-15 | 19 10 10 | 12 6 11 14 5 | 5 4 12 13 14 | 10 10 10 10 4 | 12 8 8 8 8 | 14 4 16 20 | 14 4 10 12 6 | 10 10 14 14 | 10 10 14 5 | 18 4 6 6 4 |
| Antistatic additive | S-1 S-2 S-3 S-4 S-5 S-6 S-7 S-8 | 0.1 | 1 1 | 1 1 | 1 1 | 1 1 | 1 1 | 6 | 2 | 0.1 | 0.1 |
| Using ingredient | T-1 T-2 T-3 T-4 T-5 | ||||||||||
[table 10]
| Classification | Embodiment | ||||||||||
| 41 | 42 | 43 | 44 | 45 | 46 | 47 | 48 | 49 | 50 | ||
| Kind | P-41 | P-42 | P-43 | P-44 | P-45 | P-46 | P-47 | P-48 | P-49 | P-50 | |
| The isocyanuric acid derivative | K-1 K-2 K-3 K-4 K-5 K-6 K-7 K-8 K-9 K-10 K-11 K-12 K-13 K-14 | 10.9 5 | 6 | 41 | 9 | 10 17 | 9 | 10 5 | 8 | 20 10 6 8 | 6 |
| Other lubricant | L-1 L-2 L-3 L-4 L-5 L-6 I-7 | 46 | 14 15 | 6 | 20 7 14 | 15 10 5 | 4 | 10 6 | 2 | 2 | 10 3 30 |
| Emulsifying agent | E-1 E-2 E-3 E-4 E-5 E-6 E-7 E-8 E-9 E-10 E-11 E-12 E-13 E-14 E-15 | 18 20 | 25 10 10 8 10 | 25 5 6 16 | 20 7 8 14 | 18 15 6 | 25 5 10 20 10 16 | 20 10 5 16 10 | 20 14 20 10 20 | 15 16 17 | 15 12 14 5 |
| Antistatic additive | S-1 S-2 S-8 S-4 S-5 S-6 S-7 S-8 | 0.1 | 2 | 2 | 1 | 2 1 1 | 1 | 3 8 2 1 | 4 1 1 | 4 1 1 | 1 4 |
| Using ingredient | T-1 T-2 T-3 T-4 T-5 | 0.5 | |||||||||
[table 11]
| Classification | Embodiment | ||||||||||
| 51 | 52 | 53 | 54 | 55 | 56 | 57 | 58 | 59 | 60 | ||
| Kind | P-51 | P-52 | P-53 | P-54 | P-55 | P-56 | P-57 | P-58 | P-59 | P-60 | |
| The isocyanuric acid derivative | K-1 K-2 K-3 K-4 K-5 K-6 K-7 K-8 K-9 K-10 K-11 K-12 K-13 K-14 | 6 | 5 | 12 | 27.6 | 16.9 20 | 15 10 | 8 | 5 | 12 | 25 |
| Other lubricant | L-1 L-2 L-3 L-4 L-5 L-6 L-7 | 20 33 | 10 30 17 | 6 20 | 6 11 14 | 5 21 15 | 20 | 2 | 60 | 8 5 13 | 20 |
| Emulsifying agent | E-1 E-2 E-3 E-4 E-5 E-6 E-7 E-8 E-9 E-10 E-11 E-12 E-13 E-14 E-15 | 15 10 10 | 25 6 | 15 5 15 5 20 | 12 6 1 4 7 2 | 22 | 11 16 25 | 14 20 20 30 | 28 | 25 10 6 20 | 11 16 10 14 |
| Antistatic additive | S-1 S-2 S-3 S-4 S-5 S-6 S-7 S-8 | 1 2 1 2 | 2 2 3 | 1 1 | 0.4 | 0.1 | 3 | 2 4 | 7 | 1 | 4 |
| Using ingredient | T-1 T-2 T-3 T-4 T-5 | 0.5 | |||||||||
[table 12]
| Classification | Embodiment | ||||||||
| 61 | 62 | 63 | 64 | 65 | 66 | 67 | 68 | ||
| Kind | P-61 | P-62 | P-63 | P-64 | P-65 | P-66 | P-67 | P-68 | |
| The isocyanuric acid derivative | K-1 K-2 K-3 K-4 K-5 K-6 K-7 K-8 K-9 K-10 K-11 K-12 K-13 K-14 | 8 | 5 | 14 | 20 | 10 15 | 14 | 18 | 10 15 |
| Other lubricant | L-1 L-2 L-3 L-4 L-5 L-6 L-7 | 2 | 57 | 20 4 | 15 10 | 8 12 | 10 16 | 22 | 20 |
| Emulsifying agent | E-1 E-2 E-3 E-4 E-5 E-6 E-7 E-8 E-9 E-10 E-11 E-12 E-13 E-14 E-15 | 20 14 50 | 20 11 | 14 6 8 30 | 26 12 10 5 | 22 10 O 5 10 | 16 14 12 16 | 20 16 12 10 | 10 10 14 20 |
| Antistatic additive | S-1 S-2 S-3 S-4 S-5 S-6 S-7 S-8 | 3 2 1 | 7 | 1 1 2 | 2 1 | 2 1 | 2 | 2 | 1 |
| Using ingredient | T-1 T-2 T-3 T-4 T-5 | ||||||||
[table 13]
| Classification | Comparative example | ||||||||||
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | ||
| Kind | R-1 | R-2 | R-8 | R-4 | R-5 | R-6 | R-7 | R-8 | R-9 | R-10 | |
| The isocyanuric acid derivative | K-1 K-2 K-3 K-4 K-5 K-6 K-7 K-8 K-9 K-10 K-11 K-12 K-13 K-14 | 30 20 | 6.5 | 20 12 10 | 2.4 | 16 | 14 | 45 | 20 25 | 30 | |
| Other lubricant | L-1 L-2 L-3 L-4 L-5 L-6 L-7 | 20 9 | 9 | 17 5 50 | 10 22 | 50 | 5 20 7 | 53 | 53-5 | 55 | |
| Emulsifying agent | E-1 E-2 E-3 E-4 E-5 E-6 E-7 E-8 E-9 E-10 E-11 E-12 E-13 E-14 E-15 | 34 2 12 5 15 | 8 18 10 4 | 15 6 | 10 8 | 20 30 20 7.5 20 | 5 14 15 | 5 8 8 20 | 2 | 1.5 | 5 |
| Antistatic additive | S-1 S-2 S-3 S-4 S-5 S-6 S-7 S-8 | 1 2 | 1 | 0.5 | 8 | 0.1 | 13 | 4 3 3 | |||
| Using ingredient | T-1 T-2 T-3 T-4 T-5 | 1 2 | 1 2.5 | ||||||||
[table 14]
| Classification | Comparative example | |||||||
| 11 | 12 | 13 | 14 | 15 | 16 | 17 | ||
| Kind | R-11 | R-12 | R-13 | R-14 | R-15 | R-16 | R-17 | |
| The isocyanuric acid derivative | K-1 K-2 K-3 K-4 K-5 K-6 K-7 K-8 K-9 K-10 K-11 K-12 K-13 K-14 | 30 30 | 100 | 20 | 20 | |||
| Other lubricant | L-1 L-2 L-3 L-4 L-5 L-6 L-7 | 30 | 5 25 | |||||
| Emulsifying agent | E-1 E-2 E-3 E-4 E-5 E-6 E-7 E-8 E-9 E-10 E-11 E-12 E-13 E-14 E-15 | 20 7 125 | 10 20 30 12 8 20 | 22 5 13 10 | 30 10 25 15 10 | |||
| Antistatic additive | S-1 S-2 S-3 S-4 S-5 S-6 S-7 S-8 | 0.5 | 40 15 20 25 | 20 15 15 | 4 3 3 | |||
| Using ingredient | T-1 T-2 T-3 T-4 T-5 | |||||||
Test classification 2 (each finishing agent adhering to and estimate on synthetic fiber)
Each finishing agent adhering on synthetic fiber
To evenly mix by each finishing agent of test classification 1 preparation and dilution water or dilution organic solvent, make 10% dilute solution.To inherent viscosity be 1.10, carboxyl terminal concentration is 15 equivalents/10
6After the section of the polyethylene terephthalate of g (チ Star プ) is carried out drying by conventional method, use extruder 295 ℃ of following spinning, spue from spinning head and cooling curing after mobile strand on, oil process adheres to 10% prepared dilute solution on the deflector roll that measuring pump carries out by using, use the deflector roll boundling then, draw with 3000m/ minute carry-over pinch rolls of superficial velocity, to be stretched to total stretching ratio be 1.7 times to draw roll, relax rolls by 240 ℃ then, obtains the drawn yarn of 1670dtex 192 long filaments with the form of 10kg spinning cake.
The mensuration of the adhesion amount of finishing agent
According to JIS-L1073 (synthetic fiber filament test method), use n-hexane/ethanol (50/50 volume ratio) mixed solvent as extractant, measure the adhesion amount of finishing agent on synthetic fiber.The result is shown in table 15～17.
The evaluation of pendulum wire
In above-mentioned spinning step, visual swing degree to the mobile silk that produces on draw roll is observed, and estimates by following benchmark.The result is shown in table 15～table 17.
AAA: do not produce pendulum wire
AA: almost do not produce pendulum wire
A: produce pendulum wire once in a while
B: frequently produce pendulum wire
C: the generation of pendulum wire remarkable, adjacent the silk between contact
The evaluation of fine hair
In above-mentioned spinning step, before silk was coiled into spinning cake, (DT-105 that eastern レ エ Application ジ ニ ア リ Application グ company produces) measured per 1 hour fine hair number with the fine hair counting device, estimates by following benchmark.The result is shown in table 15～table 17.
AAA: the fine hair number of mensuration is 0
AA: the fine hair number of mensuration is not less than 1 (but comprising 0)
A: the fine hair number of mensuration is 1～2
B: the fine hair number of mensuration is 3～9
C: the fine hair number of mensuration is more than 10
The evaluation of preventing property of tar
To move it on the hot-rolling of 240 ℃ of surface temperatures with initial stage tension force 1kg, the circumvolution in 500m/ minute of silk speed by the test silk that the above-mentioned spinning cake that obtains is taked, naked eyes are observed the amount that results from the tar behind 12 hours on the hot-rolling, estimate by following benchmark.The result is shown in table 15～table 17.
AAA: do not find tar.
AA: tar is arranged slightly.
A: find a spot of tar.
B: obviously find tar.
C: find a large amount of tar.
The evaluation of silk intensity
For the intensity of the test silk of being taked by the above-mentioned spinning cake that obtains, (Tianjin, island オ one ト グ ラ Off AGS-1KNG that society of Shimadzu Seisakusho Ltd. produces) measures with the strength detection device, estimates by following benchmark.The result is shown in table 15～table 17.
AAA: the silk intensity that records is more than the 8.0cN/dtex
AA: the silk intensity that records is more than 7.8 and less than 8.0cN/dtex
A: the silk intensity that records is more than 7.4 and less than 7.8cN/dtex
B: the silk intensity that records is more than 7.0 and less than 7.4cN/dtex
C: the silk intensity that records is less than 7.0cN/dtex
[table 15]
| Classification | Finishing agent | Estimate | |||||
| Kind | Give mode | Adhesion amount (%) | Pendulum wire | Fine hair | Preventing property of tar | Silk intensity | |
| Embodiment 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 | P-1 P-2 P-3 P-4 P-5 P-6 P-7 P-8 P-9 P-10 P-11 P-12 P-13 P-14 P-15 P-16 P-17 P-18 P-19 P-20 P-21 P-22 P-23 P-24 P-25 P-26 P-27 P-28 P-29 P-30 P-31 P-32 P-33 P-34 | Aqueous solution aqueous solution aqueous solution aqueous solution aqueous solution aqueous solution aqueous solution aqueous solution aqueous solution aqueous solution aqueous solution aqueous solution pure material pure material aqueous solution aqueous solution aqueous solution aqueous solution aqueous solution aqueous solution organic solvent solution organic solvent solution aqueous solution aqueous solution pure material pure material organic solvent solution aqueous solution aqueous solution aqueous solution organic solvent solution aqueous solution aqueous solution organic solvent solution | 0.8 0.8 0.8 0.6 1.0 0.8 0.8 0.8 0.8 1.0 0.8 0.8 1.0 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.7 0.8 1.2 0.8 0.8 1.4 0.8 0.8 1.0 0.8 0.8 0.8 1.0 0.8 | AAA AAA AAA AAA AAA AA AA AA AA AA AA AAA AA AA AAA AAA AAA AA AA AA AA AA AAA AAA AA A AA AAA AA AA A AA A AA | AAA AA AAA AAA AAA AAA AAA AAA AA AA AA AA AA AA AA AA AA AA AA AA AA AA AA AA AA AA AA AA AAA AA AA AA AA A | AAA AAA AAA AAA AAA AAA AA AAA AAA AAA A AAA AA A AAA AAA AAA AAA AAA AAA AA AA AA AA AA AAA AAA AA AAA AAA AAA AA AA AA | AAA AA AAA AAA AAA AAA AAA AAA AAA AAA AAA AA AA AA AAA AAA AAA AAA AAA AAA AA AA AAA AAA AAA AA AAA AAA AAA AAA AA AA AA AA |
[table 16]
| Classification | Finishing agent | Estimate | |||||
| Kind | Give mode | Adhesion amount (%) | Pendulum wire | Fine hair | Preventing property of tar | Silk intensity | |
| Embodiment 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 | P-35 P-36 P-37 P-38 P-39 P-40 P-41 P-42 P-43 P-44 P-45 P-46 P-47 P-48 P-40 P-50 P-51 P-52 P-53 P-54 P-55 P-56 P-57 P-58 P-59 P-60 P-61 P-62 P-63 P-64 P-65 P-66 P-67 P-68 | Aqueous solution pure material aqueous solution aqueous solution organic solvent solution pure material pure material aqueous solution aqueous solution aqueous solution organic solvent solution aqueous solution aqueous solution aqueous solution aqueous solution aqueous solution organic solvent solution organic solvent solution aqueous solution aqueous solution pure material aqueous solution aqueous solution pure material aqueous solution aqueous solution aqueous solution pure material aqueous solution aqueous solution aqueous solution aqueous solution aqueous solution aqueous solution | 0.8 0.8 0.8 0.8 0.8 0.8 0.6 0.8 0.8 0.8 1.2 0.8 0.9 0.8 0.8 1.0 0.8 0.8 0.8 0.8 0.6 0.8 0.8 0.8 0.6 1.0 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 | A AA AA AA A A A AA AAA AA AAA AAA AAA AAA AAA AA AA AA AA A A AA A A AAA AAA AA AA AA AAA AA A AA AA | AA A AA A AA A A AAA AA AAA AA AA AAA AA AA AAA AA AA AA AA A AA A A AA AA AA A AAA AA AAA AAA AA AA | AA AA A AA AA AA AA AAA AAA AAA AA AAA A AA A A A A AA AA AA AA A A AAA AA A A AAA AAA AAA AA AA AA | AA AA AA AA AA AA A AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AAA AA A AA AA A AA AA AAA AA AA AA AA AA AA AA |
[table 17]
| Classification | Finishing agent | Estimate | |||||
| Kind | Give mode | Adhesion amount (%) | Pendulum wire | Fine hair | Preventing property of tar | Silk intensity | |
| Comparative example 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 | R-1 R-2 R-3 R-4 R-5 R-6 R-7 R-8 R-9 R-10 R-11 R-12 R-12 R-13 R-14 R-15 R-16 R-17 | Water-based liquid organic solvent solution pure material pure material water-based liquid organic solvent solution pure material pure material pure material pure material water-based liquid water-based liquid pure material water-based liquid water-based liquid water-based liquid water-based liquid water-based liquid | 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 1.0 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 | C B C B B C C C C C B C C C C C C C | B C B C C C C C C C C C C C C C C C | C B C B C B C B B C B C C C C B C C | C C B C C C C C C C C C C C C C C C |
In table 15～17, the organic solvent of the organic solvent solution that the mode of giving is listed as is that the viscosity under 40 ℃ is 2.0 * 10
-6m
2The normal alkane of/s.
Claims (24)
1. synthetic fiber finishing agent, it contains lubricant, emulsifying agent and antistatic additive, it is characterized in that, the content of lubricant is that the content of 5～75 quality %, the emulsifying agent of finishing agent total amount is that the content of 21～94 quality % of finishing agent total amount, antistatic additive is 0.1～10 quality % of finishing agent total amount, and the following isocyanuric acid derivative of 5～45 quality % that contains the finishing agent total amount is as at least a portion of lubricant
Isocyanuric acid derivative: the partially or completely ester compounds that is selected from three (hydroxymethyl) isocyanuric acids and organic monocarboxylic acid, the partially or completely ester compounds of three (2-hydroxyethyl) isocyanuric acids and organic monocarboxylic acid, the partially or completely ester compounds of three (2-hydroxypropyl) isocyanuric acids and organic monocarboxylic acid, the partially or completely ester compounds of isocyanuric acid two (2-hydroxypropyl) and organic monocarboxylic acid, the partially or completely ester compounds of three (2-carboxy ethyl) isocyanuric acids and univalent aliphatic series hydroxy compounds, and in the partially or completely ester compounds of isocyanuric acid two (2-carboxy ethyl) and univalent aliphatic series hydroxy compounds more than a kind or 2 kinds.
2. synthetic fiber finishing agent as claimed in claim 1, wherein, described isocyanuric acid derivative is for being selected from the complete ester compounds of three (hydroxymethyl) isocyanuric acids and organic monocarboxylic acid, the complete ester compounds of three (2-hydroxyethyl) isocyanuric acids and organic monocarboxylic acid, the complete ester compounds of three (2-hydroxypropyl) isocyanuric acids and organic monocarboxylic acid, the complete ester compounds of isocyanuric acid two (2-hydroxypropyl) and organic monocarboxylic acid, the complete ester compounds of three (2-carboxy ethyl) isocyanuric acids and univalent aliphatic series hydroxy compounds, and in the complete ester compounds of isocyanuric acid two (2-carboxy ethyl) and univalent aliphatic series hydroxy compounds more than a kind or 2 kinds.
3. synthetic fiber finishing agent as claimed in claim 1, wherein, described isocyanuric acid derivative in the complete ester compounds that is selected from complete ester compounds and three (2-carboxy ethyl) isocyanuric acid of three (2-hydroxyethyl) isocyanuric acids and organic monocarboxylic acid and univalent aliphatic series hydroxy compounds more than a kind or 2 kinds.
4. synthetic fiber finishing agent as claimed in claim 1, wherein, organic monocarboxylic acid is that carbon number is that 2～22 aliphatic monocarboxylic acid, univalent aliphatic series hydroxy compounds are that carbon number is 1～26 aliphatic monobasic alcohol.
5. synthetic fiber finishing agent as claimed in claim 3, wherein, organic monocarboxylic acid is that carbon number is that 2～22 aliphatic monocarboxylic acid, univalent aliphatic series hydroxy compounds are that carbon number is 1～26 aliphatic monobasic alcohol.
6. synthetic fiber finishing agent as claimed in claim 1, wherein, the lubricant outside the isocyanuric acid derivative be selected from aliphatic ester compound, aromatic ester compound and the vegetable and animals oils lipid more than a kind or 2 kinds.
7. synthetic fiber finishing agent as claimed in claim 5, wherein, the lubricant outside the isocyanuric acid derivative be selected from aliphatic ester compound, aromatic ester compound and the vegetable and animals oils lipid more than a kind or 2 kinds.
8. synthetic fiber finishing agent as claimed in claim 7, wherein, described aliphatic ester compound be selected from the complete ester compounds of the complete ester compounds of binary or ternary aliphatic family polyalcohol and aliphatic monocarboxylic acid and aliphatic monobasic alcohol and binary or ternary aliphatic family polybasic carboxylic acid more than a kind or 2 kinds, described aromatic ester compound be selected from the complete ester compounds of the complete ester compounds of binary or ternary aromatic polyol and aliphatic monocarboxylic acid and aliphatic monobasic alcohol and binary or ternary aromatic series polybasic carboxylic acid more than a kind or 2 kinds.
9. synthetic fiber finishing agent as claimed in claim 1, wherein, described emulsifying agent be selected from ether type non-ionic surface active agent, polyol moiety ester type non-ionic surface active agent, polyoxyalkylene polyol fatty acid ester type non-ionic surface active agent, acid amide type non-ionic surface active agent and the polyoxyalkylene fatty acid amide type non-ionic surface active agent that in molecule, has polyoxy alkylidene more than a kind or 2 kinds.
10. synthetic fiber finishing agent as claimed in claim 1, wherein, described emulsifying agent be selected from polyol moiety ester type non-ionic surface active agent and the polyoxyalkylene polyol fatty acid ester type non-ionic surface active agent more than a kind or 2 kinds, this polyalcohol is selected from glycerine, castor oil, rilanit special, anhydro sorbitol and D-sorbite.
11. synthetic fiber finishing agent as claimed in claim 8, wherein, described emulsifying agent be selected from polyol moiety ester type non-ionic surface active agent and the polyoxyalkylene polyol fatty acid ester type non-ionic surface active agent more than a kind or 2 kinds, this polyalcohol is selected from glycerine, castor oil, rilanit special, anhydro sorbitol and D-sorbite.
12. synthetic fiber finishing agent as claimed in claim 1, wherein, described antistatic additive be selected from organic sulfonate, organo-sulfate salt, organophosphorus ester salt and the organic fatty hydrochlorate more than a kind or 2 kinds.
13. synthetic fiber finishing agent as claimed in claim 1, wherein, described antistatic additive is to be selected from more than a kind or 2 kinds of organophosphorus ester salt, and it is that 4～26 aliphatic list or dialkyl phosphate slaine, carbon number are that 4～26 polyoxyalkylene aliphatic list or dialkyl phosphate slaine, carbon number are that 4～26 aliphatic list or dialkyl phosphate organic amine salt and carbon number are 4～26 polyoxyalkylene aliphatic list or dialkyl phosphate organic amine salt that this organophosphorus ester salt is selected from carbon number.
14. synthetic fiber finishing agent as claimed in claim 11, wherein, described antistatic additive is to be selected from more than a kind or 2 kinds of organophosphorus ester salt, and it is that 4～26 aliphatic list or dialkyl phosphate slaine, carbon number are that 4～26 polyoxyalkylene aliphatic list or dialkyl phosphate slaine, carbon number are that 4～26 aliphatic list or dialkyl phosphate organic amine salt and carbon number are 4～26 polyoxyalkylene aliphatic list or dialkyl phosphate organic amine salt that this organophosphorus ester salt is selected from carbon number.
15. synthetic fiber finishing agent as claimed in claim 1, wherein, contain the antistatic additive of 0.3～6 quality % of the emulsifying agent of 40～85 quality % of lubricant, finishing agent total amount of 7～75 quality % of finishing agent total amount and finishing agent total amount, and the isocyanuric acid derivative of 7～35 quality % that contains the finishing agent total amount is as at least a portion of lubricant.
16. synthetic fiber finishing agent as claimed in claim 14, wherein, contain the antistatic additive of 0.3～6 quality % of the emulsifying agent of 40～85 quality % of lubricant, finishing agent total amount of 7～75 quality % of finishing agent total amount and finishing agent total amount, and the isocyanuric acid derivative of 7～35 quality % that contains the finishing agent total amount is as at least a portion of lubricant.
17. the processing method of synthetic fiber is characterized in that, makes the described synthetic fiber of claim 1 be attached to the synthetic fiber filament strand that supplies to heat treatment step with 0.1～3 quality % with finishing agent.
18. the processing method of synthetic fiber is characterized in that, makes the described synthetic fiber of claim 16 be attached to the synthetic fiber filament strand that supplies to heat treatment step with 0.1～3 quality % with finishing agent.
19. the processing method of synthetic fiber as claimed in claim 17 wherein, is made the water-based liquid of 5～30 quality % with synthetic fiber with finishing agent, makes this water-based liquid be attached to the synthetic fiber filament strand that supplies to heat treatment step with 0.1～3 quality %.
20. the processing method of synthetic fiber as claimed in claim 18 wherein, is made the water-based liquid of 5～30 quality % with synthetic fiber with finishing agent, makes this water-based liquid be attached to the synthetic fiber filament strand that supplies to heat treatment step with 0.1～3 quality %.
21. the processing method of synthetic fiber as claimed in claim 17, wherein, synthetic fiber are the industrial materials synthetic fiber.
22. the processing method of synthetic fiber as claimed in claim 20, wherein, synthetic fiber are the industrial materials synthetic fiber.
23. the processing method of synthetic fiber as claimed in claim 21, wherein, the industrial materials synthetic fiber are polyester fiber or polyamide-based fiber.
24. the processing method of synthetic fiber as claimed in claim 22, wherein, the industrial materials synthetic fiber are polyester fiber or polyamide-based fiber.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006351793 | 2006-12-27 | ||
| JP2006-351793 | 2006-12-27 | ||
| JP2006351793A JP4480176B2 (en) | 2006-12-27 | 2006-12-27 | Synthetic fiber treatment liquid and synthetic fiber treatment method |
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|---|---|
| CN101210385A true CN101210385A (en) | 2008-07-02 |
| CN101210385B CN101210385B (en) | 2012-11-21 |
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| CN2007101608461A Active CN101210385B (en) | 2006-12-27 | 2007-12-27 | Treating agent for synthetic fiber and method for treating synthetic fiber |
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|---|---|
| JP (1) | JP4480176B2 (en) |
| CN (1) | CN101210385B (en) |
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Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4840792A (en) * | 1971-10-08 | 1973-06-15 | ||
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2006
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2007
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| JP2008163489A (en) | 2008-07-17 |
| JP4480176B2 (en) | 2010-06-16 |
| CN101210385B (en) | 2012-11-21 |
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