CN101200611B - Insulation paint having both radiation heat insulation and obstructing type heat insulation and method for making same - Google Patents
Insulation paint having both radiation heat insulation and obstructing type heat insulation and method for making same Download PDFInfo
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- CN101200611B CN101200611B CN2007101905398A CN200710190539A CN101200611B CN 101200611 B CN101200611 B CN 101200611B CN 2007101905398 A CN2007101905398 A CN 2007101905398A CN 200710190539 A CN200710190539 A CN 200710190539A CN 101200611 B CN101200611 B CN 101200611B
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Abstract
Insulation paint with radiation heat insulation and barrier heat insulation and a preparation method thereof are provided, which belong to the water borne building energy saving coating field. The invention uses a transitional metal oxide, inorganic hollow particle and emulsion to produce the water borne building energy saving coating with good insulation, heat insulation effect and high performance. The coating consists of deionized water, propanediol, insulation functional materials, whiskers, pigments, fillers, emulsion and promoters. The coating performance of the coating formed on building walls is perfect. Compared with the single heat insulation mechanism insulation coating, the heat insulation effect is obvious and the heat insulation effect can lead the temperature difference to be 5 to 8 DEG C. With prominent weather resistant performance, color and luster preserving performance, water resistance and washing resistance, the coating is an insulation coating which is applied to the building external wall surface. The insulation paint with radiation heat insulation and barrier heat insulation of the invention has the advantages of benzene and formaldehyde containing-free, environmental protection, convenient construction and obvious environmental benefits, social benefits and economic benefits.
Description
Technical field
A kind of radiation heat insulation and isolation-type heat insulating coatings and preparation method thereof of having concurrently relates to a kind of thermal insulation coatings that can be used for the construction wall surface, belongs to environment-friendly water-based building energy conservation technical field of coatings.
Background technology
The aqueous architectural energy-saving coatings, it is that a kind of organic volatile (VOC) content is low, production and construction safety, the friendly type coating of green environment nonflammable, that do not have (or low) toxicity, nothing (or low) peculiar smell, meet world's coating technology trend, society and environmental benefit are big.Now, make up Sustainable development, conservation-minded society on the occasion of advocating energetically because of the scarcity of China's energy, resource, the aqueous architectural energy-saving coatings applied significance.In AND ENERGY RESOURCES CONSUMPTION IN CHINA, building energy consumption accounts for 35% of national energy consumption greatly.China has put into effect a series of policies and regulations, must take to force conservation measures to buildings.Building heat insulation coating more and more is subjected to people's favor because of advantages such as easy to use, good heat-insulation effect and economically feasibles in the heat-insulating material, and development prospect is wide, will be expected to promote the expansion of coating market and lagging material Application Areas.Different according to heat insulation mechanism of insulating mold coating for construction and heat insulation mode can be divided into it barrier thermal insulating coating, reflective heat-insulation paint and radiation heat insulation coating 3 classes.Various thermal insulation coatings respectively have its advantage, and the present invention considers two or more heat insulation mechanism are combined, and gives full play to its compound synergistic effect, develops the compound thermal insulation coatings of excellent property.The present invention mainly selects the transition metal oxide with radiation heat insulation effect and the function inorganic hollow microparticle material with heat insulation effect for use, is equipped with emulsion and auxiliary agent etc. and prepared the good water tolerance of heat insulation and preservation effect, the building energy conservation heat insulation coating that washable wiping performance is good.
Summary of the invention
The purpose of this invention is to provide a kind of radiation heat insulation and isolation-type heat insulating coatings and preparation method thereof of having concurrently, select a kind of water tolerance building energy conservation heat insulation coating of suitable heat insulation function material and the compound preparation of emulsion for use with good heat insulating.
Technical scheme of the present invention: a kind of radiation heat insulation and isolation-type heat insulating coatings of having concurrently, its each component and weight percent are as follows:
Deionized water 25%～38%,
Propylene glycol 1%～1.2%,
Heat insulation function material 12%～22%,
Pigment 2%～10%,
Filler 4%～17%,
Calcium carbonate crystal whisker 4%～10%,
Emulsion 26%～40%,
Auxiliary agent 2%～2.5%,
Described heat insulation function material is: with Fe
2O
3, MnO
2, Co
2O
3, the CuO infrared radiant material that to be raw material make by weight 1: 0.5～2: 0.08～0.3: 0.03～0.4 batching; Be equipped with hollow glass bead or ceramic hollow microballon, the weight ratio of infrared radiant material and cenosphere is 1: 0.8～3;
Described pigment is one or more in titanium dioxide, red iron oxide, organic yellow, the ultramarine;
Described filler is one or more in light calcium carbonate, water-ground limestone, mica powder, the kaolin;
Described emulsion is one or more in pure acrylic acid emulsion, benzene emulsion, the organosilicon crylic acid latex;
Described auxiliary agent comprises dispersion agent, film coalescence aid, thickening material and defoamer; Wherein dispersion agent is with OROTAN 1288, the OROTAN 731A dispersion agent of U.S. Rhom and Hass, or a kind of in 5040,5027 dispersion agents of Henkel KGaA company; Film coalescence aid is the ether alcohol kind solvent; The thickening material ACRYSOL TT-935 or the TT-615 thickening material of Rhom and Hass; Defoamer is with the NXZ defoamer of the BYK024 of Bi Ke company or Japanese Nuo Puke company.
This has the preparation method of radiation heat insulation and isolation-type heat insulating coatings concurrently, with Fe
2O
3, MnO
2, Co
2O
3, CuO is raw material, by the proportioning weighing, grinds, and it is mixed, after sieving by 300 order mesh screens, put into ceramic crucible and place high-temperature electric resistance furnace to carry out solid state sintering, 800 ℃ of temperature, insulation 6h makes infrared radiant material, adds cenosphere by proportioning again and is mixed with the heat insulation function material; Press proportion speed weighing deionized water, dispersion agent, propylene glycol in container, stir, add pigment, filler, and shear, it is uniformly dispersed with high-speed shearing machine; Add the heat insulation function material, fully moistening after, make its dispersion by high speed shear again; Add emulsion, film coalescence aid, calcium carbonate crystal whisker, thickening material, defoamer, stirring at low speed makes its dispersion; Add proper ammonia, the pH that regulates latex coating is 8～9, promptly makes and has radiation heat insulation and isolation-type heat insulating coatings concurrently.
Beneficial effect of the present invention: of the present inventionly have the coating performance excellence that radiation heat insulation and isolation-type heat insulating coatings form concurrently on external wall, effect of heat insulation is obvious than single heat insulation mechanism thermal insulation coatings, its heat insulation effect can make the temperature difference reach 5～8 ℃, and has outstanding weathering resistance, guarantor's look gloss retention, water tolerance and washable wiping.Of the present inventionly have radiation heat insulation concurrently and the isolation-type heat insulating coatings does not contain benzene, formaldehyde, help environmental protection, and easy construction, tangible environmental benefit, social benefit and economic benefit had.
Embodiment
Embodiment 1
A kind of radiation heat insulation and isolation-type heat insulating coatings (weight percentage) of having concurrently be by deionized water 27%, dispersion agent 0.6%, propylene glycol 1.1%, infrared radiant material 5%, hollow glass micropearl 5%, hollow ceramic microspheres 3%, calcium carbonate crystal whisker 8%, titanium dioxide 6%, light calcium carbonate 14.6%, emulsion 28%, film coalescence aid 1.0%, thickening material 0.5%, defoamer 0.2% is formulated.
Preparation method: with Fe
2O
3, MnO
2, Co
2O
3, CuO is raw material, by the proportioning weighing, grinds, and it is mixed, sieve by 300 order mesh screens, put into ceramic crucible and place high-temperature electric resistance furnace to carry out solid state sintering, 800 ℃ of temperature, insulation 6h makes infrared radiant material, adds cenosphere by proportioning again and is mixed with the heat insulation function material; Press proportion speed weighing deionized water, dispersion agent, propylene glycol in container, stir, add pigment, filler, and shear, it is uniformly dispersed with high-speed shearing machine; Add the heat insulation function material, fully moistening after, make its dispersion by high speed shear again; Add emulsion, film coalescence aid, calcium carbonate crystal whisker, thickening material, defoamer, stirring at low speed makes its dispersion; Add proper ammonia, the pH that regulates latex coating is 8～9, promptly makes and has radiation heat insulation and isolation-type heat insulating coatings concurrently.
Embodiment 2
A kind of radiation heat insulation and isolation-type heat insulating coatings (weight percentage) of having concurrently be by deionized water 26%, dispersion agent 0.5%, propylene glycol 1.2%, infrared radiant material 5%, hollow ceramic microspheres 10%, calcium carbonate crystal whisker 7%, titanium dioxide 5%, water-ground limestone 6%, mica powder 7.6%, emulsion 30%, film coalescence aid 1%, thickening material 0.5%, defoamer 0.2% is formulated.The preparation method is as described in the embodiment 1.
Embodiment 3
A kind of radiation heat insulation and isolation-type heat insulating coatings (weight percentage) of having concurrently be by deionized water 28%, dispersion agent 0.6%, propylene glycol 1%, infrared radiant material 4%, hollow ceramic microspheres 6%, hollow ceramic microspheres 6%, calcium carbonate crystal whisker 6%, titanium dioxide 6.9%, ultramarine 0.1%, light calcium carbonate 7.7%, emulsion 32%, film coalescence aid 1%, thickening material 0.6%, defoamer 0.1% is formulated.The preparation method is as described in the embodiment 1.
Embodiment 4
A kind of radiation heat insulation and isolation-type heat insulating coatings (weight percentage) of having concurrently be by deionized water 27%, dispersion agent 0.6%, propylene glycol 1.1%, infrared radiant material 6%, hollow ceramic microspheres 4%, hollow ceramic microspheres 10%, calcium carbonate crystal whisker 5%, titanium dioxide 3%, light calcium carbonate 4.7%, emulsion 37%, film coalescence aid 0.9%, thickening material 0.5%, defoamer 0.2% is formulated.The preparation method is as described in the embodiment 1.
Claims (2)
1. one kind has radiation heat insulation and isolation-type heat insulating coatings concurrently, it is characterized in that each component and weight percent are as follows:
Deionized water 25%～38%,
Propylene glycol 1%～1.2%,
Heat insulation function material 12%～22%,
Pigment 2%～10%,
Filler 4%～17%,
Calcium carbonate crystal whisker 4%～10%,
Emulsion 26%～40%,
Auxiliary agent 2%～2.5%,
Described heat insulation function material is: with Fe
2O
3, MnO
2, Co
2O
3, CuO is raw material by weight 1: 0.5～2: 0.08～0.3: 0.03～0.4 batching, 800 ℃ of the temperature of solid state sintering, insulation 6h makes infrared radiant material; Be equipped with hollow glass bead or ceramic hollow microballon again, the weight ratio of infrared radiant material and cenosphere is 1: 0.8～3;
Described pigment is one or more in titanium dioxide, red iron oxide, organic yellow, the ultramarine;
Described filler is one or more in light calcium carbonate, water-ground limestone, mica powder, the kaolin;
Described emulsion is one or more in pure acrylic acid emulsion, benzene emulsion, the organosilicon crylic acid latex;
Described auxiliary agent comprises dispersion agent, film coalescence aid, thickening material and defoamer; Wherein dispersion agent is with OROTAN 1288, the OROTAN 731A dispersion agent of U.S. Rhom and Hass, or a kind of in 5040,5027 dispersion agents of Henkel KGaA company; Film coalescence aid is the ether alcohol kind solvent; The thickening material ACRYSOL TT-935 or the TT-615 thickening material of Rhom and Hass; Defoamer is with the NXZ defoamer of the BYK024 of Bi Ke company or Japanese Nuo Puke company.
2. the described preparation method who has radiation heat insulation and isolation-type heat insulating coatings concurrently of claim 1 is characterized in that: with Fe
2O
3, MnO
2, Co
2O
3, CuO is raw material, by the proportioning weighing, grinds, and it is mixed, after sieving by 300 order mesh screens, put into ceramic crucible and place high-temperature electric resistance furnace to carry out solid state sintering, 800 ℃ of temperature, insulation 6h makes infrared radiant material, adds cenosphere by proportioning again and is mixed with the heat insulation function material; Press proportion speed weighing deionized water, dispersion agent, propylene glycol in container, stir, add pigment, filler, and shear, it is uniformly dispersed with high-speed shearing machine; Add the heat insulation function material, fully moistening after, make its dispersion by high speed shear again; Add emulsion, film coalescence aid, calcium carbonate crystal whisker, thickening material, defoamer, stirring at low speed makes its dispersion; Add proper ammonia, the pH that regulates latex coating is 8～9, promptly makes and has radiation heat insulation and isolation-type heat insulating coatings concurrently.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007101905398A CN101200611B (en) | 2007-11-30 | 2007-11-30 | Insulation paint having both radiation heat insulation and obstructing type heat insulation and method for making same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007101905398A CN101200611B (en) | 2007-11-30 | 2007-11-30 | Insulation paint having both radiation heat insulation and obstructing type heat insulation and method for making same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101200611A CN101200611A (en) | 2008-06-18 |
| CN101200611B true CN101200611B (en) | 2010-06-02 |
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|---|---|---|---|
| CN2007101905398A Expired - Fee Related CN101200611B (en) | 2007-11-30 | 2007-11-30 | Insulation paint having both radiation heat insulation and obstructing type heat insulation and method for making same |
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| CN101712832B (en) * | 2009-12-18 | 2012-08-22 | 大连海事大学 | Water-soluble colorful insulation coating and preparation method thereof |
| CN102234482A (en) * | 2010-04-29 | 2011-11-09 | 陈轶 | Energy-efficient priming paint |
| CN101857752B (en) * | 2010-05-28 | 2012-11-28 | 中华制漆（深圳）有限公司 | Aqueous exterior wall coating material with high solid content and low viscosity |
| CN101851453B (en) * | 2010-06-12 | 2011-12-28 | 重庆龙者低碳环保科技有限公司 | Heat reflection-emission lamina simulated-brick thermal insulation coating and preparation method thereof |
| CN102910865B (en) * | 2011-08-05 | 2015-04-22 | 上海丰慧节能环保科技有限公司 | Special bonding agent for anti-radiation fireproofing organic insulation board |
| CN102952441A (en) * | 2011-08-23 | 2013-03-06 | 庄斌文 | Heat-insulation waterproof coating |
| CN102399482B (en) * | 2011-11-18 | 2014-01-15 | 天长市通天化工有限责任公司 | Preparation method of outer wall temperature-change-resisting antioxidant color coating for factory |
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| CN102603228B (en) * | 2012-04-01 | 2014-06-04 | 刘娜 | Special diatom ooze paint for children as well as application and application method thereof |
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| CN103896536A (en) * | 2012-12-25 | 2014-07-02 | 深圳市嘉达高科产业发展有限公司 | Building external wall thermal insulating powder coating, and preparation method thereof |
| CN103173078A (en) * | 2013-02-26 | 2013-06-26 | 安徽真信涂料有限公司 | Environment-friendly exterior wall coating and preparation method thereof |
| CN103396713A (en) * | 2013-08-11 | 2013-11-20 | 深圳市文浩建材科技有限公司 | Semi-transparent aqueous heat insulation coating and preparation method thereof |
| CN103740215B (en) * | 2013-12-05 | 2016-08-24 | 上海市建筑科学研究院 | A kind of high-performance building heat-reflecting insulating coating and its preparation method and application |
| CN103709872B (en) * | 2014-01-08 | 2016-08-17 | 李占一 | A kind of environment-friendlyand and energy-saving heating coating and preparation method thereof |
| CN104212289B (en) * | 2014-09-17 | 2016-08-24 | 江苏海晟涂料有限公司 | A kind of nanometer silicate filler outer wall heat-insulating coating and preparation method thereof |
| CN104293054A (en) * | 2014-09-29 | 2015-01-21 | 潜伟清 | Ultrathin exterior wall heat insulation coating |
| CN104830173A (en) * | 2015-04-13 | 2015-08-12 | 佛山科学技术学院 | Composite aqueous acrylic acid thermal-insulation coating material and preparation method thereof |
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| CN106010029A (en) * | 2016-07-05 | 2016-10-12 | 阳泉市澳丽丝科技涂料有限公司 | Water-based outer wall heat insulation and preservation coating and preparation method thereof |
| CN106433333A (en) * | 2016-10-12 | 2017-02-22 | 贵州卓霖节能环保科技发展有限公司 | Thermal insulation coating composition as well as preparation method and application thereof |
| CN110746799A (en) * | 2019-11-18 | 2020-02-04 | 亚士漆(上海)有限公司 | Heat radiation type heat insulation coating and preparation method thereof |
| CN111454618A (en) * | 2020-04-03 | 2020-07-28 | 沪宝新材料科技（上海）股份有限公司 | Heat-insulating sand-in-water coating and preparation method thereof |
| CN113292888A (en) * | 2021-04-24 | 2021-08-24 | 广东禹昊房屋修缮有限公司 | Exterior wall heat-insulating waterproof coating and preparation method thereof |
| CN114989655B (en) * | 2022-07-08 | 2024-03-26 | 上海逸简科技有限公司 | Application of manganese ore in low-interface heat-obtaining building energy-saving paint |
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| CN101200611A (en) | 2008-06-18 |
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Assignee: Beijing great high building Decoration Design Engineering Co., Ltd. Assignor: Jiangnan University Contract record no.: 2011320010125 Denomination of invention: Insulation paint having both radiation heat insulation and obstructing type heat insulation and method for making same Granted publication date: 20100602 License type: Exclusive License Open date: 20080618 Record date: 20110920 |
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Granted publication date: 20100602 Termination date: 20121130 |