CN103709872B - A kind of environment-friendlyand and energy-saving heating coating and preparation method thereof - Google Patents
A kind of environment-friendlyand and energy-saving heating coating and preparation method thereof Download PDFInfo
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- CN103709872B CN103709872B CN201410008310.8A CN201410008310A CN103709872B CN 103709872 B CN103709872 B CN 103709872B CN 201410008310 A CN201410008310 A CN 201410008310A CN 103709872 B CN103709872 B CN 103709872B
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Abstract
The invention discloses a kind of environment-friendlyand and energy-saving heating coating, containing deionized water, acrylic emulsion, TM intermixture, wetting agent, dispersant, defoamer, superfine graphite powder, PH regulator, nano microsphere.The invention also discloses the preparation method of above-mentioned environment-friendlyand and energy-saving heating coating.The environment-friendlyand and energy-saving heating coating of the present invention has guarantor's light unfading of excellence, heatproof of generating heat, and has preferable heat resistance (50 280 degree of life-time service), weatherability and mar proof, can be widely applied to industry and civil area.
Description
Technical field
The present invention relates to a kind of coating, be specifically related to a kind of environment-friendlyand and energy-saving heating coating and preparation method thereof.
Background technology
China building overwhelming majority be high energy consumption non-economized building, building during use, heating, air-conditioning,
The aspects such as ventilation, hot water supply consume the substantial amounts of energy.In order to keep interior of building temperature, reduce disappearing of air conditioner energy source
Consumption, mutually reply building energy conservation requirement, active development is developed energy-saving material and is of great practical significance and long-range
Social meaning.
Meanwhile, energy-saving heating material is also widely used in all kinds of greenhouse, dries institute, storage tank heat.Steam oven, heating wire,
The fields such as electrothermal tube, but existing energy-saving and heat-insulating material easily ftractures under running under the conditions of rapid heat cycle, still reaches to less than being permitted
The requirement of many applications.
Summary of the invention
For overcoming above-mentioned technological deficiency, open a kind of environment-friendlyand and energy-saving heating coating of the present invention and preparation method thereof.
Environment-friendlyand and energy-saving heating coating disclosed by the invention, containing acrylic emulsion, deionized water, TM intermixture, wetting agent,
Dispersant, defoamer, graphite powder, PH regulator, nano microsphere.
By weight percentage, acrylic emulsion be 35-45%, deionized water be 18-30%, TM intermixture be 3-8%, profit
Humectant is 1-5%, dispersant is 1-3%, defoamer is 1-3%, graphite powder be 15-25%, PH regulator be 1-3%, nano microsphere be
6-10%.Preferably, acrylic emulsion be 38%, deionized water be 22%, TM intermixture be 5%, wetting agent be 3%, dispersant be
2%, defoamer be 1%, superfine graphite powder be 20%, PH regulator be 1%, nano microsphere be 8%.
Further, described TM intermixture is the intermixture of ferrum oxide and manganese dioxide, described ferrum oxide and titanium dioxide
The mixed proportion of manganese is 1:1.
Described wetting agent be in alkylbenzene or unsaturated polyester siloxanes any one, play minimizing capillary effect；
Described dispersant be in undersaturated polyacrylic acid sodium salt, amine amide any one, there is deflocculation color development function；Described froth breaking
Agent is polysiloxanes, can eliminate the bubble in material；Described PH regulator is the ammonia of concentration 28%, concentration 10% hydroxide
Any one in potassium, described nano microsphere is high-temperature calcination hollow bead, preferably nano-hollow glass microballoon.
The invention also discloses the preparation method of above-mentioned environment-friendlyand and energy-saving heating coating, by deionized water and part propylene yogurt
Add TM intermixture, graphite powder being ground particle diameter after liquid mixing is 15-25 μm, is subsequently adding remaining component and carries out paint.
The content of described partial emulsion is the 5-15% of coating total amount.
The content of described partial emulsion is the 10% of coating total amount.
The beneficial effects of the present invention is:
(1) coating of the present invention has guarantor's light unfading of excellence, heat insulation heatproof, has preferable weatherability and wear-resisting
Damage property；(2) coating applications of the present invention is extensive, can be used for Industrial Transport oil-piping, wax storage, hothouse, drying plant, and industry should
Heat retaining and exothermal effect is played with heat-conducting oil furnace, steam oven, heating wire, electrothermal tube etc. can be replaced；Civilian aspect can be used for metope,
Ground heating, various heating decorative frescos, cultivate, plant, nursery, greenhouse etc.；(3) the coating application easy construction of the present invention,
Can make mantle, dura mater coating, coating has antiseptic fire-retardant, waterproof, permanent, algae removal, lichen of going out, super cleaning function,
And releasing far infrared 2.5-25UM physical therapy frequency and negative oxygen ion body, health-care warming, change IAQ (indoor air quality)；(4) this
After bright coating uses, heat distribute uniform, indoor moist, noiselessness pollutes, without electromagenetic wave radiation, film use 10 years with
On, can life-time service without damaging.
Detailed description of the invention
Below by specific embodiment, the present invention is described in detail.
Embodiment 1:
Component proportion: by weight percentage, take acrylic emulsion be 38%, deionized water be 22%, TM intermixture (oxidation
The intermixture of ferrum and manganese dioxide, mixed proportion is 1:1) be 5%, wetting agent (alkylbenzene or unsaturated polyester siloxanes) be 3%, point
Powder (undersaturated polyacrylic acid sodium salt, amine amide) is 2%, defoamer (polysiloxanes) is 2%, graphite powder is 20%, PH regulation
Agent (ammonia of concentration 28%, concentration 10% potassium hydroxide) is 1%, nano-hollow glass microballoon is 8%.
Preparation method: add TM intermixture, graphite powder after 10% acrylic emulsion mixing of deionized water and coating total amount
Being ground particle diameter is 15-25 μm, is subsequently adding remaining component and carries out paint.
Embodiment 2:
Component proportion: by weight percentage, take acrylic emulsion be 35%, deionized water be 25%, TM intermixture (oxidation
The intermixture of ferrum and manganese dioxide, mixed proportion is 1:1) be 8%, wetting agent (alkylbenzene or unsaturated polyester siloxanes) be 1%, point
Powder (undersaturated polyacrylic acid sodium salt, amine amide) is 1%, defoamer (polysiloxanes) is 3%, graphite powder is 18%, PH regulation
Agent (ammonia of concentration 28%, concentration 10% potassium hydroxide) is 3%, nano-hollow glass microballoon is 6%.
Preparation method: add TM intermixture, graphite powder after 15% acrylic emulsion mixing of deionized water and coating total amount
Being ground particle diameter is 15-25 μm, is subsequently adding remaining component and carries out paint.
Its mass parameter of the environment-friendlyand and energy-saving heating coating of the present invention is as shown in table 1
Table 1
| Project | Technical specification |
| In a reservoir under state | Without journey uniform state after block, stirring |
| Workability | Brush two roads accessible |
| Appearance of film designs | Normally |
| Drying time (surface drying) | ≤2h |
| Alkali resistance (24h) | Without exception |
| Low-temperature stability (3 circulations) | Never degenerate |
| Wash-resistant property | >=500 times |
| Coating temp. variation resistant performance | Without exception |
| Thermostability (110 DEG C, 96h) | Unchanged |
| Anti-escherichia coli of going out | ＞ 99.9 |
| Anti-staphylococcus aureus of going out | ＞ 99.6 |
| Sheet resistance | 1.04×103Ω |
| Volume resistance | 9.40×102Ω |
| VOC (VOC)/(g/L) | 21.1g/L is unchanged |
| Soluble heavy metal (mg/kg) | Lead, cadmium, chromium, hydrargyrum, nothing |
| Power consumption | 0.2-0.6kWh/m2/h |
Environment-friendlyand and energy-saving heating coating of the present invention is of many uses, can be used for Industrial Transport oil-piping, wax storage, hothouse, drying
Equipment.Civilian metope, the ground heating of can be used for, various heating decorative frescos, cultivate, plant, nursery, greenhouse etc..The present invention's
Coating application easy construction, can make mantle, dura mater coating, and coating has antiseptic fire-retardant, waterproof, permanent, algae removal, tongue of going out
Moss, super cleaning function, and releasing far infrared 2.5-25UM physical therapy frequency and negative oxygen ion body, health-care warming, change indoor
Air quality.Product is uniformly brushed to need the place of heating.Heating temp (or is adjusted with temperature controller according to depending on brushing thickness
Control).Heat distribute moist, noiselessness uniform, indoor pollute, without electromagenetic wave radiation, film uses more than 10 years, can without damage
Life-time service.Commercial Application can replace heat-conducting oil furnace, steam oven, heating wire, electrothermal tube etc..Brushing application process is simple, brushing
To object plane to be generated heat, strip copper conductor is pasted at two ends, connects power-supply controller of electric (temperature controller), and energising is the most heatable.
In sum, although the detailed description of the invention of the present invention is to the present invention have been described in detail, but this area is general
Technical staff is it is to be understood that above-described embodiment is only description to the preferred embodiments of the present invention, rather than to the present invention
The restriction of protection domain, persons skilled in the art in the technical scope that disclosed herein, the change that can readily occur in,
All within protection scope of the present invention.
Claims (8)
1. an environment-friendlyand and energy-saving heating coating, it is characterised in that: by weight percentage, containing following component, acrylic emulsion
For 35-45%, deionized water be 18-30%, TM intermixture be 3-8%, wetting agent be 1-5%, dispersant be 1-3%, froth breaking
Agent is 1-3%, graphite powder is 15-25%, pH adjusting agent is 1-3%, nano microsphere is 6-10%, and described TM intermixture is oxidation
Ferrum and the intermixture of manganese dioxide.
2. environment-friendlyand and energy-saving heating coating as claimed in claim 1, it is characterised in that: acrylic emulsion is 38%, deionized water
Be 22%, TM intermixture be 5%, wetting agent be 3%, dispersant be 2%, defoamer be 1%, graphite powder be 20%, pH regulator
Agent is 1%, nano microsphere is 8%.
3. environment-friendlyand and energy-saving heating coating as claimed in claim 1, it is characterised in that: described ferrum oxide and the mixing of manganese dioxide
Ratio is 1:1.
4. environment-friendlyand and energy-saving heating coating as claimed in claim 1, it is characterised in that: described wetting agent is alkylbenzene or unsaturation
In polysiloxanes any one, described dispersant is undersaturated polyacrylic acid sodium salt, and described defoamer is polysiloxanes, described
PH adjusting agent is any one in the ammonia of concentration 28%, concentration 10% potassium hydroxide, and described nano microsphere is that high-temperature calcination is empty
Heart pearl.
5. environment-friendlyand and energy-saving heating coating as claimed in claim 1, it is characterised in that: described nano microsphere is nano-hollow glass
Microballon.
6. the preparation method of environment-friendlyand and energy-saving heating coating as claimed in claim 1, it is characterised in that: by deionized water and part
Add TM intermixture, graphite powder being ground particle diameter after acrylic emulsion mixing is 15-25 μm, is subsequently adding remaining component and enters
Row paint.
7. the preparation method of environment-friendlyand and energy-saving heating coating as claimed in claim 6, it is characterised in that: containing of described partial emulsion
Amount is the 5-15% of coating total amount.
8. the preparation method of environment-friendlyand and energy-saving heating coating as claimed in claim 7, it is characterised in that: containing of described partial emulsion
Amount is the 10% of coating total amount.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410008310.8A CN103709872B (en) | 2014-01-08 | 2014-01-08 | A kind of environment-friendlyand and energy-saving heating coating and preparation method thereof |
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| CN201410008310.8A CN103709872B (en) | 2014-01-08 | 2014-01-08 | A kind of environment-friendlyand and energy-saving heating coating and preparation method thereof |
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| CN103709872A CN103709872A (en) | 2014-04-09 |
| CN103709872B true CN103709872B (en) | 2016-08-17 |
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| CN111269627A (en) * | 2020-03-06 | 2020-06-12 | 荆门市诺维英新材料科技有限公司 | Energy-saving and environment-friendly heating coating and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101195725A (en) * | 2007-12-29 | 2008-06-11 | 株洲时代新材料科技股份有限公司 | Heat-insulating energy-saving paint for vehicle and method for producing the same |
| CN101200611A (en) * | 2007-11-30 | 2008-06-18 | 江南大学 | Insulation paint having both radiation heat insulation and obstructing type heat insulation and method for making same |
| CN102850936A (en) * | 2012-08-30 | 2013-01-02 | 青岛保利康新材料有限公司 | Multifunctional polymer coating material |
| CN102850887A (en) * | 2012-08-30 | 2013-01-02 | 青岛保利康新材料有限公司 | High-polymer coating material |
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2014
- 2014-01-08 CN CN201410008310.8A patent/CN103709872B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101200611A (en) * | 2007-11-30 | 2008-06-18 | 江南大学 | Insulation paint having both radiation heat insulation and obstructing type heat insulation and method for making same |
| CN101195725A (en) * | 2007-12-29 | 2008-06-11 | 株洲时代新材料科技股份有限公司 | Heat-insulating energy-saving paint for vehicle and method for producing the same |
| CN102850936A (en) * | 2012-08-30 | 2013-01-02 | 青岛保利康新材料有限公司 | Multifunctional polymer coating material |
| CN102850887A (en) * | 2012-08-30 | 2013-01-02 | 青岛保利康新材料有限公司 | High-polymer coating material |
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Effective date of registration: 20160902 Address after: 361111 No. 6 New Bridge Road, Xiangan District, Fujian, Xiamen Patentee after: Xiamen friend Technology Co., Ltd. Address before: Ping Town Longgang District of Shenzhen City, Guangdong province 518117 six Lian Shi al Ling Industrial Park in Shenzhen City Gu Konny Chemical Co. Ltd. Patentee before: Li Zhanyi |