Summary of the invention
Therefore, the object of the present invention is to provide a kind of manufacture method of grid, to solve existing grid production method forms sufficient shape profile in gate bottom problem.
For achieving the above object, the manufacture method of a kind of grid provided by the invention comprises: the semiconductor substrate is provided, forms conductive layer on the described semiconductor-based end; Spin coating photoresist layer and carry out graphically on described conductive layer forms gate pattern; By etching described gate pattern is transferred on the described conductive layer, formed grid; Described grid is carried out the directional plasma etching.
The direction of described directional plasma etching and the angle of described semiconductor-based basal surface are 70 to 90 degree.
Described plasma is an oxygen gas plasma.
The pressure of the environment of described oxygen gas plasma is 2 to 15Torr.
The radio frequency source power that produces described oxygen gas plasma is 100 to 1000 watts, and the flow of oxygen is 50 to 500sccm.
Described conductive layer is a kind of or its combination in polysilicon, the metal silicide.
This method further comprises: remove described photoresist layer by ashing, and carry out wet-cleaned.
Mutually deserved, the present invention also provides a kind of manufacture method of grid, comprising: the semiconductor substrate is provided, forms conductive layer on the described semiconductor-based end; Spin coating photoresist layer and carry out graphically on described conductive layer forms gate pattern; By etching described gate pattern is transferred on the described conductive layer, formed grid; Measure the live width of described grid, judge according to measurement result whether described gate bottom has sufficient shape profile,, described grid is carried out the directional plasma etching if having; If do not have, finish the manufacturing of grid.
Adopt optics critical size method of measurement to measure the live width of described gate bottom.
According to the time of the measurement result decision of described grid live width being carried out the directional plasma etching to described grid.
Adopt oxygen gas plasma that described grid is carried out the directional plasma etching.
The present invention also provides a kind of manufacture method of grid, comprising: form conductive layer on the first semiconductor-based end; Spin coating photoresist layer and carry out graphically on described conductive layer forms gate pattern; By etching described gate pattern is transferred on the described conductive layer, formed grid; Measure the live width of described grid; Judge according to measurement result whether described gate bottom has sufficient shape profile; If have, the grid that forms is carried out the directional plasma etching at the second follow-up semiconductor-based end.
The grid that forms is carried out at the second follow-up semiconductor-based end the time of directional plasma etching according to the measurement result decision of the suprabasil grid of first semiconductor.
Described plasma is an oxygen gas plasma.
Compared with prior art, the present invention has the following advantages:
The present invention is by directed oxygen gas plasma etching, the polymer that is formed at the gate bottom sidewall is removed, make the grid that forms have profile preferably, and then make that the grid that forms is sensitive more controlled to the unlatching of conducting channel, improved the unfailing performance of device; In addition; in the dry etching process; the volatile accessory substance that produces usually again crystallization fall after rise on the surface at the semiconductor-based end, form residual defects, also can remove residue defective and other pollutant of described semiconductor-based basal surface by the directional plasma etching.
The inventive method is also by measuring the grid of finishing etching to judge whether described gate lateral wall bottom has sufficient shape profile, whether described grid is carried out the time of directional plasma etching and directional plasma etching with decision, make the gate bottom that forms not have sufficient shape profile, and needn't carry out the directional plasma etching the suprabasil grid of each semiconductor.Simultaneously, measurement and directional plasma etching all can be finished in etching apparatus, and the described semiconductor-based end needn't take out from etching apparatus, also needn't cut into slices, and has simplified technology and has improved efficient, make cost reduce, and save time.
This method is also by measuring the suprabasil grid of the first half conductor conductor, to judge whether the grid that forms needs the directional plasma etching at follow-up the semiconductor-based end, and the time of directional plasma etching, avoid the repeatedly transmission of the semiconductor-based end between different chamber, and repeatedly expose to the open air with external environment condition in, reduced contaminated may.
Embodiment
For above-mentioned purpose of the present invention, feature and advantage can be become apparent more, the specific embodiment of the present invention is described in detail below in conjunction with accompanying drawing.
Fig. 9 is the flow chart of first embodiment of grid production method of the present invention.As shown in Figure 9, at first, provide the semiconductor substrate, on the described semiconductor-based end, form conductive layer (S200).Described semiconductor-based bottom materials comprises a semi-conductive substrate and an oxide layer, and described Semiconductor substrate can be a kind of in the semi-conducting materials such as monocrystalline silicon, polysilicon, amorphous silicon, germanium, and described thickness of oxide layer is 5 to 100nm.Described conductive layer is a kind of or its combination in polysilicon, the metal silicide, and the method that forms described conductive layer is physical vapour deposition (PVD) or chemical vapour deposition (CVD).
Spin coating photoresist and carry out graphically on described conductive layer forms gate pattern (S210).Described photoresist is a chemically-amplified resist.Before the described photoresist of spin coating, on described conductive layer, form an anti-reflecting layer earlier, described anti-reflecting layer is used for reducing reverberation the influencing forming gate pattern at exposure process of described conductive layer surface.Send into exposure sources and expose at the semiconductor-based end that will be formed with anti-reflecting layer and photoresist layer, by exposing the design transfer on the mask plate (mask) to described photoresist layer, remove the photoresist that is not exposed by developing then, the photoresist figure that remaines on the described conductive layer forms gate pattern.
The semiconductor-based end that will have described gate pattern, move into etching apparatus, removes not by the conductive layer that described gate pattern covered by the plasma dry etching, and described gate pattern is transferred on the conductive layer, forms grid (S220).
Behind etching formation grid, original position (in-situ) is carried out directional plasma etching (S230) to the described semiconductor-based basal surface that is formed with grid.Described directional plasma is an oxygen gas plasma.The bombardment direction of described directed oxygen gas plasma and the angle of described semiconductor-based basal surface are 70 to 90 degree, the pressure of the environment of described directed oxygen gas plasma is 2 to 15Torr, the radio frequency source power that produces described directed oxygen gas plasma is 100 to 1000 watts, and the flow of oxygen is 50 to 500sccm.When the conductive layer of the described polysilicon material of etching, generally select fluorine-containing gas for use, fluorine and photoresist effect meeting generate on polymer and the sidewall attached to grid, influence further carrying out of etching, cause the profile that has sufficient shape at the gate bottom sidewall that forms, by directed oxygen gas plasma etching, the polymer of described gate bottom sidewall can be removed, make grid have profile preferably, and then make grid sensitive more controlled to the unlatching of conducting channel, improved the unfailing performance of device; In addition; in the dry etching process; the volatile accessory substance that produces is crystallization and falling after rise on the surface at the semiconductor-based end again usually, forms residual defects, also can remove residue defective and other pollutant of described semiconductor-based basal surface by the directional plasma etching.
Manufacture method first embodiment to described grid is described in detail below in conjunction with accompanying drawing.Figure 10 to Figure 15 is the generalized section of each step corresponding construction of first embodiment of the grid production method according to the present invention.
As shown in figure 10, on semi-conductive substrate 300, form oxide layer 302.Described Semiconductor substrate 300 can the time polysilicon, monocrystalline silicon, amorphous silicon, germanium, arsenicization a kind of in sowing, also can be silicon on the insulating barrier.Described oxide layer 302 forms by the method for thermal oxidation or deposition, and its thickness is about 1 to 100nm.This oxide layer 302 is the gate oxide of the grid of follow-up formation, and also as the resilient coating when follow-up ion implantation technology, energetic ion is to the damage of described Semiconductor substrate 300 when reducing the ion injection.
As shown in figure 11, form a conductive layer 304 on described oxide layer 302, described conductive layer 304 is a kind of or its combination in polysilicon, the metal silicide, and described conductive layer 304 also can be a metal.Conductive layer described in the present embodiment 304 is a polysilicon.The method of its formation is physical vapour deposition (PVD) or chemical vapour deposition (CVD).
As shown in figure 12, spin coating anti-reflecting layer 305 on described conductive layer 304, spin coating photoresist layer 306 on described anti-reflecting layer 305, described anti-reflecting layer 305 reduce or eliminate the influence of reverberation in exposure process on described conductive layer 304 surfaces.Send into exposure sources and expose at the semiconductor-based end that will be formed with anti-reflecting layer 305 and photoresist layer 306, by exposing the design transfer on the mask plate (mask) to described photoresist layer 306, remove the photoresist that is not exposed by developing, the photoresist figure that remaines on the described conductive layer forms gate pattern 306a as shown in figure 13.
As shown in figure 14, be mask with described gate pattern 306a, the described conductive layer 304 of etching is removed describedly not by the conductive layer of gate pattern 306a and anti-reflecting layer 305a protection, forms grid 304a in described conductive layer 304.Described etching is the plasma dry etching, and the chemical gas of etching is generally fluoro-gas.
As shown in figure 15, the surface that will be formed with the Semiconductor substrate 300 of grid 304a expose to the open air with directed oxygen gas plasma 308 environment in, directed oxygen gas plasma etching is carried out on the surface of described Semiconductor substrate 300.This orientation oxygen gas plasma etching and aforementioned etching form grid technology and can carry out in same chamber, i.e. the directed etching of original position; The etching direction of described directional plasma and the angle of described semiconductor-based basal surface are 70 to 90 degree, the pressure of the environment of described directed oxygen gas plasma is 2 to 15Torr, the radio frequency source power that produces described directed oxygen gas plasma 308 is 100 to 1000 watts, and the flow of oxygen is 50 to 500sccm.By directed oxygen gas plasma bombardment, the polymer of described grid 304a bottom sidewall can be removed, make the grid 304a that forms have profile preferably, and then make grid 304a sensitive more controlled, improved the unfailing performance of device the unlatching of conducting channel.In addition; in the dry etching process, the usually crystallization again of volatile accessory substance of generation falls the surface at the semiconductor-based end after rise; form residual defects, can remove residue defective and other pollutant of described semiconductor-based basal surface by the directional plasma etching.In directed oxygen gas plasma etching process, the gate pattern 306a of photoresist makes described grid 304a top not be subjected to the damage of directed oxygen gas plasma etching as protective layer on described grid 304a; Simultaneously because the directivity of directed etching can not cause damage to described grid 304a side wall upper part.Described directed etching also can be carried out in other chamber, repeats no more here.
After finishing described directed oxygen gas plasma etching, remove described photoresist layer 306a and anti-reflecting layer 305a by ashing (Ash), and then carry out wet-cleaned, remove surface contaminant, form grid 304a.
Figure 16 is the flow chart of second embodiment of manufacture method of the present invention.
As shown in figure 16, provide the semiconductor substrate, on the described semiconductor-based end, form conductive layer (S300).The described semiconductor-based end, comprise a semi-conductive substrate and an oxide layer, and described Semiconductor substrate can be a kind of in the semi-conducting materials such as monocrystalline silicon, polysilicon, amorphous silicon, germanium, and described thickness of oxide layer is 5 to 100nm.Described conductive layer is a kind of or its combination in polysilicon, the metal silicide, and the method that forms described conductive layer is physical vapour deposition (PVD) or chemical vapour deposition (CVD), and conductive layer described in the present embodiment is a polysilicon.
Spin coating photoresist and carry out graphically on described conductive layer forms gate pattern (S310).Described photoresist is a chemically-amplified resist, before the described photoresist of spin coating, forms an anti-reflecting layer earlier on described conductive layer, and described anti-reflecting layer is used for reducing the reverberation of conductive layer surface in the influence of exposure process to formation gate patterns profile.Send into exposure sources and expose at the semiconductor-based end that will be formed with anti-reflecting layer and photoresist layer, by exposing the design transfer on the mask plate (mask) to described photoresist layer, remove the photoresist that is not exposed by developing, the photoresist figure that remaines on the described conductive layer forms gate pattern.
The semiconductor-based end that will have described gate pattern, move into etching apparatus, removes not by the conductive layer that described gate pattern covered by the plasma dry etching, and described gate pattern is transferred on the conductive layer, forms grid (S320).
After forming grid, measure the live width (S330) that (Optical CriticalDimension) method is measured described grid by the optics critical size at described the semiconductor-based end.Measurement to described grid can be carried out in the chamber of described semiconductor etching device, the chamber that is used to measure the grid live width is different with the chamber that etching forms grid, for example, the chamber that the described conductive layer of etching forms grid is first chamber, measures the live width of described grid and carries out at second chamber.The suprabasil a plurality of grids of described semiconductor can be regarded the diffraction grating of a reflection as, the OCD method is by a branch of polarised light being projected on the described diffraction grating and diffracted, accept the described diffraction light line data of going forward side by side by photosensitive unit and handle the live width obtain grid, the OCD method of measurement can obtain the live width at positions such as grid upper, middle and lower, can judge the profile of gate lateral wall according to the live width that records position, grid upper, middle and lower.With respect to the existing method that needs by the destructiveness monitoring of section (Crosss section) and SEM, the OCD method of measurement can be by measuring the side wall profile of grid, needn't cut, simplify technology, reduced the profile of the grid of expense and monitoring etching that can be real-time, so that the etching technics parameter is adjusted, make the gate profile that forms reach requirement.
Judge according to the result who measures whether described gate bottom has sufficient shape profile (S340),, finish manufacturing (S360) described grid if do not have.
If judgement learns that described gate bottom has sufficient shape profile according to measurement result, described first chamber is sent at this semiconductor-based end with sufficient shape profile grid, the suprabasil grid of described semiconductor is carried out directed oxygen plasma etching (S350).According to the time of the measurement result decision of described grid live width being carried out directed etching to described grid, the direction of described directed oxygen gas plasma and the angle of described semiconductor-based basal surface are 70 to 90 degree, the pressure of the environment of described directed oxygen gas plasma is 2 to 15Torr, the radio frequency source power that produces described directed oxygen gas plasma is 100 to 1000 watts, and the flow of oxygen is 50 to 500sccm.Described grid is carried out directed oxygen plasma etching also can in the 3rd other chamber, carry out, repeat no more here.After described grid carried out the directional plasma etching, finish the manufacturing of grid.
Figure 17 is the flow chart of the 3rd embodiment of manufacture method of the present invention.
As shown in figure 17, provide the semiconductor substrate, on the described semiconductor-based end, form conductive layer (S300).The described semiconductor-based end, comprise a semi-conductive substrate and an oxide layer, and described Semiconductor substrate can be a kind of in the semi-conducting materials such as monocrystalline silicon, polysilicon, amorphous silicon, germanium, and described thickness of oxide layer is 5 to 100nm.Described conductive layer is a kind of or its combination in polysilicon, the metal silicide, and the method that forms described conductive layer is physical vapour deposition (PVD) or chemical vapour deposition (CVD), and conductive layer described in the present embodiment is a polysilicon.
Spin coating photoresist and carry out graphically on described conductive layer forms gate pattern (S310).Described photoresist is a chemically-amplified resist, before the described photoresist of spin coating, forms an anti-reflecting layer earlier on described conductive layer, and described anti-reflecting layer is used for reducing the reverberation of conductive layer surface in the influence of exposure process to formation gate patterns profile.Send into exposure sources and expose at the semiconductor-based end that will be formed with anti-reflecting layer and photoresist layer, by exposing the design transfer on the mask plate (mask) to described photoresist layer, remove the photoresist that is not exposed by developing, the photoresist figure that remaines on the described conductive layer forms gate pattern.
The semiconductor-based end that will have described gate pattern, move into etching apparatus, removes not by the conductive layer that described gate pattern covered by the plasma dry etching, and described gate pattern is transferred on the conductive layer, forms grid (S320).
After forming grid, measure the live width (S330) that (Optical CriticalDimension) method is measured described grid by the optics critical size at described the semiconductor-based end.Measurement to described grid can be carried out in the chamber of described semiconductor etching device, the chamber that is used to measure the grid live width is different with the chamber that etching forms grid, for example, the chamber that the described conductive layer of etching forms grid is first chamber, measures the live width of described grid and carries out at second chamber.The suprabasil a plurality of grids of described semiconductor can be regarded the diffraction grating of a reflection as, the OCD method is by a branch of polarised light being projected on the described diffraction grating and diffracted, accept the described diffraction light line data of going forward side by side by photosensitive unit and handle the live width obtain grid, the OCD method of measurement can obtain the live width at positions such as grid upper, middle and lower, can judge the profile of gate lateral wall according to the live width that records positions such as grid upper, middle and lower.With respect to the existing method that needs by the destructiveness monitoring of section (Crosss section) and SEM, the OCD method of measurement can be by measuring the side wall profile of grid, needn't cut, simplify technology, reduced the profile of the grid of expense and monitoring etching that can be real-time, so that the etching technics parameter is adjusted, make the gate profile that forms reach requirement.
Judge according to the result who measures whether described gate bottom has sufficient shape profile (S340),, finish manufacturing (S360) described grid if do not have.
If judgement learns that described gate bottom has sufficient shape profile according to measurement result, first chamber is sent at this semiconductor-based end with sufficient shape profile, the suprabasil grid of described semiconductor is carried out directed oxygen plasma etching (S350).According to the time of the measurement result decision of described grid live width being carried out directed etching to described grid, the direction of described directed oxygen gas plasma and the angle of described semiconductor-based basal surface are 70 to 90 degree, the pressure of the environment of described directed oxygen gas plasma is 2 to 15Torr, the radio frequency source power that produces described directed oxygen gas plasma is 100 to 1000 watts, and the flow of oxygen is 50 to 500sccm.In the present embodiment, measure to judge whether described gate lateral wall bottom has sufficient shape profile by the grid of finishing etching being carried out OCD, with decision whether described grid is carried out directed oxygen gas plasma etching, and the time of directed oxygen gas plasma etching, needn't carry out the directional plasma etching to the suprabasil grid of each semiconductor; Simultaneously, measurement and directed oxygen gas plasma etching are all finished in etching apparatus, and the described semiconductor-based end needn't take out from etching apparatus, also needn't cut into slices, and has simplified technology and has improved efficient, make cost reduce simultaneously, save time.Described grid is carried out the technology of directed oxygen plasma etching and also can in the 3rd other chamber, carry out, repeat no more here.
After described grid carried out the directional plasma etching, measure the live width of the grid of the directed oxygen plasma etching of described process once more by the OCD method, and judge according to measurement result whether described gate bottom also has sufficient shape profile, if proceed the directional plasma etching; If there is not the manufacturing of finishing described grid.
Figure 18 is the flow chart of the 4th embodiment of manufacture method of the present invention.
As shown in figure 18,, on the first semiconductor-based end, form conductive layer (S400).The described first semiconductor-based end, comprised a semiconductor substrate and an oxide layer.The described semiconductor-based end can be a kind of in the semi-conducting materials such as monocrystalline silicon, polysilicon, amorphous silicon, germanium, and described thickness of oxide layer is 5 to 100nm.Described conductive layer is a kind of or its combination in polysilicon, the metal silicide, and the method that forms described conductive layer is physical vapour deposition (PVD) or chemical vapour deposition (CVD), and conductive layer described in the present embodiment is a polysilicon.
Spin coating photoresist and carry out graphically on described conductive layer forms gate pattern (S410).Described photoresist is a chemically-amplified resist, before the described photoresist of spin coating, forms an anti-reflecting layer earlier on described conductive layer, and described anti-reflecting layer is used for reducing the reverberation of conductive layer surface in the influence of exposure process to formation gate patterns profile.Send into exposure sources and expose at the first semiconductor-based end that will be formed with anti-reflecting layer and photoresist layer, by exposing the design transfer on the mask plate (mask) to described photoresist layer, remove the photoresist that is not exposed by developing, the photoresist figure that remaines on the described conductive layer forms gate pattern.
The first semiconductor-based end that will have described gate pattern, move into etching apparatus, removes not by the conductive layer that described gate pattern covered by the plasma dry etching, and described gate pattern is transferred on the conductive layer, forms grid (S420).
After forming grid, measure the live width (S430) that (Optical CriticalDimension) method is measured described grid by the optics critical size at described the semiconductor-based end.Measurement to described grid can be carried out in the chamber of described semiconductor etching device, the chamber that is used to measure the grid live width is different with the chamber that etching forms grid, for example, the chamber that the described conductive layer of etching forms grid is first chamber, measures the live width of described grid and carries out at second chamber.The suprabasil a plurality of grids of described first semiconductor can be regarded the diffraction grating of a reflection as, the OCD method is by polarised light being projected on the described diffraction grating and diffracted, accept the described diffraction light line data of going forward side by side by photosensitive unit and handle the live width obtain grid, the OCD method of measurement can obtain the live width at positions such as grid upper, middle and lower, can judge the profile of gate lateral wall according to the live width that records positions such as grid upper, middle and lower.With respect to the existing method that needs by the destructiveness monitoring gate lateral wall profile of section (Crosss section) and SEM, the OCD method of measurement can be by measuring the side wall profile of grid, and needn't cut, simplified technology, reduced expense and and the profile of the grid of monitoring etching that can be real-time, so that the etching technics parameter is adjusted, make the gate profile that forms reach requirement.
After finishing measurement, the described first semiconductor-based end, removed etching apparatus, finish manufacturing (S460) described grid to the suprabasil grid of described first semiconductor.
According to the measurement result of the suprabasil grid live width of described first semiconductor is judged whether described gate bottom has sufficient shape profile (S440);
If judgement learns that the suprabasil gate bottom of described first step semiconductor has sufficient shape profile according to measurement result, this result is fed back to described first chamber, to carrying out directed oxygen gas plasma etching (S450) in the second semiconductor-based end of finishing the grid manufacturing in described first chamber.According to the time that the measurement result of the suprabasil grid live width of described first semiconductor is determined the suprabasil grid of described second semiconductor is carried out directed oxygen gas plasma etching, described directed oxygen gas plasma is an oxygen gas plasma.The direction of described directed oxygen gas plasma and the angle of described semiconductor-based basal surface are 70 to 90 degree, the pressure of the environment of described directed oxygen gas plasma is 2 to 15Torr, the radio frequency source power that produces described oxygen gas plasma is 100 to 1000 watts, and the flow of oxygen is 50 to 500sccm.Judge whether the follow-up suprabasil grid of second semiconductor is carried out directed oxygen gas plasma etching and the time of carrying out directed oxygen plasma etching by measurement to grid at the first semiconductor-based end, finish the suprabasil grid of described second semiconductor carried out the directional plasma etching after, measure the live width of the suprabasil grid of this second semiconductor and judge its side wall profile by OCD again, with as whether the follow-up suprabasil grid of the 3rd semiconductor being carried out the directed etching of plasma ..., and the like, the described feedback of method can to(for) a plurality of semiconductor-based end of continuous manufacturing makes the grid that forms on each semiconductor-based end have profile preferably.This method can avoid the semiconductor substrate between first chamber and second chamber repeatedly transmission and repeatedly expose to the open air with external environment condition in, can save time simultaneously.
Though the present invention with preferred embodiment openly as above; but it is not to be used for limiting the present invention; any those skilled in the art without departing from the spirit and scope of the present invention; can make possible change and modification, so protection scope of the present invention should be as the criterion with the scope that claim of the present invention was defined.