CN101161113B - Abstraction of pine nut oil, residual oil cake food after abstracting and its preparing method - Google Patents
Abstraction of pine nut oil, residual oil cake food after abstracting and its preparing method Download PDFInfo
- Publication number
- CN101161113B CN101161113B CN200710157817XA CN200710157817A CN101161113B CN 101161113 B CN101161113 B CN 101161113B CN 200710157817X A CN200710157817X A CN 200710157817XA CN 200710157817 A CN200710157817 A CN 200710157817A CN 101161113 B CN101161113 B CN 101161113B
- Authority
- CN
- China
- Prior art keywords
- pine nut
- extraction
- pine
- pinenut
- benevolence
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims abstract description 29
- 239000003921 oil Substances 0.000 title abstract description 51
- 235000019198 oils Nutrition 0.000 title abstract description 51
- 235000019496 Pine nut oil Nutrition 0.000 title abstract description 10
- 239000010490 pine nut oil Substances 0.000 title abstract description 10
- 235000013305 food Nutrition 0.000 title abstract description 6
- 238000000605 extraction Methods 0.000 claims abstract description 138
- 235000014571 nuts Nutrition 0.000 claims abstract description 80
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims abstract description 79
- 235000011613 Pinus brutia Nutrition 0.000 claims abstract description 79
- 241000018646 Pinus brutia Species 0.000 claims abstract description 79
- 239000000843 powder Substances 0.000 claims abstract description 33
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 17
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 16
- 235000006886 Zingiber officinale Nutrition 0.000 claims abstract description 14
- 235000008397 ginger Nutrition 0.000 claims abstract description 14
- 238000005516 engineering process Methods 0.000 claims abstract description 9
- 240000007049 Juglans regia Species 0.000 claims abstract description 7
- 235000009496 Juglans regia Nutrition 0.000 claims abstract description 7
- 235000020234 walnut Nutrition 0.000 claims abstract description 7
- 244000037364 Cinnamomum aromaticum Species 0.000 claims abstract description 6
- 235000012550 Pimpinella anisum Nutrition 0.000 claims abstract description 3
- 244000273928 Zingiber officinale Species 0.000 claims abstract 4
- 240000004760 Pimpinella anisum Species 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000004519 grease Substances 0.000 claims description 44
- 239000002994 raw material Substances 0.000 claims description 34
- 239000000284 extract Substances 0.000 claims description 28
- 238000007789 sealing Methods 0.000 claims description 22
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 21
- 239000002893 slag Substances 0.000 claims description 17
- 230000001954 sterilising effect Effects 0.000 claims description 15
- 238000004659 sterilization and disinfection Methods 0.000 claims description 15
- 238000000926 separation method Methods 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 10
- 235000015097 nutrients Nutrition 0.000 claims description 10
- 235000021110 pickles Nutrition 0.000 claims description 10
- 238000012856 packing Methods 0.000 claims description 9
- 241000196324 Embryophyta Species 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 7
- 238000013461 design Methods 0.000 claims description 7
- 238000006062 fragmentation reaction Methods 0.000 claims description 7
- 235000020985 whole grains Nutrition 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- 235000014489 Cinnamomum aromaticum Nutrition 0.000 claims description 5
- 244000089698 Zanthoxylum simulans Species 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 238000009461 vacuum packaging Methods 0.000 claims description 5
- 238000013459 approach Methods 0.000 claims description 4
- 238000007689 inspection Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 235000007265 Myrrhis odorata Nutrition 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims 1
- 235000013409 condiments Nutrition 0.000 claims 1
- 238000007654 immersion Methods 0.000 claims 1
- 238000011017 operating method Methods 0.000 claims 1
- 235000006708 antioxidants Nutrition 0.000 abstract description 15
- 235000006667 Aleurites moluccana Nutrition 0.000 abstract 1
- 240000004957 Castanea mollissima Species 0.000 abstract 1
- 235000018244 Castanea mollissima Nutrition 0.000 abstract 1
- 244000303040 Glycyrrhiza glabra Species 0.000 abstract 1
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 abstract 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 1
- 235000017803 cinnamon Nutrition 0.000 abstract 1
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 235000011477 liquorice Nutrition 0.000 abstract 1
- 235000016709 nutrition Nutrition 0.000 abstract 1
- 230000035764 nutrition Effects 0.000 abstract 1
- 235000002639 sodium chloride Nutrition 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 241000234314 Zingiber Species 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 235000019197 fats Nutrition 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 235000019441 ethanol Nutrition 0.000 description 6
- 239000000796 flavoring agent Substances 0.000 description 6
- 235000019634 flavors Nutrition 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 235000013339 cereals Nutrition 0.000 description 5
- 239000012530 fluid Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 238000003672 processing method Methods 0.000 description 4
- 238000010298 pulverizing process Methods 0.000 description 4
- 230000003064 anti-oxidating effect Effects 0.000 description 3
- 230000007850 degeneration Effects 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 238000009700 powder processing Methods 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- 210000001835 viscera Anatomy 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 206010010144 Completed suicide Diseases 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 240000007263 Pinus koraiensis Species 0.000 description 2
- 235000011615 Pinus koraiensis Nutrition 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
- 235000019784 crude fat Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000000509 Chenopodium ambrosioides Nutrition 0.000 description 1
- 244000098897 Chenopodium botrys Species 0.000 description 1
- 235000005490 Chenopodium botrys Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- 240000009023 Myrrhis odorata Species 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 235000008591 Pinus cembroides var edulis Nutrition 0.000 description 1
- 244000003118 Pinus cembroides var. edulis Species 0.000 description 1
- 241001074085 Scophthalmus aquosus Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000003026 anti-oxygenic effect Effects 0.000 description 1
- 206010003246 arthritis Diseases 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 208000002173 dizziness Diseases 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003797 essential amino acid Substances 0.000 description 1
- 235000020776 essential amino acid Nutrition 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 150000002617 leukotrienes Chemical class 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000862 numbness Toxicity 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Landscapes
- Fats And Perfumes (AREA)
- Preparation Of Fruits And Vegetables (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
Extraction of pine nut oil, residual oil dregs food after extraction as well as its producing method, that is obtaining pine nut after exuviating and removing skin; obtaining pine nut oil by exceed critical CO2 hydro-extraction; to get out the residual oil dregs after extraction to dry, then to grind into powder, and adding Chinese chestnut powder and walnut powder to mix as well as dry again to produce complex pine nut nutrition powder. Or using the pine nut as whole body, one-half crash, quarter crash to extract residual oil dregs, then to add into a flovoring liquid composed of common salt, liquorice, aniseed, pepertree, Chinese cinnamon, fine ginger and water to bloat, then produce dainty instant pine nut. Compared with the existing technology, the present invention improves the oil-displaced ratio, and produces dainty instant pine nut foods using extracting residual dregs, improves the using ratio of the pine nut; the line exceed critical CO2 hydro-extracting technics which takes raw ginger as anti-oxidant, ethanol as entrainer, is more advanced.
Description
Technical field
The present invention relates to a kind of supercritical CO of pine nut oil
2The comprehensive utilization of extract remainder behind method for distilling and the extraction grease.
Background technology
Pine nut is traditional good merchantable brand that takes care of health, and pignolia benevolence can be promoted longevity.According to surveying and determination, every 100g pine nut benevolence contains thick protein 13.51～19.88g, crude fat 51.72～69.13g, total reducing sugar amount 8.11～13.44g, crude fibre 2.60～4.14g; Pine nut benevolence protein is made up of 18 seed amino acids, and particularly various contents of essential amino acids are all quite abundant.Crude fat comprises 13 kinds of aliphatic acid; Wherein linoleic acid accounts for 35.77%～43.13%, and leukotrienes accounts for 18.61%～37.93%, and oleic acid accounts for 12.49%～27.17%; Unrighted acid composition total amount surpasses 60%, also contains trace elements such as abundant calcium, phosphorus, manganese, brill, copper, zinc, iron.Pine nut benevolence is ambrosia, is again the dietotherapy good merchantable brand, and extremely physician, nutritionist praise highly.Point out in " Bencao Jingshu ": " the pinenut flavor is sweet, enriches blood, and vim and vigour are sufficient, and then the five internal organs are from profit, and it is not hungry to turn black ... so can prolong life, it is not old to make light of one's life by commiting suicide ".The Compendium of Material Medica record: " pinenut is warm in nature, and it is sweet, nontoxic to distinguish the flavor of, and cures mainly joint rheumatism, dizziness, and moisturizing viscera is by wandering arthritis cold air, and complement is empty, skin care, clothes are made light of one's life by commiting suicide not old for a long time ".Other has in " peace is extensively remembered ", " solar corona book on Chinese herbal medicine ", " Kaibao Bencao ", and food pine nut benevolence can be improved looks, the record of long life and anti-ageing.Chinese and western medical research proof, pine nut benevolence has the nourishing human body, moisturizing viscera, logical numbness gas, mental-tranquilization is in the big useful benefit effect of human body.Korean pine seed oil is taken from Korean pine benevolence, is a kind of green xylophyta grease of natural non-environmental-pollution, contains abundant unrighted acid, and wherein linolenic acid content is particularly abundant, is needed by human and unrighted acid that have important medical care effect.
Supercritical CO
2Fluid extraction technology is a kind of novel high-new isolation technics, in grease processing and comprehensive utilization thereof, extensive studies and application is arranged.In the extraction of pine nut oil, different with extraction conditions because of the equipment that adopts, the pine nut oil that is obtained also is not quite similar.Supercritical CO
2Fluid extraction technology itself exists operating pressure big; The extraction time is long, to having relatively high expectations of equipment, and the problem that the not ideal enough grade of extraction yield remains to be improved; And adopt entrainer that the supercritical extract process is strengthened, can effectively improve extraction yield, reduce operating pressure.The supercritical CO of pine nut oil
2Extracting is purpose to improve oil yield mainly, and pine nut benevolence is crushed to more than 60 orders, adopt higher pressure (30MPa) and select for use long-time (4 hours) to extract, and after not taking all factors into consideration oil and grease extracting, the comprehensive utilization of contained albumen in the extract remainder.Simultaneously, owing to contain a large amount of unrighted acids and oxidation easily in the pine nut, Oxidation of Fat and Oils is the process of a chain reaction; The interpolation anti-oxidant can prolong the induction period of grease; Delay the time that grease begins to ruin, but can not change the result who has degenerated, therefore when using anti-oxidant; Must grasp in the incipient stage its antioxidation of competence exertion.For grease at extraction process mesohigh, CO
2The problem of oxidation of middle remaining oxygen, contacting metal has to be solved.
Summary of the invention
The objective of the invention is to overcome above-mentioned weak point; Realization is to effective extraction of the broken raw material of difference; Reach under lower pressure; Through using entrainer and in extraction feed, adding natural anti-oxidation raw material ginger powder, provide that a kind of pine nut oil oil yield is high, antioxygenic property is good, the little a kind of supercritical CO of albuminous degeneration degree in the extract remainder
2The comprehensive utilization of extract remainder behind the method for fluid extraction pine-seed oil and the extraction grease.
Technology of the present invention is shown in accompanying drawing 1.Pine nut carries out supercritical CO through shelling, going clothing to get pine nut benevolence
2Fluid extraction gets pine-seed oil; The extraction residue takes out dries, again through be milled to powder, add other nut powder, mixing, once more dry, be packaged into compound pine nut benevolence nutrient powder.Simultaneously, can also the extraction residue be taken out that to filter out profile complete, the pine nut benevolence that the albuminous degeneration degree is little is carried out flavouring material and is pickled tasty and process instant delicious pine nut benevolence.Concrete technology is:
1. the preliminary treatment of raw material
1.1 antioxidant material preliminary treatment
Ginger is an anti-oxidant, to adopt 6～8 months ginger of growth for well.It is cleaned, be cut into the thick thin slice of 2cm after draining, be dried to moisture content about 40% in 20～25 ℃, pulverizer is pulverized, and continues to be dried to moisture content about 10%, and is subsequent use.
1.2 pine nut pretreatment of raw material
With pine nut shelling, remove scarlet, obtain pine nut benevolence, according to the difference of product, the processing of pine nut benevolence is divided into and is crushed to 40 orders, 1/4th fragmentations, 1/2nd is broken and whole.Whole grain; / 4th fragmentations; Be used to process soft package instant pine nut benevolence behind the single granularity of the pine nut benevolence of 1/2nd fragmentations or the combination grain oil and grease extracting; Be processed into compound pine nut benevolence nutrient powder after pulverizing 40 purpose pine nut benevolence oil and grease extractings, because the material gap is unfavorable for extraction for a short time during the high extraction of degree of crushing, so be crushed to 80 orders again after employing is crushed to 40 order oil and grease extractings earlier.
2. supercritical CO
2The extracting pine-seed oil process conditions
Its technology is as shown in Figure 2.Processing step is:
Connect general supply; Start refrigerating plant, start the heater of extraction kettle, separating still.
Ginger powder is added in the pine nut benevolence raw material, and addition is 1～5% of a pine nut benevolence weight, and synergist citric acid addition is 0.02～0.05% of a pine nut benevolence weight.
Mixing of materials evenly is loaded on extraction kettle, seals with sealing ring.The ethanol of 58～99% concentration is made entrainer, and use amount is not all 3～10% of extract material according to extracting pressure and raw material crushing degree, injects and carries in the agent jar.In the raw material crushing degree is that best of breed is under the 40 order situation: concentration of ethanol is 95%, and addition is 5% of the extraction material.
Extraction kettle adopts 15～35MPa, 45 ± 10 ℃, separates I and adopts 8 ± 5MPa, 40 ± 10 ℃; Separate II and adopt 5 ± 5MPa, 35 ± 10 ℃; Treat that cold machine temperature reaches 4 ℃, and extraction kettle, separate I, when separating the II preheat temperature, open the entrainer high-pressure pump entrainer is pressed into extraction kettle near design temperature.The extraction parameter is CO
2Flow is at 20～25L/h, and extracting pressure adopts 15～35MPa, the pressure of control extraction kettle and separation reactor I, II; When treating that pressure, temperature conform to setting value, pick up counting, extraction 1.5～3h, extraction is emitted grease after finishing from separating still, and gas in the emptying extraction kettle is opened the extraction kettle capping, takes out extract remainder.
3. soft package instant pinenut processing method:
Whole grain pine nut benevolence, 1/4th fragmentations, the pine nut benevolence of 1/2nd fragmentations can extract the grease of pine nut benevolence weight 40～60% after extraction; The pinenut outer shape changes little, but inside becomes loose, and the rest parts grease can keep the local flavor of pine nut benevolence; Loose structure helps the technology that adopts the short time to pickle; Concrete grammar does, the extraction residue dregs of fat (hereinafter to be referred as collection excess oil slag) that pine nut benevolence is extracted behind the grease screen, and profile is complete; The material that the albuminous degeneration degree is little is processed, and processes instant pine nut benevolence.With pine nut benevolence extract remainder is benchmark; Salt with 3～8%, 2～5% Radix Glycyrrhizae, 0.2～0.5% anise, 0.1～0.5% Chinese prickly ash, 0.1～0.3% cassia bark, 0.1～0.3% galingal, the poach system 50～90 minutes of adding 1.5～3 times of pine nut benevolence collection excess oil slag volumes; Cooling (so that below 10 ℃ for well) is filtered it, with the pine nut benevolence collection excess oil slag that filters out immerse filtrate in 2～4h pickle pine nut benevolence tasty, that will pickle and measure packing by specification; Seal with vacuum packing machine the pack back; The condition of sealing is: vacuum 0.09 MPa, and 30 kilovolts of heat-sealing voltages, sterilization: the pine nut benevolence that will pack after sealing is put into the cannery retort sterilization; Sterilization conditions is: 115～129 ℃, and 23～35 minutes.After cooling, insulation, check, process finished product, be processed into soft package instant pine nut benevolence.
4. compound pinenut nutrient powder processing method:
Be crushed to the collection excess oil slag after 40 order pine nut benevolence are extracted grease, be milled to 80 orders after the oven dry, add 10～30% rice-chestnut powder, 5～25% walnut powder makes protein content>=65%; Fat≤3% dries by the fire 30～50min down at 25～40 ℃, is dried to moisture≤7%, packing, quality inspection.
Advantage of the present invention:
1. oil extracting rate is high, oil extracting rate with do not use entrainer, oil yield has improved 5～13% under other condition same cases.
2. antioxidant effect is good, surveys its peroxide value according to national standard, and the shelf-life can reach 6 months.In raw material, add natural anti-oxidation raw material ginger, wherein polyphenoils is together extracted, both added to earlier in the grease, avoided grease in time because of contacting metal, high pressure CO in the extraction process
2Remaining O
2Deng and the oxidation that causes has solved the problem that independent extraction polyphenoils adds again, saved energy consumption and time.
3. owing to used entrainer, can correspondingly reduce the pressure in the extraction process, thereby be easy to realize industrialization, production safety, energy consumption is low.Oil yield when also having improved simultaneously under the less condition of whole grain or degree of crushing extraction has guaranteed to obtain more complete pinenut extract remainder and the production needs that do not reduce oil yield.
4. comprehensive utilization degree is high, and added value is big, and product category is many.During pine-seed oil in the past extracted, the material behind the extraction grease often was regarded as refuse, or sells as just feed, mainly was that value is very little behind high pressure because the material degree of crushing is high.Though also the someone studied whole grain extraction process, because of pine nut causes oil yield seriously to descend without broken, lost more than gain.This technology has overcome this problem, when guaranteeing oil yield, improves the degree of utilizing of pinenut extract remainder albumen, has realized comprehensive utilization.
5. aspect the processing of instant pine nut benevolence, adopted unique short-term pickling process, the pinenut raciness, process time is short.
Description of drawings
Accompanying drawing 1 is the extraction of pine nut oil, the process flow diagram of collection excess oil dregs food manufacturing approach.
Accompanying drawing 2 uses the supercritical CO of entrainer for pine nut benevolence
2The extraction sketch map.Wherein: 1 is carbon dioxide steel cylinder, and 2 is filter, and 3 is cold machine, and 4 is high-pressure metering pump, and 5 is blender, and 6 is preheater, and 7 is extraction kettle, and 9 is separation reactor I, and 10 is separation reactor I I, and 10 is flow quantity recorder, and 11 is the entrainer storage tank, 12 high-pressure metering pumps.
The specific embodiment
The supercritical CO of example 1 pine nut oil
2The extraction preparation method implements 1
The pinenut of whole grain is a raw material, and the collection excess oil slag behind the oil and grease extracting will be used to process soft package instant pine nut benevolence, so it is little to require extraction process that pine nut benevolence outward appearance is destroyed, extracts the part grease and gets final product, and the grease that is retained in the extract remainder is used to improve instant pinenut local flavor.
Connect general supply; Start refrigerating plant, start the heater of extraction kettle, separating still, extraction kettle adopts 45 ℃, separates I and adopts 8MPa, 40 ℃; Separate II and adopt 5MPa, 35 ℃.The pinenut of the whole grain after using pine nut to shell is raw material, and the antioxidant material ginger powder is added in the pinenut raw material, and addition is 1% of a pinenut weight, and synergist citric acid addition is 0.05% of a pinenut weight. The raw material that adds anti-oxidant by proportioning is loaded on extraction kettle, seals with sealing ring.
The ethanol of 99% concentration is made entrainer, and use amount is 7% of a pinenut weight, injects and carries in the agent jar.Wait to freeze end and extraction kettle and separation reactor I, II preheat temperature during, open the entrainer pump and entrainer is pressed in the extraction kettle CO near design temperature
2Flow-control when treating extraction kettle pressure near setting pressure 25MPa, is controlled the pressure of extraction kettle and separation reactor I, II at 20L/h; When treating that pressure, temperature conform to setting value, pick up counting extraction time 2.5h.Extraction finishes the back and from separating still, emits grease, and gas in the emptying extraction kettle is opened the extraction kettle capping, takes out extract remainder.
The supercritical CO of example 2 pine-seed oils
2The extraction preparation method implements 2
The pinenut of 1/2nd to 1/4th broken combination grains is a raw material; Collection excess oil slag behind the oil and grease extracting will be used to process the soft package instant pinenut; So require extraction process to destroy little to pine nut benevolence outward appearance; Extract the part grease and get final product, the grease that is retained in the extract remainder is used to improve instant pinenut local flavor.
Connect general supply; Start refrigerating plant, start the heater of extraction kettle, separating still, extraction kettle adopts 48 ℃, separates I and adopts 8MPa, 42 ℃; Separate II and adopt 5MPa, 33 ℃./ 2nd broken pinenuts after using pine nut to shell are raw material, and the antioxidant material ginger powder is added in the pinenut raw material, and addition is 1.2% of a pinenut weight, and synergist citric acid addition is 0.03% of a pinenut weight. The raw material that adds anti-oxidant by proportioning is loaded on extraction kettle, seals with sealing ring.
The ethanol of 95% concentration (selecting absolute ethyl alcohol for use) is made entrainer, and use amount is 8% of a pinenut weight, injects and carries in the agent jar.Wait to freeze end and extraction kettle and separation reactor I, II preheat temperature during, open the entrainer pump and entrainer is pressed in the extraction kettle CO near design temperature
2Flow-control when treating extraction kettle pressure near setting pressure 28MPa, is controlled the pressure of extraction kettle and separation reactor I, II at 20L/h; When treating that pressure, temperature conform to setting value, pick up counting extraction time 2.5h.Extraction finishes the back and from separating still, emits grease, and gas in the emptying extraction kettle is opened the extraction kettle capping, takes out extract remainder.
The supercritical CO of example 3 pine-seed oils
2The extraction preparation method implements 3
/ 4th broken pinenuts are raw material; Collection excess oil slag behind the oil and grease extracting will be used to process the soft package instant pinenut; So it is little to require extraction process that pine nut benevolence outward appearance is destroyed, and extracts the part grease and gets final product, the grease that is retained in the extract remainder is used to improve instant pinenut local flavor.
Connect general supply; Start refrigerating plant, start the heater of extraction kettle, separating still, extraction kettle adopts 40 ℃, separates I and adopts 10MPa, 45 ℃; Separate II and adopt 6MPa, 30 ℃./ 4th broken pinenuts after using pine nut to shell are raw material, and the antioxidant material ginger powder is added in the pinenut raw material, and addition is 2.5% of a pinenut weight, and synergist citric acid addition is 0.03% of a pinenut weight. The raw material that adds anti-oxidant by proportioning is loaded on extraction kettle, seals with sealing ring.
Select for use absolute ethyl alcohol to make entrainer, use amount is 5% of a pinenut, injects and carries in the agent jar.Wait to freeze end and extraction kettle and separation reactor I, II preheat temperature during, open the entrainer pump and entrainer is pressed in the extraction kettle CO near design temperature
2Flow-control when treating extraction kettle pressure near setting pressure 30MPa, is controlled the pressure of extraction kettle and separation reactor I, II at 20L/h; When treating that pressure, temperature conform to setting value, pick up counting extraction time 2.0h.Extraction finishes the back and from separating still, emits grease, and gas in the emptying extraction kettle is opened the extraction kettle capping, takes out extract remainder.
The supercritical CO of example 4 pine-seed oils
2The extraction preparation method implements 4
Use pulverizing 40 purpose pine nut benevolence to be raw material; Collection excess oil slag behind the oil and grease extracting will be used to process compound pinenut nutrient powder; So require extraction process to reach abundant extraction to pine nut benevolence; Extract more than 80% of the contained grease of pine nut benevolence, add rice-chestnut powder through following process, walnut powder will make the compound pinenut nutrient powder fat of final products≤5%.
Connect general supply; Start refrigerating plant, start the heater of extraction kettle, separating still, extraction kettle adopts 45 ℃, separates I and adopts 10MPa, 35 ℃; Separate II and adopt 5MPa, 30 ℃.Use pulverizing 40 purpose pine nut benevolence to be raw material, the antioxidant material ginger powder is added in the pinenut raw material, addition is 2% of a pinenut weight, and synergist citric acid addition is 0.03% of a pinenut weight. The raw material that adds anti-oxidant by proportioning is loaded on extraction kettle, seals with sealing ring.
The ethanol of 95% concentration is made entrainer, and use amount is 7% of a pinenut weight, injects and carries in the agent jar.Wait to freeze end and extraction kettle and separation reactor I, II preheat temperature during, open the entrainer pump and entrainer is pressed in the extraction kettle CO near design temperature
2Flow-control when treating extraction kettle pressure near setting pressure 30MPa, is controlled the pressure of extraction kettle and separation reactor I, II at 25 L/h; When treating that pressure, temperature conform to setting value, pick up counting extraction time 3.0h.Extraction finishes the back and from separating still, emits grease, and gas in the emptying extraction kettle is opened the extraction kettle capping, takes out extract remainder.
The supercritical CO of example 5 pine-seed oils
2The extraction preparation method implements 5
Use to be crushed to>=the pine nut benevolence of 40 order combination grains is raw material; Collection excess oil slag behind the oil and grease extracting will be used to process compound pinenut nutrient powder; So require extraction process to reach abundant extraction to pine nut benevolence; Extract more than 80% of the contained grease of pine nut benevolence, add rice-chestnut powder through following process, walnut powder will make the compound pinenut nutrient powder fat of final products≤5%.
Connect general supply; Start refrigerating plant, start the heater of extraction kettle, separating still, extraction kettle adopts 45 ℃, separates I and adopts 8MPa, 40 ℃; Separate II and adopt 5MPa, 35 ℃.Use pulverizing 40 purpose pine nut benevolence to be raw material, the antioxidant material ginger powder is added in the pinenut raw material, addition is 5% of a pinenut weight, and synergist citric acid addition is 0.05% of a pinenut weight. The raw material that adds anti-oxidant by proportioning is loaded on extraction kettle, seals with sealing ring.
The ethanol of 99% concentration is made entrainer, and use amount is 5% of a pinenut weight, injects and carries in the agent jar.Wait to freeze end and extraction kettle and separation reactor I, II preheat temperature during, open the entrainer pump and entrainer is pressed in the extraction kettle CO near design temperature
2Flow-control when treating extraction kettle pressure near setting pressure 25MPa, is controlled the pressure of extraction kettle and separation reactor I, II at 25L/h; When treating that pressure, temperature conform to setting value, pick up counting extraction time 3.0h.Extraction finishes the back and from separating still, emits grease, and gas in the emptying extraction kettle is opened the extraction kettle capping, takes out extract remainder.
Example 6 soft package instant pinenut processing methods implement 1
Supercritical CO with pine-seed oil
2Whole grain pinenut collection excess oil slag among the extraction preparation method embodiment 1 behind the extraction grease is processed.Earlier with salt 5.5%, Radix Glycyrrhizae 5.0%, anistree 0.2%, Chinese prickly ash 0.1%, cassia bark 0.2%, galingal 0.1%, add 2 times of collection excess oil slag volumes poach system 90 minutes, be cooled to below 10 ℃, filter, get filtrating, with pinenut pickle 4 hours tasty,, the pinenut that will pickle measures packing by specification; Seal with vacuum packing machine the pack back; The condition of sealing is: vacuum 0.09 MPa; 30 kilovolts of heat-sealing voltages; Sterilization: the pinenut that will pack after sealing is put into the cannery retort sterilization, and sterilization conditions is: 121 ℃, and 30 minutes.After cooling, insulation, check, process finished product, be processed into the soft package instant pinenut.
Example 7 soft package instant pinenut processing methods implement 2
Supercritical CO with pine-seed oil
2/ 2nd broken pinenuts collection excess oil slags among the extraction preparation method embodiment 2 behind the extraction grease are processed.Earlier with salt 3.5%, Radix Glycyrrhizae 3.0%, anistree 0.3%, Chinese prickly ash 0.2%, cassia bark 0.1%, galingal 0.3%, add 2.5 times of collection excess oil slag volumes poach system 80 minutes, be cooled to below 10 ℃, filter, get filtrating, with pinenut pickle 2.5 hours tasty,, the pinenut that will pickle measures packing by specification; Seal with vacuum packing machine the pack back; The condition of sealing is: vacuum 0.09 MPa; 30 kilovolts of heat-sealing voltages; Sterilization: the pinenut that will pack after sealing is put into the cannery retort sterilization, and sterilization conditions is: 121 ℃, and 30 minutes.After cooling, insulation, check, process finished product, be processed into the soft package instant pinenut.
Example 8 soft package instant pinenut processing methods implement 3
Supercritical CO with pine-seed oil
2Whole grain pinenut among the extraction preparation method embodiment 1 behind the extraction grease is processed.Earlier with salt 3.0%, Radix Glycyrrhizae 2.0%, anistree 0.5%, Chinese prickly ash 0.2%, cassia bark 0.15%, galingal 0.2%, add 1.5 times of extract remainder volumes poach system 60 minutes, be cooled to below 10 ℃, filter, get filtrating, with pinenut pickle 3 hours tasty,, the pinenut that will pickle measures packing by specification; Seal with vacuum packing machine the pack back; The condition of sealing is: vacuum 0.09 MPa; 30 kilovolts of heat-sealing voltages; Sterilization: the pinenut that will pack after sealing is put into the cannery retort sterilization, and sterilization conditions is: 121 ℃, and 30 minutes.After cooling, insulation, check, process finished product, be processed into the soft package instant pinenut.
Example 9 compound pinenut nutrient powder processing methods implement 1
To be crushed to 40 order pinenut supercritical COs
2Extraction is extracted collection excess oil slag oven dry behind the grease after be milled to 80 orders, adds 25% rice-chestnut powder, and 15% walnut powder makes protein content>=65%; Fat≤5% dried by the fire 45 minutes down at 35 ℃, was dried to moisture≤7%, packing, quality inspection.
Example 10 compound pinenut nutrient powder processing methods implement 2
To be crushed to 40 order pinenut supercritical COs
2Extraction is extracted collection excess oil slag oven dry behind the grease after be milled to 80 orders, adds 30% rice-chestnut powder, and 10% walnut powder makes protein content>=65%; Fat≤5% dried by the fire 50 minutes down at 40 ℃, was dried to moisture≤7%, packing, quality inspection.
Claims (4)
1. extraction of pine nut method is characterized in that processing step is:
Connect general supply; Start refrigerating plant, start the heater of extraction kettle, separating still
(1) preliminary treatment of raw material
1. antioxidant material preliminary treatment
Adopt 6～8 months ginger of growth that it is cleaned, be cut into the thick thin slice of 2cm after draining, be dried to moisture content about 40% in 20～25 ℃, pulverizer is pulverized, and continues to be dried to moisture content 10%, and is subsequent use;
2. pine nut pretreatment of raw material
With pine nut shelling, remove scarlet, obtain pine nut benevolence, the processing of pine nut benevolence is divided into and is crushed to 40 orders, 1/4th fragmentations, 1/2nd is broken and whole;
(2) supercritical CO
2Extracting pine-seed oil technology
Ginger powder is added in the pine nut benevolence raw material, and addition is 1～5% of a pine nut benevolence weight, and synergist citric acid addition is 0.02～0.05% of a pine nut benevolence weight;
Mixing of materials evenly is loaded on extraction kettle, seals with sealing ring, by 3～10% of extraction material add concentration be 58～99% ethanol as entrainer, inject and carry in the agent jar;
Extraction kettle adopts 15～35MPa, 45 ± 10 ℃, separates I and adopts 8 ± 5MPa, 40 ± 10 ℃; Separate II and adopt 5 ± 5MPa, 35 ± 10 ℃; Treat that cold machine temperature reaches 4 ℃, and extraction kettle, separate I, when separating the II preheat temperature, open the entrainer high-pressure pump entrainer is pressed into extraction kettle near design temperature; The extraction parameter is CO
2Flow is at 20～25L/h, and extracting pressure adopts 15～35MPa, the pressure of control extraction kettle and separation reactor I, II; When treating that pressure, temperature conform to setting value, pick up counting, extraction 1.5～3h, extraction is emitted grease after finishing from separating still, and gas in the emptying extraction kettle is opened the extraction kettle capping, takes out extract remainder;
Wherein, said entrainer: concentration is 58～99% ethanol, and use amount is 3～10% of the extraction material.
2. according to the said extraction of pine nut method of claim 1, it is characterized in that saidly in the 2. pine nut pretreatment of raw material of step (1), be under the 40 order situation in the raw material crushing degree, step (2) supercritical CO
2In the extracting pine-seed oil technology, the entrainer concentration of ethanol is 95%, and addition is 5% of the extraction material.
3. the manufacturing approach of soft package instant pinenut according to claim 1 is characterized in that:
Material formula: with whole grain pine nut benevolence, 1/4th fragmentations; / 2nd broken pine nut benevolence extract remainders through extracting after are benchmark, the water that the salt with 3～8%, 2～5% Radix Glycyrrhizae, 0.2～0.5% anise, 0.1～0.5% Chinese prickly ash, 0.1～0.3% cassia bark, 0.1～0.3% galingal, interpolation pine nut benevolence extract remainder volume are 1.5～3 times;
Operating procedure is: with above-mentioned condiment boiling 50～90 minutes, cooling was filtered; 2～4h in the pine nut benevolence collection excess oil slag immersion filtrating that filters out is pickled pine nut benevolence tasty, that will pickle measure packing by specification, seal with vacuum packing machine the pack back, and the condition of sealing is: vacuum 0.09 MPa; 30 kilovolts of heat-sealing voltages, sterilization: the pine nut benevolence that will pack after sealing is put into the cannery retort sterilization, and sterilization conditions is: 115～129 ℃; 23～35 minutes, through cooling, insulation, check.
4. the manufacturing approach of compound pinenut nutrient powder according to claim 1; It is characterized in that: will be crushed to the collection excess oil slag after 40 order pine nut benevolence are extracted grease, and be milled to 80 orders after the oven dry, and add 10～30% rice-chestnut powder; 5～25% walnut powder makes protein content>=65%; Fat≤3% dries by the fire 30～50min down at 25～40 ℃, is dried to moisture≤7%, packing, quality inspection.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710157817XA CN101161113B (en) | 2007-10-29 | 2007-10-29 | Abstraction of pine nut oil, residual oil cake food after abstracting and its preparing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710157817XA CN101161113B (en) | 2007-10-29 | 2007-10-29 | Abstraction of pine nut oil, residual oil cake food after abstracting and its preparing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101161113A CN101161113A (en) | 2008-04-16 |
| CN101161113B true CN101161113B (en) | 2012-07-25 |
Family
ID=39296153
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200710157817XA Active CN101161113B (en) | 2007-10-29 | 2007-10-29 | Abstraction of pine nut oil, residual oil cake food after abstracting and its preparing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101161113B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120213874A1 (en) * | 2008-07-09 | 2012-08-23 | Himalaya Global Holdings Ltd | Herbal solid formulation and process for preparing the same |
| CN101974366A (en) * | 2010-09-07 | 2011-02-16 | 长春大学 | Process for extracting walnut oil from large walnut kernels through supercritical extraction |
| CN102127486B (en) * | 2011-01-15 | 2012-04-25 | 湖南山润油茶科技发展有限公司 | Tea oil residue hardened paste and oil pressing method |
| CN102532086B (en) * | 2012-01-12 | 2013-07-31 | 北京林业大学 | Method for extracting proanthocyanidins from dahurian larch bark |
| CN103789084A (en) * | 2014-02-18 | 2014-05-14 | 薛传校 | Pine-seed oil and preparation method and use thereof |
| CN106579400A (en) * | 2015-10-19 | 2017-04-26 | 北京特生物化工有限公司 | Grain taking caragana seeds as main raw material and making method of grain |
| CN106433953A (en) * | 2016-11-10 | 2017-02-22 | 谭挺 | Preparation process of pinus yunnanensis pine nut oil |
| CN108342251A (en) * | 2018-05-08 | 2018-07-31 | 深圳市仙迪化妆品有限公司 | One seed pod oil and the preparation method and application thereof |
| CN108850549A (en) * | 2018-06-25 | 2018-11-23 | 天柱县森源米业有限责任公司 | A kind of defatted rice bran Multi-strain fermentation technology |
| CN109673980A (en) * | 2018-10-15 | 2019-04-26 | 广东金妮宝科技发展有限公司 | A kind of nutritional meal replacement powder and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1465682A (en) * | 2002-06-24 | 2004-01-07 | 东北林业大学 | Working method of supercritical carbon dioxide extracting pine-seed oil |
| CN1477181A (en) * | 2003-07-18 | 2004-02-25 | 孙传经 | Method for extracting walnut oil and pine oil by using supercritical CO2 reverse extrastion process |
-
2007
- 2007-10-29 CN CN200710157817XA patent/CN101161113B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1465682A (en) * | 2002-06-24 | 2004-01-07 | 东北林业大学 | Working method of supercritical carbon dioxide extracting pine-seed oil |
| CN1477181A (en) * | 2003-07-18 | 2004-02-25 | 孙传经 | Method for extracting walnut oil and pine oil by using supercritical CO2 reverse extrastion process |
Non-Patent Citations (1)
| Title |
|---|
| 胡小泓等.超临界CO_2对整粒松仁萃取的研究.《中国油脂》.2004,第29卷(第03期),62-64. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101161113A (en) | 2008-04-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101161113B (en) | Abstraction of pine nut oil, residual oil cake food after abstracting and its preparing method | |
| CN101584474B (en) | Sea cucumber blueberry health care wine and method for processing same | |
| CN103340387B (en) | Production method of sauce made of moringa oleifera leaves | |
| CN101180998A (en) | Gold vinegar tea beverage and manufacturing technology | |
| CN101020879A (en) | Process of producing fermented wolfberry fruit yellow wine | |
| CN102827752A (en) | Paeonia suffruticosa vinegar and preparation method thereof | |
| CN101797039A (en) | Liquorice health-care beverage | |
| CN104783063A (en) | Pumpkin stomach nourishing rice wine and preparation method thereof | |
| CN108517264A (en) | A kind of fruit wine of nutrition and health care and preparation method thereof | |
| CN106811371A (en) | A kind of blackberry, blueberry health liquor and preparation method thereof | |
| CN110184157A (en) | Deer blood, alcoholic drink mixed with fruit juice of rhizoma polygonati and preparation method thereof is added by wine base of mulberries fermented wine | |
| KR101698551B1 (en) | Chokeberry containing rice wine production methods | |
| CN105639633B (en) | A kind of composite pawpaw glycoprotein ferment and its production method | |
| CN105199917B (en) | Green plum barley wine and its brew method | |
| CN105420035A (en) | Preparation method for applying medlar and maca for producing high-function health liquor | |
| CN108142766A (en) | A kind of dendrobium candidum beverage and preparation method thereof | |
| CN101333485B (en) | Mulberry wine and preparation method thereof | |
| CN110079424A (en) | One kind is with Chinese olive, annesl, the mixing wine brewing of maturity period mulberry fruit and preparation method thereof | |
| CN107557243B (en) | Mixed brewed Nuomei melon wine and preparation method thereof | |
| CN106753974A (en) | A kind of mulberry fruit lily wine | |
| CN106417651B (en) | Mulberry fermented bean curd and production process thereof | |
| KR101862786B1 (en) | Ginseng sheet and method for manufacturing thereof | |
| CN1358834A (en) | Method for preparing health care herbal liquor | |
| CN108157699B (en) | Pseudo-ginseng polysaccharide beverage and preparation method thereof | |
| CN1172951C (en) | Preparation method of glycyrrizin crystal |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |