CN101158113A - Environment-friendly type highly effective scouring agent - Google Patents

Environment-friendly type highly effective scouring agent Download PDF

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Publication number
CN101158113A
CN101158113A CNA2007101313677A CN200710131367A CN101158113A CN 101158113 A CN101158113 A CN 101158113A CN A2007101313677 A CNA2007101313677 A CN A2007101313677A CN 200710131367 A CN200710131367 A CN 200710131367A CN 101158113 A CN101158113 A CN 101158113A
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CN
China
Prior art keywords
scouring agent
environment
friendly
sup
sub
Prior art date
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Granted
Application number
CNA2007101313677A
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Chinese (zh)
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CN101158113B (en
Inventor
陆建辉
王玉丰
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NANTONG KEXING CHEMICAL INDUSTRY Co Ltd
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NANTONG KEXING CHEMICAL INDUSTRY Co Ltd
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Application filed by NANTONG KEXING CHEMICAL INDUSTRY Co Ltd filed Critical NANTONG KEXING CHEMICAL INDUSTRY Co Ltd
Priority to CN2007101313677A priority Critical patent/CN101158113B/en
Publication of CN101158113A publication Critical patent/CN101158113A/en
Application granted granted Critical
Publication of CN101158113B publication Critical patent/CN101158113B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention discloses an environment-friendly scouring agent with high efficiency, which essentially comprises fatty amide, polyethenoxy ether, succinic acid, monoester sulfonate, C<SUB>12 to 14</SUB> alkyl polysaccharide glycoside, isomery C<SUB>13</SUB> hydrin polyethenoxy ether sodium dicarboxylic acid, secondary alkane sulfonate, chelating dispersant KX130 and water. The environment-friendly scouring agent with high efficiency that the invention provides has the advantages that: (1) the scouring agent is environment-friendly because the selected raw and supplementary materials are environment-friendly products and are degraded biologically into innoxious substance after entering into natural environment; (2) the scouring agent has good compatibility and high stability after compositing; (3) the scouring agent has strong resistance to alkali, the alkali resistivity is more than or equal to 240 g/L NaOH; (4) the scouring agent has strong penetrability, the sailcloth of 20 DEG C subsides less than or equal to 8S and has good emulsifying ability and detergent washing ability; (5) the scouring agent has good stability for hydrogen peroxide and the resolution ratio of the hydrogen peroxide is less than 10 percent; (6) the scouring agent has strong chelating power for metal ion and has good chelation on Cu<SUP>2+</SUP>, Fe<SUP>3+</SUP> in bleaching liquor and improves the stability of the hydrogen peroxide, etc.

Description

Environment-friendly type highly effective scouring agent
Technical field:
The present invention relates to a kind of scouring agent.
Background technology
Adjustment along with national industrial policies, reach further raising to the environmental requirement of traditional textile dyeing, traditional scouring and bleaching processing since its have that board is many, the time is long, efficient is low, energy consumption is high and the grey cloth defect more than etc. shortcoming, progressively replaced by the pre-treatment abbreviated system.
It is short that abbreviated system has flow process, low for equipment requirements, energy savings, efficient height, advantages such as compliance with environmental protection requirements, for guaranteeing that the pre-treatment abbreviated system reaches high efficiency, high-quality must strict design and control process, outstanding " height; heat; clean " three aspects, and wherein " height " promptly refers to pad working solution band liquid measure and wants high, and suitably improves the concentration of hydrogen peroxide and caustic soda, to guarantee that sufficient reactive material is arranged on the processed fabric, this just has higher requirement to employed auxiliary agent, and scouring agent particularly is because of it mainly is to cooperate caustic soda and hydrogen peroxide to remove impurity in the natural fabric (as pectin, cotton wax, protein, grease, slurry, oil stain etc.) and the bleaching, reach the capillary effect height, the band liquid measure is big, and then play concise even saturating, the purpose that removal of impurities is good and whiteness significantly improves, so should anti-highly basic, powerful oxidation corrosion resistance agent again, in addition, it is without phosphorus that the scouring agent product also will meet analyte, harmful components such as phenols are not to the people, poultry and environment work the mischief, and adapt to sustainable development and environmental requirement.
Summary of the invention:
The object of the present invention is to provide the good environment-friendly type highly effective scouring agent of a kind of performance.
Technical solution of the present invention is:
A kind of environment-friendly type highly effective scouring agent is characterized in that: mainly be made up of the composition of following percentage by weight:
Fatty acid amide polyoxyethylene ether mono succinate sodium sulfonate (AMESS) 15-20%
C 12~14APG (C 12~14APG) 15-25%
Isomery C 13Alcohol polyoxyethylene ether carboxylic acid sodium (AEC-13) 15-25%
Seconary Alkane Sulphonate Sodium 10-15%
Chelated dispersants KX130 0.1-1%
Water 18~40%.
The defoamer that also contains 0-0.01% weight.Defoamer is X-40Z.
Environment-friendly type highly effective scouring agent provided by the present invention has 1. environmental protection, and selected raw and auxiliary material is environment-friendly products, enter nature after, all can biodegradation become innocuous substance; 2. compatibility is good, and compatibility is good, compound rear stability height; 3. anti-highly basic, alkali resistance 〉=240g/L NaOH; 4. penetrability is strong, and 20 ℃ of canvas sedimentation≤8S have good emulsifying ability and washing ability; 5. good to stabilized hydrogen peroxide, decomposing hydrogen dioxide solution rate<10%; 6. strong to metal ion-chelant power, to the Cu in the bleaching liquor 2+, Fe 3+Have good chelation, improve advantages such as stabilized hydrogen peroxide.
The invention will be further described below in conjunction with embodiment.
The specific embodiment:
Embodiment 1:
A kind of environment-friendly type highly effective scouring agent, make by composition mixing, the stirring of following percentage by weight:
Fatty acid amide polyoxyethylene ether mono succinate sodium sulfonate 15%
C 12~14APG 20%
Isomery C 13Alcohol polyoxyethylene ether carboxylic acid sodium 20%
Seconary Alkane Sulphonate Sodium 8%
Chelated dispersants KX130 0.1%
Water 36.9%.
Embodiment 2:
A kind of environment-friendly type highly effective scouring agent, make by composition mixing, the stirring of following percentage by weight:
Fatty acid amide polyoxyethylene ether mono succinate sodium sulfonate 18%
C 12~14APG 25%
Isomery C 13Alcohol polyoxyethylene ether carboxylic acid sodium 15%
Seconary Alkane Sulphonate Sodium 12%
Chelated dispersants KX130 0.5%
Water 29.5%.
Embodiment 3:
A kind of environment-friendly type highly effective scouring agent, make by composition mixing, the stirring of following percentage by weight:
Fatty acid amide polyoxyethylene ether mono succinate sodium sulfonate 20%
C 12~14APG 15%
Isomery C 13Alcohol polyoxyethylene ether carboxylic acid sodium 25%
Seconary Alkane Sulphonate Sodium 15%
Chelated dispersants KX130 1%
Water 24%.
Embodiment 4:
A kind of environment-friendly type highly effective scouring agent, make by composition mixing, the stirring of following percentage by weight:
Fatty acid amide polyoxyethylene ether mono succinate sodium sulfonate 20%
C 12~14APG 23%
Isomery C 13Alcohol polyoxyethylene ether carboxylic acid sodium 22%
Seconary Alkane Sulphonate Sodium 14.9%
Chelated dispersants KX130 0.09%
Defoamer X-40Z (or defoamer S-17H or defoamer W40-50) 0.01%
Water 20%.
The environment-friendly type highly effective scouring agent that the foregoing description obtains, its main quality index:
The outward appearance light yellow transparent liquid
Ionic non-/ anion
PH value 7~9
Active matter content 〉=45%
Alkali resistance 〉=240g/LNaOH
Decomposing hydrogen dioxide solution rate<10%
20 ℃ of canvas sedimentation≤8S of penetrability
Cloud point>100 ℃.

Claims (3)

1. environment-friendly type highly effective scouring agent is characterized in that: mainly be made up of the composition of following percentage by weight:
Fatty acid amide polyoxyethylene ether mono succinate sodium sulfonate 15-20%
C 12~14APG 15-25%
Isomery C 13Alcohol polyoxyethylene ether carboxylic acid sodium 15-25%
Seconary Alkane Sulphonate Sodium 10-15%
Chelated dispersants KX130 0.1-1%
Water 18~40%.
2. environment-friendly type highly effective scouring agent according to claim 1 is characterized in that: the defoamer that also contains 0-0.01% weight.
3. environment-friendly type highly effective scouring agent according to claim 2 is characterized in that: defoamer is X-40Z.
CN2007101313677A 2007-08-28 2007-08-28 Environment-friendly type highly effective scouring agent Expired - Fee Related CN101158113B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2007101313677A CN101158113B (en) 2007-08-28 2007-08-28 Environment-friendly type highly effective scouring agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2007101313677A CN101158113B (en) 2007-08-28 2007-08-28 Environment-friendly type highly effective scouring agent

Publications (2)

Publication Number Publication Date
CN101158113A true CN101158113A (en) 2008-04-09
CN101158113B CN101158113B (en) 2011-05-25

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Application Number Title Priority Date Filing Date
CN2007101313677A Expired - Fee Related CN101158113B (en) 2007-08-28 2007-08-28 Environment-friendly type highly effective scouring agent

Country Status (1)

Country Link
CN (1) CN101158113B (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101498101B (en) * 2008-07-11 2011-01-12 浙江传化股份有限公司 Non-phosphate scouring agent and preparation thereof
CN102505468A (en) * 2011-10-19 2012-06-20 信阳市环宇针织服装有限公司 Nano tea saponin environmental-friendly high-efficiency refining agent and preparation method thereof
CN102535156A (en) * 2011-12-23 2012-07-04 北京光华纺织集团有限公司 Refining agent for color cotton
CN102644195A (en) * 2012-04-01 2012-08-22 祝洪哲 Functional additive for fibrilia modification and one-bath bleaching and preparation method thereof
CN102704266A (en) * 2012-05-22 2012-10-03 杭州美高华颐化工有限公司 High-efficiency scouring agent containing glucose structural units and preparation method thereof
CN102787499A (en) * 2012-07-24 2012-11-21 苏州市华元化工有限公司 Multifunctional refining agent and its production method
CN102787500A (en) * 2012-07-24 2012-11-21 苏州市华元化工有限公司 Refining agent for novel synthetic fibers
CN106283635A (en) * 2016-08-22 2017-01-04 绍兴市柯桥区科创高新技术开发中心 A kind of cotton scouring agent
CN106498742A (en) * 2016-10-14 2017-03-15 无锡市华诚印染剂厂 Scouring agent for color cotton fabric
CN108070465A (en) * 2017-11-14 2018-05-25 广州先盈生物科技有限公司 Multi-functional Clean products and preparation method thereof
CN108755199A (en) * 2018-06-20 2018-11-06 南通联发印染有限公司 The long vehicle dyeing production of cotton and protein fibre blended yarn weaved fabric
CN109837733A (en) * 2019-01-29 2019-06-04 合肥市东方美捷分子材料技术有限公司 A kind of cellulose fibre ecological energy-saving degreasing bleaching process
CN112593409A (en) * 2020-12-03 2021-04-02 广东湛丰精细化工有限公司 Scouring and bleaching liquid for continuous steaming of cotton and blended knitted fabric thereof and scouring and bleaching process

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100451234C (en) * 2005-06-09 2009-01-14 江苏欣捷衬布有限公司 Environmental protection typed high performance scouring agent
CN100999869A (en) * 2006-01-13 2007-07-18 上海申达二印染整有限公司 Textile printing and dyeing pretreating agent and application thereof

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101498101B (en) * 2008-07-11 2011-01-12 浙江传化股份有限公司 Non-phosphate scouring agent and preparation thereof
CN102505468B (en) * 2011-10-19 2013-10-09 信阳市环宇针织服装有限公司 Nano tea saponin environmental-friendly high-efficiency refining agent and preparation method thereof
CN102505468A (en) * 2011-10-19 2012-06-20 信阳市环宇针织服装有限公司 Nano tea saponin environmental-friendly high-efficiency refining agent and preparation method thereof
CN102535156A (en) * 2011-12-23 2012-07-04 北京光华纺织集团有限公司 Refining agent for color cotton
CN102644195A (en) * 2012-04-01 2012-08-22 祝洪哲 Functional additive for fibrilia modification and one-bath bleaching and preparation method thereof
CN102644195B (en) * 2012-04-01 2014-03-12 祝洪哲 Functional additive for fibrilia modification and one-bath bleaching and preparation method thereof
CN102704266A (en) * 2012-05-22 2012-10-03 杭州美高华颐化工有限公司 High-efficiency scouring agent containing glucose structural units and preparation method thereof
CN102787500A (en) * 2012-07-24 2012-11-21 苏州市华元化工有限公司 Refining agent for novel synthetic fibers
CN102787499A (en) * 2012-07-24 2012-11-21 苏州市华元化工有限公司 Multifunctional refining agent and its production method
CN106283635A (en) * 2016-08-22 2017-01-04 绍兴市柯桥区科创高新技术开发中心 A kind of cotton scouring agent
CN106283635B (en) * 2016-08-22 2018-08-31 绍兴市柯桥区科创高新技术开发中心 A kind of cotton scouring agent
CN106498742A (en) * 2016-10-14 2017-03-15 无锡市华诚印染剂厂 Scouring agent for color cotton fabric
CN108070465A (en) * 2017-11-14 2018-05-25 广州先盈生物科技有限公司 Multi-functional Clean products and preparation method thereof
CN108755199A (en) * 2018-06-20 2018-11-06 南通联发印染有限公司 The long vehicle dyeing production of cotton and protein fibre blended yarn weaved fabric
CN108755199B (en) * 2018-06-20 2020-09-18 南通联发印染有限公司 Long-time dyeing production method of cotton and protein fiber blended fabric
CN109837733A (en) * 2019-01-29 2019-06-04 合肥市东方美捷分子材料技术有限公司 A kind of cellulose fibre ecological energy-saving degreasing bleaching process
CN109837733B (en) * 2019-01-29 2021-08-31 合肥市东方美捷分子材料技术有限公司 Vitamin state energy-saving degreasing bleaching process for cellulose fibers
CN112593409A (en) * 2020-12-03 2021-04-02 广东湛丰精细化工有限公司 Scouring and bleaching liquid for continuous steaming of cotton and blended knitted fabric thereof and scouring and bleaching process

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PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Environmental protection typed high performance scouring agent

Effective date of registration: 20160628

Granted publication date: 20110525

Pledgee: Jiangsu Finance & Investment Company limited by guarantee

Pledgor: Jiangsu Gemei High-Tech Development Co., Ltd.

Registration number: 2016980000087

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CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20110525

Termination date: 20170828