[summary of the invention]
[technical problem that will solve]
The purpose of this invention is to provide a kind of micropore infiltrating irrigation pipeline that is suitable for agricultural, treegarden irrigation fertilising usefulness, another object of the present invention provides the preparation method of described micropore infiltrating irrigation pipeline.
[technical scheme]
The invention provides a kind of preparation method of micropore infiltrating irrigation pipeline, this method comprises the steps:
(1), clean rubber and plastics pulverized respectively be 45-70 purpose powdery, the two mixes with the ratio that is respectively 55-75 part and 20-40 part by weight;
(2), in said mixture, add 2-4 part Petropols, 0.4-0.6 part blowing agent, 0.4-0.6 part heat stabilizer and 0.6-1.4 part ethylene-vinyl acetate copolymer (EVA) back stirring 20-40min by weight, granulation;
(3), with gained particle extrusion modling in the step (2).
Rubber described in the above-mentioned steps (1) and plastics can utilize discarded rubber and plastics, as discarded tire, waste and old polyethylene (PE) product such as worn-out agricultural film, mulch film, refuse bag etc., above-mentioned discarded object is cleaned, made powder after the oven dry, and the back granulation also can be cleaned, be dried to wherein said plastics; Rubber and plastic powders are preferably the 55-65 order, and weight proportion is preferably 60-70: 25-35 part.
Petropols described in the above-mentioned steps (2) are that single, double olefinic constituents is a kind of solid shape or the aqueous polymer of raw material through being polymerized in the carbon five (C5), carbon nine (C9) cut of by-product during with petroleum cracking system ethene, mainly play viscosifying action;
Described blowing agent is an organic foaming agent, as azo compound, N-nitroso compound and sulfonyl hydrazines compound etc., its effect is to obtain to have the microcellular structure polymer product by discharging gas, reach the purpose that reduces the goods apparent density, as long as can achieve the above object, can use existing commodity, as in H blowing agent, AC, ACK, ACM, DD-1, DD-2, STK-1, STK-2, STK-M1, ACY-1 and the ACY-2 blowing agent one or more; Preferred in the present invention H blowing agent or AC (Celogen Az);
Described heat stabilizer is optional from polyvinyl chloride and vinyl chloride copolymer, organic stabilizers such as main stabilizers such as base lead salt class, metallic soap class, organic tin, antimony organic class and epoxide class, phosphorous acid esters, polyalcohols, can use existing commodity, as in CT-50A, methyl tin, nontoxic phosphite ester DB-1500, mercaptan antimony, the polyoxyethylene one or more; Preferable methyl tin in the present invention;
Described ethylene-vinyl acetate copolymer can obtain by commodity purchasing, as Leo (Dongguan) plastic raw materials Co., Ltd sell 7350,7240,630, the EVA of MH40, MP441, various models such as 18-3,14-2.
When above-mentioned various raw materials were stirred, mixing speed was 400-600 rev/min, was preferably 460-540 rev/min.
Can be with existing plastics or the employed extruder of rubber process industry during extrusion modling in the above-mentioned steps (3), KD-1280F type injection machine as the production of Ningbo City Venus plastics machinery Co., Ltd, the TEE-95 type parallel dual-screw extruder that Nanjing Rhea high polymer Co., Ltd produces, three layers of extruder of SJ-65 type that Rui'an City red flag plastics package machinery Co., Ltd produces etc.
The present invention also provides the micropore infiltrating irrigation pipeline that is obtained by method for preparing, and it is a kind of hollow tube.
The tube wall of micropore infiltrating irrigation pipeline of the present invention from outward appearance to inner essence is covered with irregular crooked micropore, described micropore is evenly distributed, the size of micropore size can make hydrone and fertilizer, pesticide molecule pass, and can prevent the obstruction that silt and root system of plant cause effectively.
The density of micropore infiltrating irrigation pipeline of the present invention is 40-110kg/m
3, be preferably 65-85kg/m
3Pipe thickness is 1.5-3mm, can select for use according to different hydraulic pressure and edaphic condition.
The physical and mechanical properties parameter of micropore infiltrating irrigation pipeline of the present invention is as follows:
According to standard GB/T2406 test, its oxygen index (OI) 〉=35; According to standard GB/T8333 test, its average burning time≤30s, average burning height≤140mm; According to standard GB/T8332 test, its average combustion range≤40mm; According to standard GB/T8627 test, its smoke density grade (SDR)≤70.
Its thermal conductivity factor is 0 ℃ of test down, and the result is less than 0.03W/ (M.K); Its moisture permeable coefficient is less than 4.4 * 10
-10G/ (M.S.PA), the wet resistance factor is 4.5 * 10
-2-6.0 * 10
-2Its vacuum dehydration rate is 3-9%; Its dimensional stability is tested 7d under 105 ± 3.7 ℃ temperature, be 6-8%; Its tearing strength is 3.50-7.0N/cm; Its compression rebound degree is tested 72h under 50% compression ratio, be 75-80%.
Micropore infiltrating irrigation pipeline of the present invention has ozone resistance preferably, places 200h and do not chap under ozone partial pressure 202Pa.And have ageing resistance preferably, through only slightly wrinkling after the test of 150h, flawless, free of pinholes, indeformable.
Micropore infiltrating irrigation pipeline infiltration of the present invention is even, and its operating pressure is the 0.1-0.5 kilogram, can regulate according to different edaphic condition; Its water percolating capacity and operating pressure, pore size are relevant, are 1.4-4.2kg/min; Its infiltration effective length is 40-80m.Infiltration soil texture state is trapezoidal during its work, generally when work 15min, infiltration soil upper width is 15-20cm, soil is 12-18cm down, permeability is 50-60cm/15min, makes steam ratio of specific heat example coordination in the soil, can not make soil block, soil erosion, and can suppress the secondary salinization of soil problem of soil.
Micropore infiltrating irrigation pipeline Applicable temperature scope of the present invention is wide, can both keep good performance down at-40-105 ℃.
Micropore infiltrating irrigation pipeline of the present invention can be according to the different demands of region and plant, and prepare different cross sectional shapes, thickness, length etc.
The micropore infiltrating irrigation pipeline scope of application of the present invention is extensive, is applicable to all kinds soil and various types of plant, especially use in the area of serious water shortages such as desert, wasteland can economize on water significantly, energy-conservation.
Micropore infiltrating irrigation pipeline of the present invention can also combine with auto-control and potential device, realizes intelligent management, reasonably carries moisture, fertilizer and agricultural chemicals for plant.
[three] beneficial effect
That micropore infiltrating irrigation pipeline of the present invention has is nontoxic, acid and alkali-resistance, oil resistant, high-low temperature resistant, anti-layer are scratched, anti-negative high voltage, anti-animal is destroyed and advantage such as mechanical damage, it is low to have pressure during use, infiltration is even, and micropore is difficult for stopping up long service life, light weight, advantages such as softness also have anti-condensation simultaneously, cut off cross-ventilation, the coefficient of heat conduction is low, is difficult for the advantage of aging cracking.Fertile, administration are fed water, given to the plant that is widely used in all kinds soil.And micropore infiltrating irrigation pipeline primary raw material of the present invention is rubber, the plastics of discarding, and has solved the recycling of defective work, and production technology is simple, has high economic worth.
[specific embodiment]
Can further be expressly understood the present invention by the specific embodiment of the invention given below, but these embodiment not limiting the scope of the invention.
Embodiment 1
(1), clean rubber and plastics are pulverized respectively is 60 purpose powderies, the two mixes with the ratio of 65 parts and 30 parts by weight;
(2), in said mixture, add 3 parts Petropols by weight, 0.5 part AC blowing agent stirs 30min, granulation behind 0.5 part methyl tin heat stabilizer and 1 part the EVA;
(3), use three layers of extruder of SJ-65 type of Rui'an City red flag plastics package machinery Co., Ltd production with gained particle extrusion modling in the step (2), wherein first section temperature of extruder is 150 ℃, second section temperature is 165 ℃, and the 3rd section temperature is 175 ℃, and die head temperature is 190 ℃.
The density of gained soakaway trench is 40kg/m
3, pipe thickness is 2.5mm.
Embodiment 2
(1), clean rubber and plastics are pulverized respectively is 55 purpose powderies, the two mixes with the ratio of 60 parts and 40 parts by weight;
(2), in said mixture, add 4 parts Petropols by weight, 0.6 part AC blowing agent stirs 30min, granulation behind 0.4 part nontoxic phosphite ester DB-1500 heat stabilizer and 0.6 part the EVA;
(3), use three layers of extruder of SJ-65 type of Rui'an City red flag plastics package machinery Co., Ltd production with gained particle extrusion modling in the step (2), wherein first section temperature of extruder is 155 ℃, second section temperature is 160 ℃, and the 3rd section temperature is 170 ℃, and die head temperature is 185 ℃.
The density of gained soakaway trench is 90kg/m
3, pipe thickness is 1.5mm.
Embodiment 3
(1), clean rubber and plastics are pulverized respectively is 65 purpose powderies, the two mixes with the ratio of 60 parts and 30 parts by weight;
(2), in said mixture, add 3 parts Petropols by weight, 0.2 part AC blowing agent and 0.1 part H blowing agent stir 30min, granulation behind the EVA of 0.15 part CT-50A heat stabilizer and 0.15 part of mercaptan antimony heat stabilizer and 1.2 parts;
(3), use the TEE-95 type parallel dual-screw extruder of Nanjing Rhea high polymer Co., Ltd production with gained particle extrusion modling in the step (2).
The density of gained soakaway trench is 110kg/m
3, pipe thickness is 3mm.
The physical and mechanical properties test of embodiment 4 soakaway trench of the present invention
Get by implementing 1 soakaway trench of the present invention for preparing, carry out following performance detection.Gained the results are shown in Table 1.
The physical and mechanical properties test of table 1 soakaway trench of the present invention
The water percolating capacity test of embodiment 5 micropore infiltrating irrigation pipelines of the present invention
Get the soakaway trench of different model of the present invention, parallel laid in herbary, according to the form below is chosen different operating pressures and effective length, tests the water percolating capacity of its 15min, and watering with the fiber reinforcement type garden pipe of same size simultaneously compares, and the results are shown in Table 2.(annotate: FT is 50 feet)
The water percolating capacity test of table 2 micropore infiltrating irrigation pipeline of the present invention
Embodiment 6
Use soakaway trench of the present invention cucumber in the booth is irrigated for a long time and to observe, the equal area of choosing identical plant number is simultaneously carried out dropper, jet pipe is irrigated relatively.Can obviously find out, there were significant differences for the increment of crop, plant height, blade size, output, quality etc., the plant of using soakaway trench of the present invention to irrigate can reach all that strain is slightly full of leaves, many, the uniformity of the straight fruit of melon, do not exist the water yield not catch up with and cause phenomenons such as (major part melon, crooked melon, lopsided melons), fruit smooth surface exquisiteness (immaculate), fruit size uniformity is compared with other water saving equipment and can be improved output 30%; Saving of labor, laborsaving; Compare with other drip irrigation, lower to water quality requirement, be difficult for to stop up, more easily apply.