CN101151283B - 制备结晶乙烯(共聚物)聚合物的方法 - Google Patents

制备结晶乙烯(共聚物)聚合物的方法 Download PDF

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Publication number
CN101151283B
CN101151283B CN2006800098709A CN200680009870A CN101151283B CN 101151283 B CN101151283 B CN 101151283B CN 2006800098709 A CN2006800098709 A CN 2006800098709A CN 200680009870 A CN200680009870 A CN 200680009870A CN 101151283 B CN101151283 B CN 101151283B
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CN
China
Prior art keywords
catalyst
titanium
ethylene
molar ratio
solid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CN2006800098709A
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English (en)
Chinese (zh)
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CN101151283A (zh
Inventor
G·莫里尼
I·M·V·卡穆拉蒂
T·达尔奥科
D·利古奥里
G·维塔尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Poliolefine Italia SRL
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Basell Poliolefine Italia SRL
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Publication of CN101151283A publication Critical patent/CN101151283A/zh
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Publication of CN101151283B publication Critical patent/CN101151283B/zh
Expired - Fee Related legal-status Critical Current
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN2006800098709A 2005-03-30 2006-03-15 制备结晶乙烯(共聚物)聚合物的方法 Expired - Fee Related CN101151283B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP05102480 2005-03-30
EP05102480.0 2005-03-30
US66726905P 2005-04-01 2005-04-01
US60/667,269 2005-04-01
PCT/EP2006/060740 WO2006103172A1 (en) 2005-03-30 2006-03-15 Process for preparing crystalline ethylene (co)polymers

Publications (2)

Publication Number Publication Date
CN101151283A CN101151283A (zh) 2008-03-26
CN101151283B true CN101151283B (zh) 2011-06-08

Family

ID=39251240

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2006800098709A Expired - Fee Related CN101151283B (zh) 2005-03-30 2006-03-15 制备结晶乙烯(共聚物)聚合物的方法

Country Status (9)

Country Link
US (1) US7834117B2 (enExample)
EP (1) EP1863856B1 (enExample)
JP (1) JP2008534724A (enExample)
KR (1) KR20070118150A (enExample)
CN (1) CN101151283B (enExample)
BR (1) BRPI0611462A2 (enExample)
ES (1) ES2435101T3 (enExample)
RU (1) RU2007139937A (enExample)
WO (1) WO2006103172A1 (enExample)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008534723A (ja) 2005-03-30 2008-08-28 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ オレフィン重合用触媒成分
WO2006103170A1 (en) * 2005-03-30 2006-10-05 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins
EP2246369B1 (en) * 2009-04-30 2012-09-05 Borealis AG Linear low density polyethylene with uniform or reversed comonomer composition distribution
US9617357B2 (en) 2012-07-02 2017-04-11 Irpc Public Company Limited. Catalyst for olefin polymerization and a method for the preparation thereof
BR112018070434B1 (pt) 2016-04-29 2022-10-25 Basell Poliolefine Italia S.R.L Componente catalisador sólido e processo para homopolimerização ou copolimerização de olefinas

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1051565A (zh) * 1989-10-18 1991-05-22 黑蒙特股份有限公司 多金属催化剂制备方法及用此生产的聚合物
EP0444606A1 (en) * 1990-02-27 1991-09-04 Mitsui Petrochemical Industries, Ltd. Ethylene/pentene-1 copolymer, process for the preparation of the same, and ethylene/pentene-1 copolymer composition
US5118768A (en) * 1990-05-11 1992-06-02 Shell Oil Company Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process
CN1075486A (zh) * 1992-01-31 1993-08-25 斯菲里玲有限公司 用于烯烃聚合的催化剂组分及催化剂

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1603724A (en) 1977-05-25 1981-11-25 Montedison Spa Components and catalysts for the polymerisation of alpha-olefins
DE3435389A1 (de) 1984-09-27 1986-04-03 Basf Ag, 6700 Ludwigshafen Verfahren zum herstellen einer titan enthaltenden katalysatorkomponente fuer ziegler-katalysatorsysteme
US5219961A (en) * 1987-07-30 1993-06-15 Ausimont S.P.A. Catalysts for preparing saturated elastomeric olefinic copolymers and terpolymers
IT1222393B (it) 1987-07-30 1990-09-05 Ausimont Spa Catalizzatori per la preparazione di copolimeri e terpolimeri olefinici elastomerici,saturi ed insaturi
SG42868A1 (en) 1989-05-08 1997-10-17 Sumitomo Chemical Co Process for producing solid catalyst for use in polymerization of olefins
IT1246614B (it) 1991-06-03 1994-11-24 Himont Inc Procedimento per la polimerizzazione in fase gas delle olefine
IT1250731B (it) 1991-07-31 1995-04-21 Himont Inc Procedimento per la preparazione di polietilene lineare a bassa densita'
IT1262934B (it) * 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1254279B (it) 1992-03-13 1995-09-14 Montecatini Tecnologie Srl Procedimento per la polimerizzazione in fase gas delle olefine
JP2584189B2 (ja) * 1993-11-26 1997-02-19 三井石油化学工業株式会社 オレフイン類の重合方法
IT1277684B1 (it) 1995-12-21 1997-11-11 Montell North America Inc Componenti e catalizzatori per la polimerizzazione delle olefine
JP2008534723A (ja) 2005-03-30 2008-08-28 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ オレフィン重合用触媒成分
WO2006103170A1 (en) 2005-03-30 2006-10-05 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1051565A (zh) * 1989-10-18 1991-05-22 黑蒙特股份有限公司 多金属催化剂制备方法及用此生产的聚合物
EP0444606A1 (en) * 1990-02-27 1991-09-04 Mitsui Petrochemical Industries, Ltd. Ethylene/pentene-1 copolymer, process for the preparation of the same, and ethylene/pentene-1 copolymer composition
US5118768A (en) * 1990-05-11 1992-06-02 Shell Oil Company Process for the production of elastomeric, primarily isotactic polyolefins and catalysts for use in said process
CN1075486A (zh) * 1992-01-31 1993-08-25 斯菲里玲有限公司 用于烯烃聚合的催化剂组分及催化剂

Also Published As

Publication number Publication date
BRPI0611462A2 (pt) 2010-09-08
EP1863856A1 (en) 2007-12-12
EP1863856B1 (en) 2013-09-18
WO2006103172A1 (en) 2006-10-05
JP2008534724A (ja) 2008-08-28
US7834117B2 (en) 2010-11-16
KR20070118150A (ko) 2007-12-13
US20090054608A1 (en) 2009-02-26
CN101151283A (zh) 2008-03-26
RU2007139937A (ru) 2009-05-10
ES2435101T3 (es) 2013-12-18

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Granted publication date: 20110608

Termination date: 20140315