CN101148634B - Detergent containing bromochlorohydantoin - Google Patents

Abstract

The present invention relates to detergent, and is especially one kind of detergent containing bromochloro hydantoin. The detergent of the present invention consists of bromochloro hydantoin in 0.1-50 wt% and other detergent in 50-99.9 wt%.

Description

The washing composition that contains bromochlorohydantoin

Technical field:

The present invention relates to a kind of washing composition, particularly a kind of washing composition that contains bromochlorohydantoin.

Background technology:

Articles for washing industry since continuous progress in science and technology and people to the pressing for of articles for washing, whole world articles for washing production is able to fast development.World's articles for washing total amount 1970 was 1637.7 ten thousand tons, nineteen ninety-five is 4300 tons (wherein soap is about 9,000,000 tons), by 5,800,000,000 people, about 7.9 kilograms of world's year consumption per head, increase the fastest during 70 to the eighties, developed country market growth trend tends to be steady since the nineties, but developing country such as Asia-Pacific and Latin American's development are in rapid growth.Estimate that to mid-21st Century, whole world articles for washing requirement will rise to 100,000,000-1.2 hundred million tons, except that part is because population growth's factor, mainly still some developing countries still exist huge potential market.

China is since reform and opening-up, the washing composition of various high-qualitys, multiple-effect, safety, soap, shampoo, body lotion etc. are a feast for the eyes on the domestic goods market, this has fully shown the prosperity scene of Chinese articles for washing industry, close in the Chinese articles for washing to wash/the soap ratio is about 75: 25.2005, national soap cumulative production was 716,274.56 tons, and 2006, national soap accumulative total was produced 710,023.93 tons, increased by 3.95% with contemporaneous comparison in 2005.Synthetic detergent accumulative total is produced 5,457,282.28 tons, increases by 12.4% with contemporaneous comparison in 2005; Synthetic detergent powder accumulative total is produced 3,333,175.16 tons, increases 8.1% with contemporaneous comparison in 2005.Chinese synthetic detergent every year is still with 8% speed increase over surplus in the of nearly 10 year.So the particularly various synthetic detergent products of articles for washing of China are still good in foreseeable future.

Existing washing composition brand is as the carving board, profoundness, and green wave, white cat, Tides etc. are mainly washed the washing composition (comprising powdery, paste and liquid state) of textiles by formulated being used to such as tensio-active agent, washing assistant and additives.Some its prescriptions of washing composition commonly used are composed as follows:

Prescription 1 (family expenses white powdery type),

Component w/% component w/%

Sodium bicarbonate 52.1 alkyl benzene sulphonate (ABS)s (side chain) 16.2

CMC 1.8 sodium silicate solutions (40%) 4.5

Tripoly phosphate sodium STPP 13.5 Sodium peroxoborate 10.0

The chlorine bleach liquor (effectively

1.8 white dyes 0.1

Chlorine 10%)

Preparation:, just replace 1.8 parts in water for 1.8 parts with chlorine bleach liquor's (available chlorine 10%) with reference to the heavy dirty powdered detergent prescription of family expenses.If adopt 90% branched-chain alkyl Phenylsulfonic acid, then the add-on of 90% branched-chain alkyl Phenylsulfonic acid is 18.0 parts, and sodium silicate solution should be used (54%) 3.6 part of solution.

Prescription 2,

Component w/% component w/%

Linear alkylbenzene sulphonic acid 12.5 sodium sulfate 46

Fatty alcohol-polyoxyethylene ether 3 carboxymethyl celluloses 1

Water glass 9 white dyess 0.03

Tripoly phosphate sodium STPP 15 mill base indigo plants, spices are an amount of

Soda ash 10

Prescription 3,

Component w/% component w/%

Fatty alcohol-polyoxyethylene ether 6 water glass 15

The nonyl phenol polyethenoxy

4 yellow soda ash 10

Ether

Tripoly phosphate sodium STPP 20 sodium sulfate 33.3

Tetrasodium pyrophosphate 10 white dyess 0.2

Carboxymethyl cellulose 1.5 essence (lemon flavor) are an amount of

Prescription 4,

Component w/% component w/%

Sodium laurylsulfate

A. water an amount of 2

(K-12)

Sodium sulfate 33 soap 3

Tripoly phosphate sodium STPP 16 CMC-Na 1

Water glass 7 C. white dyess 0.2

B. sodium alkyl benzene sulfonate

14 D. Sodium peroxoborate 15

(ABS)

Ethoxylated dodecyl alcohol

2 E. zymins, essence are an amount of

(AEO)

Preparation: A, B are mixed and made into slip, make hollow powder, sneak into C and D, E when being cooled to 30 ℃ with the high tower spray method.

Illustrate: because of this product contains oxygen-bearing bleaching agent and Sodium peroxoborate, bleachability is good, but can not wash silk, wool fabric.

Prescription 5,

Component w/% component w/%

MES-Na 15 AOS-K 8

CAS-K 2 soap 2

AEO 5 SPC-D 10

1-chlorine hydroxyl-2,2,6,6-

Sodium silicoaluminate 20 1

Tetramethyl pyridine

Yellow soda ash 15 sodium polyacrylates 6

Salt of wormwood 5 water 5

Saleratus 5 saltcake 1

Prescription 6,

Component w/% component w/%

C ₁₂Sodium alkyl benzene sulfonate 15.0 Sodium peroxoborate 25.0

Trisodium Citrate 20.0 manganous sulfates 0.01

Tripoly phosphate sodium STPP 15.0 sodium sulfate and water 24.99

Illustrate: the pH value of this product under wash conditions is 9.5～12.Mn ion remains 20%～60% to the activation of superoxide at low temperatures.

Prescription 7,

Component w/% component w/%

C ₁₂Alkyl (EO) _nEther 20.0 4A mix stone 35.0

C ₁₂The alkyl dimethyl butyric acid

Water glass 10.0 3.0

Base P-TOLUENE SULFO ACID 99 ammonium

Toxilic acid/vinylformic acid

Yellow soda ash 5.0 2.0

(3: 7) multipolymer

Polyoxyethylene glycol 2.0 water 4.0

Proteolytic enzyme 1.0 white dyess are an amount of

SPC-D 8.0 essence are an amount of

Diethylenetriamine five second

1.0 sodium sulfate decahydrate surplus

Acid sodium

Illustrate: this formulation goes tea stain and red wine to steep effective.

Prescription 8,

Component w/% component w/%

Peroxyboric acid titanium 20.0 sodium sulfate 17.1

Tetra acetyl ethylene diamine/five

Ethanoyl glucose (1: 1) 10.0 yellow soda ash 3.0

Mixture

C ₁₂Sodium alkyl benzene sulfonate 10.0 CMC 1.0

Tripoly phosphate sodium STPP 30.0 EDTA-2Na 0.2

Sodium disilicate 7.0 white dyess 0.2

Magnesium Silicate q-agent 1.0 proteinase-10 .5

Prescription 9,

Component w/% component w/%

C ₁₂Sodium alkyl benzene sulfonate 20.0 CMC 0.5

Tripoly phosphate sodium STPP 18.0 Sumizyme MPs 0.3

Bag is coated with 2.4%NaBO ₂Mistake

Water glass 10.0

Yellow soda ash 10.0

Yellow soda ash 5.0 water 5.0

White dyes 0.5 sodium sulfate 30.7

Illustrate: this product is in 40 ℃, contains available oxygen 93% after humidity 80% is stored 14d, and the washing composition that contains untreated SPC-D is 88%.

Prescription 10,

Component w/% component w/%

C ₁₂Sodium alkyl benzene sulfonate 15.0 sodium perborate tetrahydrates 25.0

Tripoly phosphate sodium STPP 10.0 proteinase-10 .4

Sodium orthophosphate 20.0 sodium sulfate 28.6

CMC 0.5 Mn ²⁺(manganous sulfate) 0.1

White dyes 0.4

Illustrate: Mn ²⁺From low temperature to high temperature, superoxide all there is good katalysis, and enzyme is not had detrimentally affect.

Prescription 11,

Component w/% component w/%

Coconut oil fat base sulfo group is sweet

10.0 white dyes 0.075～0.15

Dish alkali (38%)

C ₁₂Alkyl (EO) ₃Ether sulfuric acid

30.0 water surplus

Salt (60%)

The fatty acid distribution of coconut oil di-alcohol

4.0

Acid amides

Preparation: white dyes is dissolved in warm coconut oil fat base sultaine and C ₁₂Alkyl (EO) ₃In the ether sulfate mixture, add all the other components then.Cold wash.

Prescription 12,

Component w/% component w/%

Sodium hexametaphosphate 99 25.0 anion surfactants 20.0

Tripoly phosphate sodium STPP 10.0 CMC (carboxymethyl cellulose) 0.5

Sodium sulfate 29.5 sodium carbonate peroxides 15.0

Illustrate: the cold water washing agent.

Prescription 13,

Component w/% component w/%

Alkyl benzene sulphonate (ABS) three ethanol

15 tripoly phosphate sodium STPPs 1.2

Amine

Detergent 209 6 white dyess 0.1

Oleum Cocois alkylolamide 5 water 71.5

Alkyl trimethyl sodium-chlor 1.2

Prescription 14,

Component w/% component w/%

Dodecyl dimethyl oxygen

5.00 α-sodium olefin sulfonate 40% 25.00

Change amine (30%)

Dodecyl coconut oil base

2.00 Citric Acid, usp, Anhydrous Powder 0.25

Diglycollic amide

The straight chained alkyl sodium sulfonate

15.00 water 52.75

(60％)

Preparation: citric acid is soluble in water, stir simultaneously, add all the other compositions successively, add more than last a kind of composition restir 15min even to guarantee product.PH value 7-7.5 is described, the about 1.0Pas of viscosity.

Prescription 15,

Component w/% component w/%

C ₁₂Sodium alkyl benzene sulfonate 10.0 white dyess 0.1

C ₁₂The benzene sulfonamide triethylenetetraminehexaacetic acid

2.0 sodium sulfate 46.9

Hydramine

Fatty alcohol-polyoxyethylene ether 3.0 soap 2.0

Sodium hexametaphosphate 99 15.0 tripoly phosphate sodium STPPs 10.0

CMC-Na 1.0 water 6.0

Water glass (1: 3) 4.0

Preparation: actives is added in the material-compound tank successively, heat, stir.Add solid materials such as sodium sulfate, CMC-Na, phosphoric acid salt, stir.If viscosity is big, when adding tensio-active agent, add the water of metering, make it total solids and reach about 60%.The whitening agent of fluorescence is earlier water-soluble, add in the slip at last in, before the atomizing, control slip pH value, usable acid adjustment as required.

Prescription 16,

Component w/% component w/%

C ₁₂Sodium alkyl benzene sulfonate 12.0 sodium sulfate 48.9

Fatty alcohol-polyoxyethylene ether 4.0 soap 2.0

Sodium hexametaphosphate 99 10.0 tripoly phosphate sodium STPPs 6.0

CMC-Na 1.0 Trisodium Citrates 5.0

Water glass (1: 3) 5.0 water content 6.0

White dyes 0.1

Some main universal class detergent formulation are as follows:

1. sodium alkyl benzene sulfonate 30%, tripoly phosphate sodium STPP 30%, sodium sulfate 25.5%, water glass 6%, carboxymethyl cellulose 1.4%, white dyes 0.1%, moisture 7%.

2. sodium alkyl benzene sulfonate 25%, toluenesulfonic acid sodium salt 2.5%, lauroyl thanomin 3%, tripoly phosphate sodium STPP 30%, water glass (Na2O: SiO2=1: 2, anhydrous) 10%, carboxymethyl cellulose 2%, white dyes 0.2%, sodium sulfate 27.3% (not being suitable for full-automatic washing machine)

3. alkyl sodium sulfonate 15%, alkyl sodium sulfonate 10%, tripoly phosphate sodium STPP 16%, sodium sulfate 44%, soda ash 4%, water glass 6%, carboxymethyl cellulose 1.2%, white dyes 0.1%, moisture 3.7%.

4. sodium alkyl sulfate 28～36%, carboxymethyl cellulose 2%, white dyes 0.04%, sodium alkyl benzene sulfonate 6～10% anhydrous sodium sulphate 38～45%, Sodium hexametaphosphate 99 10%.(Sodium hexametaphosphate 99 pH value is lower)

5. alkyl sodium sulfonate 15%, non-ionic type (polyethers) 4%, fat soap 3%, tripoly phosphate sodium STPP 35%, sodium sulfate 22.9%, water glass 8%, carboxymethyl cellulose 2%, sesame optical brightener 0.1%, moisture 10%.

6. sodium alkyl benzene sulfonate 10%, non-ionic type (polyethers) 4%, fat soap 3%, tripoly phosphate sodium STPP 40%, sodium sulfate 23.5%, water glass 6%, carboxymethyl cellulose 1.4%, white dyes 0.1%, moisture 12%.

Other has the representative formulations of Japan's laundry with synthetic detergent:

(1) weakly alkaline alkyl benzene series powdered detergent:

Alkyl sodium sulfonate 20%, saltcake 44.6%, water glass 5%, tripoly phosphate sodium STPP 20%, cocoanut fatty acid diethanolamide 1%, carboxymethyl cellulose 1%, suds suppressor 2%, white dyes 0.1% adds blue whitening agent

In right amount, spices 0.3%, moisture 6%.

(2) neutral alkyl benzene series powdered detergent:

Sodium alkyl benzene sulfonate 20～35%, saltcake 40～50%, tripoly phosphate sodium STPP 0～15%, cocoanut fatty acid diethanolamide 0～5%, carboxymethyl cellulose 0～1%, higher alcohol sulfate sodium salt 0～15%, nonyl phenol is a nonionogenic tenside 0～7%, toluenesulfonic acid sodium salt 0～2%.

(3) neutral alkyl benzene series liquid washing agent:

Alkyl benzene sulphonate (ABS) sodium salt or triethanolamine salt 8～18%, trisodium phosphate 8～10%, sodium xylene sulfonate 5%, Oleum Cocois or lauric acid diethyl amide 3～%, water 70～75%.

(4) the weakly alkaline nonionic is a powdered detergent

Nonionogenic tenside (polyethers) 15～20%, carboxymethyl cellulose 8～10%, tripoly phosphate sodium STPP and water glass 20～25%, saltcake 40～50%, the alkylolamide 0～7% of Oleum Cocois resin acid.

(5) weakly alkaline or neutral nonionic liquid washing agent:

1. polyoxyethylene nonylphenol ether 12%, potassium pyrophosphate 18%, water glass 0～5%.Propylene glycol 2～15%.Carboxymethyl cellulose 3%, pigment, spices, white dyes, water are surplus.(adding water glass is weakly alkaline, and what do not add is neutral)

But above-mentioned washing composition costs an arm and a leg a bit, some contaminate environment, and some need add chlorinated lime and hydrogen peroxide, and some has special smell.

Many new raw materials have appearred in detergent industry at present, comprise tensio-active agent, auxiliary agent and auxiliary.Tensio-active agent has new negatively charged ion, positively charged ion, nonionic and fluorine surfactant, auxiliary agent and auxiliary have builder as substitute for phosphate, oxidative bleaching agent and bleach-activating agent, sanitas and antiseptic-germicide, solvent and hydrotropic agent, dye transfer inhibitor, dirt releasing agent etc. to make washing effect that improvement arranged, but the described defective of above-mentioned washing composition is not improved at all, for carving the above-mentioned defective of clothes, the invention provides a kind of new washing composition, mainly be with a kind of composition of bromochlorohydantoin, add washing composition and obtain a kind of washing composition that contains bromochlorohydantoin as washing composition.

Summary of the invention:

1, the invention provides a kind of washing composition that contains bromochlorohydantoin, this washing composition contains the bromochlorohydantoin of 0.1-50% and other composition of 50-99.9%, and described other composition is any washing composition that does not contain bromochlorohydantoin.Can be the washing composition of making as the prescription of removing bromochlorohydantoin among prescription in the background technology and the embodiment (removing bromochlorohydantoin in the embodiment 1-5 prescription also is a kind of washing composition) as an example.But the washing composition that does not contain bromochlorohydantoin preferably following (100KG contains):

The name of an article	(kg) weighs
		Sodium alkyl benzene sulfonate	7.5-15.0
Soxylat A 25-7	5-10.0
		Polyethenoxy ether sodium sulfate	1.5-5.0
Single ethanol amide	2.5-2.0
		Sodium Tetraborate	6.0-0
Polyacrylamide	2.5-0
		The oxalyl tetraacethyl disodium	1-3.0

The name of an article	(kg) weighs
		Metasilicate pentahydrate sodium	4-15.0
Soda ash	20.0-0
		The 4A zeolite	49.9.0-0

Most preferred following (80KG contains):

The name of an article	(kg) weighs
		Sodium alkyl benzene sulfonate	15
Soxylat A 25-7	7
		Polyethenoxy ether sodium sulfate	3
Single ethanol amide	5
		The 4A zeolite	17
Polyacrylamide	5
		The oxalyl tetraacethyl disodium	2
Metasilicate pentahydrate sodium	8
		Soda ash	15
Sodium peroxoborate	3

So the bromochlorohydantoin washing composition that contains of the present invention, preferably fill a prescription following (100KG contains):

The name of an article weigh (kg)

Bromochlorohydantoin 0.1-50

Sodium alkyl benzene sulfonate

Soxylat A 25-7

Polyethenoxy ether sodium sulfate

All the other add up to 50-99.9 (the amount basis of other compositions

Single ethanol amide

The bromochlorohydantoin add-on is adjusted in proportion)

Polyacrylamide

The oxalyl tetraacethyl disodium

Metasilicate pentahydrate sodium

Soda ash

Sodium peroxoborate

The 4A zeolite

Another preferably fills a prescription as follows:

The name of an article	(kg) weighs
		Bromochlorohydantoin	0.1-15
Sodium lauryl sulphate (K12)	0-18
		Alkali	20-40
Trisodium Citrate	0-20
		CMC	1-3
Sodium alkyl benzene sulfonate	0-10
		Sodium sulfate	Surplus

The bromochlorohydantoin washing composition that contains of the present invention, most preferred prescription is as follows: (100KG contains):

The name of an article	(kg) weighs
		Bromochlorohydantoin	20
Sodium alkyl benzene sulfonate	15
		Soxylat A 25-7	7
Polyethenoxy ether sodium sulfate	3
		Single ethanol amide	5
The 4A zeolite	17
		Polyacrylamide	5
The oxalyl tetraacethyl disodium	2
		Metasilicate pentahydrate sodium	8

The name of an article	(kg) weighs
		Soda ash	15
Sodium peroxoborate	3

Another most preferred prescription is as follows:: 100KG contains

The name of an article	(kg) weighs
		Bromochlorohydantoin	7.5
Sodium lauryl sulphate (K12)	9
		Alkali	30
Trisodium Citrate	10
		CMC	2
Sodium alkyl benzene sulfonate	5
		Sodium sulfate	36.5

The bromochlorohydantoin washing composition that contains of the present invention, its preparation method is as follows:

The bromochlorohydantoin of recipe quantity is joined in other mixture of ingredients, and mixing gets final product.

Preferred manufacturing procedure is as follows:

Method for making: get each raw material, mixed 30 minutes, detect, packing, promptly.

The most preferred prescription of the present invention is that the process screening obtains and has carried out following experiment, proves to reach purpose of the present invention.

Test used washing composition and be called Europe for the gram disinfectant powder for washing composition according to the embodiment of the invention 2 preparations.

1, to the washing of serious pollution vestige fabric (the big and more fabric of ight soil of bloodstain amount)

Replace the common bromochlorohydantoin washing powder that do not contain with Europe for the gram disinfectant powder, consumption reduces by half.Do not add Javelle water, add the hydrogen peroxide of common amount.Washing was warming up to 70 ℃ of time 15-20 minutes, had in the complete machine clothing that vestige all eliminates on the clothing of bloodstain.

[discuss: the common bromochlorohydantoin washing powder that do not contain is not because of there being the bleaching function, Pei Fang soil removability is in the influence of non high temperature washing in addition, life-time service has the impression that does not wash clean and takes place, thereby need interpolation hydrogen peroxide or Javelle water to brighten, and Europe is for the gram disinfectant powder, because the bleaching and disinfecting composition that itself has, the clothing after it is washed can not sent out crow blackout burnt hair, need not add other aucillary detergent and brighten]

2, the product of this product in just using simultaneously with other compared, letter sorting there are not the bloodstain and a just clothing of mark, under no heating state, the oxygenant that contains because of itself, can reach and brighten and go the effect of smelling as of rotten fish, and not needing to add again other oxidation sterilizing whitening agent (hydrogen peroxide and Javelle water), the 100F washing machine only needs 300-600 gram powder amount to get final product.Cost is lower relatively, returns the amount of washing and can reduce, and can save the cost of laundry factory on manpower and water power.This product is except that the identical stronger even decontamination cleaning function of the more similar washing powder of tool, also can reach the sterilization regulation of hygiene control department to medical article, remarkable superpower unique quality of removing raw meat, deodorizing that it has, being domestic initiation, is specialty, the special product that uses for medical institutions.

3, to the be infectious carrying out washing treatment of strong dirt of mark: under the situation of no bloodstain, get final product for restraining under the charging capacity of 200 board disinfectant powders by instruction manual with Europe, even if do not having under the situation of thermal source, its wash draining reach simultaneously sterilization hygienic requirements (the product health license is criticized piece number: defend No. the 0308th, the word (2006) of disappearing], not only wash but also sterilize.

4, the environmental protection and the sterilization of institute's sewer, sterilization: we are to finishing main draining sampling Detection of washing after the process with Europe for gram 606 medical disinfectant powders, contain in the water sample the effective bromine chlorine of 9.5-11.5ppm (* according in country's " swimming place hygienic standard " to the regulation of swimming pool water, residual chlorine amount must reach 0.3-0.5ppm in the water), that is to say Europe replace gram 606 medical disinfectant powders because of the slow-releasing of its sterilization in the process of washing clothes, the discharging behind the sterilization has been carried out in discharging to hospital sewage simultaneously, compliance with environmental protection requirements, this is that other cleaning product is not accomplished.Washing discharge water compliance with environmental protection requirements.

Because product tool washing of the present invention and disinfectant dual function, and to the skin nonirritant, under working concentration, completely safe belongs to nontoxic level application product.In the laundry shop personnel working process, particularly handled the communicable clothing of pollution clothing or tool after, wash one's hands for 500-1000 times of diluent of gram disinfectant powder etc. in available at any time Europe.

The application scheme of product:

(throwing the powder amount is example with the every machine input of the washing machine of 100F drying amount 200-350 spare)

1, public ward clothing (common stain, no bloodstain, just mark clothing):

Drop into that drying is directly main to be washed, 15-20 minute, 35-45 ℃ or normal temperature [adding washing powder 0.6-0.8kg] draining rinsing 3 times, dehydration goes out machine.

[discuss:, the washing powder amount is enlarged to 1.0-1.2kg if select the normal temperature washing.】

2, working doctor clothes (intermediate pollution mainly is that neckline, cuff and the front part of a Chinese robe or jacket are dirtier, and a small amount of blood stains are arranged individually): pre-1-2 time → draining → master of rinsing washes, 15-20 minute, 70-45 ℃ or normal temperature [added 0.8-1.2kg washing powder, 0.2-0.4L emulsifying agent, draining, rinsing 3-4 time, draining goes out machine.

[discuss: during practical application,, drop into washing more at random if can handle well with picking out with the working suit of serious bloodstain in the local Javelle water diluent aside.Only the greasy dirt that removes neckline, cuff is done to strengthen targetedly washing, as time expand, the period that selection can heat up, the purpose that reaches the emulsification degreasing gets final product.】

3, dirtier ward, Operation theatre clothing (serious pollution, many bloodstain, just mark clothing):

Pre-rinsing (rinsing is repeatedly to the watery blood of adhering on surface band is rinsed), draining add a small amount of washing powder prewashing (than dirty linen), draining, main washing, 15-20 minute, 45-75 ℃ or normal temperature [adding 1.0-1.8kg Europe] draining, rinsing 4 times for gram washing powder, 5-8L hydrogen peroxide diluent, dehydration goes out machine.

Use the cost estimating of Europe for the gram disinfectant powder:

It is example with the every machine input of the washing machine of 100F drying amount 200-350 spare that measuring and calculating background: a. throws the powder amount, and the b. washing powder is offered with 12.50 yuan of/kilogram calculating.

1, ward normal laundry (common stain, no bloodstain, just mark clothing):

Suggestion adds Europe for gram 605 washing powder amount 0.6-0.8kg (looking the increase and decrease of laundry amounts and dirt degree), unit use cost: 7.50-10.00 unit;

[discuss: compare with common washing powder, can when not having heat energy, guarantee the quality of washing, disappear, need not be added with nocuous hydrogen peroxide or Javelle water and brighten.And under the life-time service, the cleaning of washing clothes fiber background color does not have and sends out dirty phenomenon.】

2, working doctor clothes (intermediate pollution clothing, mainly be that neckline, cuff and the front part of a Chinese robe or jacket are dirtier, a small amount of blood stains are arranged individually): suggestion adds Europe for gram 605 washing powder amount 0.8-1.2kg (look the increase and decrease of laundry amounts and dirt degree, contain prewashing), unit use cost: 10.0-15.0 unit;

3, dirtier ward, Operation theatre clothing (serious pollution, many bloodstain, just mark clothing)

Suggestion adds Europe for gram 605 washing powder amount: 1.0-1.2kg (look laundry amounts and the dirt degree has increase and decrease, contain prewashing), unit use cost: 12.5-15.0 unit.

[, can under the low relatively situation of heat energy, when not having bloodstain, no longer add the Javelle water bleaching and still can guarantee the quality of washing, disappear because of Europe has certain bleaching function for gram washing powder itself.Under the life-time service, the cleaning of clothing background color, suggestion have serious bloodstain, just the working doctor clothes of mark and ward clothing drop into washing machine after picking out and managing elsewhere again, can save the use of hydrogen peroxide, Javelle water.】

The washing composition scope of application of the present invention: be used for towel not easy to fade such as hospital, hotel, Saunas, foot care, sheet etc.Be used for the crowded place of hospital, pathogenicity bo contaminated articles; The cleaning and disinfecting of every field such as food processing shop environment and container, apparatus, food and drink tool and public place, public transit vehicle, school, nursery schools and childcare centres; The safety washing and the sterilization of fabrics such as the utensil of sauna, public towel.

Washing composition tool strong dirt-removing of the present invention and sterilizing function.In the process of washing, do not damage the fabric that is embathed, do not corrode the stainless steel washing plant; Not damaging human body skin and mucous membrane, is the professional cleaning product of public fabric when shuffling;

Washing composition tool of the present invention necessarily brightens function, the careful usefulness of colored fabric that textile printing quality is bad.All colour-fast to large-scale washing center such as hospital, hotel by the fabric that added non-fading any color under bleaching such as the hydrogen peroxide washing habits mode in the past.

Detergent formulation of the present invention does not have harmful carinogenicity phenyl ring class chemical industry essence, no washing powder chemical swelling agent commonly used, no white dyes.Through the test of health authoritative institution, this product does not have any residual hazard effect to environment, the nontoxic level of real genus.

Washing is sterilization again.Remove peculiar smell.The all-round prescription of special efficacy, high reactivity thing content is compared with other detergent powder, owing to add the up-to-date sterilization composition of senior America and Europe, this effective ingredient is that various Public Goods are recommended to be used for by Environmental Protection Agency, the normal temperature washing can be brought into play superior efficacy.In washing process, have clear and definite sterilizing function simultaneously, can kill pathogen enterobacteria, pyococcus, and can inactivation of viruses.Remove mould mark, remove raw meat, deodorize, remove peculiar smell.Do not need to add again Javelle water [clorox (NaClO), dichloroisocyanuric acid sodium, TCCA (Trichloroisocyanuric acid), hydrogen peroxide (H in the use ₂O ₂)], can reduce damage to fabric, wash the back fabric sofetening, delicate fragrance is refreshing clean.

Washing composition of the present invention has the clear and definite bleaching function that brightens, its bleaching principle and Javelle water are similar, but the chemical reaction process difference, so its nocuity is well below the corrosive nature of Javelle water, the CDC experiment test can be used for the cleaning and disinfecting of fabric fully, to washing machine stainless steel body non-corroding.But the careful usefulness of colored fabric that textile printing quality is bad.All colour-fast to large-scale washing center such as hospital, hotel by the fabric that added non-fading any color under bleaching such as the hydrogen peroxide washing habits mode in the past.

Description of drawings:

Fig. 1 is a process flow sheet

Embodiment:

By the following examples, further specify the present invention, but not as limit of the present invention is limited.

Embodiment 1,

Prescription: 100KG

The name of an article	(kg) weighs
		Bromochlorohydantoin	25
Sodium alkyl benzene sulfonate	15
		Soxylat A 25-7	7
Polyethenoxy ether sodium sulfate	3
		Single ethanol amide	5
The 4A zeolite	17
		Polyacrylamide	5
The oxalyl tetraacethyl disodium	2
		Metasilicate pentahydrate sodium	8
Soda ash	5
		Sodium peroxoborate	8

Method for making: get each raw material, mixed 30 minutes, detect, packing, promptly.

Embodiment 2,

Prescription: 100KG

The name of an article weigh (kg)

Bromochlorohydantoin 7.5

Sodium lauryl sulphate (K12) 9

Alkali 30

Trisodium Citrate 10

CMC 2

Sodium alkyl benzene sulfonate 5

Sodium sulfate 36.5

Method for making: get each raw material, mixed 30 minutes, detect, packing, promptly.

Embodiment 3,

Component w/% component w/%

Bromochlorohydantoin 15.0

Sodium peroxoborate 20.0

C ₁₂Sodium alkyl benzene sulfonate 10.0

Trisodium Citrate 20.0 manganous sulfates 0.01

CMC 5.0 sodium sulfate 30

Method for making: get each raw material, mixed 30 minutes, detect, packing, promptly.

Embodiment 4,

Component w/% component w/%

Bromochlorohydantoin 10.0 CMC 1.0

Sweet 10.0 sodium sulfate 55.0 of coconut oil fat base sulfo group

Dish alkali (38%)

C ₁₂Alkyl (EO) ₃Ether sulfuric acid 20.0

Salt (60%)

Fatty acid distribution of coconut oil di-alcohol 4.0

Acid amides

Method for making: get each raw material, mixed 30 minutes, detect, packing, promptly.

Embodiment 5,

Component w/% component w/%

Bromochlorohydantoin 10

C ₁₂Sodium alkyl benzene sulfonate 10.0

C ₁₂The benzene sulfonamide triethylenetetraminehexaacetic acid

2.0 sodium sulfate 36.9

Hydramine

Fatty alcohol-polyoxyethylene ether 3.0 soap 8.0

SPC-D 15.0 yellow soda ash 10.0

CMC-Na 1.0

Water glass (1: 3) 4.0

Method for making: get each raw material, mixed 30 minutes, detect, packing, promptly.

Embodiment 6,

Other detergent formulation that add bromochlorohydantoin are as follows:

1、

The name of an article	Ratio (%, m/m)
		Sodium alkyl benzene sulfonate	30.0
Soda ash	4.0
		Water glass	8.0
Saltcake	40.0
		Tripoly phosphate sodium STPP	16.8
Carboxymethyl cellulose	1.0

2、

The name of an article	Ratio (%, m/m)
		Nonionogenic tenside	11.0
Alkyl benzene sulphonate (ABS)	1.5
		Tripoly phosphate sodium STPP	32.0
Yellow soda ash	19.0
		Water glass	8-18.0
Cellulose sodium carboxymethyl	1.0
		Sodium sulfate	Balance

3、

4、

The name of an article	Ratio (%, m/m)	Example (%, m/m)
			Bromochlorohydantoin	0.1-50	30
Sodium alkyl benzene sulfonate	10-20	20
			Soxylat A 25-7	3-8	5

The name of an article	Ratio (%, m/m)	Example (%, m/m)
			Water glass	2-10	7
Poly carboxylic acid sodium	1-3	3
			Yellow soda ash	2-10	8
Zeolite	5-25	25
			Trolamine	2-5	2

5、

The name of an article	Ratio (%, m/m)
		Sodium alkyl benzene sulfonate	45
Saltcake	31
		The urea element	16
Essence	8

6、

The name of an article	Ratio (%, m/m)
		Sodium alkyl benzene sulfonate	50
Calcite	32
		Dyestuff	In right amount
Sanitas	In right amount

7、

The name of an article	Ratio (%, m/m)
		Citric acid	12

The name of an article	Ratio (%, m/m)
		Phosphoric acid	2
SODIUM PHOSPHATE, MONOBASIC	20
		Acidic sodium pyrophosphate	0.5
Sodium xylene sulfonate	4
		Polyoxyethylene nonylphenol ether	1
Tripoly phosphate sodium STPP	0.5
		Sodium-chlor	4

8、

The name of an article	Ratio (%, m/m)	Example (%, m/m)
			Bromochlorohydantoin	0.1-50	35
Sodium alkyl benzene sulfonate	10-20	16
			Soxylat A 25-7	3-8	5
Coconut monoethanol amide	2-7	6
			Water glass	2-10	5
Poly carboxylic acid sodium	1-3	2
			Yellow soda ash	2-10	8
Zeolite	5-25	21
			Trolamine	2-5	2

9、

Title	Ratio (%, m/m)	Example (%, m/m)
			Bromochlorohydantoin	0.1-30％	18
Dodecyl sodium sulfonate potassium	5-20	18
			Benzene sulfonic acid sodium salt	5-10	10
Zeolite	30-50	40
			Yellow soda ash	5-10	5
Poly-polysaccharide	1-3	2
			Water glass	2-10	7

10、

Title	Ratio (%, m/m)
		The fiber powder	30
BORAX DECAHYDRATED	15
		Sodium Tetraborate	5
Zeolite	3
		Ethanol	3
The positive propoxy propyl alcohol	3
		Shampoo	3

Claims (2)

1. a washing composition is characterized in that, wherein the prescription of the described washing composition of 100kg is as follows:

The name of an article weigh (kg)

Bromochlorohydantoin 7.5

Sodium lauryl sulphate 9

Alkali 30

Trisodium Citrate 10

Xylo-Mucine 2

Sodium alkyl benzene sulfonate 5

Sodium sulfate 36.5.

2. the purposes of the described washing composition of claim 1 is used for the washing of hospital, hotel, Saunas, foot care towel not easy to fade, sheet; The cleaning and disinfecting that is used for the utensil of the crowded place of hospital, pathogenicity bo contaminated articles, food-processing container, food and drink tool, sauna.