JP6923588B2 - Detergent set and how to use it - Google Patents
Detergent set and how to use it Download PDFInfo
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- JP6923588B2 JP6923588B2 JP2019070311A JP2019070311A JP6923588B2 JP 6923588 B2 JP6923588 B2 JP 6923588B2 JP 2019070311 A JP2019070311 A JP 2019070311A JP 2019070311 A JP2019070311 A JP 2019070311A JP 6923588 B2 JP6923588 B2 JP 6923588B2
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- sodium percarbonate
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- detergent
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- 239000003599 detergent Substances 0.000 title claims description 50
- 239000000203 mixture Substances 0.000 claims description 99
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 59
- 229940045872 sodium percarbonate Drugs 0.000 claims description 59
- 238000004140 cleaning Methods 0.000 claims description 32
- 150000007524 organic acids Chemical class 0.000 claims description 30
- 239000012459 cleaning agent Substances 0.000 claims description 27
- 238000002156 mixing Methods 0.000 claims description 25
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 15
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 6
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 5
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 3
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 3
- 239000001530 fumaric acid Substances 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 239000011976 maleic acid Substances 0.000 claims description 3
- 239000001630 malic acid Substances 0.000 claims description 3
- 235000011090 malic acid Nutrition 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 239000004744 fabric Substances 0.000 description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 30
- 238000004061 bleaching Methods 0.000 description 24
- 230000000052 comparative effect Effects 0.000 description 19
- 230000001954 sterilising effect Effects 0.000 description 14
- 238000010438 heat treatment Methods 0.000 description 11
- 238000005406 washing Methods 0.000 description 9
- 239000012535 impurity Substances 0.000 description 8
- 230000001877 deodorizing effect Effects 0.000 description 7
- 239000000835 fiber Substances 0.000 description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000008399 tap water Substances 0.000 description 6
- 235000020679 tap water Nutrition 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 238000011109 contamination Methods 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 235000005985 organic acids Nutrition 0.000 description 3
- 210000002374 sebum Anatomy 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 244000299461 Theobroma cacao Species 0.000 description 2
- 235000009470 Theobroma cacao Nutrition 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000004453 electron probe microanalysis Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- KJPHTXTWFHVJIG-UHFFFAOYSA-N n-ethyl-2-[(6-methoxypyridin-3-yl)-(2-methylphenyl)sulfonylamino]-n-(pyridin-3-ylmethyl)acetamide Chemical compound C=1C=C(OC)N=CC=1N(S(=O)(=O)C=1C(=CC=CC=1)C)CC(=O)N(CC)CC1=CC=CN=C1 KJPHTXTWFHVJIG-UHFFFAOYSA-N 0.000 description 2
- 235000020095 red wine Nutrition 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- -1 builders Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Description
本発明は洗浄剤セット及びその使用方法に関し、より詳細には衣料、住居及び自動食器洗浄機等に適用することが可能な洗浄剤セット及びその使用方法に関する。 The present invention relates to a cleaning agent set and a method of using the cleaning agent set, and more particularly to a cleaning agent set and a method of using the cleaning agent set that can be applied to clothes, houses, automatic dishwashers, and the like.
洗濯用洗剤や石鹸等の洗剤組成物は、一般に、被洗浄物の表面から不純物、汚れ及び染みを物理的に除去する機能を有する。これらの洗剤組成物は界面活性剤を含有しており、不純物等を当該界面活性剤のミセル中に取り込み、被洗浄物の表面からバルクに取り去る。 Detergent compositions such as laundry detergents and soaps generally have the function of physically removing impurities, stains and stains from the surface of the object to be cleaned. These detergent compositions contain a surfactant, and impurities and the like are taken into the micelles of the surfactant and removed from the surface of the object to be cleaned in bulk.
しかし、これらの洗濯用洗剤及び石鹸は、油汚れ及び疎水性の染みの除去に対しては、洗浄効果が低い。そのため、油汚れ等に対しては、これらを界面活性剤で取り除く代わりに、漂白剤を用いて漂白することが行われている。 However, these laundry detergents and soaps have a low cleaning effect on the removal of oil stains and hydrophobic stains. Therefore, for oil stains and the like, bleaching is performed using a bleaching agent instead of removing them with a surfactant.
そのような漂白剤としては、例えば、特許文献１に開示の洗剤組成物が挙げられる。この洗剤組成物によれば、過酸化水素源と、少なくとも一つのテルペンとを組み合わせて含有させることにより、繊維を害することなく着色した織物を洗浄することができるとされている。そして、特許文献１には、過酸化水素源の一例として過炭酸ナトリウム（炭酸ナトリウム過酸化水素化物）が挙げられている。 Examples of such a bleaching agent include the detergent composition disclosed in Patent Document 1. According to this detergent composition, it is said that a colored woven fabric can be washed without damaging the fibers by containing a hydrogen peroxide source in combination with at least one terpene. And in Patent Document 1, sodium percarbonate (sodium percarbonate) is mentioned as an example of a hydrogen peroxide source.
しかし、過酸化水素源として過炭酸ナトリウムを用いても、繊維に対するダメージを十分に抑制することはできない。また、過炭酸ナトリウムを常温で用いた場合には、水に対する溶解性が低く、漂白力も弱いことから、例えば、大気圧下では４０℃〜８０℃に洗剤組成物を加温して用いる必要がある。これにより、過炭酸ナトリウムを洗剤組成物に用いた場合には、当該洗剤組成物を加温するのに要する使用コストの増大が問題となる。また、前記数値範囲内にまで洗剤組成物を加温するための時間も必要となり、作業効率も低いという問題がある。 However, even if sodium percarbonate is used as a hydrogen peroxide source, damage to fibers cannot be sufficiently suppressed. Further, when sodium percarbonate is used at room temperature, its solubility in water is low and its bleaching power is weak. Therefore, for example, it is necessary to heat the detergent composition to 40 ° C. to 80 ° C. under atmospheric pressure. be. As a result, when sodium percarbonate is used in the detergent composition, an increase in the usage cost required for heating the detergent composition becomes a problem. Further, it takes time to heat the detergent composition within the above numerical range, and there is a problem that the work efficiency is low.
本発明は前記問題点に鑑みなされたものであり、その目的は、常温でも繊維へのダメージを低減して被洗浄物の洗浄及び漂白等を可能にし、使用コストの低減及び作業効率の向上を図ることが可能な洗浄剤セット及びその使用方法を提供することにある。 The present invention has been made in view of the above problems, and an object of the present invention is to reduce damage to fibers even at room temperature to enable cleaning and bleaching of an object to be cleaned, reducing usage costs and improving work efficiency. It is an object of the present invention to provide a cleaning agent set which can be planned and a method of using the cleaning agent set.
本発明の洗浄剤セットは、前記の課題を解決するために、炭酸ナトリウム過酸化水素化物を含む第１組成物と、有機酸を含む第２組成物とを備え、前記第１組成物と前記第２組成物は分けて保存されるものであり、前記第１組成物と前記第２組成物とは、前記有機酸が前記炭酸ナトリウム過酸化水素化物に対し質量基準で０．２〜０．５の配合割合となるように混合されて洗剤組成物を構成することを特徴とする。 In order to solve the above-mentioned problems, the detergent set of the present invention comprises a first composition containing sodium percarbonate and a second composition containing an organic acid, and the first composition and the above-mentioned The second composition is stored separately, and in the first composition and the second composition, the organic acid is 0.2 to 0 on a mass basis with respect to the sodium percarbonate. It is characterized in that it is mixed so as to have a blending ratio of 5 to form a detergent composition.
前記構成の洗浄剤セットは、第１組成物と第２組成物とをそれぞれ分けて保存するものであり、これらを混合することで洗剤組成物を構成する。第１組成物に含まれる炭酸ナトリウム過酸化水素化物は漂白作用を有するため、被洗浄物に付着している不純物、汚れ及び染みを漂白する。また、炭酸ナトリウム過酸化水素化物は発泡性を有するため、被洗浄物に付着している不純物等を物理的に除去する。さらに、炭酸ナトリウム過酸化水素化物は、消臭、滅菌及び殺菌作用も有するので、被洗浄物の消臭や滅菌、殺菌も可能にする。 The detergent set having the above structure is for storing the first composition and the second composition separately, and the detergent composition is formed by mixing these. Since the sodium percarbonate contained in the first composition has a bleaching action, it bleaches impurities, stains and stains adhering to the object to be cleaned. In addition, since sodium percarbonate has effervescent properties, impurities and the like adhering to the object to be cleaned are physically removed. Furthermore, since sodium percarbonate also has deodorizing, sterilizing and sterilizing effects, it also enables deodorizing, sterilizing and sterilizing the object to be cleaned.
一方、第２組成物に含まれる有機酸は、第１組成物と第２組成物を混合することで炭酸ナトリウム過酸化水素化物の水に対する溶解性の低下を抑制する。そのため、例えば、４０℃〜８０℃程度に加温しなくても、常温での使用を可能にする。また、炭酸ナトリウム過酸化水素化物の漂白作用の低下も抑制するので、加温しなくても、常温で優れた漂白作用を発揮させることができる。これにより、加温に要する使用コストの削減が図れ、かつ、加温作業の省略による作業効率の向上が図れる。しかも、被洗浄物が繊維である場合にも、有機酸と併用することで当該繊維に与えるダメージを低減して洗浄することができる。 On the other hand, the organic acid contained in the second composition suppresses a decrease in the solubility of sodium percarbonate in water by mixing the first composition and the second composition. Therefore, for example, it can be used at room temperature without heating to about 40 ° C. to 80 ° C. In addition, since the decrease in the bleaching action of sodium percarbonate is also suppressed, an excellent bleaching action can be exhibited at room temperature without heating. As a result, the usage cost required for heating can be reduced, and the work efficiency can be improved by omitting the heating work. Moreover, even when the object to be cleaned is a fiber, it can be washed by reducing the damage given to the fiber by using it in combination with an organic acid.
尚、前記洗剤組成物に於ける有機酸と炭酸ナトリウム過酸化水素化物の配合割合は、当該有機酸が炭酸ナトリウム過酸化水素化物に対し質量基準で０．２〜０．５の範囲である。前記配合割合を０．２以上にすることで、常温に於ける炭酸ナトリウム過酸化水素化物の過度な溶解性の低下、及び漂白力の低下を抑制することができる。その一方、前記配合割合を０．５以下にすることで、洗剤組成物が過度に酸性となるのを抑制することができる。 The blending ratio of the organic acid and the sodium percarbonate in the detergent composition is in the range of 0.2 to 0.5 on a mass basis with respect to the sodium percarbonate. By setting the blending ratio to 0.2 or more, it is possible to suppress an excessive decrease in the solubility of the sodium percarbonate at room temperature and a decrease in the bleaching power. On the other hand, by setting the blending ratio to 0.5 or less, it is possible to prevent the detergent composition from becoming excessively acidic.
前記の構成に於いては、前記有機酸がコハク酸、フマル酸、リンゴ酸、クエン酸、マレイン酸、酒石酸及び乳酸からなる群より選ばれる少なくとも１種であることが好ましい。これらの有機酸を用いることにより、炭酸ナトリウム過酸化水素化物の溶解性や漂白力の低下を一層抑制することができる。 In the above configuration, it is preferable that the organic acid is at least one selected from the group consisting of succinic acid, fumaric acid, malic acid, citric acid, maleic acid, tartaric acid and lactic acid. By using these organic acids, it is possible to further suppress the decrease in solubility and bleaching power of sodium percarbonate.
また、前記の構成に於いては、前記洗浄剤セットが衣料用、住居用及び自動食器洗浄機用であることが好ましい。 Further, in the above configuration, it is preferable that the cleaning agent set is for clothes, a house, and an automatic dishwasher.
本発明の洗浄方法は、前記の課題を解決するために、前記洗浄剤セットを用いた洗浄剤セットの使用方法であって、被洗浄物に、前記第１組成物と前記第２組成物を混合して得られる洗剤組成物を接触させる工程を含むことを特徴とする。 The cleaning method of the present invention is a method of using a cleaning agent set using the cleaning agent set in order to solve the above-mentioned problems, and the first composition and the second composition are added to an object to be cleaned. It is characterized by including a step of bringing the detergent compositions obtained by mixing into contact with each other.
前記の構成によれば、有機酸が炭酸ナトリウム過酸化水素化物に対し質量基準で０．２〜０．５の配合割合となるように、第１組成物と第２組成物を混合することで洗剤組成物を構成する。この洗剤組成物中には炭酸ナトリウム過酸化水素化物が含まれているため、被洗浄物に付着している不純物、汚れ及び染みを漂白する。また、炭酸ナトリウム過酸化水素化物は発泡性を有するため、被洗浄物に付着している不純物等を物理的に除去する。さらに、炭酸ナトリウム過酸化水素化物は、消臭、滅菌及び殺菌作用も有するので、被洗浄物の消臭や滅菌、殺菌も可能にする。 According to the above configuration, the first composition and the second composition are mixed so that the organic acid has a blending ratio of 0.2 to 0.5 with respect to the sodium percarbonate on a mass basis. Consists of a detergent composition. Since this detergent composition contains sodium percarbonate, it bleaches impurities, stains and stains adhering to the object to be cleaned. In addition, since sodium percarbonate has effervescent properties, impurities and the like adhering to the object to be cleaned are physically removed. Furthermore, since sodium percarbonate also has deodorizing, sterilizing and sterilizing effects, it also enables deodorizing, sterilizing and sterilizing the object to be cleaned.
また、洗剤組成物中には有機酸も含まれているため、炭酸ナトリウム過酸化水素化物の水に対する溶解性の低下を抑制する。そのため、例えば、４０℃〜８０℃程度に加温しなくても、常温で被洗浄物の洗浄を可能にする。また、炭酸ナトリウム過酸化水素化物の漂白作用の低下も抑制するので、加温しなくても、常温で優れた漂白が可能になる。しかも、被洗浄物が繊維である場合にも、有機酸と併用することで当該繊維に与えるダメージを低減して洗浄することができる。 Further, since the detergent composition also contains an organic acid, it suppresses a decrease in the solubility of sodium percarbonate in water. Therefore, for example, it is possible to wash the object to be cleaned at room temperature without heating to about 40 ° C. to 80 ° C. In addition, since the decrease in the bleaching action of sodium percarbonate is suppressed, excellent bleaching at room temperature is possible without heating. Moreover, even when the object to be cleaned is a fiber, it can be washed by reducing the damage given to the fiber by using it in combination with an organic acid.
尚、前記洗剤組成物に於ける有機酸と炭酸ナトリウム過酸化水素化物の配合割合は、当該有機酸が炭酸ナトリウム過酸化水素化物に対し質量基準で０．２〜０．５の範囲である。前記配合割合を０．２以上にすることで、常温に於ける炭酸ナトリウム過酸化水素化物の過度な溶解性の低下、及び漂白力の低下を抑制することができる。その一方、前記配合割合を０．５以下にすることで、洗剤組成物が過度に酸性となるのを抑制することができる。 The blending ratio of the organic acid and the sodium percarbonate in the detergent composition is in the range of 0.2 to 0.5 on a mass basis with respect to the sodium percarbonate. By setting the blending ratio to 0.2 or more, it is possible to suppress an excessive decrease in the solubility of the sodium percarbonate at room temperature and a decrease in the bleaching power. On the other hand, by setting the blending ratio to 0.5 or less, it is possible to prevent the detergent composition from becoming excessively acidic.
前記の構成に於いては、前記被洗浄物に対する洗剤組成物の接触を常温で行うことが好ましい。これにより、加温に要する使用コストの削減が図れ、かつ、加温作業の省略による作業効率の向上が図れる。 In the above configuration, it is preferable that the detergent composition is brought into contact with the object to be cleaned at room temperature. As a result, the usage cost required for heating can be reduced, and the work efficiency can be improved by omitting the heating work.
前記の構成に於いては、前記洗剤組成物のｐＨが６．５〜８の範囲内であることが好ましい。これにより、対象洗浄物に対するダメージを低減することができる。 In the above configuration, the pH of the detergent composition is preferably in the range of 6.5-8. As a result, damage to the target cleaning object can be reduced.
本発明によれば、炭酸ナトリウム過酸化水素化物を含む第１組成物と、有機酸を含む第２組成物とを、当該有機酸が炭酸ナトリウム過酸化水素化物に対し質量基準で０．２〜０．５の配合割合となるように混合して用いることにより、常温でも被洗浄物へのダメージを低減して被洗浄物の洗浄及び漂白を可能にし、使用コストの低減及び作業効率の向上を図ることが可能な洗浄剤セット及びその使用方法を提供することができる。 According to the present invention, the first composition containing sodium percarbonate and the second composition containing an organic acid are obtained from 0.2 to 0.2 on a mass basis with respect to the sodium percarbonate having the organic acid. By mixing and using so as to have a blending ratio of 0.5, damage to the object to be cleaned is reduced even at room temperature, enabling cleaning and bleaching of the object to be cleaned, reducing usage costs and improving work efficiency. It is possible to provide a cleaning agent set that can be planned and a method of using the cleaning agent set.
本発明の実施の形態に係る洗浄剤セット、及び洗浄剤セットの使用方法について以下に説明する。 The cleaning agent set according to the embodiment of the present invention and the method of using the cleaning agent set will be described below.
（洗浄剤セット）
本実施の形態に係る洗浄剤セットは、炭酸ナトリウム過酸化水素化物を含む第１組成物と、有機酸を含む第２組成物とを備える。本実施の形態の洗浄剤セットに於いて、第１組成物と第２組成物は分けて保存されるものである。洗浄剤セットの使用の際に、第１組成物と第２組成物を混合し、洗浄剤としての洗剤組成物を作製する。尚、本明細書に於いて、「洗浄剤」とは、第１組成物、第２組成物及びこれらを混合して得られる洗剤組成物を総称する意味である。
(Cleaning agent set)
The detergent set according to the present embodiment includes a first composition containing sodium percarbonate and a second composition containing an organic acid. In the detergent set of the present embodiment, the first composition and the second composition are stored separately. When using the detergent set, the first composition and the second composition are mixed to prepare a detergent composition as a cleaning agent. In addition, in this specification, a "cleaning agent" is a generic meaning of a first composition, a second composition, and a detergent composition obtained by mixing these.
前記第１組成物は、炭酸ナトリウム過酸化水素化物（２Ｎａ２ＣＯ３・３Ｈ２Ｏ２又はＮａ２ＣＯ３・１．５Ｈ２Ｏ２）を少なくとも含む。第１組成物は粒子状又は粉末状であることが好ましい。 It said first composition comprising at least sodium peroxyhydrate carbonate (2Na 2 CO 3 · 3H 2 O 2 or Na 2 CO 3 · 1.5H 2 O 2). The first composition is preferably in the form of particles or powder.
前記炭酸ナトリウム過酸化水素化物は被洗浄物に対し漂白作用を及ぼす機能を有する。また、炭酸ナトリウム過酸化水素化物は発泡性も有するため、被洗浄物に付着している不純物、汚れ行う染みを物理的に除去する機能を有する。 The sodium percarbonate has a function of exerting a bleaching action on the object to be washed. In addition, since sodium percarbonate also has effervescence, it has a function of physically removing impurities adhering to the object to be cleaned and stains that cause stains.
炭酸ナトリウム過酸化水素化物の第１組成物中に於ける含有量は、下限値が第１組成物の全質量に対し５０質量％以上、好ましくは８０質量％以上、より好ましくは９０質量％以上である。また、前記含有量の上限値は、第１組成物の全質量に対し１００質量％以下である。炭酸ナトリウム過酸化水素化物の含有量の下限値を５０質量％以上にすることにより、漂白作用及び洗浄作用の過度な低下を抑制することができる。その一方、炭酸ナトリウム過酸化水素化物の含有量の上限値を１００質量％以下にすることにより、不溶物を低減することができる。 The lower limit of the content of sodium percarbonate in the first composition is 50% by mass or more, preferably 80% by mass or more, more preferably 90% by mass or more, based on the total mass of the first composition. Is. The upper limit of the content is 100% by mass or less with respect to the total mass of the first composition. By setting the lower limit of the content of sodium percarbonate to 50% by mass or more, it is possible to suppress an excessive decrease in the bleaching action and the cleaning action. On the other hand, the insoluble matter can be reduced by setting the upper limit of the content of sodium percarbonate to 100% by mass or less.
前記第１組成物には、炭酸ナトリウム過酸化水素化物の機能を過度に損なわない範囲で、必要に応じて他の任意成分が含まれていてもよい。 The first composition may contain other optional components, if necessary, as long as the functions of the sodium percarbonate are not excessively impaired.
前記第２組成物は、有機酸を少なくとも含む。有機酸の併用により、第１組成物と第２組成物の混合を常温で行っても、炭酸ナトリウム過酸化水素化物の水に対する溶解性が低下するのを防止することができる。また、炭酸ナトリウム過酸化水素化物の漂白性の低下も抑制することができる。 The second composition contains at least an organic acid. By using the organic acid in combination, it is possible to prevent the solubility of the sodium percarbonate in water from being lowered even if the first composition and the second composition are mixed at room temperature. In addition, a decrease in bleaching property of sodium percarbonate can be suppressed.
前記有機酸は、コハク酸、フマル酸、リンゴ酸、クエン酸、マレイン酸、酒石酸及び乳酸からなる群より選ばれる少なくとも１種である。これらの有機酸のうち、炭酸ナトリウム過酸化水素化物の水に対する溶解性、洗浄性、及び漂白性の観点からは、クエン酸、コハク酸が好ましい。 The organic acid is at least one selected from the group consisting of succinic acid, fumaric acid, malic acid, citric acid, maleic acid, tartaric acid and lactic acid. Of these organic acids, citric acid and succinic acid are preferable from the viewpoint of solubility, detergency, and bleaching property of sodium percarbonate in water.
前記有機酸の第２組成物中に於ける含有量は、下限値が第２組成物の全質量に対し９０質量％以上、好ましくは９５質量％以上、より好ましくは９８質量％以上である。また、前記含有量の上限値は、第２組成物の全質量に対し１００質量％以下である。有機酸の含有量の下限値を９０質量％以上にすることにより、漂白作用及び洗浄作用の過度な低下を抑制することができる。その一方、有機酸の含有量の上限値を１００質量％以下にすることにより、洗剤組成物の安定化を図ることができる。 The lower limit of the content of the organic acid in the second composition is 90% by mass or more, preferably 95% by mass or more, and more preferably 98% by mass or more with respect to the total mass of the second composition. The upper limit of the content is 100% by mass or less with respect to the total mass of the second composition. By setting the lower limit of the content of the organic acid to 90% by mass or more, it is possible to suppress an excessive decrease in the bleaching action and the cleaning action. On the other hand, by setting the upper limit of the content of the organic acid to 100% by mass or less, the detergent composition can be stabilized.
前記第２組成物には、有機酸の機能を過度に損なわない範囲で、必要に応じて他の任意成分が含まれていてもよい。そのような任意成分としては、例えば、界面活性剤、ビルダー、色素、蛍光増白剤、漂白剤、消泡剤、ｐＨ調整剤、酸化防止剤、防腐剤、香料等が挙げられる。さらに、必要に応じて、水、溶媒等の液体媒体を含有してもよい。 The second composition may contain other optional components, if necessary, as long as the functions of the organic acid are not excessively impaired. Such optional ingredients include, for example, surfactants, builders, pigments, optical brighteners, bleaches, defoamers, pH regulators, antioxidants, preservatives, fragrances and the like. Further, if necessary, a liquid medium such as water or a solvent may be contained.
前記界面活性剤としては、例えば、アニオン界面活性剤、ノニオン界面活性剤、カチオン界面活性剤、両性界面活性剤等が挙げられる。 Examples of the surfactant include anionic surfactants, nonionic surfactants, cationic surfactants, amphoteric surfactants and the like.
任意成分の含有量は特に限定されず、適宜必要に応じて設定することができる。 The content of the optional component is not particularly limited and can be appropriately set as needed.
前記第１組成物と第２組成物を混合して得られる洗剤組成物に於いて、有機酸と炭酸ナトリウム過酸化水素化物との配合割合は、当該有機酸が炭酸ナトリウム過酸化水素化物に対し質量基準で０．２〜０．５の範囲内であり、好ましくは０．３〜０．４である。前記配合割合を０．２以上にすることで、常温に於ける炭酸ナトリウム過酸化水素化物の過度な溶解性の低下、及び漂白力の低下を抑制することができる。その一方、前記配合割合を０．５以下にすることで、洗剤組成物のｐＨを中性近くにすることができる。 In the detergent composition obtained by mixing the first composition and the second composition, the mixing ratio of the organic acid and the sodium percarbonate is such that the organic acid is the sodium percarbonate. It is in the range of 0.2 to 0.5 on a mass basis, preferably 0.3 to 0.4. By setting the blending ratio to 0.2 or more, it is possible to suppress an excessive decrease in the solubility of the sodium percarbonate at room temperature and a decrease in the bleaching power. On the other hand, by setting the blending ratio to 0.5 or less, the pH of the detergent composition can be made close to neutral.
また、前記第１組成物と第２組成物を混合して得られる洗剤組成物のｐＨは、６．５〜８の範囲内であり、好ましくは７．０〜８．０、より好ましくは６．８〜７．２である。洗剤組成物のｐＨを６．５以上にすることにより、洗浄性の低下を防止することができる。また、洗濯機等を用いて被洗浄物の洗浄を行う場合、当該洗濯機等に於いて鉄でできた部分に錆が発生するのを抑制することができる。その一方、洗剤組成物のｐＨを８以下にすることにより、対象洗浄物のダメージを低減することができる。 The pH of the detergent composition obtained by mixing the first composition and the second composition is in the range of 6.5 to 8, preferably 7.0 to 8.0, and more preferably 6. It is .8 to 7.2. By setting the pH of the detergent composition to 6.5 or higher, deterioration of detergency can be prevented. Further, when the object to be washed is washed using a washing machine or the like, it is possible to suppress the generation of rust on the portion made of iron in the washing machine or the like. On the other hand, by setting the pH of the detergent composition to 8 or less, damage to the target cleaning object can be reduced.
本実施の形態に係る洗浄剤セットは、衣料用、住居用及び自動食器洗浄機用として好適に用いることができる。 The cleaning agent set according to the present embodiment can be suitably used for clothes, a house, and an automatic dishwasher.
（洗浄剤セットの使用方法）
本実施の形態に係る洗浄剤セットの使用方法は、前記第１組成物と第２組成物を混合して得られる洗剤組成物を、被洗浄物に接触させる工程を少なくとも含む。前記工程は被洗浄物の洗浄、漂白、消臭、及び滅菌又は殺菌を行うので、洗浄工程、漂白工程、消臭工程、及び滅菌又は殺菌工程としての機能を果たす。
(How to use the cleaning agent set)
The method of using the cleaning agent set according to the present embodiment includes at least a step of bringing the detergent composition obtained by mixing the first composition and the second composition into contact with the object to be cleaned. Since the process performs cleaning, bleaching, deodorizing, and sterilizing or sterilizing the object to be cleaned, it functions as a cleaning step, a bleaching step, a deodorizing step, and a sterilization or sterilization step.
被洗浄物としては特に限定されず、例えば、衣料や布製品、自動食器洗浄機等が挙げられる。 The object to be washed is not particularly limited, and examples thereof include clothing, cloth products, and automatic dishwashers.
前記工程は、例えば、被洗浄物が衣料や布製品である場合、当該衣料等が投入された水に第１組成物及び第２組成物をそれぞれ添加することで、洗剤組成物が水に溶解した洗浄液を構成する。この洗浄液には炭酸ナトリウム過酸化水素化物が含まれるため、当該炭酸ナトリウム過酸化水素化物が有する漂白作用や発泡性により、衣料等に付着した不純物、汚れ及び染みを漂白し、及び物理的に除去して洗浄することができる。また、炭酸ナトリウム過酸化水素化物は、消臭、滅菌及び殺菌作用も有するため、衣料等の消臭や滅菌、殺菌も可能である。 In the above step, for example, when the object to be cleaned is clothing or a cloth product, the detergent composition is dissolved in water by adding the first composition and the second composition to the water into which the clothing or the like is added. Consists of the cleaning solution. Since this cleaning solution contains sodium percarbonate, impurities, stains and stains adhering to clothing and the like are bleached and physically removed by the bleaching action and foaming property of the sodium percarbonate. Can be washed. Further, since sodium percarbonate also has deodorizing, sterilizing and sterilizing effects, it is possible to deodorize, sterilize and sterilize clothing and the like.
前記工程は任意の温度条件下で行うことができる。換言すれば、本実施の形態の使用方法で用いられる洗浄液の温度は任意であり、特に限定されない。第１組成物に含まれる炭酸ナトリウム過酸化水素化物は、常温では水に対する溶解性が低いため、従来は、４０℃〜８０℃の範囲に洗浄液を加温することで、炭酸ナトリウム過酸化水素化物の水に対する溶解性を確保していた。しかし、本実施の形態では、第２組成物に含まれる有機酸を混合して併用することで、常温に於いても炭酸ナトリウム過酸化水素化物の水に対する溶解性が低下するのを抑制する。その結果、加温することなく炭酸ナトリウム過酸化水素化物が溶解した洗浄液にて、被洗浄物の洗浄等が可能となる。また、有機酸の混合は、炭酸ナトリウム過酸化水素化物が有する漂白作用の機能の低下も抑制する。これにより、被洗浄物に対し良好な洗浄性及び漂白性を発揮させることができる。尚、本明細書に於いて「溶解性」とは、任意の洗浄時間内における、炭酸ナトリウム過酸化水素化物の水への溶解の程度を意味する。また、本明細書に於いて、「常温」とは５℃〜３５℃の温度範囲にあることを意味する。 The step can be performed under any temperature condition. In other words, the temperature of the cleaning liquid used in the method of use of the present embodiment is arbitrary and is not particularly limited. Since the sodium percarbonate contained in the first composition has low solubility in water at room temperature, conventionally, the sodium percarbonate is formed by heating the cleaning solution in the range of 40 ° C to 80 ° C. Was ensured to be soluble in water. However, in the present embodiment, by mixing and using the organic acid contained in the second composition in combination, it is possible to suppress the decrease in the solubility of sodium percarbonate in water even at room temperature. As a result, it is possible to wash the object to be cleaned with a cleaning solution in which sodium percarbonate is dissolved without heating. The mixing of organic acids also suppresses the deterioration of the bleaching function of sodium percarbonate. As a result, good detergency and bleaching property can be exhibited for the object to be cleaned. In addition, in this specification, "solubility" means the degree of dissolution of sodium percarbonate in water within an arbitrary washing time. Further, in the present specification, "room temperature" means that the temperature is in the temperature range of 5 ° C to 35 ° C.
洗剤組成物の洗浄液中における濃度は、２ｇ／Ｌ〜６ｇ／Ｌが好ましく、３ｇ／Ｌ〜６ｇ／Ｌがより好ましく、５ｇ／Ｌ〜６ｇ／Ｌが特に好ましい。前記濃度の下限値を２ｇ／Ｌ以上にすることで被洗浄物に対する洗浄性の維持が図られる。その一方、前記濃度の上限値を６ｇ／Ｌ以下にすることで、被洗浄物が衣料である場合に、前記工程後に行われる水によるすすぎ性を良好に維持することができる。 The concentration of the detergent composition in the cleaning liquid is preferably 2 g / L to 6 g / L, more preferably 3 g / L to 6 g / L, and particularly preferably 5 g / L to 6 g / L. By setting the lower limit of the concentration to 2 g / L or more, the detergency of the object to be cleaned can be maintained. On the other hand, by setting the upper limit of the concentration to 6 g / L or less, when the object to be washed is clothing, the rinseability with water performed after the step can be well maintained.
前記工程に於いて、被洗浄物が衣料の場合、洗浄剤（洗剤組成物）の容量（リットル）と、衣料の質量（ｋｇ）との比（以下、「浴比」という。）は、［洗浄液の容量（リットル）］／［衣料の質量（ｋｇ）］で２〜２０が好ましく、３〜１０以下がより好ましく、３〜４以下が特に好ましい。前記浴比を２以上にすることで、被洗浄物に対する逆汚染の防止が図られる。その一方、前記浴比を２０以下にすることで、洗浄効率の低下を抑制することができる。 In the above step, when the object to be cleaned is clothing, the ratio of the volume (liter) of the cleaning agent (detergent composition) to the mass (kg) of the clothing (hereinafter referred to as "bath ratio") is [ The volume (liter) of the cleaning liquid / [mass of clothing (kg)] is preferably 2 to 20, more preferably 3 to 10 or less, and particularly preferably 3 to 4 or less. By setting the bath ratio to 2 or more, it is possible to prevent back-contamination of the object to be cleaned. On the other hand, by setting the bath ratio to 20 or less, it is possible to suppress a decrease in cleaning efficiency.
本実施の形態の洗浄方法に於いては、前記工程の後に水によるすすぎ工程を行ってもよい。また、すすぎ工程は複数回行うことも可能である。すすぎ工程で用いる水の温度は特に限定されないが、通常は常温である。また、水の量も特に限定されず、適宜必要に応じて設定することができる。 In the cleaning method of the present embodiment, a rinsing step with water may be performed after the step. Further, the rinsing step can be performed a plurality of times. The temperature of the water used in the rinsing step is not particularly limited, but is usually room temperature. Further, the amount of water is not particularly limited and can be set as needed.
以下、本発明に関し実施例を用いて詳細に説明するが、本発明はその要旨を超えない限り、以下の実施例に限定されるものではない。 Hereinafter, the present invention will be described in detail with reference to examples, but the present invention is not limited to the following examples as long as the gist of the present invention is not exceeded.
（実施例１）
本実施例においては、被洗浄物として、５ｃｍ×５ｃｍのＷＦＫ１０Ｄ標準汚染布（綿、皮脂及び顔料が付着した汚染布。Ｗｆｋ Ｔｅｓｔｇｅｗｅｂｅ ＧｍｂＨ）１枚、及び 標準汚染布を綿タオルに縫いつけたものとバスタオル４枚（略１ｋｇ）を用いた。この被洗浄物を家庭用洗濯機（製品名：ＮＡ−ＶＸ８５００Ｒ、パナソニック（株）製、１０ｋｇ洗い）にタオルとバスタオルを投入し、常温（水温９℃）の水（水道水）２０Ｌを入れた。また、本実施例に係る洗浄剤セットとして、炭酸ナトリウム過酸化水素化物からなる第１組成物１０ｇと、クエン酸からなる第２組成物４ｇとを、同時に家庭用洗濯機内に投入した（有機酸の炭酸ナトリウム過酸化水素化物に対する質量基準での混合割合０．４）。尚、浴比（［洗浄液の容量（リットル）］／［衣料の質量（ｋｇ）］）は２０とした。
(Example 1)
In this embodiment, as the object to be cleaned, one 5 cm × 5 cm WFK10D standard contaminated cloth (contaminated cloth with cotton, sebum and pigment attached. Wfk Testgewebe GmbH) and a standard contaminated cloth are sewn on a cotton towel. Four bath towels (approximately 1 kg) were used. Put towels and bath towels in a household washing machine (product name: NA-VX8500R, manufactured by Panasonic Corporation, 10 kg wash), and put 20 L of water (tap water) at room temperature (water temperature 9 ° C). rice field. Further, as a detergent set according to this example, 10 g of the first composition composed of sodium percarbonate and 4 g of the second composition composed of citric acid were simultaneously put into a household washing machine (organic acid). Mixing ratio of sodium percarbonate to sodium percarbonate on a mass basis 0.4). The bath ratio ([volume of cleaning liquid (liter)] / [mass of clothing (kg)]) was set to 20.
続いて、洗浄後の被洗浄物を１分間脱水した後、常温（９℃）の水（水道水）４０Ｌを入れ、３分間すすいだ。すすぎは１回行った。 Subsequently, after dehydrating the object to be washed after washing for 1 minute, 40 L of water (tap water) at room temperature (9 ° C.) was added and rinsed for 3 minutes. Rinsing was done once.
すすぎ後、被洗浄物を５分間脱水し、ＷＦＫ１０Ｄ標準汚染布を取り出して乾燥を行った。乾燥は、室温１８℃、湿度６０％の屋内干しの環境下で２０時間行った。 After rinsing, the object to be washed was dehydrated for 5 minutes, and the WFK10D standard contaminated cloth was taken out and dried. The drying was carried out for 20 hours in an indoor drying environment at room temperature of 18 ° C. and humidity of 60%.
（実施例２）
本実施例に於いては、実施例１のＷＦＫ１０Ｄ標準汚染布に代えて、５ｃｍ×５ｃｍのＷＦＫ２０Ｄ標準汚染布（皮脂及び顔料が付着した汚染布。Ｗｆｋ Ｔｅｓｔｇｅｗｅｂｅ ＧｍｂＨ）を用いた。それ以外は、実施例１と同様にして、被洗浄物の洗浄、すすぎ及び乾燥を行った。
(Example 2)
In this example, instead of the WFK10D standard contaminated cloth of Example 1, a 5 cm × 5 cm WFK20D standard contaminated cloth (contaminated cloth with sebum and pigment attached. Wfk Testgebe GmbH) was used. Other than that, the object to be washed was washed, rinsed and dried in the same manner as in Example 1.
（実施例３）
本実施例に於いては、実施例１のＷＦＫ１０Ｄ標準汚染布に代えて、５ｃｍ×５ｃｍのＷＦＫ１０Ｌ標準汚染布（赤ワインが付着した汚染布。Ｗｆｋ Ｔｅｓｔｇｅｗｅｂｅ ＧｍｂＨ）を用いた。それ以外は、実施例１と同様にして、被洗浄物の洗浄、すすぎ及び乾燥を行った。
(Example 3)
In this example, instead of the WFK10D standard contaminated cloth of Example 1, a 5 cm × 5 cm WFK10L standard contaminated cloth (contaminated cloth with red wine attached. Wfk Testgebe GmbH) was used. Other than that, the object to be washed was washed, rinsed and dried in the same manner as in Example 1.
（実施例４）
本実施例に於いては、実施例１のＷＦＫ１０Ｄ標準汚染布に代えて、５ｃｍ×５ｃｍのＥＭＰＡ１１２標準汚染布（ココアが付着した汚染布。ＥＭＰＡ社製）を用いた。それ以外は、実施例１と同様にして、被洗浄物の洗浄、すすぎ及び乾燥を行った。
(Example 4)
In this example, instead of the WFK10D standard contaminated cloth of Example 1, a 5 cm × 5 cm EMPA112 standard contaminated cloth (contaminated cloth with cocoa adhered, manufactured by EMPA) was used. Other than that, the object to be washed was washed, rinsed and dried in the same manner as in Example 1.
（比較例１）
本比較例においては、被洗浄物として実施例１と同じものを用いた。この被洗浄物を家庭用洗濯機（製品名：ＮＡ−ＶＸ８５００Ｒ、パナソニック（株）製、１０ｋｇ洗い）に約１ｋｇ投入し、常温（水温９℃）の水（水道水）２０Ｌを入れた。さらに本比較例では、洗剤として中性洗剤（製品名：ＴＫエコソープ、高松油脂（株）製）を用い、１０ｇを家庭用洗濯機内に投入した。尚、浴比（［洗浄液の容量（リットル）］／［衣料の質量（ｋｇ）］）は２０とした。
(Comparative Example 1)
In this comparative example, the same material as in Example 1 was used as the object to be cleaned. About 1 kg of this object to be washed was put into a household washing machine (product name: NA-VX8500R, manufactured by Panasonic Corporation, 10 kg wash), and 20 L of water (tap water) at room temperature (water temperature 9 ° C.) was added. Further, in this comparative example, a neutral detergent (product name: TK Ecosoap, manufactured by Takamatsu Oil & Fat Co., Ltd.) was used as a detergent, and 10 g was put into a household washing machine. The bath ratio ([volume of cleaning liquid (liter)] / [mass of clothing (kg)]) was set to 20.
続いて、洗浄後の被洗浄物を１分間脱水した後、常温（９℃）の水（水道水）４０Ｌを入れ、３分間すすいだ。すすぎは１回行った。 Subsequently, after dehydrating the object to be washed after washing for 1 minute, 40 L of water (tap water) at room temperature (9 ° C.) was added and rinsed for 3 minutes. Rinsing was done once.
すすぎ後、被洗浄物を５分間脱水し、ＷＦＫ１０Ｄ標準汚染布のみを取り出して乾燥を行った。乾燥は、室温１８℃、湿度６０％の屋内干しの環境下で２０時間行った。 After rinsing, the object to be washed was dehydrated for 5 minutes, and only the WFK10D standard contaminated cloth was taken out and dried. The drying was carried out for 20 hours in an indoor drying environment at room temperature of 18 ° C. and humidity of 60%.
（比較例２）
本比較例に於いては、比較例１のＷＦＫ１０Ｄ標準汚染布に代えて、５ｃｍ×５ｃｍのＷＦＫ２０Ｄ標準汚染布（皮脂及び顔料が付着した汚染布。Ｗｆｋ Ｔｅｓｔｇｅｗｅｂｅ ＧｍｂＨ）を用いた。それ以外は、比較例１と同様にして、被洗浄物の洗浄、すすぎ及び乾燥を行った。
(Comparative Example 2)
In this comparative example, instead of the WFK10D standard contaminated cloth of Comparative Example 1, a 5 cm × 5 cm WFK20D standard contaminated cloth (contaminated cloth with sebum and pigment attached. Wfk Testgebe GmbH) was used. Other than that, the object to be washed was washed, rinsed and dried in the same manner as in Comparative Example 1.
（比較例３）
本比較例に於いては、比較例１のＷＦＫ１０Ｄ標準汚染布に代えて、５ｃｍ×５ｃｍのＷＦＫ１０Ｌ標準汚染布（赤ワインが付着した汚染布。Ｗｆｋ Ｔｅｓｔｇｅｗｅｂｅ ＧｍｂＨ）を用いた。それ以外は、比較例１と同様にして、被洗浄物の洗浄、すすぎ及び乾燥を行った。
(Comparative Example 3)
In this comparative example, a 5 cm × 5 cm WFK10L standard contaminated cloth (contaminated cloth with red wine attached. Wfk Testgebe GmbH) was used instead of the WFK10D standard contaminated cloth of Comparative Example 1. Other than that, the object to be washed was washed, rinsed and dried in the same manner as in Comparative Example 1.
（比較例４）
本比較例に於いては、比較例１のＷＦＫ１０Ｄ標準汚染布に代えて、５ｃｍ×５ｃｍのＥＭＰＡ１１２標準汚染布（ココアが付着した汚染布。ＥＭＰＡ社製）を用いた。それ以外は、比較例１と同様にして、被洗浄物の洗浄、すすぎ及び乾燥を行った。
(Comparative Example 4)
In this comparative example, a 5 cm × 5 cm EMPA112 standard contaminated cloth (contaminated cloth with cocoa adhered, manufactured by EMPA) was used instead of the WFK10D standard contaminated cloth of Comparative Example 1. Other than that, the object to be washed was washed, rinsed and dried in the same manner as in Comparative Example 1.
（洗浄率の測定）
実施例１〜４及び比較例１〜４に係る洗浄後の標準汚染布及び洗浄前の標準汚染布について、それぞれ反射率の測定を行った。反射率の測定には、反射率計（製品名：ＴＲ−１０００Ｄ、東京電色（株）製）を用いた。
(Measurement of cleaning rate)
The reflectances of the standard contaminated cloth after cleaning and the standard contaminated cloth before cleaning according to Examples 1 to 4 and Comparative Examples 1 to 4 were measured, respectively. A reflectance meter (product name: TR-1000D, manufactured by Tokyo Denshoku Co., Ltd.) was used for measuring the reflectance.
さらに測定した反射率の測定値に基づき、以下の計算式で各実施例及び比較例に係る標準汚染布の洗浄率を算出した。結果を表１及び表２に示す。
洗浄率（％）＝（Ｒｗ−Ｒｓ）／（Ｒｏ−Ｒｓ）×１００
Ｒｗ：洗浄後の標準汚染布の反射率、Ｒｓ：洗浄前の標準汚染布の反射率、Ｒｏ：汚染前の白布（各標準汚染布における汚染前の白布）の反射率
Furthermore, based on the measured value of the measured reflectance, the cleaning rate of the standard contaminated cloth according to each Example and Comparative Example was calculated by the following formula. The results are shown in Tables 1 and 2.
Cleaning rate (%) = (Rw-Rs) / (Ro-Rs) × 100
Rw: Reflectance of standard contaminated cloth after cleaning, Rs: Reflectance of standard contaminated cloth before cleaning, Ro: Reflectance of white cloth before contamination (white cloth before contamination in each standard contaminated cloth)
表１及び表２から明らかな通り、それぞれの標準汚染布に於いて、実施例１〜４に係る洗浄剤セットを用いて洗浄を行った場合、比較例１〜４に係る一般の中性洗剤を用いた場合と比較して、いずれも洗浄率の値が高く、良好な洗浄作用及び漂白作用を示すことが確認された。 As is clear from Tables 1 and 2, when cleaning is performed using the cleaning agent set according to Examples 1 to 4 in each standard contaminated cloth, the general neutral detergent according to Comparative Examples 1 to 4 is used. It was confirmed that the values of the cleaning rate were high and good cleaning action and bleaching action were exhibited as compared with the case of using.
（実施例５）
本実施例に係る洗浄剤セットについて、常温の水に対する溶解性試験を行った。
すなわち、炭酸ナトリウム過酸化水素化物からなる第１組成物５ｇと、クエン酸からなる第２組成物２ｇとを、常温（水温１１℃）の水（水道水）１０００ｍｌに投入し、３０秒毎に５秒間ガラス棒で撹拌した。その結果、炭酸ナトリウム過酸化水素化物の水への投入後、約１分５０秒で完全に溶解したことが確認された。
(Example 5)
The detergent set according to this example was subjected to a solubility test in water at room temperature.
That is, 5 g of the first composition composed of sodium percarbonate and 2 g of the second composition composed of citric acid are added to 1000 ml of water (tap water) at room temperature (water temperature 11 ° C.) every 30 seconds. The mixture was stirred with a glass rod for 5 seconds. As a result, it was confirmed that the sodium percarbonate was completely dissolved in about 1 minute and 50 seconds after being added to water.
（比較例５）
炭酸ナトリウム過酸化水素化物について、常温の水に対する溶解性試験を行った。
すなわち、炭酸ナトリウム過酸化水素化物５ｇを常温（水温１１℃）の水（水道水）１０００ｍｌに投入し、３０秒毎に５秒間ガラス棒で撹拌した。その結果、炭酸ナトリウム過酸化水素化物の水への投入後、約１０分間を経過しても完全に溶解することはなく、不溶解分が確認された。
(Comparative Example 5)
Sodium percarbonate was tested for solubility in water at room temperature.
That is, 5 g of sodium percarbonate was added to 1000 ml of water (tap water) at room temperature (water temperature 11 ° C.), and the mixture was stirred with a glass rod every 30 seconds for 5 seconds. As a result, it was confirmed that the sodium percarbonate was not completely dissolved even after about 10 minutes had passed since it was added to water, and an insoluble component was confirmed.
Claims (5)
前記第１組成物と前記第２組成物は分けて保存されるものであり、
前記第１組成物と前記第２組成物とは、前記有機酸が前記炭酸ナトリウム過酸化水素化物に対し質量基準で０．２〜０．５の配合割合となるように混合されて洗剤組成物を構成する衣料用、住居用及び自動食器洗浄機用の洗浄剤セット。 A first composition containing sodium percarbonate and a second composition containing an organic acid are provided.
The first composition and the second composition are stored separately.
The first composition and the second composition are mixed so that the organic acid is mixed with the sodium percarbonate in a blending ratio of 0.2 to 0.5 on a mass basis to form a detergent composition. Detergent set for clothing, housing and automatic dishwashers that make up.
被洗浄物に、前記第１組成物と前記第２組成物を混合して得られる洗剤組成物を接触させる工程を含む衣料用、住居用及び自動食器洗浄機用の洗浄剤セットの使用方法。 A method of using the cleaning agent set for clothing, housing and automatic dishwasher using the cleaning agent set for clothing, residential use and automatic dishwasher according to claim 1 or 2.
A method for using a cleaning agent set for clothing, housing, and an automatic dishwasher, which comprises a step of contacting a cleaning object with a detergent composition obtained by mixing the first composition and the second composition.
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| IL113815A0 (en) * | 1994-06-01 | 1995-08-31 | Procter & Gamble | Detergent compositions containing oleoyl sarcosinate and enzymes |
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