CN101135644B - 一种汞离子荧光显色化合物及汞离子检测方法与试纸 - Google Patents
一种汞离子荧光显色化合物及汞离子检测方法与试纸 Download PDFInfo
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- CN101135644B CN101135644B CN200710026150A CN200710026150A CN101135644B CN 101135644 B CN101135644 B CN 101135644B CN 200710026150 A CN200710026150 A CN 200710026150A CN 200710026150 A CN200710026150 A CN 200710026150A CN 101135644 B CN101135644 B CN 101135644B
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- 150000001875 compounds Chemical class 0.000 claims abstract description 51
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- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052753 mercury Inorganic materials 0.000 claims abstract description 20
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- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 abstract description 3
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- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 3
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- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 3
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CN200710026150A CN101135644B (zh) | 2007-08-16 | 2007-08-16 | 一种汞离子荧光显色化合物及汞离子检测方法与试纸 |
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Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101718994B1 (ko) * | 2009-09-16 | 2017-03-23 | 포항공과대학교 산학협력단 | 무기 및 유기수은종을 형광을 통하여 감지하는 화학량계의 개발 |
CN102086206B (zh) * | 2009-12-03 | 2013-01-30 | 大连理工大学 | 一类荧光探针及其制备方法和用途 |
CN102375020A (zh) * | 2010-08-19 | 2012-03-14 | 华东师范大学 | 多胸腺嘧啶dna修饰金电极电化学检测汞离子的方法 |
CN102516992A (zh) * | 2011-12-07 | 2012-06-27 | 天津工业大学 | 一种检测Hg2+离子的荧光探针及其合成方法和用途 |
CN102721674B (zh) * | 2012-05-24 | 2014-08-06 | 北京化工大学 | Eu-香草醛类Schiff碱-邻菲罗啉-Zn四元荧光增强体系、制备方法及应用 |
CN103436253B (zh) * | 2013-08-19 | 2015-01-07 | 滨州医学院 | 一种检测亚铁离子的罗丹明荧光探针及其制备方法 |
CN104004028B (zh) * | 2014-06-06 | 2016-04-13 | 南京工业大学 | 一种检测Hg2+的多通道分子探针及其制备方法 |
CN106188074B (zh) * | 2016-07-06 | 2018-01-16 | 常州工程职业技术学院 | 一类水溶性铁离子荧光探针及其制备方法 |
CN107522753B (zh) * | 2017-09-08 | 2019-09-24 | 山东师范大学 | 一种烯丙基亚胺桥联二茂铁-罗丹明b多通道响应受体分子及其合成方法和应用 |
CN110596084B (zh) * | 2019-08-26 | 2024-06-07 | 江苏大学 | 一种检测汞离子的荧光试纸及检测方法 |
CN111995632B (zh) * | 2020-08-10 | 2023-08-11 | 西北师范大学 | 一种均苯三罗丹明酰胺传感器分子及其合成和应用 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0623599A1 (de) * | 1993-03-26 | 1994-11-09 | Ciba-Geigy Ag | Optischer Sensor zur Bestimmung von Kationen |
CN1101929A (zh) * | 1994-09-29 | 1995-04-26 | 华东理工大学 | 一种具有双发色团的荧光染料及其制备方法 |
CN1158854A (zh) * | 1995-11-24 | 1997-09-10 | 希巴特殊化学控股公司 | 用于光聚合的硼酸盐助引发剂 |
CN1544944A (zh) * | 2003-11-27 | 2004-11-10 | 上海交通大学 | 一种以罗丹明为母体的荧光探针及制备方法 |
US20040235022A1 (en) * | 2003-03-19 | 2004-11-25 | Ralf Mauritz | Quality control method for manufacturing biopolymer arrays |
CN1752750A (zh) * | 2005-09-16 | 2006-03-29 | 厦门大学 | 检测水中汞离子的化学试剂及其制备方法 |
-
2007
- 2007-08-16 CN CN200710026150A patent/CN101135644B/zh not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0623599A1 (de) * | 1993-03-26 | 1994-11-09 | Ciba-Geigy Ag | Optischer Sensor zur Bestimmung von Kationen |
CN1101929A (zh) * | 1994-09-29 | 1995-04-26 | 华东理工大学 | 一种具有双发色团的荧光染料及其制备方法 |
CN1158854A (zh) * | 1995-11-24 | 1997-09-10 | 希巴特殊化学控股公司 | 用于光聚合的硼酸盐助引发剂 |
US20040235022A1 (en) * | 2003-03-19 | 2004-11-25 | Ralf Mauritz | Quality control method for manufacturing biopolymer arrays |
CN1544944A (zh) * | 2003-11-27 | 2004-11-10 | 上海交通大学 | 一种以罗丹明为母体的荧光探针及制备方法 |
CN1752750A (zh) * | 2005-09-16 | 2006-03-29 | 厦门大学 | 检测水中汞离子的化学试剂及其制备方法 |
Non-Patent Citations (4)
Title |
---|
Georges J., Arnaud, N., Parise, L..Limitations arising from optical saturation in fluorescenceandthermal lens spectrometries using pulsed laserexcitation:application to the determination of the fluorescencequantum yield of rhodamine 6G.Applied Spectroscopy50 12.1996,50(12),1505-1511. |
Georges J.,Arnaud,N.,Parise,L..Limitations arising from optical saturation in fluorescenceandthermal lens spectrometries using pulsed laserexcitation:application to the determination of the fluorescencequantum yield of rhodamine 6G.Applied Spectroscopy50 12.1996,50(12),1505-1511. * |
王钢等.罗丹明6G水相荧光光度法测定汞.岩矿测试12 2.1993,12(2),159-160. |
王钢等.罗丹明6G水相荧光光度法测定汞.岩矿测试12 2.1993,12(2),159-160. * |
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