CN101120010B - 基于茂金属的磷手性膦 - Google Patents
基于茂金属的磷手性膦 Download PDFInfo
- Publication number
- CN101120010B CN101120010B CN200680004909.8A CN200680004909A CN101120010B CN 101120010 B CN101120010 B CN 101120010B CN 200680004909 A CN200680004909 A CN 200680004909A CN 101120010 B CN101120010 B CN 101120010B
- Authority
- CN
- China
- Prior art keywords
- ligand
- metallocene
- bis
- substituted
- phosphorus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 0 CC=C(C(OC(C=CI(C)=C1)=C1Br)=CC=*C)Br Chemical compound CC=C(C(OC(C=CI(C)=C1)=C1Br)=CC=*C)Br 0.000 description 4
- IBFIEAOXSAFFPS-QMMMGPOBSA-N CCO[C@@H](Cc1ccc[s]1)C(O)=O Chemical compound CCO[C@@H](Cc1ccc[s]1)C(O)=O IBFIEAOXSAFFPS-QMMMGPOBSA-N 0.000 description 1
- MHIJWNWEFRCKIK-UHFFFAOYSA-N SC1CC=CC1 Chemical compound SC1CC=CC1 MHIJWNWEFRCKIK-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B53/00—Asymmetric syntheses
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0500702.6 | 2005-01-14 | ||
| GBGB0500702.6A GB0500702D0 (en) | 2005-01-14 | 2005-01-14 | Novel metallocene-based phosphorus chiral phosphines |
| PCT/GB2006/000114 WO2006075166A1 (en) | 2005-01-14 | 2006-01-13 | Metallocene-based phosphorus chiral phosphines |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101120010A CN101120010A (zh) | 2008-02-06 |
| CN101120010B true CN101120010B (zh) | 2013-07-03 |
Family
ID=34224566
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200680004909.8A Active CN101120010B (zh) | 2005-01-14 | 2006-01-13 | 基于茂金属的磷手性膦 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7906669B2 (enExample) |
| EP (1) | EP1844061B1 (enExample) |
| JP (1) | JP5112881B2 (enExample) |
| CN (1) | CN101120010B (enExample) |
| AT (1) | ATE476437T1 (enExample) |
| AU (1) | AU2006205652B2 (enExample) |
| CA (1) | CA2594893C (enExample) |
| DE (1) | DE602006015910D1 (enExample) |
| ES (1) | ES2348060T3 (enExample) |
| GB (2) | GB0500702D0 (enExample) |
| WO (1) | WO2006075166A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5320283B2 (ja) * | 2006-04-12 | 2013-10-23 | ソルヴィーアス アクチェンゲゼルシャフト | フェロセンジホスフィン |
| WO2008055942A1 (en) * | 2006-11-10 | 2008-05-15 | Solvias Ag | Preparation of optically pure ferrocenediphosphines |
| EP2125210A1 (en) * | 2007-02-20 | 2009-12-02 | Solvias AG | Bis (ferrocenylphosphino) ferrocene ligands used in asymmetric hydrogenation reactions |
| US9394326B2 (en) * | 2011-08-08 | 2016-07-19 | Novomer, Inc. | Catalysts and methods for polymer synthesis |
| CN116120378B (zh) * | 2021-11-15 | 2025-06-06 | 中国科学院上海有机化学研究所 | 一种二茂铁双齿膦配体催化丁二烯制备己二腈的方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2001236912A1 (en) * | 2000-02-10 | 2001-08-20 | The Penn State Research Foundation | Chiral ferrocene phosphines and their use in asymmetric catalytic reactions |
| JP2005041847A (ja) | 2003-07-25 | 2005-02-17 | Nippon Chem Ind Co Ltd | フェロセンを置換基に有する光学活性リンキラルジホスフィン化合物、該化合物の中間体、該化合物の製造方法及び該化合物を用いる不斉合成反応、並びに該化合物を配位子として有する金属錯体触媒及び該金属錯体触媒を用いる不斉合成反応をする方法 |
| GB0400720D0 (en) | 2004-01-14 | 2004-02-18 | Stylacats Ltd | Novel ferrocene-based phosphorus chiral phosphines |
-
2005
- 2005-01-14 GB GBGB0500702.6A patent/GB0500702D0/en not_active Ceased
-
2006
- 2006-01-13 WO PCT/GB2006/000114 patent/WO2006075166A1/en not_active Ceased
- 2006-01-13 GB GB0600713A patent/GB2422604A/en not_active Withdrawn
- 2006-01-13 CA CA2594893A patent/CA2594893C/en active Active
- 2006-01-13 JP JP2007550840A patent/JP5112881B2/ja active Active
- 2006-01-13 DE DE602006015910T patent/DE602006015910D1/de active Active
- 2006-01-13 AT AT06700701T patent/ATE476437T1/de active
- 2006-01-13 AU AU2006205652A patent/AU2006205652B2/en active Active
- 2006-01-13 CN CN200680004909.8A patent/CN101120010B/zh active Active
- 2006-01-13 US US11/813,987 patent/US7906669B2/en active Active
- 2006-01-13 EP EP06700701A patent/EP1844061B1/en active Active
- 2006-01-13 ES ES06700701T patent/ES2348060T3/es active Active
Non-Patent Citations (2)
| Title |
|---|
| Nobuhiko Oohara, Kosuke katagiri, et al..A novel P-chirogenic phosphine ligand, (S,S)-1,2-bis-[(ferrocenyl)methylphosphino]ethane:synthesis and use inrhodium-catalyzed asymmetric hydrogenation and palladium-catalyzed asymmetric allylic alkylation..Tetrahedron: Asymmetry14.2003,142171-2175. * |
| Ulrike Nettekoven, Michael Widhalm, et al..Steric and electronic ligand perturbations in catalysis:asymmetric allylic substitution reactions using C2-symmetricalphosphorus-chiral (Bi)ferrocenyl donors..J. Org. Chem.66.2001,66759-770. * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2006075166A1 (en) | 2006-07-20 |
| GB2422604A (en) | 2006-08-02 |
| CA2594893C (en) | 2014-05-13 |
| GB0500702D0 (en) | 2005-02-23 |
| JP2008526938A (ja) | 2008-07-24 |
| AU2006205652A1 (en) | 2006-07-20 |
| CA2594893A1 (en) | 2006-07-20 |
| ATE476437T1 (de) | 2010-08-15 |
| CN101120010A (zh) | 2008-02-06 |
| JP5112881B2 (ja) | 2013-01-09 |
| DE602006015910D1 (de) | 2010-09-16 |
| US20090137824A1 (en) | 2009-05-28 |
| EP1844061A1 (en) | 2007-10-17 |
| US7906669B2 (en) | 2011-03-15 |
| ES2348060T3 (es) | 2010-11-29 |
| EP1844061B1 (en) | 2010-08-04 |
| AU2006205652B2 (en) | 2010-09-09 |
| GB0600713D0 (en) | 2006-02-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: SOLVAYAS STOCK CO., LTD. Free format text: FORMER OWNER: PHOENIX MEDICINE CO., LTD. Effective date: 20091106 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20091106 Address after: Basel Applicant after: Solvias AG Address before: Britain Merseyside Applicant before: Phoenix Chemicals Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |