CN101112349A - Shampoo composition provided with anti-dandruff and opsonize efficacy - Google Patents
Shampoo composition provided with anti-dandruff and opsonize efficacy Download PDFInfo
- Publication number
- CN101112349A CN101112349A CNA2007101357815A CN200710135781A CN101112349A CN 101112349 A CN101112349 A CN 101112349A CN A2007101357815 A CNA2007101357815 A CN A2007101357815A CN 200710135781 A CN200710135781 A CN 200710135781A CN 101112349 A CN101112349 A CN 101112349A
- Authority
- CN
- China
- Prior art keywords
- shampoo composite
- shampoo
- percent
- surfactant
- dandruff
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The present invention provides a shampoo compound which has the effects of scurf removal and conditioning. The shampoo compound of the present invention includes the following components with the weight percentages: a) 5 percent to 50 percent surfactant; b) 0.01 percent to 10 percent alkyl propyl dimethyl 2, 3 dihydroxy ammonium chloride alkyl quaternary ammonium salts; c) 0.01 percent to 10 percent non-volatile siloxane; d) 0.01 percent to 3 percent cationic polymer; e) 0.01 percent to 5 percent scurf-removing agent and f) deionized water. Compared with other scurf-removing shampoos, the shampoo compound of the present invention has better effect conditioning of the scalp and hair and better scurf-removing and itch reliving effects.
Description
Technical field
The present invention relates to a kind of shampoo composite, be specifically related to have the shampoo composite of anti-dandruff and opsonic action.
Background technology
Occurred many shampoo composites that excellent cleaning hair and conditioning hair effect can be provided on the market, these shampoo composites contain multiple rinse additives such as detersive surfactant, cationic cellulose, cation guar gum, polysiloxanes conditioner mostly.But when containing alkyl quaternary ammonium salts commonly used such as three-cetyl chloride ammonium in the shampoo composite, then can increase the zest of shampoo, head pruritus dandruff phenomenon is well improved.
The shampoo that contains the anti-dandruff composition also is to have bought in market, and they are to have introduced the anti-dandruff active substance on the basis of detersive surfactant.Wherein, Chang Yong anti-dandruff composition mainly contains 1-oxygen-2-mercaptopyridine salt or selenium sulfide, sulfur, coal tar, ketoconazole, climbazole and 0ctopirox etc.When using anti-dandruff dose, in the finite concentration scope, better effects is arranged, when use amount is big, also scalp is produced zest.
United States Patent (USP) 5624666 is enumerated and claimed anion surfactant, cationic polymer and the Zinc Pyrithione shampoo composite as dandruff removing agent that comprises.Though these shampoos make every effort to the conditioning effect and anti-dandruff between reach optimum balance, but the compound action with better anti-dandruff effect and conditioning performance is difficult to reach, deposition anti-dandruff active substance can be to opsonic action on hair and scalp, and particularly Qing Jie hair feel has a negative impact.
Shampoo composite reaches better anti-dandruff effect and conditioning performance and depends on all many-sides such as the amount of the consumption of the cationic polymer that uses in type and proportioning, the especially compositions of each conditioning component in the shampoo formula and anti-dandruff dose and type, the type of employed dandruff removing agent, employed anion surfactant and type.
Summary of the invention
Although it is very difficult to obtain the shampoo composite of anti-dandruff efficacy and conditioning performance perfect combination, the applicant still finds to use alkyl propyl-dimethyl 2,3 dihydroxy ammonium chloride class alkyl quaternary ammonium saltss are during as conditioner, can not only effectively reduce the zest of anti-dandruff shampoo, and can effectively improve wet comb and do the comb performance.
The purpose of this invention is to provide a kind of shampoo composite, can not only reduce the zest of shampoo, improve the shampoo mildness, and can play the effect of the effective removal dandruff scalp with anti-dandruff effect and conditioning performance.
Shampoo composite provided by the present invention comprises following component by weight percentage:
A) 5% to 50% surfactant;
B) 0.01% to 10% alkyl propyl-dimethyl 2,3 dihydroxy ammonium chloride class alkyl quaternary ammonium saltss;
C) 0.01% to 10% fixedness siloxanes;
D) 0.01% to 3% cationic polymer;
E) anti-dandruff dose of 0.01% to 5%; With
F) deionized water.
The various compositions of shampoo composite of the present invention will be described below, the qualification of also having described the various selection compositions that are applicable in the specific embodiments of the present invention and preferred composition, component in addition and having made.Except as otherwise noted, all percentage ratio and ratio be all with the percentage by weight of the total weight gained of shampoo composite of the present invention, and described composition is all with the cubage of active ingredient.
A. surfactant
The surfactant that the present invention adopts can be to be selected from least a in anion surfactant, zwitterionic surfactant and the non-ionic surface active agent, it accounts for shampoo composite weight 5%-50%, be preferably 5%-25%, more preferably 8%-20% most preferably is 10%-18%.Above-mentioned anion surfactant not only can play cleaning and blistered performance, and should be compatible on physics and chemical property with other component of the present invention, and can keep the attractive in appearance and stable of shampoo composite.
It is following at least a to be applicable to that anion surfactant of the present invention comprises: alkylsulfonate; alkyl sulfate; acylated amino salt; polyoxyethylene alkyl ether sulfate salt; alkylbenzenesulfonate; N-acyl group-N methyl taurine salt; alpha-alefinically sulfonate; the higher fatty acids sulfonated ester; the alkyl ether acetate; the polyoxyethylene alkyl ether acetate; fatty acid soaps; alkyl phosphate salt; the N-lauroyl glutamate; N-palmityl glutamate, Glu; N-lauroyl-Ethylglycocoll salt; N-Hamposyl L salt and N-myristoyl-Beta-alanine salt.
It is following at least a to be applicable to that zwitterionic surfactant of the present invention comprises: alkyl betaine-type surfactant, amido betaine type surfactant, sulfobetaines type surfactant, hydroxyl sulfo betaine type surfactant, amidosulfobetaines type surfactant, phosphoric acid betaine type surfactant, imidazolinium betaine type surfactant, alanine type surfactant and amino acid type surfactant.
Wherein, preferably CAB lauramide, betanin lauryl dimethyl aminoacetate, fatty acid distribution of coconut oil amido propyl betaine, fatty acid distribution of coconut oil dimethylamino acetas betanin, lauryl hydroxyl sulfo betaine, 2-alkyl-N-carboxymethyl-N-ethoxy-imidazolinium betaine, lauryl imino-diacetic propyl ester, N-[3-alkyl (12,14) oxygen-2-hydroxypropyl]-L-arginine hydrochloride.
Be applicable to that ionic surfactant pack of the present invention draws together following at least a: polyoxyethylene fatty acid ester, polyoxyethylene hydrogenated Oleum Ricini, polyoxyethylene dehydration Pyrusussuriensis (sugar) alcohol fatty acid ester, polyoxy fatty acid glyceride, polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene glycol, fatty acid distribution of coconut oil alkane alcohol amide, sucrose fatty acid ester, alkylglycoside, alkyl glycerol base glucoside and methyl glucoside fatty acid ester.Wherein, preferred polyethylene glycol mono stearate, decyl glyceryl monolaurate, single Tridocosanoin, polyoxyethylene lauryl ether, polyoxyethylene 8 stearate ether, polyoxyethylene mountain Yu acid ether, polyoxyethylene (160) polyoxypropylene (30) glycol, alkylglycoside.
B. alkyl propyl-dimethyl 2,3 dihydroxy ammonium chloride class alkyl quaternary ammonium saltss
Its alkyl of alkyl quaternary ammonium salts that is suitable for shampoo composite of the present invention is side chain or the linear chain structure that contains 4 above carbochains, be preferably the alkyl propyl-dimethyl 2 that contains 12 above carbochains, 3 dihydroxy ammonium chloride, most preferably be alkyl propyl-dimethyl 2, the 3 dihydroxy ammonium chloride of the carbochain that contains 12 above straight chains.It should be compatible on physics and chemical property with other component of the present invention, and can keep the stability of shampoo composite, attractive in appearance or performance.
It is 0.01%-10% that alkyl propyl-dimethyl 2,3 dihydroxy ammonium chloride class alkyl quaternary ammonium saltss of the present invention account for shampoo composite weight, is preferably 0.05%-8.0%.
C. non-volatile siloxane
It is 0.01%-10% that non-volatile siloxane conditioner of the present invention accounts for shampoo composite weight, is preferably 0.05%-8.0%, and more preferably 0.1%-5% most preferably is 0.5%-4.0%.The siloxanes hair conditioner that the is used for shampoo composite preferably viscosity under 25 ℃ is 20-2, and 000,000 centistoke is preferred 1,000-1,500,000 centistokes, most preferably 10,000-1,000,000 centistoke.
The preferred non-volatile siloxane conditioner of the present invention mixes in shampoo composite usually, thus make its with disperse insoluble granule separately, the discontinuous phase form exists, and is also referred to as " droplet ".This droplet will suspend in the suspending agent of describing usually below.This siloxanes hair conditioner comprises siloxanes fluids hair conditioner such as siloxanes fluids, also can comprise other composition, as siloxane glue and silicone resin, with deposition that strengthens siloxanes fluids or the gloss that improves hair.
Term " non-volatile " is meant and has silicone material very little or that almost do not have vapour pressure under environmental condition herein.Boiling point under 1 atmospheric pressure preferably is at least about 250 ℃, more preferably at least about 275 ℃, most preferably at least about 300 ℃.At 25 ℃ or more under the low temperature, vapour pressure is preferably less than about 0.2mmHg, most preferably less than about 0.1mmHg.
Other siloxanes hair conditioner that is used for shampoo composite comprises silicone oil, and this silicone oil is a kind of flowable silicone material, and its viscosity under 25 ℃ is less than 1,000,000 centistoke, preferred 5-1,000,000 centistoke, more preferably 10-600,000 centistoke, more preferably 10-500 again, 000 centistoke, 10-300 most preferably, 000 centistoke.Suitable silicone oil comprises poly-alkylsiloxane, poly-aryl siloxanes, poly-alkaryl siloxanes, polyether siloxane copolymer and its mixture.
Other suitable siloxanes fluids that is applicable to silicone conditioning agent is an insoluble silicone glue.These glue are polysiloxane, and the viscosity in the time of 25 ℃ is more than or equal to 1,000,000 centistoke.The matter average molecular weight of siloxane glue surpasses 200,000 centistoke, usually between 200,000-1,000,000 centistoke, at least a as in polydimethylsiloxane, dimethyl siloxane-methyl ethylene silicone copolymers, the dimethyl siloxane-diphenyl siloxane-methyl ethylene silicone copolymers.
The siloxanes hair conditioner also comprises polydimethylsiloxane glue (viscosity greater than 1,000,000 centistoke) and polydimethyl siloxane oil (viscosity is about 10-100,000 centistoke).
D. anti-dandruff dose
It is 0.01%-5% that in the shampoo composite of the present invention anti-dandruff dose accounts for shampoo composite weight, is preferably 0.5%-1.5%.
In the shampoo composite of the present invention anti-dandruff dose comprises at least a in the following material: pyrithione slaine, ketoconazole, miconazole, Octopirox, IPBC, climbazole, selenium sulfide, sulfur, coal tar.Preferred anti-dandruff dose is Zinc Pyrithione (ZPT), ketoconazole, Octopirox, climbazole, and preferred anti-dandruff dose is Zinc Pyrithione (ZPT), ketoconazole, Octopirox.ZPT is a flat crystal, can or not wrap up with the oils and fats parcel.In order to reduce zest and/or to increase anti-dandruff effect, can use parcel ZPT, its wrappage is various oil substances, the oils and fats of parcel ZPT can be alkane, paraffin oil, vegetable oil, animal oil and their lipid or mixture.
Be applicable to that anti-dandruff dose of the present invention can be microgranular or dissolved form, can be preferably compatible with the physicochemical property of other component of shampoo composite, keep the stability of shampoo composite.Anti-dandruff dose optimum quantum of utilization can determine that this can realize those skilled in the art according to the composition of employed concrete anti-dandruff dose of kind and compositions.
E. cationic polymer
Be applicable to that cationic polymer of the present invention can be dissolved in the shampoo composite, perhaps in shampoo composite, form the liquid condensation layer, can promote the opsonic action of shampoo, can promote that in application process the polysiloxane particle among the present invention deposits on hair and/or the scalp from shampoo composite.
It is 0.01%-3% that in the shampoo composite of the present invention anti-dandruff dose accounts for shampoo composite weight, preferred 0.1%-1.0%.Be applicable to that cationic charge density of the present invention is 0.1-1.2 milliequivalent/gram, preferred 0.3-0.8 milliequivalent/gram, more preferably 0.5-0.7 milliequivalent/gram, wherein the molecular weight of cationic polymer is greater than 600,000, be preferably 800,000-2,000,000, more preferably 1,000,000-1,500,000, most preferably be 1,250,000-1,350,000.Preferably, the molecular weight of this cationic polymer is lower than 5,000,000.
The charge density of this cationic polymer can be measured according to the Kjledah1 method.It will be appreciated by those skilled in the art that the charge density that contains amino polymer will become with pH and amino isoelectric point, IP.Described pH value is generally about 3 to about 9, is about 4 to about 8 the most commonly.
Term " polymer " used herein " comprise by a kind of material of monomer polymerization generation or by the material (being copolymer) of two kinds of monomer polymerizations generations or material or the naturally occurring polymer that produces by multiple monomer polymerization.
The cationic polymer that is applicable to shampoo of the present invention comprises at least a in the following material: cation guar gum, polyquaternary ammonium salt-2, polyquaternary ammonium salt-4, polyquaternary ammonium salt-7, polyquaternary ammonium salt-10, polyquaternary ammonium salt-11, Salcare SC60 (ciba company), Salcare SC96 (ciba company).Preferred cationic guar gum, polyquaternary ammonium salt-4, polyquaternary ammonium salt-7, polyquaternary ammonium salt-10, most preferably polyquaternary ammonium salt-10.
F. water
In the shampoo composite of the present invention, except the above composition and other optional auxiliary element, be supplemented to requirement with deionization.
G. optional components
Shampoo composite of the present invention can also comprise one or more optional members, and optional member comprises that suspending agent, antistatic additive, antioxidant, foam booster, viscosity modifier, thickening agent, PH regulator, antiseptic, pigment, organic solvent or diluent, pearling agent, spice, aliphatic alcohol etc. are known or is effective to additional optional components among hair nursing or the personal care product.
The suspending agent that is suitable for shampoo composite of the present invention should play and make siloxanes conditioning composition protect special suspended state, to keep its homogeneously dispersed state in shampoo composite.
It is 0.01%-10.0% that the suspending agent that is suitable for shampoo composite of the present invention accounts for shampoo composite weight, preferred 0.1%-8.0%.
The suspending agent that is suitable for shampoo composite of the present invention comprises at least a in following: HANSHENGJIAO, acrylate copolymer (with Carbopol SF-1 is trade name, buys from NOVEON company), hydroxypropyl cellulose, hydroxypropyl guar gum, polyvinyl pyrrolidone and maleic anhydride-methyl ethylene ether copolymer.Preferred HANSHENGJIAO, acrylate copolymer.
Optional antistatic additive can be water-insoluble cationic surfactant, accounts for the 0.1%-5.0% of composition weight usually.The concrete non-limiting example of suitable antistatic additive is a quaternary ammonium salt-80.
The foam booster that is used for shampoo composite of the present invention comprises cocos nucifera oil acyl monoethanolamine, cocos nucifera oil acyl diethanolamine and their mixture.
Viscosity modifier of selecting for use and thickening agent are used for shampoo composite of the present invention with effective dose ground, to regulate mastic to suitable viscosity.The concrete non-limiting example of this viscosity modifier and thickening agent comprises: sodium chloride, ammonium chloride and their mixture.
Shampoo composite with anti-dandruff effect and conditioning performance of the present invention, use alkyl propyl-dimethyl 2,3 dihydroxy ammonium chloride class alkyl quaternary ammonium saltss are as conditioner, and can not only effectively reduce the zest of anti-dandruff shampoo through scientific matching with other shampoo component, and can effectively improve wet comb and do the comb performance, and play the effect of the effective removal dandruff.
Shampoo composite of the present invention can by any known or other effectively be suitable for providing the technology preparation of shampoo composite, the method that prepare shampoo composite of the present invention comprises the preparation and the hybrid technology of routine.
Shampoo composite of the present invention uses with the cleaning of routine and the mode of conditioning hair, and comprise following step: (a) water is with the hair moistening; (b) the above-mentioned shampoo composite (2-20 gram) with effective dose is administered on the hair, rubs in hair and on the scalp and smears shampoo composite, thereby make compositions contact with scalp with hair; (C) water rinsing shampoo composite from the hair.These steps can repeat many times as required, to reach cleaning, conditioning and anti-dandruff efficacy.
The specific embodiment
Be the indefiniteness embodiment of shampoo composite of the present invention below.Providing of these embodiment only is for illustrative purposes, can not be interpreted as limitation of the invention.Because without departing from the spirit and scope of the present invention, can carry out many conversion to the present invention.In these embodiments, unless stated otherwise, all concentration all is that the weight with shampoo composite is the percentage by weight that the basis draws.Used term " small amount of matter " refers to those optional materials, as antiseptic, viscosity modifier, PH regulator, spice, pigment etc.
Preparation embodiment
The method for preparing shampoo composite (seeing Table 1) in embodiment (I, III, V) and the Comparative Examples (II, IV, VI) suitably is as follows: will about 1/3 join in the blending tank that strap clamp overlaps to whole surfactants and part water, under slowly stirring, be heated to about 70 ℃ to 80 ℃, then add 16 octadecanol, glycol distearate, coconut oil single ethanol amide, two lauramide propyl-dimethyls 2,3-dihydroxypropyl ammonium chloride, zinc sulfate etc. further mix.If there is conditioning polymer (as polyquaternary ammonium salt-7 and polyquaternary ammonium salt-10), can add at this moment after pre-dispersed.Mixing is at least about after 30 minutes, and this mixture is cooled to about 50 ℃, and cation guar gum is pre-dispersed in the water, obtains about 0.1% to about 10% aqueous solution, with this dispersion liquid and aforementioned mixture mix homogeneously.Cooling gained mixture is collected these mixture in the finished product jar, under agitation adds remaining surfactant and remaining ingredient, continues to stir, and guarantees to obtain uniform mixture.After adding all components, can add viscosity modifier and pH regulator agent as required, viscosity and the pH value of regulating product arrive suitable degree.Randomly can add an amount of small amount of matter at last, supply with deionized water at last.
The composition of table 1. shampoo composite
| Component | Embodiment and Comparative Examples (%) | |||||
| I | II | III | IV | V | VI | |
| Fatty alcohol-ether sodium sulfate | 12 | 12 | ||||
| Sodium alkyl sulfate | 5 | 5 | ||||
| Ammonium alkyl sulfate | 12 | 12 | 12 | 12 | ||
| Fatty alcohol ether ammonium sulfate | 5 | 5 | 5 | 5 | ||
| 16 octadecanol | 1.0 | 1.0 | 1.0 | 1.0 | ||
| Glycol distearate | 1.5 | 1.5 | 2.0 | 2.0 | 2.0 | 2.0 |
| The coconut oil single ethanol amide | 1.0 | 1.0 | 1.0 | 1.0 | 0.5 | 0.5 |
| Zinc sulfate | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
| Cation guar gum | 0.5 | 0.5 | 0.3 | 0.3 | 0.1 | 0.1 |
| Zinc Pyrithione | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 | 1.0 |
| Polyquaternary ammonium salt-7 | 0.2 | 0.2 | 0.4 | 0.4 | ||
| Polyquaternary ammonium salt-10 | 0.5 | 0.5 | ||||
| Two lauramide propyl-dimethyls 2,3-dihydroxypropyl ammonium chloride | 0.5 | -- | 0.3 | -- | 1.0 | -- |
| Cocamido propyl betaine | 2.0 | 2.0 | 1.0 | 1.0 | 1.0 | 1.0 |
| Coconut oleoyl amine both sexes sodium acetate | 2.0 | 2.0 | 2.0 | 2.0 | ||
| Siloxanes | 1.5 | 1.5 | 1.5 | 1.5 | 1.2 | 1.2 |
| Pantothenylol | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
| Small amount of matter | In right amount | |||||
| Water | Surplus | |||||
Effect embodiment
Effect evaluation method for embodiment is: the shampoo composite of preparation embodiment (I, III, V) and Comparative Examples (II, IV, VI) is done the contrast test, promptly prepare example I and Comparative Example II and do the contrast test, preparation EXAMPLE III and Comparative Examples I V do the contrast test, preparation EXAMPLE V and Comparative Examples VI do the contrast test, issue test crowd (each 50 people) contrast respectively and use.
According to identical method hair washing, every kind of shampoo used for two weeks when the tester used the shampoo sample.The people of half uses a kind of shampoo wherein earlier, second half people uses another kind of shampoo earlier, for example, when I and II contrast test sample, 25 people are at the last fortnight I shampoo on probation, two weeks of back are tried out II shampoo, and 25 people are at the last fortnight II shampoo on probation in addition, and two weeks of back are tried out I shampoo.The tester according to oneself feel mark.Standards of grading adopt 7 fens systems, and 1 minute the poorest, and 7 minutes best, and mark is high more good more.
The various shampoo composite results of use of table 2. are estimated
| Evaluation index (7 fens systems, 1 minute is the poorest, and 7 minutes are best, mark is high more good more) | ||||
| The hair drying comb rational faculty | The wet Comb rational faculty | Do and send out pliability | The scalp comfort level | |
| Example I | 5.8 | 5.7 | 5.8 | 6.0 |
| Comparative Example II | 4.9 | 4.7 | 4.5 | 4.4 |
| EXAMPLE III | 5.6 | 5.4 | 5.5 | 5.2 |
| Comparative Examples I V | 4.7 | 4.5 | 4.3 | 4.3 |
| EXAMPLE V | 6.2 | 6.1 | 6.0 | 6.3 |
| Comparative Examples VI | 4.6 | 4.4 | 4.2 | 4.0 |
Claims (10)
1. shampoo composite comprises following component by weight percentage:
A), 5% to 50% surfactant;
B), 0.01% to 10% alkyl propyl-dimethyl 2,3 dihydroxy ammonium chloride class alkyl quaternary ammonium saltss;
C), 0.01% to 10% fixedness siloxanes;
D), 0.01% to 3% cationic polymer;
E), anti-dandruff dose of 0.01% to 5%; With
F), deionized water.
2. according to the shampoo composite of claim 1, described alkyl propyl-dimethyl 2,3 its alkyl of dihydroxy ammonium chloride class alkyl quaternary ammonium salts are side chain or the linear chain structure that contain 4 above carbochains, be preferably the carbon-chain structure that contains more than 12, most preferably be the carbon-chain structure that contains 12 above straight chains.
3. according to the shampoo composite of claim 1 or 2, described surfactant is to be selected from least a in anion surfactant, zwitterionic surfactant and the non-ionic surface active agent.
4. according to the shampoo composite of claim 3, described surface-active contents is preferably 5% to 25%, and more preferably 8% to 20%, most preferably be 10% to 18%.
5. according to the shampoo composite of claim 1 or 2, the viscosity of described fixedness siloxanes under 25 ℃ is 20-2, and 000,000 centistoke is preferred 1,000-1,500,000 centistokes, most preferably 10,000-1,000,000 centistoke.
6. according to the shampoo composite of claim 5, described fixedness content of siloxane is preferably 0.05% to 8.0%, and more preferably 0.1% to 5%, most preferably be 0.5% to 4.0%.
7. according to the shampoo composite of claim 1, described cationic polymer is to be selected from least a in cation guar gum, polyquaternary ammonium salt-2, polyquaternary ammonium salt-4, polyquaternary ammonium salt-7, polyquaternary ammonium salt-10, the polyquaternary ammonium salt-11.
8. according to the shampoo composite of claim 7, the charge density of described cationic polymer is between 0.1 to 1.2meq/g, and molecular weight is between 500,000 to 2,000,000.
9. according to the shampoo composite of claim 1, described anti-dandruff dose is to be selected from least a in Zinc Pyrithione, ketoconazole, miconazole, Octopirox, IPBC, climbazole, selenium sulfide, sulfur, the coal tar.
10. according to the shampoo composite of claim 9, described Zinc Pyrithione is the flat crystal with the oils and fats parcel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007101357815A CN101112349B (en) | 2007-08-16 | 2007-08-16 | Shampoo composition provided with anti-dandruff and opsonize efficacy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007101357815A CN101112349B (en) | 2007-08-16 | 2007-08-16 | Shampoo composition provided with anti-dandruff and opsonize efficacy |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101112349A true CN101112349A (en) | 2008-01-30 |
| CN101112349B CN101112349B (en) | 2011-05-18 |
Family
ID=39020979
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007101357815A Expired - Fee Related CN101112349B (en) | 2007-08-16 | 2007-08-16 | Shampoo composition provided with anti-dandruff and opsonize efficacy |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101112349B (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010127924A3 (en) * | 2009-05-08 | 2011-12-22 | Unilever Plc | Hair care composition comprising zinc - based anti - dandruff agent, conazole fungicide and cationic deposition polymer |
| CN102641283A (en) * | 2012-04-07 | 2012-08-22 | 张红 | Medicine for treating scurf and preparing method thereof |
| CN102716045A (en) * | 2012-06-11 | 2012-10-10 | 广东拉芳日化有限公司 | Shampoo composition containing double anti-dandruff agents |
| CN102920618A (en) * | 2012-11-12 | 2013-02-13 | 和大为 | Cleaning product for cleaning industrial and mining heavy dirt and preparation method of cleaning product |
| CN103330650A (en) * | 2013-05-14 | 2013-10-02 | 广州市白云联佳精细化工厂 | Composition with characteristics of moisturizing, scurf removing and itching alleviating |
| CN104323929A (en) * | 2014-10-31 | 2015-02-04 | 重庆环驰科技有限公司 | Shampoo with controllable viscosity and preparation method thereof |
| CN104784068A (en) * | 2014-01-16 | 2015-07-22 | 拜尔斯道夫股份有限公司 | Hair loss preventing shampoo composition |
| CN104936654A (en) * | 2013-02-08 | 2015-09-23 | 宝洁公司 | Method of enhancing deposition of antidandruff agents on infundibulum |
| CN107951751A (en) * | 2017-12-20 | 2018-04-24 | 佛山市洛克威特科技有限公司 | A kind of anti-dandruff Chinese medicine rich mixture conditioning shampoo |
| CN109689014A (en) * | 2016-09-07 | 2019-04-26 | 荷兰联合利华有限公司 | Antimicrobial personal cleaning compositions |
| US11058624B2 (en) | 2014-02-06 | 2021-07-13 | The Procter And Gamble Company | Hair care composition comprising cationic polymers and anionic particulates |
| US11197810B2 (en) | 2016-03-24 | 2021-12-14 | The Procter And Gamble Company | Hair care compositions comprising malodor reduction compositions |
| CN114042004A (en) * | 2021-11-25 | 2022-02-15 | 中轻日化科技有限公司 | Pearlescent composition for hair washing and caring products and preparation method and application thereof |
| US11642353B2 (en) | 2014-02-06 | 2023-05-09 | The Procter & Gamble Company | Hair care composition comprising antidandruff agent and polyquaternium-6 |
| US11679065B2 (en) | 2020-02-27 | 2023-06-20 | The Procter & Gamble Company | Compositions with sulfur having enhanced efficacy and aesthetics |
| US11904036B2 (en) | 2017-10-10 | 2024-02-20 | The Procter & Gamble Company | Sulfate free clear personal cleansing composition comprising low inorganic salt |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11964038B2 (en) | 2018-10-04 | 2024-04-23 | The Procter & Gamble Company | Personal care composition comprising water insoluble solid organic compound |
| JP2023549517A (en) | 2020-12-04 | 2023-11-27 | ザ プロクター アンド ギャンブル カンパニー | Hair care composition containing malodor reducing substances |
| US20220378684A1 (en) | 2021-05-14 | 2022-12-01 | The Procter & Gamble Company | Shampoo Compositions Containing a Sulfate-Free Surfactant System and Sclerotium Gum Thickener |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU8761698A (en) * | 1998-07-30 | 2000-02-21 | Procter & Gamble Company, The | Hair care compositions |
| JP4405832B2 (en) * | 2004-03-15 | 2010-01-27 | 中央化学株式会社 | Flux composition |
| FR2881954B1 (en) * | 2005-02-11 | 2007-03-30 | Oreal | COSMETIC COMPOSITION COMPRISING A CATION, A CATIONIC POLYMER, A SOLID COMPOUND AND A STARCH AND COSMETIC TREATMENT PROCESS |
| US20060182702A1 (en) * | 2005-02-11 | 2006-08-17 | L'oreal | Composition containing a cation, a cationic polymer, a solid compound and a starch, and cosmetic treatment process |
-
2007
- 2007-08-16 CN CN2007101357815A patent/CN101112349B/en not_active Expired - Fee Related
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010127924A3 (en) * | 2009-05-08 | 2011-12-22 | Unilever Plc | Hair care composition comprising zinc - based anti - dandruff agent, conazole fungicide and cationic deposition polymer |
| EA019630B1 (en) * | 2009-05-08 | 2014-05-30 | Унилевер Н.В. | Hair care composition |
| CN102641283A (en) * | 2012-04-07 | 2012-08-22 | 张红 | Medicine for treating scurf and preparing method thereof |
| CN102716045A (en) * | 2012-06-11 | 2012-10-10 | 广东拉芳日化有限公司 | Shampoo composition containing double anti-dandruff agents |
| CN102716045B (en) * | 2012-06-11 | 2014-01-15 | 广东拉芳日化有限公司 | Shampoo composition containing double anti-dandruff agents |
| CN102920618A (en) * | 2012-11-12 | 2013-02-13 | 和大为 | Cleaning product for cleaning industrial and mining heavy dirt and preparation method of cleaning product |
| CN102920618B (en) * | 2012-11-12 | 2014-06-11 | 和大为 | Cleaning product for cleaning industrial and mining heavy dirt and preparation method of cleaning product |
| CN104936654A (en) * | 2013-02-08 | 2015-09-23 | 宝洁公司 | Method of enhancing deposition of antidandruff agents on infundibulum |
| CN103330650A (en) * | 2013-05-14 | 2013-10-02 | 广州市白云联佳精细化工厂 | Composition with characteristics of moisturizing, scurf removing and itching alleviating |
| CN103330650B (en) * | 2013-05-14 | 2015-01-21 | 广州市白云联佳精细化工厂 | Composition with characteristics of moisturizing, scurf removing and itching alleviating |
| CN104784068A (en) * | 2014-01-16 | 2015-07-22 | 拜尔斯道夫股份有限公司 | Hair loss preventing shampoo composition |
| CN104784068B (en) * | 2014-01-16 | 2018-01-12 | 拜尔斯道夫股份有限公司 | Hair loss preventing shampoo composition |
| US11058624B2 (en) | 2014-02-06 | 2021-07-13 | The Procter And Gamble Company | Hair care composition comprising cationic polymers and anionic particulates |
| US11642353B2 (en) | 2014-02-06 | 2023-05-09 | The Procter & Gamble Company | Hair care composition comprising antidandruff agent and polyquaternium-6 |
| CN104323929A (en) * | 2014-10-31 | 2015-02-04 | 重庆环驰科技有限公司 | Shampoo with controllable viscosity and preparation method thereof |
| CN104323929B (en) * | 2014-10-31 | 2017-08-29 | 重庆环驰科技有限公司 | Controllable shampoo of a kind of viscosity and preparation method thereof |
| US11197810B2 (en) | 2016-03-24 | 2021-12-14 | The Procter And Gamble Company | Hair care compositions comprising malodor reduction compositions |
| US11197809B2 (en) | 2016-03-24 | 2021-12-14 | The Procter And Gamble Company | Hair care compositions comprising malodor reduction compositions |
| CN109689014A (en) * | 2016-09-07 | 2019-04-26 | 荷兰联合利华有限公司 | Antimicrobial personal cleaning compositions |
| US11904036B2 (en) | 2017-10-10 | 2024-02-20 | The Procter & Gamble Company | Sulfate free clear personal cleansing composition comprising low inorganic salt |
| CN107951751A (en) * | 2017-12-20 | 2018-04-24 | 佛山市洛克威特科技有限公司 | A kind of anti-dandruff Chinese medicine rich mixture conditioning shampoo |
| US11679065B2 (en) | 2020-02-27 | 2023-06-20 | The Procter & Gamble Company | Compositions with sulfur having enhanced efficacy and aesthetics |
| CN114042004A (en) * | 2021-11-25 | 2022-02-15 | 中轻日化科技有限公司 | Pearlescent composition for hair washing and caring products and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101112349B (en) | 2011-05-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101112349B (en) | Shampoo composition provided with anti-dandruff and opsonize efficacy | |
| RU2517692C1 (en) | Concentrated liquid detergent composition and method for production thereof | |
| KR20180110121A (en) | Sulfate-free personal hygiene compositions and methods of using such compositions | |
| CN1154467C (en) | Hair conditioner and 2-in-1 conditioning shampoo | |
| CN1037813C (en) | Hair conditioning compositions with silicone conditioning agent containing silicone resin | |
| CN1323190A (en) | Conditioning shampoo compositions | |
| CN102614096A (en) | Conditioner shampoo composite | |
| JP4829536B2 (en) | Betaine-type compound and detergent composition containing the same | |
| JP6095141B2 (en) | Shampoo composition comprising a low viscosity silicone polymer | |
| CN1681475A (en) | Striped liquid personal cleansing compositions containing a cleansing phase and a separate benefit phase | |
| CN101528190B (en) | Shampoo composition | |
| HUT65093A (en) | Shampoo compositions containing anionic surfactant and nonionic silicon conditioning agent | |
| FR2781367A1 (en) | DETERGENT COSMETIC COMPOSITIONS AND USE | |
| CN102552056B (en) | Shampoo composition | |
| KR20180108833A (en) | Personal hygiene compositions and methods of using such compositions | |
| US20150313832A1 (en) | Method of reducing frizz and improving moisturization | |
| CN105263467A (en) | Method of preparing hair conditioning composition comprising polyol | |
| IE41913B1 (en) | Shampoo compositions | |
| CN100335031C (en) | Hair conditioning compositions | |
| FR3060326B1 (en) | COMPOSITION COMPRISING AT LEAST TWO ANIONIC SURFACTANTS, A NON-IONIC SURFACTANT AND AN AMPHOTERIC SURFACTANT, AND AT LEAST ONE ORGANOSILANE | |
| WO2023020299A1 (en) | Stable composition carrying urea or derivative thereof | |
| US20150313823A1 (en) | Cationic pyrithione dispersion | |
| CN104011139B (en) | The purposes of acid in organopolysiloxane preparation process | |
| GB2552566A (en) | Compositions and methods | |
| CN103845231A (en) | Shampoo conditioning composition containing PPG-3 octyl ether |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161010 Address after: Hamburg Germany No. 48 D-20253 Street Una Patentee after: BEIERSDORF AG Address before: The British Virgin Islands, Lalude town overseas business center No. 957 mailbox Patentee before: Shengfeng Group Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110518 Termination date: 20200816 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |