CN101096486B - Temperature-resistant rust anticorrosion paint and preparation method thereof - Google Patents
Temperature-resistant rust anticorrosion paint and preparation method thereof Download PDFInfo
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- CN101096486B CN101096486B CN2006100361490A CN200610036149A CN101096486B CN 101096486 B CN101096486 B CN 101096486B CN 2006100361490 A CN2006100361490 A CN 2006100361490A CN 200610036149 A CN200610036149 A CN 200610036149A CN 101096486 B CN101096486 B CN 101096486B
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- rust
- temperature
- fire resistant
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 239000003973 paint Substances 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 10
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims abstract 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 24
- -1 Poly(tributoxy titanium) Polymers 0.000 claims description 17
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 16
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 16
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 14
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 9
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 claims description 8
- 239000005639 Lauric acid Substances 0.000 claims description 8
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 8
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 8
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 8
- 239000004312 hexamethylene tetramine Substances 0.000 claims description 8
- 229910052725 zinc Inorganic materials 0.000 claims description 8
- 239000011701 zinc Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- KXEOSTAFIDYVEF-UHFFFAOYSA-N [Si](O)(O)(O)O.[F] Chemical compound [Si](O)(O)(O)O.[F] KXEOSTAFIDYVEF-UHFFFAOYSA-N 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 239000010445 mica Substances 0.000 claims description 7
- 229910052618 mica group Inorganic materials 0.000 claims description 7
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 7
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- DGXKDBWJDQHNCI-UHFFFAOYSA-N dioxido(oxo)titanium nickel(2+) Chemical compound [Ni++].[O-][Ti]([O-])=O DGXKDBWJDQHNCI-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 12
- 238000000576 coating method Methods 0.000 abstract description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- 229910052742 iron Inorganic materials 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 229910000831 Steel Inorganic materials 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract description 2
- 230000008878 coupling Effects 0.000 abstract description 2
- 238000010168 coupling process Methods 0.000 abstract description 2
- 238000005859 coupling reaction Methods 0.000 abstract description 2
- 239000000945 filler Substances 0.000 abstract description 2
- 239000003292 glue Substances 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 abstract description 2
- 239000011347 resin Substances 0.000 abstract description 2
- 239000010959 steel Substances 0.000 abstract description 2
- 230000009970 fire resistant effect Effects 0.000 abstract 5
- 239000002671 adjuvant Substances 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 230000000415 inactivating effect Effects 0.000 abstract 1
- 238000010422 painting Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to a fire resistant and anticorrosive coating paint with rust and the preparing method, which solves the technique problem how to provide a 300Deg. C fire resistant and anticorrosive coating paint with rust and the preparing method. The invention generates the modified polysilicate with fluosilicic acid and ethyl orthosilicate, which disperses color, filler and adjuvant in the glue solution of the composite binding material with the newest coupling dispersing technique, mixing the phosphoric acid solution; forming the active coating material system which removes the rust of the steel and iron. The paint can react with the iron rust and forms the fast and inactivating coating, which forms fire resistant, anti-rust and anticorrosive coating owing to the inorganic resin as the main film substance. The fire resistant and anticorrosive coating paint is provided with the advantages of anti-rust and fire resistant, which doesn't need to derust when painting the metal surface.
Description
Technical field
The present invention relates to a kind of temperature-resistant rust anticorrosion paint and preparation method thereof.
Background technology
Also be not with the rust high-temperature resistant coating on the existing market.
Summary of the invention
The technical problem to be solved in the present invention is how to fill up the above-mentioned blank of prior art, provides a kind of and can bear high temperature more than 300 ℃, and have temperature-resistant rust anticorrosion paint of antirust, anti-corrosion function and preparation method thereof.
For solving the problems of the technologies described above, temperature-resistant rust anticorrosion paint of the present invention is made by the raw material of following weight ratio:
Weight percent is 10% polyvinyl butyral acetal ethanolic soln: 5～25 parts;
Dioxide-containing silica accounts for 28% tetraethyl silicate: 10～50 parts;
Weight percent is 35% fluorine silicic acid aqueous solution: 3～18 parts;
Mica powder or silica powder or its mixture: 0.5～6 part;
Shrink sorbyl alcohol lauric acid monoesters: 0.3～5 part;
Hexamethylenetetramine: 0.3～8 part;
Poly(tributoxy titanium): 0.3～3 part;
Four alkali zinc yellows: 3～10 parts;
Phosphite: 0.5～8 part;
Deionized water: 3～6 parts
Nickel titanate: 5～10 parts;
Thiocarbamide: 0.3～3 part;
Phosphoric acid: 2～8 parts;
Alcohol: 3～8 parts
Except that having indicated, the purity of other raw materials should meet the requirement of industrial first grade in the above-mentioned raw materials.
The preparation method of above-mentioned temperature-resistant rust anticorrosion paint is as follows:
1) gets 10～50 parts of heavy dioxide-containing silicas and account for 28% tetraethyl silicate and drop in the reactor, stir, slowly drop into 3～18 parts heavy 35% fluorine silicic acid aqueous solution, under 25～80 ℃ of temperature, reacted 1～5 hour, form inorganic filming substance matter A;
2) mica powder, the silica powder of getting 5～25 parts of heavy weight percents, 10% polyvinyl butyral acetal ethanolic soln, 0.5～8 part of heavy phosphite, 0.3～3 part of heavy poly(tributoxy titanium), 0.3～5 part heavy shrink sorbyl alcohol lauric acid monoesters, 0.3～8 part of heavy hexamethylenetetramine, 0.3～3 part of heavy thiocarbamide, 5～10 parts of heavy nickel titanates, 3～10 parts heavy four alkali zinc yellows, 0.5～6 part of weight drops into grinding dispersion in the shredder, forms mixed pulp B.
3) get the deionized water of 2～8 parts of heavy phosphoric acid, 3～6 parts of weights, the alcohol of 3～8 parts of weights mixes, component C;
4) getting A, B, C respectively mixes to stir evenly and gets final product;
The invention use silicofluoric acid and tetraethyl silicate reaction generate the modified polysilicate ester, use the up-to-date advanced coupling technology that disperses, pigment, filler, auxiliary agent, fully be distributed in the glue of compoiste adhering material, mix with phosphoric acid solution again, form the vanish system of the floating rust of active removal steel surface.This coating can react with iron rust, forms filming of firm passivation, owing to being main film forming substance with the inorganic resin, and the last thermostable rustproof corrosion protection coating that forms of filming.
Phosphoric acid mainly works the effect of derusting in the prescription in prescription, and phosphorous acid ester, hexamethylenetetramine, thiocarbamide play inhibition, passivation to metal; Four alkali zinc yellows play the protection metal and avoid preservative activity; Poly(tributoxy titanium) is a coupling agent; Shrink sorbyl alcohol lauric acid monoesters has the froth breaking effect, and zinc powder, nickel titanate have high temperature resistant, preservative activity simultaneously, and polyvinyl acetal liquid plays auxiliary filming function.
Temperature-resistant rust anticorrosion paint of the present invention has antirust, resistant to elevated temperatures advantage.When using its paint metals surface, needn't make processing of rust removing to general floating rust in advance.
Embodiment
Below temperature-resistant rust anticorrosion paint of the present invention and preparation method thereof is described further:
Embodiment one: the preparation method of temperature-resistant rust anticorrosion paint of the present invention is as follows:
1) dioxide-containing silica of getting 10 kiloponds accounts for 28% tetraethyl silicate and drops in the reactor, stirs, and slowly drops into 35% fluorine silicic acid aqueous solution of 3 kiloponds, reacts 1～5 hour under 25～80 ℃ of temperature, forms inorganic filming substance matter A;
2) weight percent 10% polyvinyl butyral acetal ethanolic soln, the phosphite of 0.5 kilopond, the poly(tributoxy titanium) of 0.3 kilopond, the shrink sorbyl alcohol lauric acid monoesters of 0.3 kilopond, the hexamethylenetetramine of 0.3 kilopond, the thiocarbamide of 0.3 kilopond, the nickel titanate of 5 kiloponds, four alkali zinc yellows of 3 kiloponds, the mica powder of 0.5 kilopond, the silica powder of getting 5 kiloponds drops into to grind in the shredder and disperses, and forms mixed pulp B.
3) get the phosphoric acid of 2 kiloponds, the deionized water of 3 kiloponds, the alcohol of 3 kiloponds mixes, and gets component C;
4) getting A, B, C respectively mixes to stir evenly and gets final product;
Embodiment two: temperature-resistant rust anticorrosion paint of the present invention, the preparation method is as described in the enforcement mode one, and the consumption of each raw material is as follows in the prescription:
Weight percent is 10% polyvinyl butyral acetal ethanolic soln: 25 kilograms;
Dioxide-containing silica accounts for 28% tetraethyl silicate: 50 kilograms;
Weight percent is 35% fluorine silicic acid aqueous solution: 8 kilograms;
Mica powder or silica powder or its mixture: 6 kilograms;
Shrink sorbyl alcohol lauric acid monoesters: 5 kilograms;
Hexamethylenetetramine: 8 kilograms;
Poly(tributoxy titanium): 3 kilograms;
Four alkali zinc yellows: 10 kilograms;
Phosphite: 8 kilograms;
Deionized water: 6 kilograms;
Nickel titanate: 10 kilograms;
Thiocarbamide: 3 kilograms;
Phosphoric acid: 8 kilograms;
Alcohol: 8 kilograms
Embodiment three: temperature-resistant rust anticorrosion paint of the present invention, the preparation method is as described in the enforcement mode one, and the consumption of each raw material is as follows in the prescription:
Weight percent is 10% polyvinyl butyral acetal ethanolic soln: 15 kilograms;
Dioxide-containing silica accounts for 28% tetraethyl silicate: 30 kilograms;
Weight percent is 35% fluorine silicic acid aqueous solution: 10.5 kilograms;
Mica powder or silica powder or its mixture: 3.25 kilograms;
Shrink sorbyl alcohol lauric acid monoesters: 2.65 kilograms;
Hexamethylenetetramine: 4.15 kilograms;
Poly(tributoxy titanium): 1.65 kilograms;
Four alkali zinc yellows: 6.5 kilograms;
Phosphite: 4.25 kilograms;
Deionized water: 4.5 kilograms
Nickel titanate: 7.5 kilograms;
Thiocarbamide: 1.65 kilograms;
Phosphoric acid: 5 kilograms;
Alcohol: 5.5 kilograms.
Except that the raw material of having indicated, the purity of other raw materials should meet the requirement of industrial first grade in the above-mentioned embodiment.Certainly, mix different pigment, this coating can be made into multiple color.
Control experiment one: get two hardwares, brush traditional primer for rusty surface and this temperature-resistant rust anticorrosion paint respectively, put into baking oven for heating to 300 ℃, and be incubated 5 minutes.As a result, the former enamelled coating generation oxidation, variable color, local shedding; The latter does not have considerable change.
Control experiment two: get two hardwares, brush traditional primer for rusty surface and this temperature-resistant rust anticorrosion paint respectively, imbed in the moist earth, through after six months, take out respectively, scrape coating off, the former has obvious rusty stain, and the latter does not have considerable change.
Claims (2)
1. temperature-resistant rust anticorrosion paint is made by the raw material of following weight ratio:
Weight percent is 10% polyvinyl butyral acetal ethanolic soln: 5～25 parts;
Dioxide-containing silica accounts for 28% tetraethyl silicate: 10～50 parts;
Weight percent is 35% fluorine silicic acid aqueous solution: 3～18 parts;
Mica powder or silica powder or its mixture: 0.5～6 part;
Shrink sorbyl alcohol lauric acid monoesters: 0.3～5 part;
Hexamethylenetetramine: 0.3～8 part;
Poly(tributoxy titanium): 0.3～3 part;
Four alkali zinc yellows: 3～10 parts;
Phosphite: 0.5～8 part;
Deionized water: 3～6 parts
Nickel titanate: 5～10 parts;
Thiocarbamide: 0.3～3 part;
Phosphoric acid: 2～8 parts;
Alcohol: 3～8 parts
Except that having indicated, the purity of other raw materials should meet the requirement of industrial first grade in the above-mentioned raw materials.
2. a method for preparing the described temperature-resistant rust anticorrosion paint of claim 1 comprises the steps:
1) gets 10～50 parts of heavy dioxide-containing silicas and account for 28% tetraethyl silicate and drop in the reactor, stir, slowly drop into 3～18 parts heavy 35% fluorine silicic acid aqueous solution, under 25～80 ℃ of temperature, reacted 1～5 hour, form inorganic filming substance matter A;
2) mica powder, the silica powder of getting 5～25 parts of heavy weight percents, 10% polyvinyl butyral acetal ethanolic soln, 0.5～8 part of heavy phosphite, 0.3～3 part of heavy poly(tributoxy titanium), 0.3～5 part heavy shrink sorbyl alcohol lauric acid monoesters, 0.3～8 part of heavy hexamethylenetetramine, 0.3～3 part of heavy thiocarbamide, 5～10 parts of heavy nickel titanates, 3～10 parts heavy four alkali zinc yellows, 0.5～6 part of weight drops into grinding dispersion in the shredder, forms mixed pulp B;
3) get the deionized water of 2～8 parts of heavy phosphoric acid, 3～6 parts of weights, the alcohol of 3～8 parts of weights mixes, component C;
4) getting A, B, C respectively mixes to stir evenly and gets final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100361490A CN101096486B (en) | 2006-06-29 | 2006-06-29 | Temperature-resistant rust anticorrosion paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100361490A CN101096486B (en) | 2006-06-29 | 2006-06-29 | Temperature-resistant rust anticorrosion paint and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101096486A CN101096486A (en) | 2008-01-02 |
| CN101096486B true CN101096486B (en) | 2010-06-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006100361490A Expired - Fee Related CN101096486B (en) | 2006-06-29 | 2006-06-29 | Temperature-resistant rust anticorrosion paint and preparation method thereof |
Country Status (1)
| Country | Link |
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Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101586016B (en) * | 2008-05-23 | 2012-12-19 | 彭文表 | High-temperature adhesive and high temperature energy-saving compound material therewith |
| CN101993620B (en) * | 2009-08-13 | 2012-06-27 | 长沙固特瑞新材料科技有限公司 | Preparation method of aqueous rusty convertible anticorrosive paint |
| CN101824254B (en) * | 2010-05-10 | 2012-08-22 | 江苏科技大学 | Organosilicon-modified polyvinyl butyral coil coating |
| CN102181210A (en) * | 2011-05-27 | 2011-09-14 | 广东德康化工实业有限公司 | Preparation method of inorganic workshop primer |
| CN102153931B (en) * | 2011-05-27 | 2013-04-10 | 广东德康化工实业有限公司 | Anti-scratch abrasion-resistant paint |
| CN104830171B (en) * | 2015-05-15 | 2017-07-28 | 上海海悦涂料有限公司 | A kind of color method of preapring for an unfavorable turn of events of inorganic high-temperature resistant paint and wheel funnel |
| CN105062251A (en) * | 2015-08-19 | 2015-11-18 | 赵栋 | High-temperature-resistant, anti-rust and anti-corrosive paint |
| CN108034354B (en) * | 2017-12-14 | 2020-04-28 | 石家庄市油漆厂 | Nano ceramic coating for resisting high temperature of 800 ℃ and preparation process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1116223A (en) * | 1994-07-30 | 1996-02-07 | 廖龙 | Paint with rust preventive and removing function |
| CN1228800A (en) * | 1996-07-30 | 1999-09-15 | 精细金属粉末股份有限公司 | Anti-corrosion composition and method for producing its base (binder) |
| CN1472266A (en) * | 2002-08-02 | 2004-02-04 | 上海佳加室内装潢工程有限公司 | Polyvinyl acetal acid-and alkali-resistant and washing resistant paint |
-
2006
- 2006-06-29 CN CN2006100361490A patent/CN101096486B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1116223A (en) * | 1994-07-30 | 1996-02-07 | 廖龙 | Paint with rust preventive and removing function |
| CN1228800A (en) * | 1996-07-30 | 1999-09-15 | 精细金属粉末股份有限公司 | Anti-corrosion composition and method for producing its base (binder) |
| CN1472266A (en) * | 2002-08-02 | 2004-02-04 | 上海佳加室内装潢工程有限公司 | Polyvinyl acetal acid-and alkali-resistant and washing resistant paint |
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| CN101096486A (en) | 2008-01-02 |
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| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Guangdong Dekang Chemistry Industry Co., Ltd. Assignor: Peng Wenbiao Contract record no.: 2011440000690 Denomination of invention: Temperature-resistant rust anticorrosion paint and preparation method thereof Granted publication date: 20100609 License type: Exclusive License Open date: 20080102 Record date: 20110719 |
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| TR01 | Transfer of patent right |
Effective date of registration: 20170816 Address after: Hetang District of Pengjiang Tang Xi Xi Fang Hongmiao south two road 529095 Guangdong city of Jiangmen province No. 2 Patentee after: Jiangmen Apple Chemical Co., Ltd. Address before: 529331 Guangdong Province, Kaiping City Industrial Park Guangdong Yueshan Dekang Chemical Industry Co. Ltd. Patentee before: Peng Wenbiao |
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Granted publication date: 20100609 Termination date: 20180629 |
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