CN102153931B - Anti-scratch abrasion-resistant paint - Google Patents
Anti-scratch abrasion-resistant paint Download PDFInfo
- Publication number
- CN102153931B CN102153931B CN 201110140056 CN201110140056A CN102153931B CN 102153931 B CN102153931 B CN 102153931B CN 201110140056 CN201110140056 CN 201110140056 CN 201110140056 A CN201110140056 A CN 201110140056A CN 102153931 B CN102153931 B CN 102153931B
- Authority
- CN
- China
- Prior art keywords
- component
- resistant paint
- scratch abrasion
- fluorinated alkyl
- scratch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000005299 abrasion Methods 0.000 title claims abstract description 20
- 239000003973 paint Substances 0.000 title claims abstract description 20
- -1 fluorinated alkyl silicate ester Chemical class 0.000 claims abstract description 29
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 13
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 13
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 13
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 claims abstract description 13
- 229920002545 silicone oil Polymers 0.000 claims abstract description 13
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical group NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 19
- 239000010703 silicon Substances 0.000 claims description 19
- 239000004593 Epoxy Substances 0.000 claims description 12
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 12
- 239000004698 Polyethylene Substances 0.000 claims description 12
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 12
- 229920000573 polyethylene Polymers 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 9
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 7
- 239000012895 dilution Substances 0.000 claims description 6
- 238000010790 dilution Methods 0.000 claims description 6
- 239000012046 mixed solvent Substances 0.000 claims description 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 4
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- 239000004576 sand Substances 0.000 claims description 4
- 239000002002 slurry Substances 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 abstract description 5
- 239000004809 Teflon Substances 0.000 abstract 1
- 229920006362 Teflon® Polymers 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- 239000001993 wax Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- WYMSBXTXOHUIGT-UHFFFAOYSA-N paraoxon Chemical compound CCOP(=O)(OCC)OC1=CC=C([N+]([O-])=O)C=C1 WYMSBXTXOHUIGT-UHFFFAOYSA-N 0.000 description 2
- 150000001349 alkyl fluorides Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
An anti-scratch abrasion-resistant paint comprises a component A and a component B separated packaged. The component A is formulated from the following materials by weight percentage: 55% of silicone acrylic resin and fluorinated alkyl silicate ester, 60% of epoxy resin, erucyl amide, ployethylene wax, Teflon, silane coupling agents and YCK-5010, and 10% of silicone oil. The component B is biuret. The paint has the characteristic of scratch and abrasion resistance and a good film forming property.
Description
Technical field
The present invention relates to a kind of Anti-scratch abrasion-resistant paint and preparation method thereof.
Background technology
Prior art there is not yet inorganic modified organic Anti-scratch abrasion-resistant paint in the market at present.
Summary of the invention
It is high that the problem to be solved in the present invention provides a kind of intensity hardness, and Anti-scratch abrasion-resistant paint.
The present invention is achieved in that a kind of Anti-scratch abrasion-resistant paint, comprises respectively A component and the B component of packing, and the A component is made by following weight per-cent:
55% organosilicon acrylic resin 10%-60% fluorinated alkyl silicon ester 3-25%
60% Resins, epoxy 10%-60% erucicamide 0.5%-8%
Polyethylene wax 0.1%-5% tetrafluoroethylene 0-5%
Silane coupling agent 0.1%-5% YCK-5010 0.1%-2%
10% silicone oil 0.1%-2%
The B component is biuret.
Above-mentioned materials is except indicating, other material purity should meet industrial first grade requirement
Described a kind of Anti-scratch abrasion-resistant paint, its special character is: the preparation of described fluorinated alkyl silicon ester, comprising the steps: to get 10-60 part 28% tetraethyl silicate drops in the reactor, stir and slowly drop into 35% silicate fluoride solution of 2-25 part, 25-80 ℃ of range temperature internal reaction 1-5 hour, form the fluorinated alkyl silicon ester.
Described a kind of Anti-scratch abrasion-resistant paint, its special character is: the preparation of described A component comprises the steps:
(1) is dropped in the still, begin to stir, then slowly drop into (4), (5), (6) respectively in the still, stir and formed the Uniform Dispersion slurry in 1-2 hour, then in (2), (3), (7), (8), (9), the input still, stirred 0.5-1 hour, again through the sand mill grinding distribution to fineness 10 μ m, make the A component.
Described a kind of Anti-scratch abrasion-resistant paint, its special character is: A component in use: B component volume 2:0.5-1.
Described a kind of Anti-scratch abrasion-resistant paint, its special character is: in use, use N-BUTYL ACETATE: the mixed solvent dilution of dimethylbenzene=8:2 is used.
The present invention
A kind of Anti-scratch abrasion-resistant paint has anti-zoned wear-resisting characteristic, and good film-forming property.
Embodiment
Embodiment 1
A kind of Anti-scratch abrasion-resistant paint comprises respectively A component and the B component of packing, and the A component is made by following weight per-cent:
55% organosilicon acrylic resin, 60% fluorinated alkyl silicon ester 10%
60% Resins, epoxy, 25% erucicamide 4.6%
Polyethylene wax 0.1% silane coupling agent 0.1%
YCK-5010 0.1% 10% silicone oil 0.1%
The B component is biuret.
Above-mentioned materials is except indicating, other material purity should meet industrial first grade requirement
The preparation of described fluorinated alkyl silicon ester comprises the steps: to get 10 part of 28% tetraethyl silicate and drops in the reactor, stirs and slowly drops into 2 parts 35% silicate fluoride solution, 25-80 ℃ of range temperature internal reaction 1-5 hour, forms the alkyl fluoride silicon ester.
The preparation of described A component comprises the steps:
55% organosilicon acrylic resin is dropped in the still, begin to stir, then slowly drop into erucicamide, polyethylene wax respectively in the still, stir and formed the Uniform Dispersion slurry in 1-2 hour, then fluorinated alkyl estersil ester, Resins, epoxy, silane coupling agent, BYK-3011, silicone oil (1%) are dropped in the still, stirred 0.5-1 hour, again through the sand mill grinding distribution to fineness 10 μ m, make the A component.
A component in use: B component volume 2:0.5.
In use, use N-BUTYL ACETATE: the mixed solvent dilution of dimethylbenzene=8:2 is used.
Described YCK-5010 is produced by YCK company, and chemistry polymer silicon by name changes propylene liquid, the anti-zoned and smooth effect of tool.
Embodiment 2
The A component is made by following weight per-cent:
55% organosilicon acrylic resin, 32% fluorinated alkyl silicon ester 3%
60% Resins, epoxy, 60% erucicamide 4.6%
Polyethylene wax 0.1% silane coupling agent 0.1%
YCK-5010 0.1% 10% silicone oil 0.1%
The B component is biuret.
The preparation of described fluorinated alkyl silicon ester comprises the steps: to get 10 part of 28% tetraethyl silicate and drops in the reactor, stirs and slowly drops into 25 parts 35% silicate fluoride solution, 25-80 ℃ of range temperature internal reaction 1-5 hour, forms the fluorinated alkyl silicon ester.
A component in use: B component volume 2:1.
In use, use N-BUTYL ACETATE: the mixed solvent dilution of dimethylbenzene=8:2 is used.
Embodiment 3
The A component is made by following weight per-cent:
55% organosilicon acrylic resin, 23% fluorinated alkyl estersil ester 25%
60% Resins, epoxy, 30% erucicamide 8%
Polyethylene wax 5% silane coupling agent 5%
BYK-3011 2% silicone oil (1%) 2%
Embodiment 4
The A component is made by following weight per-cent:
55% organosilicon acrylic resin, 46% fluorinated alkyl silicon ester 15%
60% Resins, epoxy, 30% erucicamide 0.5%
Polyethylene wax 3% silane coupling agent 3.5%
BYK-3011 1% 10% silicone oil 1%
Embodiment 5
A kind of Anti-scratch abrasion-resistant paint comprises respectively A component and the B component of packing, and the A component is made by following weight per-cent:
55% organosilicon acrylic resin, 60% fluorinated alkyl silicon ester 5%
60% Resins, epoxy, 30% erucicamide 3.6%
Polyethylene wax 0.1% tetrafluoroethylene 1%
Silane coupling agent 0.1% YCK-5010 0.1%
10% silicone oil 0.1%
The B component is biuret.
The preparation of described A component comprises the steps:
55% organosilicon acrylic resin is dropped in the still, begin to stir, then slowly drop into erucicamide, polyethylene wax and tetrafluoroethylene respectively in the still, stir and formed the Uniform Dispersion slurry in 1-2 hour, then fluorinated alkyl silicon ester, Resins, epoxy, silane coupling agent, YCK-5010,10% silicone oil are dropped in the still, stirred 0.5-1 hour, again through the sand mill grinding distribution to fineness 10 μ m, make the A component.
A component in use: B component volume 2:0.5.
In use, use N-BUTYL ACETATE: the mixed solvent dilution of dimethylbenzene=8:2 is used.
Embodiment 6
The A component is made by following weight per-cent:
55% organosilicon acrylic resin, 10% fluorinated alkyl silicon ester 25%
60% Resins, epoxy, 60% erucicamide 3.6%
Polyethylene wax 0.1% tetrafluoroethylene 1%
Silane coupling agent 0.1% YCK-5010 0.1%
10% silicone oil 0.1%
The B component is biuret.
A component in use: B component volume 2:1.
In use, use N-BUTYL ACETATE: the mixed solvent dilution of dimethylbenzene=8:2 is used.
Embodiment 7
The A component is made by following weight per-cent:
55% organosilicon acrylic resin, 25% fluorinated alkyl silicon ester 3%
60% Resins, epoxy, 45% erucicamide 8%
Polyethylene wax 5% tetrafluoroethylene 5%
Silane coupling agent 5% YCK-5010 2%
10% silicone oil 2%
Embodiment 8
The A component is made by following weight per-cent:
55% organosilicon acrylic resin, 50% fluorinated alkyl silicon ester 8%
60% Resins, epoxy, 30% erucicamide 0.5%
Polyethylene wax 3% tetrafluoroethylene 3%
Silane coupling agent 3.5% YCK-5010 1%
10% silicone oil 1%
Above-described only is preferential embodiment of the present invention.Should be pointed out that for the person of ordinary skill of the art in the situation that does not break away from the principle of the invention, can also make some improvement and modification, this also is considered as protection scope of the present invention.
Claims (5)
1. an Anti-scratch abrasion-resistant paint comprises respectively A component and the B component of packing, and the A component is made by following weight per-cent:
(1) 55% organosilicon acrylic resin 10%-60%
(2) fluorinated alkyl silicon ester 3-25%
(3) 60% Resins, epoxy 10%-60%
(4) erucicamide 0.5%-8%
(5) polyethylene wax 0.1%-5%
(6) tetrafluoroethylene 0-5%
(7) silane coupling agent 0.1%-5%
（8）YCK-5010 0.1%-2%
(9) 10% silicone oil 0.1%-2%
The B component is biuret.
2. a kind of Anti-scratch abrasion-resistant paint according to claim 1, it is characterized in that: the preparation of described fluorinated alkyl silicon ester, comprising the steps: to get 10-60 part 28% tetraethyl silicate drops in the reactor, stir and slowly drop into 35% silicate fluoride solution of 2-25 part, 25-80 ℃ of range temperature internal reaction 1-5 hour, form the fluorinated alkyl silicon ester.
3. a kind of Anti-scratch abrasion-resistant paint according to claim 1, it is characterized in that: the preparation of described A component comprises the steps:
(1) is dropped in the still, begin to stir, then slowly drop into (4), (5), (6) respectively in the still, stir and formed the Uniform Dispersion slurry in 1-2 hour, then in (2), (3), (7), (8), (9), the input still, stirred 0.5-1 hour, again through the sand mill grinding distribution to fineness 10 μ m, make the A component.
4. a kind of Anti-scratch abrasion-resistant paint according to claim 1 is characterized in that: A component: B component=2:0.5-1 in use.
5. a kind of Anti-scratch abrasion-resistant paint according to claim 1 is characterized in that: in use, use N-BUTYL ACETATE: the mixed solvent dilution use of dimethylbenzene=8:2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110140056 CN102153931B (en) | 2011-05-27 | 2011-05-27 | Anti-scratch abrasion-resistant paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110140056 CN102153931B (en) | 2011-05-27 | 2011-05-27 | Anti-scratch abrasion-resistant paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102153931A CN102153931A (en) | 2011-08-17 |
| CN102153931B true CN102153931B (en) | 2013-04-10 |
Family
ID=44435620
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110140056 Expired - Fee Related CN102153931B (en) | 2011-05-27 | 2011-05-27 | Anti-scratch abrasion-resistant paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102153931B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103305109B (en) * | 2013-06-04 | 2015-12-23 | 彭文表 | A kind of PU wear-resistant paint |
| CN108329792A (en) * | 2017-10-25 | 2018-07-27 | 江苏广盛源科技发展有限公司 | A kind of wear-resistant paint |
| CN107629631A (en) * | 2017-10-25 | 2018-01-26 | 江苏广盛源科技发展有限公司 | A kind of wear-resistant aluminum alloy section bar steel ring material |
| CN108587275A (en) * | 2018-04-23 | 2018-09-28 | 苏州聚康新材料科技有限公司 | A kind of preparation method of low temperature resistant wear-resistant paint |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1556162A (en) * | 2004-01-09 | 2004-12-22 | 南京工业大学 | nano transparent wear-resistant composite coating |
| CN101096486A (en) * | 2006-06-29 | 2008-01-02 | 彭文表 | Temperature-resistant rust anticorrosion paint and preparation method thereof |
| EP2216311A1 (en) * | 2009-01-30 | 2010-08-11 | Silicalia S.L. | Reinforced natural or conglomerated stone plate-like element and multilayered protective coating thereof |
| CN101845257A (en) * | 2010-05-28 | 2010-09-29 | 彭文表 | Graffiti-resistant paint and use method thereof |
| CN101899253A (en) * | 2010-07-09 | 2010-12-01 | 孟鋆辉 | Wear-resistant and high temperature-resistant powder coating for preventing corrosion of inside and outside of steel pipeline |
-
2011
- 2011-05-27 CN CN 201110140056 patent/CN102153931B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1556162A (en) * | 2004-01-09 | 2004-12-22 | 南京工业大学 | nano transparent wear-resistant composite coating |
| CN101096486A (en) * | 2006-06-29 | 2008-01-02 | 彭文表 | Temperature-resistant rust anticorrosion paint and preparation method thereof |
| EP2216311A1 (en) * | 2009-01-30 | 2010-08-11 | Silicalia S.L. | Reinforced natural or conglomerated stone plate-like element and multilayered protective coating thereof |
| CN101845257A (en) * | 2010-05-28 | 2010-09-29 | 彭文表 | Graffiti-resistant paint and use method thereof |
| CN101899253A (en) * | 2010-07-09 | 2010-12-01 | 孟鋆辉 | Wear-resistant and high temperature-resistant powder coating for preventing corrosion of inside and outside of steel pipeline |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102153931A (en) | 2011-08-17 |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130410 |