CN101076246A - 含磷酸酯的农业化学组合物 - Google Patents
含磷酸酯的农业化学组合物 Download PDFInfo
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- CN101076246A CN101076246A CNA2005800327563A CN200580032756A CN101076246A CN 101076246 A CN101076246 A CN 101076246A CN A2005800327563 A CNA2005800327563 A CN A2005800327563A CN 200580032756 A CN200580032756 A CN 200580032756A CN 101076246 A CN101076246 A CN 101076246A
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- alkyl
- acid
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- 239000012872 agrochemical composition Substances 0.000 title description 5
- 150000003014 phosphoric acid esters Chemical class 0.000 title 1
- 239000000203 mixture Substances 0.000 claims description 58
- -1 alkyl phosphate Chemical compound 0.000 claims description 56
- 239000000463 material Substances 0.000 claims description 38
- 125000000217 alkyl group Chemical group 0.000 claims description 23
- 150000001875 compounds Chemical class 0.000 claims description 20
- 239000004009 herbicide Substances 0.000 claims description 18
- 229910019142 PO4 Inorganic materials 0.000 claims description 16
- 235000021317 phosphate Nutrition 0.000 claims description 16
- 239000010452 phosphate Substances 0.000 claims description 16
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 15
- 150000002148 esters Chemical class 0.000 claims description 14
- 239000003905 agrochemical Substances 0.000 claims description 13
- 244000025254 Cannabis sativa Species 0.000 claims description 12
- 241000196324 Embryophyta Species 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 150000005690 diesters Chemical class 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 150000001345 alkine derivatives Chemical class 0.000 claims description 10
- 230000002363 herbicidal effect Effects 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- 239000003375 plant hormone Substances 0.000 claims description 8
- BACHBFVBHLGWSL-JTQLQIEISA-N rac-diclofop methyl Natural products C1=CC(O[C@@H](C)C(=O)OC)=CC=C1OC1=CC=C(Cl)C=C1Cl BACHBFVBHLGWSL-JTQLQIEISA-N 0.000 claims description 8
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 claims description 8
- PVSGXWMWNRGTKE-UHFFFAOYSA-N 5-methyl-2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]pyridine-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC=C(C)C=C1C(O)=O PVSGXWMWNRGTKE-UHFFFAOYSA-N 0.000 claims description 7
- QRSHQJLLXXEYPS-UHFFFAOYSA-N azane;5-ethyl-2-(4-methyl-5-oxo-4-propan-2-yl-1h-imidazol-2-yl)pyridine-3-carboxylic acid Chemical compound [NH4+].[O-]C(=O)C1=CC(CC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 QRSHQJLLXXEYPS-UHFFFAOYSA-N 0.000 claims description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- INGIWRVQMCUAKP-UHFFFAOYSA-N (2-butan-2-ylphenyl) dihydrogen phosphate Chemical class CCC(C)C1=CC=CC=C1OP(=O)(O)O INGIWRVQMCUAKP-UHFFFAOYSA-N 0.000 claims description 5
- BZZRUHJGDOBTJL-UHFFFAOYSA-N 11-methyldodecan-1-ol;phosphoric acid Chemical compound OP(O)(O)=O.CC(C)CCCCCCCCCCO BZZRUHJGDOBTJL-UHFFFAOYSA-N 0.000 claims description 5
- 229920006395 saturated elastomer Polymers 0.000 claims description 5
- YUVKUEAFAVKILW-UHFFFAOYSA-N 2-(4-{[5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoic acid Chemical compound C1=CC(OC(C)C(O)=O)=CC=C1OC1=CC=C(C(F)(F)F)C=N1 YUVKUEAFAVKILW-UHFFFAOYSA-N 0.000 claims description 4
- CTSLUCNDVMMDHG-UHFFFAOYSA-N 5-bromo-3-(butan-2-yl)-6-methylpyrimidine-2,4(1H,3H)-dione Chemical compound CCC(C)N1C(=O)NC(C)=C(Br)C1=O CTSLUCNDVMMDHG-UHFFFAOYSA-N 0.000 claims description 4
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims description 4
- RXCPQSJAVKGONC-UHFFFAOYSA-N Flumetsulam Chemical compound N1=C2N=C(C)C=CN2N=C1S(=O)(=O)NC1=C(F)C=CC=C1F RXCPQSJAVKGONC-UHFFFAOYSA-N 0.000 claims description 4
- IRECWLYBCAZIJM-UHFFFAOYSA-N Flumiclorac pentyl Chemical group C1=C(Cl)C(OCC(=O)OCCCCC)=CC(N2C(C3=C(CCCC3)C2=O)=O)=C1F IRECWLYBCAZIJM-UHFFFAOYSA-N 0.000 claims description 4
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 4
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 claims description 4
- HFBWPRKWDIRYNX-UHFFFAOYSA-N Trietazine Chemical compound CCNC1=NC(Cl)=NC(N(CC)CC)=N1 HFBWPRKWDIRYNX-UHFFFAOYSA-N 0.000 claims description 4
- XCSGPAVHZFQHGE-UHFFFAOYSA-N alachlor Chemical compound CCC1=CC=CC(CC)=C1N(COC)C(=O)CCl XCSGPAVHZFQHGE-UHFFFAOYSA-N 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- JXCGFZXSOMJFOA-UHFFFAOYSA-N chlorotoluron Chemical compound CN(C)C(=O)NC1=CC=C(C)C(Cl)=C1 JXCGFZXSOMJFOA-UHFFFAOYSA-N 0.000 claims description 4
- MZZBPDKVEFVLFF-UHFFFAOYSA-N cyanazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)(C)C#N)=N1 MZZBPDKVEFVLFF-UHFFFAOYSA-N 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 230000000855 fungicidal effect Effects 0.000 claims description 4
- 239000000417 fungicide Substances 0.000 claims description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 4
- 239000002917 insecticide Substances 0.000 claims description 4
- NRXQIUSYPAHGNM-UHFFFAOYSA-N ioxynil Chemical compound OC1=C(I)C=C(C#N)C=C1I NRXQIUSYPAHGNM-UHFFFAOYSA-N 0.000 claims description 4
- QYPPRTNMGCREIM-UHFFFAOYSA-N methylarsonic acid Chemical compound C[As](O)(O)=O QYPPRTNMGCREIM-UHFFFAOYSA-N 0.000 claims description 4
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- AAEVYOVXGOFMJO-UHFFFAOYSA-N prometryn Chemical compound CSC1=NC(NC(C)C)=NC(NC(C)C)=N1 AAEVYOVXGOFMJO-UHFFFAOYSA-N 0.000 claims description 4
- XVOKUMIPKHGGTN-UHFFFAOYSA-N Imazethapyr Chemical compound OC(=O)C1=CC(CC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 XVOKUMIPKHGGTN-UHFFFAOYSA-N 0.000 claims description 3
- 239000000642 acaricide Substances 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 3
- 230000000844 anti-bacterial effect Effects 0.000 claims description 3
- 239000003899 bactericide agent Substances 0.000 claims description 3
- GINJFDRNADDBIN-FXQIFTODSA-N bilanafos Chemical compound OC(=O)[C@H](C)NC(=O)[C@H](C)NC(=O)[C@@H](N)CCP(C)(O)=O GINJFDRNADDBIN-FXQIFTODSA-N 0.000 claims description 3
- 239000012141 concentrate Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 230000001069 nematicidal effect Effects 0.000 claims description 3
- 239000005645 nematicide Substances 0.000 claims description 3
- 230000008635 plant growth Effects 0.000 claims description 3
- 239000002574 poison Substances 0.000 claims description 3
- 231100000614 poison Toxicity 0.000 claims description 3
- 235000019260 propionic acid Nutrition 0.000 claims description 3
- 239000003128 rodenticide Substances 0.000 claims description 3
- GXEKYRXVRROBEV-FBXFSONDSA-N (1r,2s,3r,4s)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid Chemical compound C1C[C@@H]2[C@@H](C(O)=O)[C@@H](C(=O)O)[C@H]1O2 GXEKYRXVRROBEV-FBXFSONDSA-N 0.000 claims description 2
- IPPAUTOBDWNELX-UHFFFAOYSA-N (2-ethoxy-2-oxoethyl) 5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoate Chemical group C1=C([N+]([O-])=O)C(C(=O)OCC(=O)OCC)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 IPPAUTOBDWNELX-UHFFFAOYSA-N 0.000 claims description 2
- BXKKQFGRMSOANI-UHFFFAOYSA-N 1-methoxy-3-[4-[(2-methoxy-2,4,4-trimethyl-3h-chromen-7-yl)oxy]phenyl]-1-methylurea Chemical compound C1=CC(NC(=O)N(C)OC)=CC=C1OC1=CC=C2C(C)(C)CC(C)(OC)OC2=C1 BXKKQFGRMSOANI-UHFFFAOYSA-N 0.000 claims description 2
- XZIDTOHMJBOSOX-UHFFFAOYSA-N 2,3,6-TBA Chemical compound OC(=O)C1=C(Cl)C=CC(Cl)=C1Cl XZIDTOHMJBOSOX-UHFFFAOYSA-N 0.000 claims description 2
- OHDYZVVLNPXKDX-UHFFFAOYSA-N 2,3-dichlorobenzonitrile Chemical compound ClC1=CC=CC(C#N)=C1Cl OHDYZVVLNPXKDX-UHFFFAOYSA-N 0.000 claims description 2
- 239000002794 2,4-DB Substances 0.000 claims description 2
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 claims description 2
- BDQWWOHKFDSADC-UHFFFAOYSA-N 2-(2,4-dichloro-3-methylphenoxy)-n-phenylpropanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C)OC1=CC=C(Cl)C(C)=C1Cl BDQWWOHKFDSADC-UHFFFAOYSA-N 0.000 claims description 2
- WNTGYJSOUMFZEP-UHFFFAOYSA-N 2-(4-chloro-2-methylphenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=C(Cl)C=C1C WNTGYJSOUMFZEP-UHFFFAOYSA-N 0.000 claims description 2
- NUPJIGQFXCQJBK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)-5-(methoxymethyl)nicotinic acid Chemical compound OC(=O)C1=CC(COC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 NUPJIGQFXCQJBK-UHFFFAOYSA-N 0.000 claims description 2
- CABMTIJINOIHOD-UHFFFAOYSA-N 2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]quinoline-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC2=CC=CC=C2C=C1C(O)=O CABMTIJINOIHOD-UHFFFAOYSA-N 0.000 claims description 2
- JLYFCTQDENRSOL-UHFFFAOYSA-N 2-chloro-N-(2,4-dimethylthiophen-3-yl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound COCC(C)N(C(=O)CCl)C=1C(C)=CSC=1C JLYFCTQDENRSOL-UHFFFAOYSA-N 0.000 claims description 2
- KZNDFYDURHAESM-UHFFFAOYSA-N 2-chloro-n-(2-ethyl-6-methylphenyl)-n-(propan-2-yloxymethyl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(COC(C)C)C(=O)CCl KZNDFYDURHAESM-UHFFFAOYSA-N 0.000 claims description 2
- LLWADFLAOKUBDR-UHFFFAOYSA-N 2-methyl-4-chlorophenoxybutyric acid Chemical compound CC1=CC(Cl)=CC=C1OCCCC(O)=O LLWADFLAOKUBDR-UHFFFAOYSA-N 0.000 claims description 2
- UPMXNNIRAGDFEH-UHFFFAOYSA-N 3,5-dibromo-4-hydroxybenzonitrile Chemical compound OC1=C(Br)C=C(C#N)C=C1Br UPMXNNIRAGDFEH-UHFFFAOYSA-N 0.000 claims description 2
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 claims description 2
- NYRMIJKDBAQCHC-UHFFFAOYSA-N 5-(methylamino)-2-phenyl-4-[3-(trifluoromethyl)phenyl]furan-3(2H)-one Chemical compound O1C(NC)=C(C=2C=C(C=CC=2)C(F)(F)F)C(=O)C1C1=CC=CC=C1 NYRMIJKDBAQCHC-UHFFFAOYSA-N 0.000 claims description 2
- VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 claims description 2
- 239000002890 Aclonifen Substances 0.000 claims description 2
- XKJMBINCVNINCA-UHFFFAOYSA-N Alfalone Chemical compound CON(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XKJMBINCVNINCA-UHFFFAOYSA-N 0.000 claims description 2
- 239000005472 Bensulfuron methyl Substances 0.000 claims description 2
- JDWQITFHZOBBFE-UHFFFAOYSA-N Benzofenap Chemical compound C=1C=C(Cl)C(C)=C(Cl)C=1C(=O)C=1C(C)=NN(C)C=1OCC(=O)C1=CC=C(C)C=C1 JDWQITFHZOBBFE-UHFFFAOYSA-N 0.000 claims description 2
- 239000005484 Bifenox Substances 0.000 claims description 2
- XTFNPKDYCLFGPV-OMCISZLKSA-N Bromofenoxim Chemical compound C1=C(Br)C(O)=C(Br)C=C1\C=N\OC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O XTFNPKDYCLFGPV-OMCISZLKSA-N 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- DXXVCXKMSWHGTF-UHFFFAOYSA-N Chlomethoxyfen Chemical compound C1=C([N+]([O-])=O)C(OC)=CC(OC=2C(=CC(Cl)=CC=2)Cl)=C1 DXXVCXKMSWHGTF-UHFFFAOYSA-N 0.000 claims description 2
- HSSBORCLYSCBJR-UHFFFAOYSA-N Chloramben Chemical compound NC1=CC(Cl)=CC(C(O)=O)=C1Cl HSSBORCLYSCBJR-UHFFFAOYSA-N 0.000 claims description 2
- LPXYXBZAXFTFKH-UHFFFAOYSA-N ClC=1C(=C(C(=NC1)C(=O)O)C(=O)O)Cl Chemical compound ClC=1C(=C(C(=NC1)C(=O)O)C(=O)O)Cl LPXYXBZAXFTFKH-UHFFFAOYSA-N 0.000 claims description 2
- 239000005500 Clopyralid Substances 0.000 claims description 2
- NPOJQCVWMSKXDN-UHFFFAOYSA-N Dacthal Chemical group COC(=O)C1=C(Cl)C(Cl)=C(C(=O)OC)C(Cl)=C1Cl NPOJQCVWMSKXDN-UHFFFAOYSA-N 0.000 claims description 2
- NDUPDOJHUQKPAG-UHFFFAOYSA-N Dalapon Chemical compound CC(Cl)(Cl)C(O)=O NDUPDOJHUQKPAG-UHFFFAOYSA-N 0.000 claims description 2
- 239000005503 Desmedipham Substances 0.000 claims description 2
- HCRWJJJUKUVORR-UHFFFAOYSA-N Desmetryn Chemical compound CNC1=NC(NC(C)C)=NC(SC)=N1 HCRWJJJUKUVORR-UHFFFAOYSA-N 0.000 claims description 2
- 239000005504 Dicamba Substances 0.000 claims description 2
- LBGPXIPGGRQBJW-UHFFFAOYSA-N Difenzoquat Chemical compound C[N+]=1N(C)C(C=2C=CC=CC=2)=CC=1C1=CC=CC=C1 LBGPXIPGGRQBJW-UHFFFAOYSA-N 0.000 claims description 2
- 239000005507 Diflufenican Substances 0.000 claims description 2
- 239000005508 Dimethachlor Substances 0.000 claims description 2
- IKYICRRUVNIHPP-UHFFFAOYSA-N Dimethametryn Chemical compound CCNC1=NC(NC(C)C(C)C)=NC(SC)=N1 IKYICRRUVNIHPP-UHFFFAOYSA-N 0.000 claims description 2
- 239000005630 Diquat Substances 0.000 claims description 2
- 239000005510 Diuron Substances 0.000 claims description 2
- NRFQZTCQAYEXEE-UHFFFAOYSA-N Fenclorim Chemical compound ClC1=CC(Cl)=NC(C=2C=CC=CC=2)=N1 NRFQZTCQAYEXEE-UHFFFAOYSA-N 0.000 claims description 2
- 239000005514 Flazasulfuron Substances 0.000 claims description 2
- HWATZEJQIXKWQS-UHFFFAOYSA-N Flazasulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)C(F)(F)F)=N1 HWATZEJQIXKWQS-UHFFFAOYSA-N 0.000 claims description 2
- AOQMRUTZEYVDIL-UHFFFAOYSA-N Flupoxam Chemical compound C=1C=C(Cl)C(COCC(F)(F)C(F)(F)F)=CC=1N1N=C(C(=O)N)N=C1C1=CC=CC=C1 AOQMRUTZEYVDIL-UHFFFAOYSA-N 0.000 claims description 2
- PXRROZVNOOEPPZ-UHFFFAOYSA-N Flupropanate Chemical compound OC(=O)C(F)(F)C(F)F PXRROZVNOOEPPZ-UHFFFAOYSA-N 0.000 claims description 2
- YWBVHLJPRPCRSD-UHFFFAOYSA-N Fluridone Chemical compound O=C1C(C=2C=C(C=CC=2)C(F)(F)F)=CN(C)C=C1C1=CC=CC=C1 YWBVHLJPRPCRSD-UHFFFAOYSA-N 0.000 claims description 2
- 239000005559 Flurtamone Substances 0.000 claims description 2
- 239000005562 Glyphosate Substances 0.000 claims description 2
- 239000005566 Imazamox Substances 0.000 claims description 2
- 239000005981 Imazaquin Substances 0.000 claims description 2
- 239000005570 Isoxaben Substances 0.000 claims description 2
- ANFHKXSOSRDDRQ-UHFFFAOYSA-N Isoxapyrifop Chemical compound C1CCON1C(=O)C(C)OC(C=C1)=CC=C1OC1=NC=C(Cl)C=C1Cl ANFHKXSOSRDDRQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005572 Lenacil Substances 0.000 claims description 2
- SUSRORUBZHMPCO-UHFFFAOYSA-N MC-4379 Chemical compound C1=C([N+]([O-])=O)C(C(=O)OC)=CC(OC=2C(=CC(Cl)=CC=2)Cl)=C1 SUSRORUBZHMPCO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005574 MCPA Substances 0.000 claims description 2
- 239000005575 MCPB Substances 0.000 claims description 2
- 101150039283 MCPB gene Proteins 0.000 claims description 2
- 239000005578 Mesotrione Substances 0.000 claims description 2
- 239000005580 Metazachlor Substances 0.000 claims description 2
- RRVIAQKBTUQODI-UHFFFAOYSA-N Methabenzthiazuron Chemical compound C1=CC=C2SC(N(C)C(=O)NC)=NC2=C1 RRVIAQKBTUQODI-UHFFFAOYSA-N 0.000 claims description 2
- YFYIWIZSIVZILB-UHFFFAOYSA-N N.[P] Chemical compound N.[P] YFYIWIZSIVZILB-UHFFFAOYSA-N 0.000 claims description 2
- LVKTWOXHRYGDMM-UHFFFAOYSA-N Naproanilide Chemical compound C=1C=C2C=CC=CC2=CC=1OC(C)C(=O)NC1=CC=CC=C1 LVKTWOXHRYGDMM-UHFFFAOYSA-N 0.000 claims description 2
- CCGPUGMWYLICGL-UHFFFAOYSA-N Neburon Chemical compound CCCCN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 CCGPUGMWYLICGL-UHFFFAOYSA-N 0.000 claims description 2
- 239000005587 Oryzalin Substances 0.000 claims description 2
- 239000005588 Oxadiazon Substances 0.000 claims description 2
- CHNUNORXWHYHNE-UHFFFAOYSA-N Oxadiazon Chemical compound C1=C(Cl)C(OC(C)C)=CC(N2C(OC(=N2)C(C)(C)C)=O)=C1Cl CHNUNORXWHYHNE-UHFFFAOYSA-N 0.000 claims description 2
- 239000005590 Oxyfluorfen Substances 0.000 claims description 2
- OQMBBFQZGJFLBU-UHFFFAOYSA-N Oxyfluorfen Chemical compound C1=C([N+]([O-])=O)C(OCC)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 OQMBBFQZGJFLBU-UHFFFAOYSA-N 0.000 claims description 2
- 239000005594 Phenmedipham Substances 0.000 claims description 2
- 239000005595 Picloram Substances 0.000 claims description 2
- RSVPPPHXAASNOL-UHFFFAOYSA-N Prodiamine Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C(N)=C1[N+]([O-])=O RSVPPPHXAASNOL-UHFFFAOYSA-N 0.000 claims description 2
- 239000005602 Propyzamide Substances 0.000 claims description 2
- VXMNDQDDWDDKOQ-UHFFFAOYSA-N Pyrazosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2N(N=CC=2C(O)=O)C)=N1 VXMNDQDDWDDKOQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005606 Pyridate Substances 0.000 claims description 2
- JTZCTMAVMHRNTR-UHFFFAOYSA-N Pyridate Chemical compound CCCCCCCCSC(=O)OC1=CC(Cl)=NN=C1C1=CC=CC=C1 JTZCTMAVMHRNTR-UHFFFAOYSA-N 0.000 claims description 2
- 239000005616 Rimsulfuron Substances 0.000 claims description 2
- JXVIIQLNUPXOII-UHFFFAOYSA-N Siduron Chemical compound CC1CCCCC1NC(=O)NC1=CC=CC=C1 JXVIIQLNUPXOII-UHFFFAOYSA-N 0.000 claims description 2
- YIJZJEYQBAAWRJ-UHFFFAOYSA-N Thiazopyr Chemical compound N1=C(C(F)F)C(C(=O)OC)=C(CC(C)C)C(C=2SCCN=2)=C1C(F)(F)F YIJZJEYQBAAWRJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005624 Tralkoxydim Substances 0.000 claims description 2
- WHKUVVPPKQRRBV-UHFFFAOYSA-N Trasan Chemical compound CC1=CC(Cl)=CC=C1OCC(O)=O WHKUVVPPKQRRBV-UHFFFAOYSA-N 0.000 claims description 2
- 239000005627 Triclopyr Substances 0.000 claims description 2
- 235000021307 Triticum Nutrition 0.000 claims description 2
- NUFNQYOELLVIPL-UHFFFAOYSA-N acifluorfen Chemical compound C1=C([N+]([O-])=O)C(C(=O)O)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 NUFNQYOELLVIPL-UHFFFAOYSA-N 0.000 claims description 2
- DDBMQDADIHOWIC-UHFFFAOYSA-N aclonifen Chemical compound C1=C([N+]([O-])=O)C(N)=C(Cl)C(OC=2C=CC=CC=2)=C1 DDBMQDADIHOWIC-UHFFFAOYSA-N 0.000 claims description 2
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明涉及农业化学组合物,其包含:a)一种或多种选自农药和植物激素的物质;和b)一种或多种选自烷基磷酸酯和烷基芳基磷酸酯的物质,其特征在于,组分b)的化合物含有一个或多个支链烷基。
Description
技术领域
本发明涉及农业化学组合物,其包含一种或多种农药活性物质和/或一种或多种植物激素,以及一种或多种选自含有支链烷基的烷基磷酸酯和含有支链烷基的烷基芳基磷酸酯的物质。
背景技术
磷酸酯提高农药(除草剂、杀虫剂、杀真菌剂、杀螨剂、杀菌剂、杀软体动物剂、杀线虫剂和杀鼠剂)和植物激素的生物活性,改进在水介质和有机介质两者中的溶解度,和农药组合物中各成分的相容性。
大多数农药是除草剂,然后是杀虫剂和杀真菌剂。最重要的除草剂是例如通过抑制光合作用、脂肪酸生物合成或氨基酸生物合成而作用于植物传输系统并导致对植物发芽和生长造成抑制直至导致植物死亡的化学物质。
植物激素控制如生长、开花节律、细胞分裂和种子成熟之类的生理反应。
可以根据取决于作用时间和有效浓度而变的植物生长或由活性物质对叶子的作用引起的对植物的损害,测定农药或植物激素的生物活性。
为了最理想地发挥农药作用,农药必须润湿叶绿素并在其中保留足够长的时间,或活性物质必须渗透过叶面。为此,如在大量专利文献中所述,在农药配方中添加改进活性物质的润湿能力、溶解度、乳化能力或吸附特性的助剂。
对农业化学组合物,例如作物保护配制剂提出关于在极端温度条件下长时间贮存时的化学和物理稳定性方面的高要求。此外,组合物在施用到农田的过程中承受高剪切力。
发明内容
已经惊奇地发现,包含下列组分的农业化学组合物,例如作物保护配制剂:
a)一种或多种选自农药和植物激素的物质和
b)一种或多种选自烷基磷酸酯和烷基芳基磷酸酯的物质,其特征在于组分b)的化合物包含一个或多个支链烷基,
该组合物表现出农药活性的显著提高,改进具有物理化学性质差别很大的成分(农药、辅助剂、分散剂、电解质等等)的相容性,提高农药和适当时的其他成分在水介质和有机介质两者中的溶解度,且即使在高度负荷下也是稳定的。此外,支链烷基磷酸酯和含支链烷基的烷基芳基磷酸酯是良好的分散剂或乳化剂,并因此可杰出地用于分散体,尤其是悬浮液和乳液中。
本发明因此提供包含下列组分的组合物:
a)一种或多种选自农药和植物激素的物质和
b)一种或多种选自烷基磷酸酯和烷基芳基磷酸酯的物质,
其特征在于组分b)的化合物包含一个或多个支链烷基,
在本发明的优选实施方案中,组分b)的化合物中存在的所有烷基均是支链的。
在本发明的进一步优选实施方案中,组分b)的化合物的所有烷基中的碳原子数总计为6至36,优选6至30,特别优选8至22。
在本发明的进一步优选实施方案中,所述组分b)的一种或多种物质选自式(I)的化合物
其中
R1是含有6至30个,优选8至22个,特别优选12至18个碳原子的支化的、饱和或不饱和的烷基或链烯基,或芳基,特别是苯基,该芳基被1至3个各自彼此独立地含有3至18个,优选4至12个碳原子的支链烷基取代,
R2和R3各自彼此独立地为氢、碱金属、碱土金属、取代或未取代的铵或有机碱性基团或R1,
A1、A2和A3各自彼此独立地为含有2至4个碳原子的亚烷基,且
x、y和z各自彼此独立地为0至30,优选1至20,特别优选4至10,尤其优选6至8的数,
且其特征在于其包含一个或多个支链烷基。
式(I)的化合物中A1、A2和A3各自彼此独立地特别为亚乙基、亚丙基或亚丁基。
在本发明的进一步优选实施方案中,所述组分b)的一种或多种物质选自任选含有环氧乙烷单元的异十三烷基磷酸酯和它们的盐。这些化合物中优选的化合物是含有0至30个,优选1至20个,特别优选2至10个环氧乙烷单元的那些化合物。特别优选的是异十三烷基磷酸酯的混合物,其中单酯比例为40至60wt%,且二酯比例为40至60wt%。
在本发明的进一步优选实施方案中,所述组分b)的一种或多种物质选自任选含有环氧乙烷单元的三仲丁基苯酚磷酸酯,和它们的盐。这些化合物中优选的化合物是含有4至8个环氧乙烷单元的那些化合物。特别优选的是三仲丁基苯酚磷酸酯的混合物,其中单酯比例为40至60wt%,且二酯比例为40至60wt%。
本发明的组合物中所用的含支链烷基的组分b)的物质与不含支链烷基或只含直链烷基的类似化合物相比具有更好地提高活性的优点。
本发明的组合物中所用的组分b)的物质是以已知方式如下制备的:使十氧化四磷或正磷酸和脂肪醇或烷氧基化脂肪醇或相应芳族醇与小比例的三酯反应以形成单酯和二酯,并在适当时,随后用合适的碱性化合物,例如用碱金属氢氧化物,尤其是用NaOH和KOH,优选用KOH,以及用碱性氨基酸,例如精氨酸、鸟氨酸、赖氨酸、Oxylsin和链烷醇胺,例如三乙醇胺、二乙醇胺、单乙醇胺或用取代或未取代的铵化合物中和。
在本发明的进一步优选实施方案中,所述组分a)的一种或多种物质选自农药,优选选自除草剂、杀虫剂、杀真菌剂、杀螨剂、杀菌剂、杀软体动物剂、杀线虫剂和杀鼠剂。在这些物质中,除草剂又是优选的。
合适的除草剂是,但本发明不限于此,乙草胺、三氟羧草醚、苯草醚、丙烯醛、甲草胺、莠灭净、杀草强、黄草灵、莠去津、草除灵、苄嘧磺隆、苯达松、吡草酮、双丙氨膦、治草醚、双丙氨磷(Bilanafos)、除草定、溴丁酰草胺、杀草全、溴苯腈、丁草胺、氟丙嘧草酯、甲氧除草醚(Chlormethoxyfen)、草灭平、氯乙酸、氯溴隆、氯嘧磺隆、绿麦隆、草枯醚、绿麦隆、氯酞酸甲酯、炔草酸(Clodinafop)、炔草酯、二氯吡啶酸、氯甲酰草胺、草净津、2,4-D、2,4-DB、Diamuron、茅草枯、甜菜安、敌草净、麦草畏、二氯苯腈(Dichlorbenil)、2,4-滴丙酸、禾草灵、野燕枯、吡氟酰草胺、丁恶隆、二甲草胺、异戊乙净、二甲吩草胺、氨基乙氟灵、敌草快、敌草隆、草藻灭、胺苯磺隆、伐草克、解草啶、唑禾草灵(酸)、唑禾草灵、麦草氟、唑禾草灵甲酯(Fenoxaprop-methyl)、啶嘧磺隆、吡氟禾草灵、精吡氟禾草灵、唑嘧磺草胺、氟烯草酸、氟烯草酸(-phenyl)、乙羧氟草醚、唑嘧磺草胺、Flumeturon、丙炔氟草胺、氟胺草唑、四氟丙酸、氟啶草酮、呋草酮、氟磺胺草醚、杀木膦、草铵膦、草甘膦、氟吡甲禾灵、甲咪唑烟酸、甲基咪草烟(Imazameth)、咪草酯、甲氧咪草烟、甲咪唑烟酸、咪唑烟酸、咪唑喹啉酸、咪唑乙烟酸、咪唑乙烟酸铵、碘苯腈、异丙隆、异恶草胺、异恶草醚、乳氟禾草灵、环草定、利谷隆、MCPA、MCPB、2甲4氯丙酸、苯噻酰草胺、表硝草酮、吡唑草胺、甲基苯噻隆、甲胂酸、草不绿、吡喃隆、萘丙胺、萘草胺、草不隆、壬酸、氟草敏、氨磺乐灵、恶草酮、乙氧氟草醚、百草枯、甜菜宁、氨氯吡啶酸、丙草胺、氨氟乐灵、扑灭通、扑草净、毒草胺、扑灭津、异丙草胺、炔苯酰草胺、苄草唑、吡嘧磺隆、稗草丹、哒草特、二氯喹啉酸、喹禾灵、精喹禾灵、砜嘧磺隆、环草隆、西玛津、西草净、氨基磺酸、2,3,6-TBA、TCA、甲氧去草净、特丁津、Terbutyrin、三氯乙酸、绿草定、草达津、噻吩草胺、噻草啶、三甲苯草酮(Trialkoxydim)、草达津和它们的盐。
在本发明的特别优选实施方案中,所述组分a)的一种或多种物质选自炔草酯和咪唑乙烟酸铵。
本发明的组合物的组分b)的磷酸酯适合用作例如固体形式和凝胶或糊状形式两者并优选可喷洒液体形式的作物保护配制剂中的辅助剂。
本发明的组合物可以以作为粉末、丸粒、片剂或颗粒形式的固体形式制备,所述粉末、丸粒、片剂或颗粒在使用之前溶于水中。固体制剂包含优选20至80,特别优选50至75,尤其优选60至70wt%的所述组分a)的一种或多种物质,和优选5至60,特别优选10至30wt%的所述组分b)的一种或多种物质。在使用之前稀释的浓缩物配制剂包含优选5至50,特别优选20至40wt%的组分a)的一种或多种物质,和优选5至70wt%的组分b)的一种或多种物质。
本发明的组合物可以通过常规方法应用。将含水浓缩物和固体配制剂在施用之前用适量的水稀释。
每公顷施用的农药和/或植物激素的量为0.1至5千克,优选0.3至2.5千克。组分b)的物质的量为0.10至2.1千克/公顷。为喷洒制成的配制剂的体积为50至1000升/公顷。
本发明的组合物可以包含表面活性剂、增稠剂、抗胶凝剂、防冻剂、溶剂、分散剂、乳化剂、防腐剂、其它辅助剂、粘结剂、防沫剂、稀释剂、崩解剂和润湿剂。
在本发明的进一步优选实施方案中,本发明的组合物包含阴离子型表面活性剂。优选的阴离子型表面活性剂是直链和支链烷基硫酸盐、烷基磺酸盐、烷基羧酸盐、烷基磷酸盐、烷基磺基琥珀酸盐和烷基牛磺酸盐,烷基酯磺酸盐、芳基烷基磺酸盐和烷基醚硫酸盐。
烷基硫酸盐是式ROSO3M的水溶性盐或酸,其中R优选为C10-C24烃基,特别优选为含有10至20个碳原子的烷基或羟烷基,尤其优选为C12-C18-烷基或羟烷基。M是氢或阳离子,优选碱金属阳离子(例如钠、钾、锂)或铵或取代铵,例如甲基-、二甲基-和三甲基-铵阳离子,或季铵阳离子,例如四甲基铵阳离子和二甲基哌啶阳离子和衍生自烷基胺(例如乙胺、二乙胺、三乙胺和它们的混合物)的季铵阳离子。
烷基醚硫酸盐是式RO(A)mSO3M的水溶性盐或酸,其中R优选为未取代的C10-C24烷基或羟烷基,特别优选为C12-C20-烷基或羟烷基,尤其优选为C12-C18-烷基或羟烷基。A是乙氧基或丙氧基单元,m是大于0的数,通常约0.5至约6,特别优选约0.5至约3,且M是氢原子或阳离子,优选金属阳离子(例如钠、钾、锂、钙、镁等等)、铵或取代铵阳离子。取代铵阳离子的例子是甲基-、二甲基-、三甲基-铵阳离子,和季铵阳离子,例如四甲基铵和二甲基哌啶阳离子,以及衍生自烷基胺(例如乙胺、二乙胺、三乙胺或它们的混合物)的那些。其例子可以提到C12-C18-烷基聚乙氧基化物(1.0)硫酸盐、C12-C16-烷基聚乙氧基化物(2.25)硫酸盐、C12-C18-烷基聚乙氧基化物(3.0)硫酸盐、C12-C18-烷基聚乙氧基化物(4.0)硫酸盐,其中阳离子是钠或钾。
同样适合的是含有直链或支链C6-C22-烷基链的烷基磺酸盐,例如伯链烷烃磺酸盐、仲链烷烃磺酸盐、烷基芳基磺酸盐,例如含有C5-C20-烷基链的线性烷基苯磺酸盐,烷基萘磺酸盐,萘磺酸盐和甲醛的缩合产物,木素磺酸盐,烷基酯磺酸盐,即C8-C20-羧酸(即脂肪酸)的磺化线性酯,C8-C24烯烃磺酸盐,通过碱土金属柠檬酸盐的热解产物的磺化制成的磺化聚羧酸。
进一步适合的阴离子型表面活性剂选自烷基甘油硫酸盐、脂肪酰基甘油硫酸盐、油基甘油硫酸盐、烷基酚醚硫酸盐、烷基磷酸盐、烷基醚磷酸盐、羟乙基磺酸盐(例如酰基羟乙基磺酸盐)、N-酰基牛磺酸盐、烷基琥珀酰胺酸盐、磺基琥珀酸盐、磺基琥珀酸盐的单酯(尤其是饱和和不饱和C12-C18单酯)和磺基琥珀酸盐的二酯(尤其是饱和和不饱和C12-C18二酯)、酰基肌氨酸盐、烷基多糖的硫酸盐(例如烷基多苷的硫酸盐)、支链伯烷基硫酸盐和烷基聚乙氧基羧酸盐,例如式RO(CH2CH2O)kCH2COO-M+的那些,其中R是C8-C22-烷基,k是0至10的数,M是形成可溶盐的阳离子。
在进一步优选实施方案中,所述组分b)的一种或多种物质与所述一种或多种阴离子型表面活性剂的重量比为95∶5至5∶95,优选80∶20至20∶80,特别优选80∶20至70∶30,或20∶80至30∶70。
在进一步优选实施方案中,本发明的组合物包含一种或多种非离子型表面活性剂、两性表面活性剂和/或阳离子型表面活性剂作为另外的组分。其中优选的是含有一种或多种非离子型表面活性剂和/或一种或多种两性表面活性剂作为另外的组分的那些本发明组合物。
适合的非离子型表面活性剂优选是脂肪醇乙氧基化物(烷基聚乙二醇)、烷基酚聚乙二醇、烷基硫醇聚乙二醇、脂肪胺乙氧基化物(烷基氨基聚乙二醇)、脂肪酸乙氧基化物(酰基聚乙二醇)、聚丙二醇乙氧基化物(例如,Pluronics)、脂肪酸羟烷基酰胺(脂肪酸酰胺聚乙二醇)、N-烷基-和N-烷氧基-聚羟基脂肪酸酰胺、烷基多糖、蔗糖酯、山梨糖醇酯和聚二醇醚。
适合的两性表面活性剂优选是两性乙酸盐(amphoacetate),特别优选为单羧酸盐和二羧酸盐,例如椰油两性羧基丙酸盐、椰油酰氨基羧基丙酸、椰油两性羧基甘氨酸盐(或也称作椰油两性二乙酸盐)和椰油两性乙酸盐。
可以使用的阳离子型表面活性剂是氯化或溴化二-(C10-C24)-烷基二甲铵,优选氯化或溴化二-(C12-C18)-烷基二甲铵;氯化或溴化(C10-C24)-烷基二甲基乙铵;氯化或溴化(C10-C24)-烷基三甲铵,优选氯化或溴化十六烷基三甲铵和氯化或溴化(C20-C22)-烷基三甲铵;氯化或溴化(C10-C24)-烷基二甲基苄铵,优选氯化(C12-C18)-烷基二甲基苄铵;氯化或溴化N-(C10-C18)-烷基吡啶,优选为氯化或溴化N-(C12-C16)-烷基吡啶;氯化、溴化或单烷基硫酸N-(C10-C18)-烷基异喹啉;氯化N-(C12-C18)-烷基多酰基氨基甲酰基甲基吡啶;氯化、溴化或单烷基硫酸N-(C12-C18)-烷基-N-甲基-吗啉;氯化、溴化或单烷基硫酸N-(C12-C18)-烷基-N-乙基-吗啉;氯化(C16-C18)-烷基五氧乙基铵;氯化二异丁基苯氧基乙氧基乙基二甲基苄铵;N,N-二乙基氨基-乙基硬脂基酰胺和-油基酰胺与盐酸、乙酸、乳酸、柠檬酸、磷酸形成的盐;氯化、溴化或单烷基硫酸N-酰基氨基-乙基-N,N-二乙基-N-甲基铵,和氯化、溴化或单烷基硫酸N-酰基氨基乙基-N,N-二乙基-N-苄基铵,其中酰基优选为硬脂酰基或油酰基。
可用的增稠剂是占最终组合物的0.01至5wt%的黄原胶和/或纤维素,例如羧基-、甲基-、乙基-或丙基-纤维素。适合的溶剂是水、乙二醇、二甘醇和单丙二醇。
适合的分散剂和乳化剂为2至30摩尔环氧乙烷和/或0至5摩尔环氧丙烷与含有8至22个碳原子的线性脂肪醇、与含有12至22个碳原子的脂肪酸和与在烷基中含有8至15个碳原子的烷基酚的加合产物;1至30摩尔环氧乙烷与甘油的加合产物的C12-C18-脂肪酸单酯和二酯;含有6至22个碳原子的饱和和不饱和脂肪酸的甘油单酯和二酯和失水山梨糖醇单酯和二酯和它们的环氧乙烷加合产物;15至60摩尔环氧乙烷与蓖麻油和/或硬化蓖麻油的加合产物;多元醇酯,尤其是聚甘油酯,例如聚甘油聚蓖麻醇酸酯和聚甘油聚-12-羟基硬脂酸酯。同样适合的是多种这些物质类型的化合物的混合物。环氧乙烷和/或环氧丙烷与脂肪醇、脂肪酸、烷基酚,脂肪酸的甘油单酯和二酯和失水山梨糖醇单酯和二酯,或与蓖麻油的加合产物是已知的市售产品。它们是平均烷氧化度相应于环氧乙烷和/或环氧丙烷和与其进行加合反应的底物的物质量的比率的同系物混合物。
其它辅助剂可以是聚甘油酯、醇乙氧基化物、烷基多糖、脂肪胺乙氧基化物、失水山梨糖醇-和山梨糖醇-乙氧基化物衍生物,和烷基(链烯基)琥珀酸酐的衍生物。适用于固体配制剂的粘结剂是聚乙烯基吡咯烷酮、聚乙烯醇、羧甲基纤维素、糖,例如蔗糖、山梨糖醇或淀粉。适合的稀释剂、吸收剂或载体是炭黑、牛脂、高岭土、硬脂酸铝、硬脂酸钙或硬脂酸镁、三聚磷酸钠、四硼酸钠、硫酸钠、硅酸盐和苯甲酸钠。纤维素,例如羧甲基纤维素、聚乙烯基吡咯烷酮、乙酸钠或钾、碳酸盐、碳酸氢盐、倍半碳酸盐、硫酸铵或磷酸氢钾用作崩解剂。可以使用醇乙氧基化物/丙氧基化物作为润湿剂。
在本发明的进一步优选实施方案中,本发明的组合物除含有组分b)的一种或多种物质外,不含其它表面活性物质。表面活性物质的概念包括,例如,表面活性剂、助表面活性剂和乳化剂。
在本发明的进一步优选实施方案中,本发明的组合物含水。
本发明的组合物适合例如以有利的方式用于杂草控制。本发明因此进一步提供本发明的组合物用于杂草控制的用途。
此外,本发明的组合物还有利地适用于调节植物生长。本发明因此进一步提供本发明的组合物用于调节植物生长的用途。
具体实施方式
实施例
下面通过实施例解释本发明,但实施例决不应被视为限制性的。
步骤A:磷酸酯的制备(辅助剂I、III和V)
在四颈圆底烧瓶中预先加入异十三烷基醇聚二醇醚,并通过在适当反应温度下缓慢添加71克五氧化二磷以引起反应。各种不同的异十三烷基醇聚二醇醚在此以表1所列的量使用。
表1 异十三烷基醇聚二醇醚的量
辅助剂 | 每单位异十三烷基醇聚二醇醚的环氧乙烷单元数 | 量[克] |
I | 5 | 420 |
III | 6 | 464 |
V | 10 | 640 |
然后用9克脱盐的水(E-水)将反应混合物水解。
步骤B:被中和的磷酸酯的制备(辅助剂II和IV)
将500克得自步骤A的磷酸酯、105克增溶剂(丙二醇)和50克E-水称入配有温度计和回流冷凝器的四颈烧瓶。然后,在50-60℃下,通过滴液漏斗缓慢添加120克50wt%氢氧化钾水溶液或85.6克50wt%氢氧化钠水溶液。所得最终产物是根据式(Ia)和表2的产物。
表2:辅助剂I至V
辅助剂 | R1 | A1和A2 | x | y和R2 | R3 |
I | i-C13-烷基 | -CH2CH2- | 5 | y=0;R2=H(40%)y=5;R2=i-C13-烷基(60%) | H |
II | i-C13-烷基 | -CH2CH2- | 5 | y=0;R2=Na(40%)y=5;R2=i-C13-烷基(60%) | Na |
III | i-C13-烷基 | -CH2CH2- | 6 | y=0;R2=H(40%)y=6;R2=i-C13-烷基(60%) | H |
IV | i-C13-烷基 | -CH2CH2- | 6 | y=0;R2=K(40%)y=6;R2=i-C13-烷基(60%) | K |
V | i-C13-烷基 | -CH2CH2- | 10 | y=0;R2=H(40%)y=10;R2=i-C13-烷基(60%) | H |
辅助剂I至V在炔草酯方面的效力
通过将市售配制剂Topic 240与水混合而制备试验配制剂,该配制剂如制造商(Syngenta)所述每升配制剂含有240克炔草酯。在该乳液中以相当于0.25%w/v(2.5克/升)浓度的量添加辅助剂。将这些试验溶液根据下表以不同浓度(以g a.i./ha计的浓度数据,其中a.i.是指活性成分)在温室中施用到处于2-3叶期期间的植物品种野燕麦(Avena fatura L.)(AVEFA)上。
在21天后,通过将仍然存在的植物部分称重(鲜重),评估除草配制剂的效力。结果显示在表3中。
表3:磷酸化异十三烷基烷氧基化物对炔草酯效力的影响
炔草酯[g a.i./ha] | 辅助剂 | 鲜重[克]AVEFA |
- | - | 17.48 |
5 | - | 15.69 |
5 | I | 1.54 |
5 | II | 1.70 |
5 | III | 1.60 |
5 | IV | 2.30 |
5 | V | 4.25 |
辅助剂I至V在咪唑乙烟酸铵方面的效力
通过将咪唑乙烟酸铵水溶液调节至5毫摩尔的浓度,制备试验配制剂。在该溶液中以相当于0.25%w/v(2.5克/升)浓度的量添加辅助剂。将这些试验溶液根据下表以不同浓度(以g ae/ha计的浓度数据,其中ae是指酸当量)在温室中施用到处于2-3叶期期间的植物品种龙葵(Solanum Nigrum L.)(SOLNI)和黑麦草(Lolium perenneL.)(LOLPE)上。
在14天后,通过将仍然存在的植物部分称重(鲜重),评估除草配制剂的效力。结果显示在表4中。
表4:磷酸化异十三烷基烷氧基化物对咪唑乙烟酸铵效力的影响
咪唑乙烟酸铵[g ae/ha] | 辅助剂 | 鲜重[克] | |
SOLNI | LOLPE | ||
- | - | 15.42 | 13.97 |
4.0 | - | 10.61 | 13.40 |
4.0 | I | 2.44 | 5.69 |
4.0 | II | 2.34 | 8.70 |
4.0 | III | 2.04 | 8.59 |
4.0 | IV | 3.05 | 9.65 |
4.0 | V | 6.23 | 10.45 |
Claims (19)
1.一种组合物,其包含下列组分:
a)一种或多种选自农药和植物激素的物质和
b)一种或多种选自烷基磷酸酯和烷基芳基磷酸酯的物质,
其中组分b)的化合物包含一个或多个支链烷基,
2.权利要求1的组合物,其中组分b)的化合物中存在的所有烷基均是支链的。
3.权利要求1或2的组合物,其中组分b)的化合物的所有烷基中的碳原子数总计为6至36,优选6至30,特别优选8至22。
5.权利要求1至4中任一项的组合物,其中所述组分b)的一种或多种物质选自任选含有环氧乙烷单元的异十三烷基磷酸酯和它们的盐。
6.权利要求5的组合物,其中异十三烷基磷酸酯包含0至30,优选1至20,特别优选2至10个环氧乙烷单元。
7.权利要求5或6的组合物,其中组分b)的物质选自异十三烷基磷酸酯的混合物,其中单酯比例为40至60wt%,且二酯比例为40至60wt%。
8.权利要求1至4中任一项的组合物,其中所述组分b)的一种或多种物质选自任选含有环氧乙烷单元的三仲丁基苯酚磷酸酯,和它们的盐。
9.权利要求8的组合物,其中三仲丁基苯酚磷酸酯包含4至8个环氧乙烷单元。
10.权利要求8或9的组合物,其中所述组分b)的物质选自三仲丁基苯酚磷酸酯的混合物,其中单酯比例为40至60wt%,且二酯比例为40至60wt%。
11.权利要求1至10中任一项的组合物,其中所述组分a)的一种或多种物质选自农药,优选除草剂、杀虫剂、杀真菌剂、杀螨剂、杀菌剂、杀软体动物剂、杀线虫剂和杀鼠剂。
12.权利要求11的组合物,其中所述组分a)的一种或多种物质选自除草剂,优选为乙草胺、三氟羧草醚、苯草醚、丙烯醛、甲草胺、莠灭净、杀草强、黄草灵、莠去津、草除灵、苄嘧磺隆、苯达松、吡草酮、双丙氨膦、治草醚、双丙氨磷、除草定、溴丁酰草胺、杀草全、溴苯腈、丁草胺、氟丙嘧草酯、甲氧除草醚、草灭平、氯乙酸、氯溴隆、氯嘧磺隆、绿麦隆、草枯醚、绿麦隆、氯酞酸甲酯、炔草酸、炔草酯、二氯吡啶酸、氯甲酰草胺、草净津、2,4-D、2,4-DB、Diamuron、茅草枯、甜菜安、敌草净、麦草畏、二氯苯腈、2,4-滴丙酸、禾草灵、野燕枯、吡氟酰草胺、丁恶隆、二甲草胺、异戊乙净、二甲吩草胺、氨基乙氟灵、敌草快、敌草隆、草藻灭、胺苯磺隆、伐草克、解草啶、唑禾草灵(酸)、唑禾草灵、麦草氟、唑禾草灵甲酯、啶嘧磺隆、吡氟禾草灵、精吡氟禾草灵、唑嘧磺草胺、氟烯草酸、氟烯草酸(-phenyl)、乙羧氟草醚、唑嘧磺草胺、Flumeturon、丙炔氟草胺、氟胺草唑、四氟丙酸、氟啶草酮、呋草酮、氟磺胺草醚、杀木膦、草铵膦、草甘膦、氟吡甲禾灵、甲咪唑烟酸、甲基咪草烟、咪草酯、甲氧咪草烟、甲咪唑烟酸、咪唑烟酸、咪唑喹啉酸、咪唑乙烟酸、咪唑乙烟酸铵、碘苯腈、异丙隆、异恶草胺、异恶草醚、乳氟禾草灵、环草定、利谷隆、MCPA、MCPB、2甲4氯丙酸、苯噻酰草胺、表硝草酮、吡唑草胺、甲基苯噻隆、甲胂酸、草不绿、吡喃隆、萘丙胺、萘草胺、草不隆、壬酸、氟草敏、氨磺乐灵、恶草酮、乙氧氟草醚、百草枯、甜菜宁、氨氯吡啶酸、丙草胺、氨氟乐灵、扑灭通、扑草净、毒草胺、扑灭津、异丙草胺、炔苯酰草胺、苄草唑、吡嘧磺隆、稗草丹、哒草特、二氯喹啉酸、喹禾灵、精喹禾灵、砜嘧磺隆、环草隆、西玛津、西草净、氨基磺酸、2,3,6-TBA、TCA、甲氧去草净、特丁津、Terbutyrin、三氯乙酸、绿草定、草达津、噻吩草胺、噻草啶、三甲苯草酮、草达津和它们的盐。
13.权利要求12的组合物,其中所述组分a)的一种或多种物质选自炔草酯和咪唑乙烟酸铵。
14.权利要求1至13中任一项的组合物,其中它是以固体制剂形式存在,并包含20至80wt%的所述组分a)的一种或多种物质和5至60wt%的所述组分b)的一种或多种物质。
15.权利要求1至13中任一项的组合物,其中它是以浓缩物配制剂形式存在,并包含5至50wt%的所述组分a)的一种或多种物质和5至70wt%的所述组分b)的一种或多种物质。
16.权利要求1至15中任一项的组合物,其中除了所述组分b)的一种或多种物质外,该组合物不含其它表面活性物质。
17.权利要求1至16中任一项的组合物,其中该组合物还含有水。
18.权利要求1至17中任一项的组合物用于杂草控制的用途。
19.权利要求1至17中任一项的组合物用于调节植物生长的用途。
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DE102007036187A1 (de) * | 2007-08-02 | 2008-06-19 | Clariant International Limited | Alkoxylierte Phosphorsäuretriester mit hohem Alkoxylierungsgrad |
CN101802097B (zh) | 2007-08-02 | 2012-11-14 | 科莱恩金融(Bvi)有限公司 | 含有通过二醇单元桥接的磷原子的磷酸酯 |
DE102007036188A1 (de) | 2007-08-02 | 2008-06-19 | Clariant International Limited | Verfahren zur Herstellung alkoxylierter Phosphorsäuretriester |
DE102007036186A1 (de) * | 2007-08-02 | 2008-06-19 | Clariant International Limited | Phosphorsäureester enthaltend über Polyol-Einheiten verbrückte Phosporatome |
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CN105010334B (zh) * | 2015-07-09 | 2017-03-15 | 上海交通大学 | 一种控制植物蚜虫的杀虫剂及其制备和应用 |
CN116568137A (zh) | 2020-12-01 | 2023-08-08 | 拜耳公司 | 包含甲基二磺隆和tehp的组合物 |
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2007
- 2007-03-27 IL IL182238A patent/IL182238A0/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102893998A (zh) * | 2012-11-13 | 2013-01-30 | 安徽丰乐农化有限责任公司 | 一种除草水悬浮剂 |
Also Published As
Publication number | Publication date |
---|---|
WO2006034817A2 (de) | 2006-04-06 |
EP1799036A2 (de) | 2007-06-27 |
KR20070057879A (ko) | 2007-06-07 |
MX2007003730A (es) | 2007-04-23 |
EP1799036B1 (de) | 2011-11-09 |
IL182238A0 (en) | 2007-09-20 |
US20070275854A1 (en) | 2007-11-29 |
JP2008514664A (ja) | 2008-05-08 |
ES2373730T3 (es) | 2012-02-08 |
CA2581183A1 (en) | 2006-04-06 |
WO2006034817A3 (de) | 2006-07-13 |
BRPI0515958A (pt) | 2008-08-12 |
DE102004047092A1 (de) | 2006-03-30 |
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