CN101069514A - Sterilizing agent containing copper gluconate - Google Patents
Sterilizing agent containing copper gluconate Download PDFInfo
- Publication number
- CN101069514A CN101069514A CNA2007100286600A CN200710028660A CN101069514A CN 101069514 A CN101069514 A CN 101069514A CN A2007100286600 A CNA2007100286600 A CN A2007100286600A CN 200710028660 A CN200710028660 A CN 200710028660A CN 101069514 A CN101069514 A CN 101069514A
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- CN
- China
- Prior art keywords
- copper gluconate
- bactericide
- sodium sulfonate
- copper
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical compound [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 title claims abstract description 43
- 229940108925 copper gluconate Drugs 0.000 title claims abstract description 43
- 239000003206 sterilizing agent Substances 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 230000000844 anti-bacterial effect Effects 0.000 claims description 29
- 239000003899 bactericide agent Substances 0.000 claims description 29
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 13
- 239000011734 sodium Substances 0.000 claims description 13
- 229910052708 sodium Inorganic materials 0.000 claims description 13
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 12
- JHXVRRJXCDAINK-UHFFFAOYSA-N NC(=O)N.N#CC#N Chemical compound NC(=O)N.N#CC#N JHXVRRJXCDAINK-UHFFFAOYSA-N 0.000 claims description 8
- 235000018927 edible plant Nutrition 0.000 claims description 8
- 241000282376 Panthera tigris Species 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- ZCXLQZOQWCXFNN-UHFFFAOYSA-N copper;hexanedioic acid Chemical compound [Cu].OC(=O)CCCCC(O)=O ZCXLQZOQWCXFNN-UHFFFAOYSA-N 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- 239000011575 calcium Substances 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- 239000003995 emulsifying agent Substances 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 claims description 5
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims description 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- UDHMTPILEWBIQI-UHFFFAOYSA-N butyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)OCCCC)=CC=CC2=C1 UDHMTPILEWBIQI-UHFFFAOYSA-N 0.000 claims description 4
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 4
- 239000000203 mixture Substances 0.000 abstract description 6
- 208000025865 Ulcer Diseases 0.000 abstract description 5
- 231100000397 ulcer Toxicity 0.000 abstract description 5
- 201000010099 disease Diseases 0.000 abstract description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 4
- 230000000855 fungicidal effect Effects 0.000 abstract description 4
- 239000000417 fungicide Substances 0.000 abstract description 4
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 abstract description 3
- 240000008067 Cucumis sativus Species 0.000 abstract description 3
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 abstract description 3
- 240000007124 Brassica oleracea Species 0.000 abstract description 2
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 abstract description 2
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 abstract description 2
- 241000196324 Embryophyta Species 0.000 abstract description 2
- 244000183278 Nephelium litchi Species 0.000 abstract description 2
- 230000001737 promoting effect Effects 0.000 abstract description 2
- 241000233679 Peronosporaceae Species 0.000 abstract 1
- 239000002671 adjuvant Substances 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 description 12
- 239000010949 copper Substances 0.000 description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 11
- 239000007921 spray Substances 0.000 description 6
- 241000207199 Citrus Species 0.000 description 5
- 241000238631 Hexapoda Species 0.000 description 5
- 241000700159 Rattus Species 0.000 description 5
- 235000020971 citrus fruits Nutrition 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 231100000636 lethal dose Toxicity 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 241000488581 Panonychus citri Species 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 231100000053 low toxicity Toxicity 0.000 description 3
- 230000000638 stimulation Effects 0.000 description 3
- 208000035143 Bacterial infection Diseases 0.000 description 2
- 230000001154 acute effect Effects 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 208000022362 bacterial infectious disease Diseases 0.000 description 2
- YEOCHZFPBYUXMC-UHFFFAOYSA-L copper benzoate Chemical compound [Cu+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 YEOCHZFPBYUXMC-UHFFFAOYSA-L 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 231100000820 toxicity test Toxicity 0.000 description 2
- 238000009602 toxicology test Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 239000005739 Bordeaux mixture Substances 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 241001674939 Caulanthus Species 0.000 description 1
- 241001529387 Colletotrichum gloeosporioides Species 0.000 description 1
- 239000005752 Copper oxychloride Substances 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 241000233614 Phytophthora Species 0.000 description 1
- 239000005820 Prochloraz Substances 0.000 description 1
- 241000589649 Xanthomonas campestris pv. campestris Species 0.000 description 1
- 241000589655 Xanthomonas citri Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- 231100000293 acute skin toxicity Toxicity 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 230000005200 bud stage Effects 0.000 description 1
- HKMOPYJWSFRURD-UHFFFAOYSA-N chloro hypochlorite;copper Chemical compound [Cu].ClOCl HKMOPYJWSFRURD-UHFFFAOYSA-N 0.000 description 1
- 229940120693 copper naphthenate Drugs 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 1
- SEVNKWFHTNVOLD-UHFFFAOYSA-L copper;3-(4-ethylcyclohexyl)propanoate;3-(3-ethylcyclopentyl)propanoate Chemical compound [Cu+2].CCC1CCC(CCC([O-])=O)C1.CCC1CCC(CCC([O-])=O)CC1 SEVNKWFHTNVOLD-UHFFFAOYSA-L 0.000 description 1
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 description 1
- IURRXCRWRKQLGC-UHFFFAOYSA-N copper;quinolin-8-ol Chemical compound [Cu].C1=CN=C2C(O)=CC=CC2=C1.C1=CN=C2C(O)=CC=CC2=C1 IURRXCRWRKQLGC-UHFFFAOYSA-N 0.000 description 1
- FWBOFUGDKHMVPI-UHFFFAOYSA-K dicopper;2-oxidopropane-1,2,3-tricarboxylate Chemical compound [Cu+2].[Cu+2].[O-]C(=O)CC([O-])(C([O-])=O)CC([O-])=O FWBOFUGDKHMVPI-UHFFFAOYSA-K 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 description 1
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a fungicide containing copper gluconate. Its composition includes (by wt%) 0.01-0.07% of copper gluconate, 0-0.015% of fungicide, 0-0.057% of adjuvant and the rest is water. The invented fungicide can be uniformly dispersed in the water medium, and can be used for effectively promoting crop growth and controlling diseases of plants, such as orange ulcer, litchi downy mildew, anthracnose, black rot of cabbage and angular leaf spot of cucumber, etc.
Description
Technical field
The present invention relates to a kind of bactericide, relate to a kind of bactericide that contains copper gluconate specifically.
Background technology
Copper fungicide has original control efficiency to the crop bacterial disease, mainly contain two classes at present, one class is inorganic copper agent, as copper sulphate, bordeaux mixture, Kocide SD, copper oxychloride etc., another kind of is the organic copper preparation, as tiger glue adipic acid copper, copper rosinate, green bacterium copper, Thiodiazole-copper, copper acetate, amino acid copper, copper citrate, copper humate, copper naphthenate, copper benzoate, copper 8-hydroxyquinolinate, prochloraz nantokite, terephthalic acid (TPA) copper, butene dioic acid copper etc.Studies show that, inorganic copper agent easily stimulates the generation of insect, as citrus red mite (crm) is had spread effect, though the organic copper bactericide can or lessly not bring out insect outburst, but it is most water insoluble, therefore formulations such as missible oil, wetting powder or suspending agent be can only be processed into usually, can't processing aqua or soluble powder product be become.
The copper gluconate relative molecular mass is 453.8, and former medicine is light blue powder, and is very easily water-soluble.But do not see that copper gluconate is used in the report in the bactericide at present.
Summary of the invention
It is good to the objective of the invention is to utilize copper gluconate to develop a kind of control efficiency, insect is had no stimulation, and can be processed into the bactericide of aqua or soluble powder.
We by with copper gluconate and or other bactericide, auxiliary agent adds in the entry, the bactericide that obtains not only control efficiency is good, insect is had no stimulation, and can be processed into various formulations, thereby realized purpose of the present invention.
The bactericide that contains copper gluconate of the present invention is characterized in that by gross mass mark 100%, by copper gluconate 0.01～0.07%, and bactericide 0～0.015%, auxiliary agent 0～0.057%, the water of surplus is formed.
Described copper gluconate can be buied from the market, described bactericide can be the bactericide of using always, for example white urea cyanogen, tiger glue adipic acid copper etc., used auxiliary agent can be the surfactant that uses of conventional pesticide or carrier etc., as surfactants such as sodium butylnaphthalenesulfonate (Nekal BX), di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate (dispersing agent NNO), dodecyl sodium sulfonate calcium, emulsifier 0204C, dodecylbenzene sodium sulfonate or sodium lignin sulfonates, in the kaolin support etc. one or more.
The described bactericide that contains copper gluconate is characterized in that and can be made up of copper gluconate 0.07% and water 99.93%.
The described bactericide that contains copper gluconate, it is characterized in that can be by copper gluconate 0.05%, and butyl is sodium sulfonate 0.003% how, and di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 0.002% and water 99.945% are formed.
The described bactericide that contains copper gluconate, its feature can be by copper gluconate 0.035%, white urea cyanogen 0.007%, butyl is sodium sulfonate 0.003% how, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 0.002%, dodecyl sodium sulfonate calcium 0.002%, kaolin 0.05% and water 99.901% are formed.
The described bactericide that contains copper gluconate, its feature can be by copper gluconate 0.01%, tiger glue adipic acid copper 0.015%, emulsifier 0204C 0.005%, dodecylbenzene sodium sulfonate 0.002%,, sodium lignin sulfonate 0.005% and water 99.963% are formed.
The described preparation method who contains the bactericide of copper gluconate mixes described each component.
The toxicology neasuring result shows the acute oral half lethal dose (LD50) of copper gluconate to the SD rat: in female rats is 1780mg/kg, its 95% credible 989～3200mg/kg that is limited to, at male rat is 3160mg/kg, its 95% fiducial limit fails to obtain, according among the standard GB 15670-1995 " agriculture chemical registration toxicology test method " " the acute oral toxicity grade scale of agricultural chemicals ", belong to low toxicity level; Copper gluconate to acute female, the male rat of SD rat through skin half lethal dose (LD50) all greater than 2150mg/kg.According among the standard GB 15670-1995 " agriculture chemical registration toxicology test method " " the acute dermal toxicity grade scale of agricultural chemicals ", belong to low toxicity level; Copper gluconate belongs to the moderate excitant to eye, is 0 to skin irritatin intensity mean scores.In addition, because glucose is the necessary nutriment of crop.Indoor virulence is learned to measure and is shown, copper gluconate is to citrus ulcer Xanthomonas campestris pv.citri (Hasse), anthraenose Colletotrichumgloeosporioides Penz., wild cabbage black rot (Xan thomonas Campestris PV.Campestris (Pammel) Dowson), lichee frost epidemic disease mould (Peronophthora titchic Chen ex ko et al), the obvious sterilization effect is all arranged, and citrus red mite (crm) grown and reproduction rate has no adverse effects, can not stimulate citrus red mite (crm) propagation, natural enemy is grown as the predation mite, the breeding influence is minimum, by foliage spray, can partly pass through Foliage Absorption.
The field control effectiveness test result shows the bactericide that only contains copper gluconate, does not add any other bactericide, and auxiliary agent and synergist can both be prevented and treated citrus ulcer effectively, and control efficiency is more than 85%.Use by copper gluconate is mixed with other bactericide, can also obviously increase drug effect, as being mixed with white urea cyanogen, the laboratory test results co-toxicity coefficient surpasses 140, and field control effectiveness test shows higher by 10% than white urea cyanogen list agent control efficiency.
The bactericide that contains copper gluconate of the present invention both can disperse in aqueous medium well, effectively controlling plant diseases bacterial disease especially, citrus ulcer for example, lichee frost epidemic disease is mould, anthraenose, cabbage black rot, angulars leaf spot of cucumber etc. have facilitation to the crop biology simultaneously, and insect are had no stimulation, soup is converted water and is sprayed to tree crown, diffusibility on the blade face is good, and low toxicity, therefore has bigger promotional value.
Embodiment
Following examples are to further specify of the present invention, are not limitations of the present invention.
Embodiment 1:
Copper gluconate 0.07kg and water 99.930kg are mixed,, respectively sprayed once in 10 days, 30 days, 50 days behind the fallen flowers in the citrus garden with atomizers spray, control efficiency reaches 85.33%.
Embodiment 2:
With copper gluconate 0.050kg, sodium butylnaphthalenesulfonate 0.003kg, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 0.002kg and water 99.945kg mix, use atomizers spray, the control citrus ulcer respectively sprayed once behind the fallen flowers in 10 days, 30 days, 50 days, and control efficiency reaches 85.19%.
Embodiment 3:
With copper gluconate 0.035kg, frost urea cyanogen 0.007kg, sodium butylnaphthalenesulfonate 0.003kg, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 0.002kg, dodecyl sodium sulfonate calcium 0.002kg, kaolin 0.050kg and water 99.901kg mix, use atomizers spray, the control peronophythora litchi respectively sprays medicine 1 time in the nearly maturing stage of bud stage, young fruit period and fruit, and control efficiency reaches 88.72%, is 77.00% and use single white urea cyanogen wetting powder to this sick control efficiency.
Embodiment 4:
With copper gluconate 0.010kg, tiger glue adipic acid copper 0.015kg, emulsifier 0204C 0.005kg, dodecylbenzene sodium sulfonate 0.002kg, sodium lignin sulfonate 0.005kg and water 99.963kg mix, and use atomizers spray, are used to prevent and treat angular leaf spot of cucumber, control efficiency can reach 90%, and can increase production 3～5%.
Claims (6)
1. a bactericide that contains copper gluconate is characterized in that by gross mass mark 100%, by copper gluconate 0.01～0.07%, and bactericide 0～0.015%, auxiliary agent 0～0.057%, the water of surplus is formed.
2. a kind of bactericide that contains copper gluconate according to claim 1, it is characterized in that described bactericide is white urea cyanogen or tiger glue adipic acid copper, described auxiliary agent be in sodium butylnaphthalenesulfonate, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, dodecyl sodium sulfonate calcium, emulsifier 0204C, dodecylbenzene sodium sulfonate, sodium lignin sulfonate, the kaolin one or more.
3. a kind of bactericide that contains copper gluconate according to claim 1 is characterized in that being made up of copper gluconate 0.07% and water 99.93%.
4. a kind of bactericide that contains copper gluconate according to claim 1 is characterized in that by copper gluconate 0.05%, and butyl is sodium sulfonate 0.003% how, and di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 0.002% and water 99.945% are formed.
5. a kind of bactericide that contains copper gluconate according to claim 1, it is characterized in that by copper gluconate 0.035%, frost urea cyanogen 0.007%, butyl is sodium sulfonate 0.003% how, di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate 0.002%, dodecyl sodium sulfonate calcium 0.002%, kaolin 0.05% and water 99.901% are formed.
6. a kind of bactericide that contains copper gluconate according to claim 1 is characterized in that by copper gluconate 0.01% tiger glue adipic acid copper 0.015%, emulsifier 0204C 0.005%, dodecylbenzene sodium sulfonate 0.002%,, sodium lignin sulfonate 0.005% and water 99.963% are formed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100286600A CN100546475C (en) | 2007-06-19 | 2007-06-19 | A kind of bactericide that contains copper gluconate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100286600A CN100546475C (en) | 2007-06-19 | 2007-06-19 | A kind of bactericide that contains copper gluconate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101069514A true CN101069514A (en) | 2007-11-14 |
| CN100546475C CN100546475C (en) | 2009-10-07 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2007100286600A Expired - Fee Related CN100546475C (en) | 2007-06-19 | 2007-06-19 | A kind of bactericide that contains copper gluconate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100546475C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104488617A (en) * | 2014-12-12 | 2015-04-08 | 李春德 | Prevention method for plant bacterial canker |
| CN108834889A (en) * | 2018-05-31 | 2018-11-20 | 贵州盛达生植物发展有限公司 | A kind of tissue culture seeding cultivating method promoting dendrobium candidum disease resistance |
| CN115403486A (en) * | 2022-09-21 | 2022-11-29 | 宁波三江益农化学有限公司 | A kind of cymoxanil copper and its preparation method and application |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1044608A1 (en) * | 1999-03-31 | 2000-10-18 | Altinco, S.L. | A phtosanitary product comprising quaternary ammonium salts as enhancers |
| US6403533B2 (en) * | 2000-01-27 | 2002-06-11 | Rohm And Haas Company | Stabilized microbicide formulation |
| CN1284457C (en) * | 2002-04-19 | 2006-11-15 | 广东省昆虫研究所 | Germicide for preventing and controlling downy mildew of lichee |
-
2007
- 2007-06-19 CN CNB2007100286600A patent/CN100546475C/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104488617A (en) * | 2014-12-12 | 2015-04-08 | 李春德 | Prevention method for plant bacterial canker |
| CN108834889A (en) * | 2018-05-31 | 2018-11-20 | 贵州盛达生植物发展有限公司 | A kind of tissue culture seeding cultivating method promoting dendrobium candidum disease resistance |
| CN115403486A (en) * | 2022-09-21 | 2022-11-29 | 宁波三江益农化学有限公司 | A kind of cymoxanil copper and its preparation method and application |
| CN115403486B (en) * | 2022-09-21 | 2024-09-03 | 宁波三江益农化学有限公司 | A kind of cymoxanil copper cyanide and its preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100546475C (en) | 2009-10-07 |
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