CN101062007A - Pearl powder and the preparing method thereof - Google Patents
Pearl powder and the preparing method thereof Download PDFInfo
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- CN101062007A CN101062007A CN 200710111476 CN200710111476A CN101062007A CN 101062007 A CN101062007 A CN 101062007A CN 200710111476 CN200710111476 CN 200710111476 CN 200710111476 A CN200710111476 A CN 200710111476A CN 101062007 A CN101062007 A CN 101062007A
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Abstract
The invention discloses a new type pearl imperial powder, which comprises the following steps: choosing fresh water pearl, sea water pearl, sea water pearl quality layer; washing; drying; grinding; salting; enzymolyzing; decolorizing; condensing; crystallizing; drying; grinding; building-up highly effective tender skin factor; sterilizing; getting water-soluble pearl powder. This preparing method is sensible, which possesses better stability.
Description
Technical field
The present invention relates to a kind of cosmetics, is a kind of pearl cosmetic product---pearl powder specifically.Product of the present invention is water-soluble because of Margarita powder, solubility property is good, dissolution velocity is fast, be easily absorbed by the body, add efficient skin care composition and Margarita powder simultaneously and play complementary effect, the phenomenon that powder body comes off in the time of effectively reducing skin allergy and make facial film has strengthened the beauty and skin care effect of Margarita greatly.The invention still further relates to the preparation method of this pearl cosmetic skin care item.
Background technology
Margarita is preserved the spring product as famous and precious skin care, the history in existing several thousand.China uses pearl cosmetic also with a long history, and put down in writing according to Compendium of Material Medica: " Margarita is coated with face, makes us moist good color.Be coated with brothers, peeling skin hangnail, the energyization face goes dim, makes the gloss pure white ".Why Margarita has remarkable efficacy like this, according to modern medicine studies have shown that contain a large amount of human bodies in the Margarita can not synthetic aminoacid, the trace element of the skin growth factor and needed by human, can regulate the endocrine of human body, promote the body metabolism, suppress the lipofuscin growth, strengthen the epidermis cell vigor, delaying cell aging.
At present, it is a feast for the eyes that state contains the cosmetics of Margarita, but these type of cosmetics mostly select for use Margarita powder or Margarita layer powder to make raw material, composition is more single, and Margarita or Margarita layer powder contain a large amount of calcium carbonate or calcium ion, all skin had stimulation, occurs the skin allergy phenomenon easily; Or be not absorbed by the body because of its processing is coarse or absorb slow, or do not contain the active ingredient that the beauty and skin care effect is arranged that can directly be absorbed by human body skin because of its reality, or the kind of Margarita active ingredient and content is all low and mixed composition by other and offset, thereby can not embody the beauty and skin care effectiveness of Margarita.
Summary of the invention
The object of the present invention is to provide the tender white muscle skin of a kind of energy, smooth away wrinkles, eliminate chloasma, strengthen skin vitality, effectively delaying decrepitude of skin and the novel pearl powder that plays beautifying skin-protection function.
A kind of pearl powder, contain the component of following weight percent:
Water soluble Margarita ultrafine powder 95-98% and PHA 2-5%.
The mode of comparative optimization is can also contain the hyaluronic acid of weight percentage≤3%, to strengthen its moisture-keeping function.
Further, can also contain the collagen protein of weight percentage≤2%, collagen protein has the effect of preserving moisture and repairing skin, uses with water soluble Margarita ultrafine powder and PHA etc., can promote the performance of Margarita powder and PHA effect.
The present invention also provides a kind of preparation method of pearl powder, comprises following process:
(1) preparation of water soluble Margarita ultrafine powder: get Margarita or nacre and clean, dry, be crushed to more than 120 orders; Get Margarita powder and add entry, make into suspension, add lactic acid reaction, fermentation culture 30-36h in proportion, and boiling 15 minutes after-filtration, get filtrate I; Filtering residue is the Margarita keratin; Filtering residue is softening and clean to there being the calcium ion reaction with diluted acid, adds 10 times distilled water, heat sterilization, the cooling back transfers pH value to 4.5-5.5, adds the carase that is equivalent to solid content weight 1～3%, at 45-50 ℃ of following hydrolysis 4-6 hour, heats enzyme denaturing; Cooling transfers pH value to 7.0-8.0 again, and adding is equivalent to the trypsin of solid content weight 1-3%, at 48 ± 2 ℃ of following hydrolysis 4-6 hours, and the heating enzyme denaturing, decolouring, cooling back filter pressing gets filtrate II; With filtrate I mix with filtrate II water soluble pearl liquid, reconcentration, crystallization, drying, pulverizing, sterilization obtain water soluble Margarita powder;
(2) preparation of PHA: described PHA refers to the high viscosity Carboxymethyl Chitosan with High Substitution Degree, it is prepared by following method: 1. get chitin and add 40-50% (wt%) NaOH solution that 7-10 doubly measures and put and take off acetyl under 100 ℃ the environment and handle 2 times, clean, dry the full-bodied chitosan of deacetylation more than 97%; 2. add the isopropyl alcohol that 6-10 doubly measures, after expansion 1-2 hour microwave treatment 3-5 minute, 40-50% (wt%) the NaOH solution alkalization that adding 5-8 doubly measures 1-2 hour, microwave treatment 3-5 minute again, be added dropwise to 5-6 times of monoxone and carrying out the carboxy methylation processing under the low temperature below 60 ℃ more than 3 hours, with diluted acid neutralization, with ethanol washing, the drying of 75% (V/V), pulverize carboxymethyl chitosan; 3. repetitive operation 2. carry out the secondary carboxy methylation handle the high viscosity Carboxymethyl Chitosan with High Substitution Degree, i.e. PHA;
(3) water intaking dissolving pearl powder and PHA stir, and pack sterilization and get final product.
The used Margarita of the present invention can be mussel pearl, sea water pearls, sea water pearls matter layer.
This pearl powder of the present invention, contain water soluble Margarita ultrafine powder and PHA, the raw material that adopts is all from natural, water soluble Margarita ultrafine powder and PHA are except that all possessing tangible beauty and skin care effect, PHA also has the skin care effect, and water soluble Margarita ultrafine powder after treatment can not produce illeffects to skin; Component is reasonable, and each composition brings out the best in each other, comprehensive effect height; Two all work in coordination with, with skin stronger affinity is arranged, its nutrition is easy to by skin absorbs, and improve and the recovery skin elasticity, make skin produce the effect of tender,smooth and white, reach tender white muscle skin, smooth away wrinkles, eliminate chloasma, strengthen skin vitality, effectively delaying decrepitude of skin and play beautifying skin-protection function.Preparation method of the present invention is scientific and reasonable, has kept the active ingredient in the raw material as far as possible, and has removed composition such as calcium, has not only improved content of effective but also active ingredient is easily absorbed by the body, and stability is preferably arranged.
The specific embodiment
The invention will be further described below in conjunction with specific embodiment, to help understanding content of the present invention.
Embodiment 1: the preparation of water soluble Margarita powder
Getting Margarita or pearly layer is broken to more than 120 orders through rinsing, drying, first pulverizing, fine powder.Getting Margarita powder adds in 10 times of treated water purification of amount (deionized water or distilled water), make into suspension, calculate with calcium content in the Margarita, add L-lactic acid is in proportion reacted away calcium carbonate in batches, room temperature or 50-100 ℃ of continuous down the stirring till the nacre powder stops dissolving, fermentation culture 30-36h boils 15 minutes after-filtration, gets filtrate I; Filtering residue is the Margarita keratin, softening and clean with diluted acid to there being the calcium ion reaction, the distilled water that adds 10 times of amounts, heat sterilization, cooling back transfers pH value to 4.5-5.5, add the carase that is equivalent to solid content weight 1-3% (＞2000u/mg), at 45-50 ℃ of following hydrolysis 4-6 hour, be heated to 100 ℃ of enzyme denaturing 10 minutes, cooling; Transfer pH value to 7.0-8.0 again, add the trypsin 1000-15000u/mg that is equivalent to solid content weight 1～3%), at 48 ± 2 ℃ of following hydrolysis 4-6 hours, be heated to 100 ℃ and carried out enzyme denaturing 20 minutes, cooling back filter pressing gets filtrate II; Filtrate I mix with filtrate II water soluble pearl liquid, add the 1-2% active carbon and be heated to 100 ℃ and decoloured 30 minutes, be cooled to 50 ℃ of filter pressings, reconcentration, crystallization, drying, pulverizing, sterilization obtain water soluble Margarita powder.
Embodiment 2: the preparation of PHA:
1. get 45%NaOH solution that chitin adds 9 times of amounts put 100 ℃ environment down insulation 3h take off acetyl and handle, clean, oven dry, repetitive operation once the high viscosity chitosan of deacetylation more than 97%; 2. the isopropyl alcohol that adds 8 times of amounts, behind the expansion 1h microwave treatment 3-5 minute, the 45%NaOH solution alkalization 1.5h that adds 6 times, microwave treatment 3-5 minute again, be added dropwise to 5-6 times of monoxone at low temperatures (below 60 ℃) carry out carboxylated processing 3h, with diluted acid neutralization, 75% ethanol washing, dry, pulverize carboxyl chitosan semifinished product; 3. repetitive operation 2. once, purified crystals gets high substituted degree carboxyl chitosan, promptly PHA is pulverized, is packaged spare.
Embodiment 3
Prescription:
Water soluble Margarita powder 98 gram PHA 2 grams
Preparation method:
Prepare water soluble Margarita ultrafine powder by the method among the embodiment 1, prepare PHA by the method in the implementation column 2.Described pearl powder is prepared by following method: water intaking dissolving pearl powder and PHA, the method that increases progressively with equivalent stirs, and packs with the co-60 radiation sterilization to get final product.
Embodiment 4
Prescription:
Water soluble Margarita powder 97 gram PHA 3 grams
Identical among preparation method and the embodiment 3.
Embodiment 5
Prescription:
Water soluble Margarita powder 95 gram PHA 5 grams
Identical among preparation method and the embodiment 3.
Embodiment 6: water intaking dissolubility Margarita powder 95 grams, and PHA 2 grams, plant skin care elite 3 grams mix in the rearmounted agitator stirring, and pack, and get final product with the co-60 radiation sterilization.
Embodiment 7: water intaking dissolubility Margarita powder 95 grams, and the efficient skin care factor 3 grams, plant skin care elite 2 grams mix in the rearmounted agitator stirring, and pack, and get final product with the co-60 radiation sterilization.The wherein efficient skin care factor is PHA 2 grams, collagen protein 1 gram.
Embodiment 8: water intaking dissolubility Margarita powder 96 grams, and the efficient skin care factor 3 grams, plant skin care elite 1 gram mixes in the rearmounted agitator stirring, and packs, and gets final product with the co-60 radiation sterilization.The wherein efficient skin care factor is made up of PHA 2 grams and hyaluronic acid 1 gram.
Embodiment 9
Water intaking dissolubility Margarita powder 95 grams, the efficient skin care factor 4 grams, plant skin care elite 1 gram mixes in the rearmounted agitator stirring, and packs, and gets final product with the co-60 radiation sterilization.The wherein efficient skin care factor is restrained by PHA 2 and hyaluronic acid 1 restrains, collagen protein 1 gram is formed.
Claims (7)
1, a kind of pearl powder, contain the component of following weight percent:
Water soluble Margarita ultrafine powder 95-98% and PHA 2-5%.
2, pearl powder as claimed in claim 1 is characterized in that: the hyaluronic acid that also contains weight content≤3%.
3, pearl powder as claimed in claim 1 or 2 is characterized in that: the collagen protein that also contains weight content≤2%.
4, Margarita as claimed in claim 1 or 2 is unloaded powder, it is characterized in that,
Described water soluble Margarita ultrafine powder is to prepare material by following method: get Margarita or nacre and clean, dry, be crushed to more than 120 orders; Get Margarita powder and add entry, make into suspension, add lactic acid reaction, fermentation culture 30-36h, and boiling 15 minutes after-filtration, get filtrate I, filtering residue is the Margarita keratin; Filtering residue is softening and clean to there being the calcium ion reaction with diluted acid, adds 10 times distilled water, heat sterilization, the cooling back transfers pH value to 4.5-5.5, adds the carase that is equivalent to solid content weight 1～3%, at 45-50 ℃ of following hydrolysis 4-6 hour, heats enzyme denaturing; Cooling transfers pH value to 7.0-8.0 again, and adding is equivalent to the trypsin of solid content weight 1-3%, at 48 ± 2 ℃ of following hydrolysis 4-6 hours, and the heating enzyme denaturing, decolouring, cooling back filter pressing gets filtrate II; With filtrate I mix with filtrate II water soluble pearl liquid, reconcentration, crystallization, drying, pulverizing, sterilization obtain water soluble Margarita powder;
Described PHA is the material by the preparation of following method: chitin adds 40-50%NaOH solution that 7-10 doubly measures to be put and takes off acetyl under 100 ℃ the environment and handle 2 times, clean, dry the full-bodied chitosan of deacetylation more than 97%; Add the isopropyl alcohol that 6-10 doubly measures, after expansion 1-2 hour microwave treatment 3-5 minute, the 40-50%NaOH solution alkalization that adding 5-8 doubly measures 1-2 hour, microwave treatment 3-5 minute again, be added dropwise to 5-6 times of monoxone and carrying out the carboxy methylation processing under the low temperature below 60 ℃ more than 3 hours, with diluted acid neutralization, the ethanol washing with 75%, drying, pulverize carboxymethyl chitosan; Repetitive operation 2. carry out the secondary carboxy methylation handle the high viscosity Carboxymethyl Chitosan with High Substitution Degree, i.e. PHA.
5, Margarita as claimed in claim 3 is unloaded powder, it is characterized in that,
Described water soluble Margarita ultrafine powder is to prepare material by following method: get Margarita or nacre and clean, dry, be crushed to more than 120 orders; Get Margarita powder and add entry, make into suspension, add lactic acid reaction, fermentation culture 30-36h, and boiling 15 minutes after-filtration, get filtrate I; Filtering residue is the Margarita keratin; Filtering residue is softening and clean to there being the calcium ion reaction with diluted acid, adds 10 times distilled water, heat sterilization, the cooling back transfers pH value to 4.5-5.5, adds the carase that is equivalent to solid content weight 1～3%, at 45-50 ℃ of following hydrolysis 4-6 hour, heats enzyme denaturing; Cooling transfers pH value to 7.0-8.0 again, and adding is equivalent to the trypsin of solid content weight 1-3%, at 48 ± 2 ℃ of following hydrolysis 4-6 hours, and the heating enzyme denaturing, decolouring, cooling back filter pressing gets filtrate II; With filtrate I mix with filtrate II water soluble pearl liquid, reconcentration, crystallization, drying, pulverizing, sterilization obtain water soluble Margarita powder;
Described PHA is the material by the preparation of following method: 1. get chitin and add 40-50%NaOH solution that 7-10 doubly measures and put and take off acetyl under 100 ℃ the environment and handle 2 times, clean, dry the full-bodied chitosan of deacetylation more than 97%; 2. add the isopropyl alcohol that 6-10 doubly measures, after expansion 1-2 hour microwave treatment 3-5 minute, the 40-50%NaOH solution alkalization that adding 5-8 doubly measures 1-2 hour, microwave treatment 3-5 minute again, be added dropwise to 5-6 times of monoxone and carrying out the carboxy methylation processing under the low temperature below 60 ℃ more than 3 hours, with diluted acid neutralization, the ethanol washing with 75%, drying, pulverize carboxymethyl chitosan; 3. repetitive operation 2. carry out the secondary carboxy methylation handle the high viscosity Carboxymethyl Chitosan with High Substitution Degree, i.e. PHA.
6, a kind of power must be asked the preparation method of 1 described pearl powder, comprises following process:
(1) preparation of water soluble Margarita ultrafine powder: get Margarita or nacre and clean, dry, be crushed to more than 120 orders; Get Margarita powder and add entry, make into suspension, add lactic acid reaction, fermentation culture 30-36h, and boiling 15 minutes after-filtration, get filtrate I; Filtering residue is the Margarita keratin; Filtering residue is softening and clean to there being the calcium ion reaction with diluted acid, adds 10 times distilled water, heat sterilization, the cooling back transfers pH value to 4.5-5.5, adds the carase that is equivalent to solid content weight 1～3%, at 45-50 ℃ of following hydrolysis 4-6 hour, heats enzyme denaturing; Cooling transfers pH value to 7.0-8.0 again, and adding is equivalent to the trypsin of solid content weight 1-3%, at 48 ± 2 ℃ of following hydrolysis 4-6 hours, and the heating enzyme denaturing, decolouring, cooling back filter pressing gets filtrate II; With filtrate I mix with filtrate II water soluble pearl liquid, reconcentration, crystallization, drying, pulverizing, sterilization obtain water soluble Margarita powder;
(2) preparation of PHA: described PHA refers to the high viscosity Carboxymethyl Chitosan with High Substitution Degree, it is prepared by following method: 1. get chitin and add 40-50%NaOH solution that 7-10 doubly measures and put and take off acetyl under 100 ℃ the environment and handle 2 times, clean, dry the full-bodied chitosan of deacetylation more than 97%; 2. add the isopropyl alcohol that 6-10 doubly measures, after expansion 1-2 hour microwave treatment 3-5 minute, the 40-50%NaOH solution alkalization that adding 5-8 doubly measures 1-2 hour, microwave treatment 3-5 minute again, be added dropwise to 5-6 times of monoxone and carrying out the carboxy methylation processing under the low temperature below 60 ℃ more than 3 hours, with diluted acid neutralization, the ethanol washing with 75%, drying, pulverize carboxymethyl chitosan; 3. repetitive operation 2. carry out the secondary carboxy methylation handle the high viscosity Carboxymethyl Chitosan with High Substitution Degree, i.e. PHA;
(3) water intaking dissolving pearl powder and PHA stir, and pack sterilization and get final product.
7, the preparation method of pearl powder as claimed in claim 6 is characterized in that: also add hyaluronic acid and/or collagen protein stirs together in described step (3).
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| CN 200710111476 CN101062007A (en) | 2007-06-25 | 2007-06-25 | Pearl powder and the preparing method thereof |
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| CN 200710111476 CN101062007A (en) | 2007-06-25 | 2007-06-25 | Pearl powder and the preparing method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101669893B (en) * | 2008-09-10 | 2012-11-07 | 北京因科瑞斯医药科技有限公司 | Chinese medicinal mask powder with function of improving skin moisture and preparation method thereof |
| CN104043114A (en) * | 2014-06-09 | 2014-09-17 | 浙江海力生生物科技有限公司 | Medicine composition with collagen and water-soluble pearl powder as well as preparation, preparation method and application of medicine composition |
| CN105168257A (en) * | 2015-09-09 | 2015-12-23 | 陈贵卿 | Processing method of pearl liquid, pearl ginseng liquid and pearl powder easily absorbed by human body |
| CN106265412A (en) * | 2016-08-04 | 2017-01-04 | 海南京润珍珠生物技术股份有限公司 | A kind of method utilizing probiotics fermention to prepare Margarita hydrolyzed solution |
| CN107496195A (en) * | 2017-08-01 | 2017-12-22 | 杭州惠博士健康产业有限公司 | A kind of recombined human hyaluronic acid compositions and its application in cosmetics |
-
2007
- 2007-06-25 CN CN 200710111476 patent/CN101062007A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101669893B (en) * | 2008-09-10 | 2012-11-07 | 北京因科瑞斯医药科技有限公司 | Chinese medicinal mask powder with function of improving skin moisture and preparation method thereof |
| CN104043114A (en) * | 2014-06-09 | 2014-09-17 | 浙江海力生生物科技有限公司 | Medicine composition with collagen and water-soluble pearl powder as well as preparation, preparation method and application of medicine composition |
| CN105168257A (en) * | 2015-09-09 | 2015-12-23 | 陈贵卿 | Processing method of pearl liquid, pearl ginseng liquid and pearl powder easily absorbed by human body |
| CN106265412A (en) * | 2016-08-04 | 2017-01-04 | 海南京润珍珠生物技术股份有限公司 | A kind of method utilizing probiotics fermention to prepare Margarita hydrolyzed solution |
| CN106265412B (en) * | 2016-08-04 | 2019-03-26 | 海南京润珍珠生物技术股份有限公司 | A method of hydrolyzed pearl solution is prepared using probiotics fermention |
| CN107496195A (en) * | 2017-08-01 | 2017-12-22 | 杭州惠博士健康产业有限公司 | A kind of recombined human hyaluronic acid compositions and its application in cosmetics |
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Open date: 20071031 |